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Search Results (410)

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Keywords = hot gas conditioning

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22 pages, 14333 KiB  
Article
A Transient Combustion Study in a Brick Kiln Using Natural Gas as Fuel by Means of CFD
by Sergio Alonso-Romero, Jorge Arturo Alfaro-Ayala, José Eduardo Frias-Chimal, Oscar A. López-Núñez, José de Jesús Ramírez-Minguela and Roberto Zitzumbo-Guzmán
Processes 2025, 13(8), 2437; https://doi.org/10.3390/pr13082437 - 1 Aug 2025
Viewed by 223
Abstract
A brick kiln was experimentally studied to measure the transient temperature of hot gases and the compressive strength of the bricks, using pine wood as fuel, in order to evaluate the thermal performance of the actual system. In addition, a transient combustion model [...] Read more.
A brick kiln was experimentally studied to measure the transient temperature of hot gases and the compressive strength of the bricks, using pine wood as fuel, in order to evaluate the thermal performance of the actual system. In addition, a transient combustion model based on computational fluid dynamics (CFD) was used to simulate the combustion of natural gas in the brick kiln as a hypothetical case, with the aim of investigating the potential benefits of fuel switching. The theoretical stoichiometric combustion of both pine wood and natural gas was employed to compare the mole fractions and the adiabatic flame temperature. Also, the transient hot gas temperature obtained from the experimental wood-fired kiln were compared with those from the simulated natural gas-fired kiln. Furthermore, numerical simulations were carried out to obtain the transient hot gas temperature and NOx emissions under stoichiometric, fuel-rich, and excess air conditions. The results of CO2 mole fractions from stoichiometric combustion demonstrate that natural gas may represent a cleaner alternative for use in brick kilns, due to a 44.08% reduction in emissions. Contour plots of transient hot gases temperature, velocity, and CO2 emission inside the kiln are presented. Moreover, the time-dependent emissions of CO2, H2O, and CO at the kiln outlet are shown. It can be concluded that the presence of CO mole fractions at the kiln outlet suggests that the transient combustion process could be further improved. The low firing efficiency of bricks and the thermal efficiency obtained are attributed to uneven temperatures distributions inside the kiln. Moreover, hot gas temperature and NOx emissions were found to be higher under stoichiometric conditions than under fuel-rich or excess of air conditions. Therefore, this work could be useful for improving the thermal–hydraulic and emissions performance of brick kilns, as well as for future kiln design improvements. Full article
(This article belongs to the Special Issue Numerical Simulation of Flow and Heat Transfer Processes)
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17 pages, 1742 KiB  
Article
Assessment of Aerodynamic Properties of the Ventilated Cavity in Curtain Wall Systems Under Varying Climatic and Design Conditions
by Nurlan Zhangabay, Aizhan Zhangabay, Kenzhebek Akmalaiuly, Akmaral Utelbayeva and Bolat Duissenbekov
Buildings 2025, 15(15), 2637; https://doi.org/10.3390/buildings15152637 - 25 Jul 2025
Viewed by 318
Abstract
Creating a comfortable microclimate in the premises of buildings is currently becoming one of the priorities in the field of architecture, construction and engineering systems. The increased attention from the scientific community to this topic is due not only to the desire to [...] Read more.
