Search Results (54)

In recent years, frequent vehicle–bridge pier collision accidents have posed a serious threat to people’s economic and life security. In order to avert the impairment of reinforced concrete bridge piers (RCBPs) under the impact of vehicles, three kinds of Mg–Al alloy AlSi10Mg anti-collision structures designed by selective laser melting (SLM) printing were tested by the numerical simulation method in this study: an ultra-high performance concrete (UHPC) anti-collision structure, a bio-inspired honeycomb column thin-walled structure (BHTS) buffer interlayer, and a UHPC–BHTS composite structure were used to reduce the damage degree of RCBPs caused by vehicle impact. In accordance with the prototype configuration of the pier, a scaled model with a scale ratio of 1:10 was fabricated. Three anti-collision structures were installed on the reinforced concrete (RC) column specimens for the steel ball impact test. The impact simulation under low-energy and high-energy input was carried out successively, and the protective effect of the three anti-collision devices on the RC column was comprehensively evaluated. The outcomes demonstrate that the BHTS buffer interlayer and the UHPC–BHTS composite structure are capable of converting the shear failure of RC columns into bending failure, thereby exerting an efficacious role in safeguarding RC columns. The damage was evaluated under all impact conditions of BHTS and UHPC–BHTS composite structures, and the RC column only suffered slight damage, while the RC column without protective measures and the RC column with the UHPC anti-collision structure alone showed serious damage and collapse behavior. This approach can offer a valuable reference for anti-collision design within analogous projects. Full article

Polyvinyl butyral (PVB) is a specialty polymer primarily used as an interlayer in laminated glass applications with no current circularity plan after the end of its life. This study presents a comprehensive recycling strategy for postconsumed PVB wastes based on a remelting–restabilization approach. Thermo-oxidative degradation of PVB was analyzed under heat and shear stress conditions in an internal mixer apparatus. The degradation mechanism of plasticized PVB (p-PVB) and unplasticized PVB (u-PVB) was identified as chain scission through melt flow rate (MFR), intrinsic viscosity (IV), and yellowness index (YI) characterization. Six different antioxidant (AO) formulations were screened for their effectiveness in inhibiting degradation in both neat u-PVB and p-PVB, as well as retrieved PVB. The phenolic antioxidants 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene and 4-[[4,6-bis(octylsulfanyl)-1,3,5-triazin-2-yl]amino]-2,6-di-tert-butylphenol were found to be the most effective ones based on MFR, oxidation onset temperature (OOT), and YI evaluations, while the optimal AO concentration was determined at 0.3% w/w. Furthermore, upscaling of the process was achieved by mixing virgin PVB and high-quality retrieved PVB wastes with AOs in a twin-screw extruder. Testing of the recycled samples confirmed that the selected AOs offered resilience against degradation at reprocessing and protection during the next service life of the material. Full article

In recent years, with the increasing patient population, the need for complex and patient-centric medications has increased enormously. Traditional manufacturing techniques such as direct blending, high shear granulation, and dry granulation can be used to develop simple solid oral medications. However, it is well known that “one size fits all” is not true for pharmaceutical medicines. Depending on the age, sex, and disease state, each patient might need a different dose, combination of medicines, and drug release pattern from the medications. By employing traditional practices, developing patient-centric medications remains challenging and unaddressed. Over the last few years, much research has been conducted exploring various additive manufacturing techniques for developing on-demand, complex, and patient-centric medications. Among all the techniques, nozzle-based additive manufacturing platforms such as pressure-assisted microsyringe (PAM) and fused deposition modeling (FDM) have been investigated thoroughly to develop various medications. Both nozzle-based techniques involve the application of thermal energy. However, PAM can also be operated under ambient conditions to process semi-solid materials. Nozzle-based techniques can also be paired with the hot melt extrusion (HME) process for establishing a continuous manufacturing platform by employing various in-line process analytical technology (PAT) tools for monitoring critical process parameters (CPPs) and critical material attributes (CMAs) for delivering safe, efficacious, and quality medications to the patient population without compromising critical quality attributes (CQAs). This review covers an in-depth discussion of various critical parameters and their influence on product quality, along with a note on the continuous manufacturing process, quality by design, and future perspectives. Full article