Creating a comfortable microclimate in the premises of buildings is currently becoming one of the priorities in the field of architecture, construction and engineering systems. The increased attention from the scientific community to this topic is due not only to the desire to ensure healthy and favorable conditions for human life but also to the need for the rational use of energy resources. This area is becoming particularly relevant in the context of global challenges related to climate change, rising energy costs and increased environmental requirements. Practice shows that any technical solutions to ensure comfortable temperature, humidity and air exchange in rooms should be closely linked to the concept of energy efficiency. This allows one not only to reduce operating costs but also to significantly reduce greenhouse gas emissions, thereby contributing to sustainable development and environmental safety. In this connection, this study presents a parametric assessment of the influence of climatic and geometric factors on the aerodynamic characteristics of the air cavity, which affect the heat exchange process in the ventilated layer of curtain wall systems. The assessment was carried out using a combined analytical calculation method that provides averaged thermophysical parameters, such as mean air velocity (Vs), average internal surface temperature (tin.sav), and convective heat transfer coefficient (αs) within the air cavity. This study resulted in empirical average values, demonstrating that the air velocity within the cavity significantly depends on atmospheric pressure and façade height difference. For instance, a 10-fold increase in façade height leads to a 4.4-fold increase in air velocity. Furthermore, a three-fold variation in local resistance coefficients results in up to a two-fold change in airflow velocity. The cavity thickness, depending on atmospheric pressure, was also found to affect airflow velocity by up to 25%. Similar patterns were observed under ambient temperatures of +20 °C, +30 °C, and +40 °C. The analysis confirmed that airflow velocity is directly affected by cavity height, while the impact of solar radiation is negligible. However, based on the outcomes of the analytical model, it was concluded that the method does not adequately account for the effects of solar radiation and vertical temperature gradients on airflow within ventilated façades. This highlights the need for further full-scale experimental investigations under hot climate conditions in South Kazakhstan. The findings are expected to be applicable internationally to regions with comparable climatic characteristics. Ultimately, a correct understanding of thermophysical processes in such structures will support the advancement of trends such as Lightweight Design, Functionally Graded Design, and Value Engineering in the development of curtain wall systems, through the optimized selection of façade configurations, accounting for temperature loads under specific climatic and design conditions. Full article
(This article belongs to the Section Building Energy, Physics, Environment, and Systems)
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27 pages, 53601 KiB  
Article
Depositional Evolution and Controlling Factors of the Lower–Middle Jurassic in the Kuqa Depression, Tarim Basin, Northwest China
by Ming Ma, Changsong Lin, Yongfu Liu, Hao Li, Wenfang Yuan, Jingyan Liu, Chaoqun Shi, Manli Zhang and Fan Xu
Appl. Sci. 2025, 15(14), 7783; https://doi.org/10.3390/app15147783 - 11 Jul 2025
Viewed by 276
Abstract
The Lower–Middle Jurassic of the Kuqa Depression consists of terrestrial clastic deposits containing coal seams and thick lacustrine mudstones, and is of great significance for oil and gas exploration. Based on the comprehensive analysis of core, well-logging, outcrop, and seismic data, the sequence [...] Read more.
The Lower–Middle Jurassic of the Kuqa Depression consists of terrestrial clastic deposits containing coal seams and thick lacustrine mudstones, and is of great significance for oil and gas exploration. Based on the comprehensive analysis of core, well-logging, outcrop, and seismic data, the sequence stratigraphy, depositional systems, and the controlling factors of the basin filling in the depression are systematically documented. Four primary depositional systems, including braided river delta, meandering river delta, lacustrine, and swamp deposits, are identified within the Ahe, Yangxia, and Kezilenuer Formations of the Lower–Middle Jurassic. The basin fills can be classified into two second-order and nine third-order sequences (SQ1–SQ9) confined by regional or local unconformities and their correlative conformities. This study shows that the sedimentary evolution has undergone the following three stages: Stage I (SQ1–SQ2) primarily developed braided river, braided river delta, and shallow lacustrine deposits; Stage II (SQ3–SQ5) primarily developed meandering river, meandering river delta, and extensive deep and semi-deep lacustrine deposits; Stage III (SQ6–SQ9) primarily developed swamp (SQ6–SQ7), meandering river delta, and shore–shallow lacustrine deposits (SQ8–SQ9). The uplift of the Tianshan Orogenic Belt in the Early Jurassic (Stage I) may have facilitated the development of braided fluvial–deltaic deposits. The subsequential expansion of the sedimentary area and the weakened sediment supply can be attributed to the planation of the source area and widespread basin subsidence, with the transition of the depositional environments from braided river delta deposits to meandering river delta and swamp deposits. The regional expansion or rise of the lake during Stage II was likely triggered by the hot and humid climate conditions, possibly associated with the Early Jurassic Toarcian Oceanic Anoxic Event. The thick swamp deposits formed during Stage III may be controlled by the interplay of rational accommodation, warm and humid climatic conditions, and limited sediment supply. Milankovitch cycles identified in Stage III further reveal that coal accumulation was primarily modulated by long-period eccentricity forcing. Full article
(This article belongs to the Section Earth Sciences)
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17 pages, 4414 KiB  
Article
Mechanical Characteristics of 26H2MF and St12T Steels Under Torsion at Elevated Temperatures
by Waldemar Dudda
Materials 2025, 18(13), 3204; https://doi.org/10.3390/ma18133204 - 7 Jul 2025
Viewed by 273
Abstract
The concept of “material effort” appears in continuum mechanics wherever the response of a material to the currently existing state of loads and boundary conditions loses its previous, predictable character. However, within the material, which still descriptively remains a continuous medium, new physical [...] Read more.
The concept of “material effort” appears in continuum mechanics wherever the response of a material to the currently existing state of loads and boundary conditions loses its previous, predictable character. However, within the material, which still descriptively remains a continuous medium, new physical structures appear and new previously unused physical features of the continuum are activated. The literature is dominated by a simplified way of thinking, which assumes that all these states can be characterized and described by one and the same measure of effort—for metals it is the Huber–Mises–Hencky equivalent stress. Quantitatively, perhaps 90% of the literature is dedicated to this equivalent stress. The remaining authors, as well as the author of this paper, assume that there is no single universal measure of effort that would “fit” all operating conditions of materials. Each state of the structure’s operation may have its own autonomous measure of effort, which expresses the degree of threat from a specific destruction mechanism. In the current energy sector, we are increasingly dealing with “low-cycle thermal fatigue states”. This is related to the fact that large, difficult-to-predict renewable energy sources have been added. Professional energy based on coal and gas units must perform many (even about 100 per year) starts and stops, and this applies not only to the hot state, but often also to the cold state. The question arises as to the allowable shortening of start and stop times that would not to lead to dangerous material effort, and whether there are necessary data and strength characteristics for heat-resistant steels that allow their effort to be determined not only in simple states, but also in complex stress states. Do these data allow for the description of the material’s yield surface? In a previous publication, the author presented the results of tension and compression tests at elevated temperatures for two heat-resistant steels: St12T and 26H2MF. The aim of the current work is to determine the properties and strength characteristics of these steels in a pure torsion test at elevated temperatures. This allows for the analysis of the strength of power turbine components operating primarily on torsion and for determining which of the two tested steels is more resistant to high temperatures. In addition, the properties determined in all three tests (tension, compression, torsion) will allow the determination of the yield surface of these steels at elevated temperatures. They are necessary for the strength analysis of turbine elements in start-up and shutdown cycles, in states changing from cold to hot and vice versa. A modified testing machine was used for pure torsion tests. It allowed for the determination of the sample’s torsion moment as a function of its torsion angle. The experiments were carried out at temperatures of 20 °C, 200 °C, 400 °C, 600 °C, and 800 °C for St12T steel and at temperatures of 20 °C, 200 °C, 400 °C, 550 °C, and 800 °C for 26H2MF steel. Characteristics were drawn up for each sample and compared on a common graph corresponding to the given steel. Based on the methods and relationships from the theory of strength, the yield stress and torsional strength were determined. The yield stress of St12T steel at 600 °C was 319.3 MPa and the torsional strength was 394.4 MPa. For 26H2MH steel at 550 °C, the yield stress was 311.4 and the torsional strength was 382.8 MPa. St12T steel was therefore more resistant to high temperatures than 26H2MF. The combined data from the tension, compression, and torsion tests allowed us to determine the asymmetry and plasticity coefficients, which allowed us to model the yield surface according to the Burzyński criterion as a function of temperature. The obtained results also allowed us to determine the parameters of the Drucker-Prager model and two of the three parameters of the Willam-Warnke and Menetrey-Willam models. The research results are a valuable contribution to the design and diagnostics of power turbine components. Full article
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12 pages, 3521 KiB  
Article
Effect of Alternating Magnetic Field Intensity on Microstructure and Corrosion Properties of Deposited Metal in 304 Stainless Steel TIG Welding
by Jinjie Wang, Jiayi Li, Haokai Wang, Zan Ju, Juan Fu, Yong Zhao and Qianhao Zang
Metals 2025, 15(7), 761; https://doi.org/10.3390/met15070761 - 6 Jul 2025
Viewed by 326
Abstract
Stainless steel, due to its exceptional comprehensive properties, has been widely adopted as the primary material for liquid cargo tank containment systems and pipelines in liquefied natural gas (LNG) carriers. However, challenges such as hot cracking, excessive deformation, and the deterioration of welded [...] Read more.