In addition to impurities in recycled aluminum alloys, non-metallic inclusions are a significant factor that deteriorates the material’s castability and final mechanical properties. This, therefore, restricts the ability to transition from a primary to secondary aluminum alloy. In this study, the cleanliness of the recycled A357 alloy was evaluated through non-metallic inclusions’ characterization, hydrogen content measurement, fluidity test, and casting defects identification. The non-metallic inclusions generated during the recycling process of A357 alloy were collected by the pressurized melt filtration technique. All of the inclusion types collected during filtration were examined and identified by analytical scanning electron microscopy (SEM). Extra additions of up to 2 wt.% swarf in these secondary A357 alloys were designed to simulate highly contaminated alloys. Different to the conventional melt cleaning technologies that mainly focus on complete removal of inclusions, this study developed a novel approach that combines the removal of easily removeable inclusions while preserving well-dispersed inclusions that do not adversely affect the mechanical properties. This study demonstrates that high shear melt conditioning (HSMC) technology can achieve well-dispersed small non-metallic inclusions, low hydrogen content, improved fluidity, and fewer casting defects. As a result, the melt quality of the recycled A357 alloys has achieved a quality comparable to that of primary A357 alloy. Full article

Based on a physical water model with a scaling factor of 0.5 and a coupled flow–heat transfer–solidification numerical model, this study investigates the influence of the submerged entry nozzle (SEN) depth on the mold surface behavior, slag entrapment, internal flow field, temperature distribution, and initial solidification behavior in slab casting. The results indicate that when the SEN depth is too shallow (80 mm), the slag layer on the narrow face is thin, leading to slag entrapment. Within a certain range of SEN depths (less than 170 mm), increasing the SEN depth reduces the impact on the mold walls, shortening the “plateau period” of stagnated growth on the narrow face shell. This allows the upper recirculation flow to develop more fully, resulting in an increase in the surface flow velocity and an expansion in the high-temperature region near the meniscus, which promotes uniform slag melting but also heightens the risk of slag entrainment due to shear stress at the liquid surface (with 110 mm being the most stable condition). As the SEN depth continues to increase, the surface flow velocity gradually decreases, and the maximum fluctuation in the liquid surface diminishes, while the full development of the upper recirculation zone leads to a higher and more uniform meniscus temperature. This suggests that in practical production, it is advisable to avoid this critical SEN depth. Instead, the immersion depth should be controlled at a slightly shallower position (around 110 mm) or a deeper position (around 190 mm). Full article

Currently, fast-melting SBS (Styrene-Butadiene-Styrene)-modified asphalt is widely used in pavements. However, in practical applications, complex environmental factors accelerate the deterioration of asphalt material properties, significantly affecting the service life of roads during their operational period. This study aims to examine the effects of complex environmental factors, including thermal oxidation, ultraviolet radiation, and various concentrations of salt solutions, on the high and low-temperature rheological properties of fast-melting SBS-modified asphalt (abbreviated as SBS-T-modified asphalt). Pressure aging–ultraviolet aging coupling and pressure aging–ultraviolet aging different concentration salt solution coupling were selected as the aging groups to simulate complex environmental conditions. Additionally, base asphalt and pressure-aged asphalt were used as control groups. The rheological properties of SBS-T-modified asphalt were evaluated using a dynamic shear rheometer (DSR) and bending beam rheometer (BBR). The results indicate that multiple-factor coupling aging reduces both the high-temperature and low-temperature performance of SBS-T-modified asphalt compared to single-factor aging, although the impact on rheological properties is not consistent across all conditions. After the combined effects of UV aging and pressure aging, the rutting resistance and high-temperature performance of SBS-T-modified asphalt are most severely impacted. However, when coupled with salt-solution aging, the rutting resistance of SBS-T-modified asphalt improves, with the complex modulus increasing by approximately 30%. This indicates that the presence of the salt solution enhances the high-temperature performance of the asphalt. An analysis of the low-temperature rheological properties of SBS-T-modified asphalt based on Burgers model shows that the low-temperature rheological performance of SBS-T-modified asphalt worsens under three-factor coupling aging compared to two-factor or single-factor aging, leading to poorer crack resistance. Notably, after adding salt solutions, the thermal sensitivity of SBS-T-modified asphalt increases significantly, with the ΔTc value decreasing approximately sixfold for every 2% increase in salt concentration. Full article

To achieve laser direct welding of glass and metal without optical contact is hard, owing to the large difference in thermal expansion and thermal conductivity between glass and metal and an insignificant melting area. In this study, the high-power picosecond pulsed laser was selected to successfully weld the aluminosilicate glass/6061 aluminum alloy with a gap of 35 ± 5 μm between glass and metal. The results show that the molten glass and metal diffuse and mix at the interface. No defects such as microcracks or holes are observed in the diffusion mixing zone. Due to the relatively large gap, the glass collapsed after melting and caulking, resulting in an approximately arc-shaped microcrack between modified glass and unmodified glass or weakly modified glass. The shape of the glass modification zone and thermal accumulation are influenced by the single-pulse energy and linear energy density of the picosecond laser during welding, resulting in variations in the number and size of defects and the shape of the glass modification zone. By reasonably tuning the two factors, the shear strength of the joint reaches 15.98 MPa. The diffusion and mixing at the interface and the mechanical interlocking effect of the glass modification zone are the main reasons for achieving a high shear strength of the joint. This study will provide reference and new ideas for the laser transmission welding of glass and metal in the non-optical contact conditions. Full article