Stainless steel, due to its exceptional comprehensive properties, has been widely adopted as the primary material for liquid cargo tank containment systems and pipelines in liquefied natural gas (LNG) carriers. However, challenges such as hot cracking, excessive deformation, and the deterioration of welded joint performance during stainless steel welding significantly constrain the construction quality and safety of LNG carriers. While conventional tungsten inert gas (TIG) welding can produce high-integrity welds, it is inherently limited by shallow penetration depth and low efficiency. Magnetic field-assisted TIG welding technology addresses these limitations by introducing an external magnetic field, which effectively modifies arc morphology, refines grain structure, enhances penetration depth, and improves corrosion resistance. In this study, TIG bead-on-plate welding was performed on 304 stainless steel plates, with a systematic investigation into the dynamic arc behavior during welding, as well as the microstructure and anti-corrosion properties of the deposited metal. The experimental results demonstrate that, in the absence of a magnetic field, the welding arc remains stable without deflection. As the intensity of the alternating magnetic field intensity increases, the arc exhibits pronounced periodic oscillations. At an applied magnetic field intensity of 30 mT, the maximum arc deflection angle reaches 76°. With increasing alternating magnetic field intensity, the weld penetration depth gradually decreases, while the weld width progressively expands. Specifically, at 30 mT, the penetration depth reaches a minimum value of 1.8 mm, representing a 44% reduction compared to the non-magnetic condition, whereas the weld width peaks at 9.3 mm, corresponding to a 9.4% increase. Furthermore, the ferrite grains in the weld metal are significantly refined at higher alternating magnetic field intensities. The weld metal subjected to a 30 mT alternating magnetic field exhibits the highest breakdown potential, the lowest corrosion rate, and the most protective passive film, indicating superior corrosion resistance compared to other tested conditions. Full article
(This article belongs to the Special Issue Advanced Metal Welding and Joining Technologies—2nd Edition)
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14 pages, 3059 KiB  
Article
Effect of Hydrogen and Hydrogen-Blended Natural Gas on Additive-Manufactured 316L Stainless Steel in Ambient Oil and Gas Environments
by Gerardo Gamboa, Ali Babakr and Marcus L. Young
Metals 2025, 15(7), 689; https://doi.org/10.3390/met15070689 - 20 Jun 2025
Viewed by 332
Abstract
For over five decades, blending hydrogen into existing natural gas pipelines has been explored as a potential solution to reduce greenhouse gas emissions. Despite its promise, implementing this approach has been slow due to concerns about hydrogen embrittlement (HE) and its interactions with [...] Read more.
For over five decades, blending hydrogen into existing natural gas pipelines has been explored as a potential solution to reduce greenhouse gas emissions. Despite its promise, implementing this approach has been slow due to concerns about hydrogen embrittlement (HE) and its interactions with various metals. Stainless steel alloys like 316L are commonly used in hydrogen service due to their superior resistance to HE. However, the impact of additive manufacturing (AM) on 316L’s susceptibility to HE when subjected to gas charging has not been thoroughly investigated. To fill this knowledge gap, we created conventionally manufactured and AM 316L tensile bars and solubility specimens, which were then exposed to hydrogen-blended natural gas at 10 MPa with a 50% blend and 100% pure H2. Both conventionally manufactured and additively manufactured specimens had as-received/printed samples that were used as controls. The samples underwent mechanical evaluation through tensile testing and hot chemical extraction to assess hydrogen solubility. Further analysis revealed significant changes in the microstructure near the fracture area of the soaked samples using scanning electron microscope fractography and metallography. These findings were compared with our previous work on traditionally produced 316L bar stock, which demonstrated that AM processing conditions can yield superior performance in terms of resistance to HE. Notably, this study provides valuable insights into the effects of AM on 316L’s susceptibility to HE when subjected to gas charging. The results have significant implications for the development and implementation of AM 316L for hydrogen/natural gas applications in pressure regulators when AM processing conditions are well-controlled. This article is a revised and expanded version of a paper entitled “Effect of Hydrogen-Blended Natural Gas on Additive Manufactured 316L Stainless Steel in Pressure Regulator Environments”, which was presented at TMS in Las Vegas, March 2025. Full article
(This article belongs to the Special Issue Hydrogen Embrittlement of Metals and Alloys)
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22 pages, 1664 KiB  
Article
Techno-Economic Assessment of Alternative-Fuel Bus Technologies Under Real Driving Conditions in a Developing Country Context
by Marc Haddad and Charbel Mansour
World Electr. Veh. J. 2025, 16(6), 337; https://doi.org/10.3390/wevj16060337 - 19 Jun 2025
Viewed by 742
Abstract
The long-standing need for a modern public transportation system in Lebanon, a developing country of the Middle East with an almost exclusive dependence on costly and polluting passenger cars, has become more pressing in recent years due to the worsening economic crisis and [...] Read more.
The long-standing need for a modern public transportation system in Lebanon, a developing country of the Middle East with an almost exclusive dependence on costly and polluting passenger cars, has become more pressing in recent years due to the worsening economic crisis and the onset of hyperinflation. This study investigates the potential reductions in energy use, emissions, and costs from the possible introduction of natural gas, hybrid, and battery-electric buses compared to traditional diesel buses in local real driving conditions. Four operating conditions were considered including severe congestion, peak, off-peak, and bus rapid transit (BRT) operation. Battery-electric buses are found to be the best performers in any traffic operation, conditional on having clean energy supply at the power plant and significant subsidy of bus purchase cost. Natural gas buses do not provide significant greenhouse gas emission savings compared to diesel buses but offer substantial reductions in the emission of all major pollutants harmful to human health. Results also show that accounting for additional energy consumption from the use of climate-control auxiliaries in hot and cold weather can significantly impact the performance of all bus technologies by up to 44.7% for electric buses on average. Performance of all considered bus technologies improves considerably in free-flowing traffic conditions, making BRT operation the most beneficial. A vehicle mix of diesel, natural gas, and hybrid bus technologies is found most feasible for the case of Lebanon and similar developing countries lacking necessary infrastructure for a near-term transition to battery-electric technology. Full article
(This article belongs to the Special Issue Zero Emission Buses for Public Transport)
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23 pages, 3668 KiB  
Review
A Review of Intelligent Methods for Environmental Risk Identification in Polar Drilling and Well Completion
by Ruitong Wei, Song Deng, Xiaopeng Yan, Mingguo Peng, Ke Ke, Lei Wang, Zhiqiang Hu, Kai Yang, Bingzhao Huo and Linglong Cao
Processes 2025, 13(6), 1873; https://doi.org/10.3390/pr13061873 - 13 Jun 2025
Viewed by 433
Abstract
The Arctic region is rich in oil and gas resources and has great potential for development. It has become a new hot spot for international development. However, the harsh climatic and geological conditions and fragile ecosystems in the Arctic region put forward stringent [...] Read more.
The Arctic region is rich in oil and gas resources and has great potential for development. It has become a new hot spot for international development. However, the harsh climatic and geological conditions and fragile ecosystems in the Arctic region put forward stringent technical requirements for oil and gas development. Polar permafrost has an impact on the growth of plant roots and the absorption of water. When drilling activities are carried out, the permafrost layer may be broken, resulting in the erosion of polar soil and disorder of the water balance, thus affecting local vegetation and ecosystems. Moreover, the legal system of polar environmental protection is lacking, and it is necessary to form a perfect risk assessment method to improve the relevant laws and regulations. Therefore, it is very important to study the environmental risk identification technology for polar drilling. For polar drilling, it is necessary to establish a risk source classification and identification method for environmental pollution events. However, at present, it mainly faces the following challenges: poor polar environment, lack of monitoring data, and lack of a legal system for polar environmental protection. By systematically discussing risk identification technology, the application and applicable models of different types of risk evaluation methods are categorized and summarized, the advantages and disadvantages of different types of risk evaluation methods and their application effects are analyzed based on the unique environment of the polar regions, and then the development direction of the future environmental risk identification technology for polar drilling is proposed. In order to accelerate the development of polar drilling environmental risk identification technology, research should be focused on the following three aspects: ① Promoting the multi-dimensional integration of polar drilling environmental pollution index data, to make up for the short board of less relevant data in the polar region. ② Combining the machine modeling algorithm with risk evaluation of polar drilling environmental pollution to improve the scientificity and accuracy of the evaluation results. ③ Establishing a scientific and accurate polar drilling environmental pollution risk identification system to reduce pollution risk. Full article
(This article belongs to the Section Energy Systems)
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31 pages, 6448 KiB  
Review
Review of Research on Supercritical Carbon Dioxide Axial Flow Compressors
by Yong Tian, Dexi Chen, Yuming Zhu, Peng Jiang, Bo Wang, Xiang Xu and Xiaodi Tang
Energies 2025, 18(12), 3081; https://doi.org/10.3390/en18123081 - 11 Jun 2025
Viewed by 538
Abstract
Since the beginning of the 21st century, the supercritical carbon dioxide (sCO2) Brayton cycle has emerged as a hot topic of research in the energy field. Among its key components, the sCO2 compressor has received significant attention. In particular, axial-flow [...] Read more.
Since the beginning of the 21st century, the supercritical carbon dioxide (sCO2) Brayton cycle has emerged as a hot topic of research in the energy field. Among its key components, the sCO2 compressor has received significant attention. In particular, axial-flow sCO2 compressors are increasingly being investigated as power systems advance toward high power scaling. This paper reviews global research progress in this field. As for performance characteristics, currently, sCO2 axial-flow compressors are mostly designed with large mass flow rates (>100 kg/s), near-critical inlet conditions, multistage configurations with relatively low stage pressure ratios (1.1–1.2), and high isentropic efficiencies (87–93%). As for internal flow characteristics, although similarity laws remain applicable to sCO2 turbomachinery, the flow dynamics are strongly influenced by abrupt variations in thermophysical properties (e.g., viscosities, sound speeds, and isentropic exponents). High Reynolds numbers reduce frictional losses and enhance flow stability against separation but increase sensitivity to wall roughness. The locally reduced sound speed may induce shock waves and choke, while drastic variation in the isentropic exponent makes the multistage matching difficult and disperses normalized performance curves. Additionally, the quantitative impact of a near-critical phase change remains insufficiently understood. As for the experimental investigation, so far, it has been publicly shown that only the University of Notre Dame has conducted an axial-flow compressor experimental test, for the first stage of a 10 MW sCO2 multistage axial-flow compressor. Although the measured efficiency is higher than that of all known sCO2 centrifugal compressors, the inlet conditions evidently deviate from the critical point, limiting the applicability of the results to sCO2 power cycles. As for design and optimization, conventional design methodologies for axial-flow compressors require adaptations to incorporate real-gas property correction models, re-evaluations of maximum diffusion (e.g., the DF parameter) for sCO2 applications, and the intensification of structural constraints due to the high pressure and density of sCO2. In conclusion, further research should focus on two aspects. The first is to carry out more fundamental cascade experiments and numerical simulations to reveal the complex mechanisms for the near-critical, transonic, and two-phase flow within the sCO2 axial-flow compressor. The second is to develop loss models and design a space suitable for sCO2 multistage axial-flow compressors, thus improving the design tools for high-efficiency and wide-margin sCO2 axial-flow compressors. Full article
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16 pages, 13161 KiB  
Article
Experimental Assessment of the Effects of Gas Composition on Volatile Flames of Coal and Biomass Particles in Oxyfuel Combustion Using Multi-Parameter Optical Diagnostics
by Tao Li, Haowen Chen and Benjamin Böhm
Processes 2025, 13(6), 1817; https://doi.org/10.3390/pr13061817 - 8 Jun 2025
Viewed by 474
Abstract
This experimental study examines the particle-level combustion behavior of high-volatile bituminous coal and walnut shell particles in oxyfuel environments, with a particular focus on the gas-phase ignition characteristics and the structural development of volatile flames. Particles with similar size and shape distributions (a [...] Read more.
This experimental study examines the particle-level combustion behavior of high-volatile bituminous coal and walnut shell particles in oxyfuel environments, with a particular focus on the gas-phase ignition characteristics and the structural development of volatile flames. Particles with similar size and shape distributions (a median diameter of about 126 µm and an aspect ratio of around 1.5) are combusted in hot flows generated using lean, flat flames, where the oxygen mole fraction is systematically varied in both CO2/O2 and N2/O2 atmospheres while maintaining comparable gas temperatures and particle heating rates. The investigation employs a high-speed multi-camera diagnostic system combining laser-induced fluorescence of OH, diffuse backlight-illumination, and Mie scattering to simultaneously measure the particle size, shape, and velocity; the ignition delay time; and the volatile flame dynamics during early-stage volatile combustion. Advanced detection algorithms enable the extraction of these multiple parameters from spatiotemporally synchronized measurements. The results reveal that the ignition delay time decreases with an increasing oxygen mole fraction up to 30 vol%, beyond which point further oxygen enrichment no longer accelerates the ignition, as the process becomes limited by the volatile release rate. In contrast, the reactivity of volatile flames shows continuous enhancement with an increasing oxygen mole fraction, indicating non-premixed flame behavior governed by the diffusion of oxygen toward the particles. The analysis of the flame stand-off distance demonstrates that volatile flames burn closer to the particles at higher oxygen mole fractions, consistent with the expected scaling of O2 diffusion with its partial pressure. Notably, walnut shell and coal particles exhibit remarkably similar ignition delay times, volatile flame sizes, and OH-LIF intensities. The substitution of N2 with CO2 produces minimal differences, suggesting that for 126 µm particles under high-heating-rate conditions, the relatively small variations in the heat capacity and O2 diffusivity between these diluents have negligible effects on the homogeneous combustion phenomena observed. Full article
(This article belongs to the Special Issue Experiments and Diagnostics in Reacting Flows)
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14 pages, 2552 KiB  
Article
Architecting Porosity Through Monomer Engineering: Hypercrosslinked Polymers for Highly Selective CO2 Capture from CH4 or N2
by Lin Liu, Qi Zhang, Xue Leng, Rui Song and Zheng-Bo Han
Polymers 2025, 17(12), 1592; https://doi.org/10.3390/polym17121592 - 6 Jun 2025
Viewed by 503
Abstract
Natural gas purification and the mitigation of carbon dioxide (CO2) emissions from flue gases are critical steps in alleviating the greenhouse effect and significantly mitigate multiple environmental challenges associated with global warming. Hypercrosslinked polymers (HCPs) have become a hot topic as [...] Read more.
Natural gas purification and the mitigation of carbon dioxide (CO2) emissions from flue gases are critical steps in alleviating the greenhouse effect and significantly mitigate multiple environmental challenges associated with global warming. Hypercrosslinked polymers (HCPs) have become a hot topic as prospective adsorbents for gas purification and separation, owing to their low cost and scalability. Hence, TPB-Ben, TPB-Nap, and TPB-Ant were synthesized through a solvent knitting strategy, with the modification in the size of the monomers serving as a distinctive feature. This alteration aimed to explore the impact of phenyl ring quantity on the polymers’ gas adsorption and separation efficiency. All HCPs showed outstanding selective separation capability of CO2 from CO2/CH4 and CO2/N2 mixtures, such as TPB-Ben-3-2 (CO2/CH4: 10.77; CO2/N2: 59.72), TPB-Nap-3-2 (CO2/CH4: 9.12; CO2/N2: 61.31), and TPB-Ant-3-2 (CO2/CH4: 10.00; CO2/N2: 62.89), which could be potential candidate adsorbents for natural gas purification and CO2 capture. Considering the mild reaction conditions, low cost, efficient gas adsorption, and the potential for scalable production, these polymers are considered ideal selective solid adsorbents for capturing CO2. This further highlights the significance of the solvent knitting strategy. Full article
(This article belongs to the Special Issue Application and Development of Polymer-Based Catalysts)
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22 pages, 3663 KiB  
Article
Simulation-Based Prediction of Office Buildings Energy Performance Under RCP Scenarios Across All U.S. Climate Zones
by Sepideh Niknia and Mehdi Ghiai
Architecture 2025, 5(2), 34; https://doi.org/10.3390/architecture5020034 - 29 May 2025
Cited by 1 | Viewed by 1430
Abstract
Buildings account for a significant portion of global energy consumption and are increasingly vulnerable to the adverse effects of climate change, including rising greenhouse gas emissions and shifting weather patterns. These disruptions significantly impact energy demand, necessitating proactive measures to ensure buildings remain [...] Read more.
Buildings account for a significant portion of global energy consumption and are increasingly vulnerable to the adverse effects of climate change, including rising greenhouse gas emissions and shifting weather patterns. These disruptions significantly impact energy demand, necessitating proactive measures to ensure buildings remain functional, sustainable, and energy efficient. This study offers a novel contribution by systematically comparing the energy performance of office building prototypes using a simulation-based method across all U.S. climate zones under projected Representative Concentration Pathways (RCPs) 4.5 (moderate emissions) and 8.5 (high emissions) for the years 2050 and 2080. This multi-scale and multi-scenario simulation provides a nationally comprehensive view of how building size and climate conditions interact to influence vulnerability to future energy demand shifts. The findings reveal that medium-sized office buildings are the most vulnerable to climate change, with an average Energy Unit Intensity (EUI) increase of 12.5% by 2080 under RCP 8.5, compared to a 7.4% rise for large office buildings and a slight decline of 2.5% for small office buildings. Hot and humid cities such as Miami, FL, experience the highest increases, with EUI projected to rise by 21.2% for medium offices, while colder regions like Fairbanks, AK, show reductions of up to 18.2% due to decreasing heating demands. These results underscore the urgent need for climate-compatible building design strategies, particularly in high-risk areas. As climate change intensifies, integrating resilience-focused policies will safeguard energy systems and ensure long-term occupant comfort. Full article
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15 pages, 3876 KiB  
Article
Research on the Development Mechanism of Air Thermal Miscible Flooding in the High Water Cut Stage of Medium to High Permeability Light Oil Reservoirs
by Daode Hua, Changfeng Xi, Peng Liu, Tong Liu, Fang Zhao, Yuting Wang, Hongbao Du, Heng Gu and Mimi Wu
Energies 2025, 18(11), 2783; https://doi.org/10.3390/en18112783 - 27 May 2025
Viewed by 346
Abstract
Currently, the development of oil reservoirs with high water cut faces numerous challenges, including poor economic efficiency, difficulties in residual oil recovery, and a lack of effective development technologies. In light of these issues, this paper conducts research on gas drive development during [...] Read more.
Currently, the development of oil reservoirs with high water cut faces numerous challenges, including poor economic efficiency, difficulties in residual oil recovery, and a lack of effective development technologies. In light of these issues, this paper conducts research on gas drive development during the high water cut stage in middle–high permeability reservoirs and introduces an innovative technical approach for air thermal miscible flooding. In this study, the Enhanced Oil Recovery (EOR) mechanism and the dynamic characteristics of thermal miscible flooding were investigated through laboratory experiments and numerical simulations. The N2 and CO2 flooding experiments indicate that gas channeling is likely to occur when miscible flooding cannot be achieved, due to the smaller gas–water mobility ratio compared to the gas–oil mobility ratio during the high water cut stage. Consequently, the enhanced recovery efficiency of N2 and CO2 flooding is limited. The experiment on air thermal miscible flooding demonstrates that under conditions of high water content, this method can form a stable high-temperature thermal oxidation front. The high temperature, generated by the thermal oxidation front, promotes the miscibility of flue gas and crude oil, effectively inhibiting gas flow, preventing gas channeling, and significantly enhancing oil recovery. Numerical simulations indicate that the production stage of air hot miscible flooding in reservoirs with middle–high permeability and high water cut can be divided into three phases: pressurization and drainage response, high efficiency and stable production with a low air–oil ratio, and low efficiency production with a high air–oil ratio. These phases can enable efficient development during the high water cut stage in medium to high permeability reservoirs, with the theoretical EOR range expected to exceed 30%. Full article
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20 pages, 733 KiB  
Article
Energy Optimization in Hotels: Strategies for Efficiency in Hot Water Systems
by Yarelis Valdivia Nodal, Luis Angel Iturralde Carrera, Araceli Zapatero-Gutiérrez, Mario Antonio Álvarez Guerra Plasencia, Royd Reyes Calvo, José M. Álvarez-Alvarado and Juvenal Rodríguez-Reséndiz
Algorithms 2025, 18(6), 301; https://doi.org/10.3390/a18060301 - 22 May 2025
Viewed by 585
Abstract
This paper presents a procedure for the energy optimization of domestic hot water (DHW) systems in hotels located in tropical climates that use centralized air conditioning systems. The study aims to maximize heat recovery from chillers and reduce the fuel consumption of auxiliary [...] Read more.
This paper presents a procedure for the energy optimization of domestic hot water (DHW) systems in hotels located in tropical climates that use centralized air conditioning systems. The study aims to maximize heat recovery from chillers and reduce the fuel consumption of auxiliary heaters by optimizing operational variables such as water mass flow in the primary and secondary DHW circuits and outlet temperature of the backup system. The optimization is implemented using genetic algorithms (GA), which enable the identification of the most efficient flow configurations under variable thermal demand conditions. The proposed methodology integrates a thermoenergetic model validated with real operational data and considers the dynamic behavior of hotel occupancy and water demand. The results show that the optimized strategy reduces auxiliary heating use by up to 75%, achieving annual energy savings of 8244 kWh, equivalent to 2.3 tons of fuel, and preventing the emission of 10.5 tons of CO2. This study contributes to the design of sustainable energy systems in the hospitality sector and provides replicable strategies for similar climatic and operational contexts. Full article
(This article belongs to the Section Combinatorial Optimization, Graph, and Network Algorithms)
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17 pages, 1390 KiB  
Article
Laser-Powered Homogeneous Pyrolysis (LPHP) of Lignin Dispersed into Gas Phase
by Mohamad Barekati-Goudarzi, Lavrent Khachatryan, Rubik Asatryan, Dorin Boldor and Bert C. Lynn
Molecules 2025, 30(10), 2215; https://doi.org/10.3390/molecules30102215 - 19 May 2025
Viewed by 353
Abstract
The gas-phase delivery of lignin into the hot zone of cw-CO2 laser-powered homogeneous pyrolysis (LPHP) reactor under “wall-less” conditions led to the breakdown of lignin macromolecules into neutral oligomers and paramagnetic fragments deposited onto the reactor cell walls. The formation of PAHs [...] Read more.
The gas-phase delivery of lignin into the hot zone of cw-CO2 laser-powered homogeneous pyrolysis (LPHP) reactor under “wall-less” conditions led to the breakdown of lignin macromolecules into neutral oligomers and paramagnetic fragments deposited onto the reactor cell walls. The formation of PAHs was observed during the defragmentation of lignin, accelerated with increased laser power. Remarkably, no phenolic compounds were detected among lignin fragments—intermediate radicals and neutral oligomers. It is concluded that the PAH and soot-like conjugated particulates are formed in the hot zone of the LPHP reactor, resembling the high-temperature combustion processes. The key role of the resonantly stabilized radicals in the formation of low-molecular-weight PAHs is outlined. An alternative pathway is proposed for the generation of PAH involving the formation of cyclopentadienyl radical precursors (CPDa) that are adsorbed onto or trapped within lignin macromolecules. Full article
(This article belongs to the Special Issue Advances in Polymer Materials Based on Lignocellulosic Biomass)
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