This research explores the development of thermoplastic vulcanizate (TPV) blends derived from natural rubber (NR) and ethylene–butene copolymer (EBC) using a specific blend ratio and melt mixing technique. A comprehensive full factorial design of experiments (DOE) methodology is employed to optimize the processing parameters. TPVs are produced through dynamic vulcanization, combining rubber crosslinking and melt blending within a thermoplastic matrix under high temperatures and shear. The physico-mechanical properties of these TPVs are then analyzed. The objective is to enhance their mechanical performance by assessing the influence of blend ratio, mixing temperature, rotor speed, and mixing time on crucial properties, including tensile strength, elongation at break, compression set, tear strength, and hardness. Analysis of variance (ANOVA) identifies the optimal processing conditions that significantly improve material performance. Validation is achieved through atomic force microscopy (AFM), confirming the phase-separated structure and, thus, the success of dynamic vulcanization. Rubber process analyzer (RPA) and dynamic mechanical analyzer (DMA) assessments provide insights into the viscoelastic behavior and dynamic mechanical responses. Deconvolution analysis of temperature-dependent tan δ peaks reveals intricate microstructural interactions influencing the glass transition temperature (T_g). The optimized TPVs exhibit enhanced stiffness and effective energy dissipation capabilities across a wide temperature range, making them suitable for applications demanding thermal and mechanical load resistance. This study underscores the pivotal role of precise processing control in tailoring the properties of NR/EBC TPVs for specialized industrial uses. It highlights the indispensable contribution of the DOE methodology to TPV optimization, advancing material science and engineering, particularly for industries requiring robust and flexible materials. Full article

Olivine, the most abundant mineral in the upper mantle, exhibits elastic anisotropy. Understanding the seismic anisotropy and flow patterns in the upper mantle hinges on the crystallographic preferred orientation (CPO) of olivine. Similarly, hydrous minerals, which also display elastic anisotropy, play a crucial role in explaining seismic anisotropy in numerous subduction zones. High-temperature and -pressure simple shear experiments reveal that the CPO of amphibole can lead to significant seismic anisotropy. In this study, peridotite samples originating from the southern end of the Mariana Trench, commonly containing amphibole, were analyzed. The microdeformation fabric and seismic anisotropy were examined. The results indicate a weak fabric strength in olivine, yet identifiable deformation fabrics of A/D, D, and AG were observed. Various dislocation structures suggest that olivine experiences complex deformation across various temperatures. Not only can the original slip system transform, but the melt/fluid resulting from melting also has a substantial impact on the peridotite. Deformation precedes the melt/rock interaction, resulting in a strong melt/rock reaction under near-static conditions. Furthermore, the modal content of amphibole significantly alters the seismic anisotropy of peridotite. An increase in amphibole content (types I, III, and IV) enhances seismic anisotropy, particularly for type I amphibole. Notably, the presence of type I fabric amphibole promotes the Vs1 polarization direction parallel to the trench in subduction zones, a phenomenon observed in other subduction zones. Therefore, when considering mantle peridotite regions rich in amphibole, the impact of amphibole on seismic anisotropy must be accounted for. Full article

This article compares two exfoliation options of multilayered silicate, one considering the action of shear stress and temperature during melt compounding and another taking into account the action of the thermo-mechanical pretreatment of multilayered silicate in a plasticizer common to the starch and polyvinyl alcohol (PVOH), the two polymers from the compound. Increasing the action time of the shear stress and temperature during melt compounding proved to be an ineffective method for silicate exfoliation following the high degradability of starch and PVOH under thermo-mechanical conditions and the loss of hydration of the multilayered silicate under thermo-mechanical conditions. The obtained results prove that, by pretreating before embedding into the desired starch-PVOH matrix, it was possible to cancel the electrostatic attractions between the component lamellae of a multilayered silicate. During melt compounding with the two polymers, new attractions between the obtained lamellae and the polar groups of each polymer from the blend were settled, and so, without the usage of a liquid plasticizer, exfoliated intercalated nanocomposites were achieved. The improved properties and the practical importance of the new nanocomposites regards the obtaining of a non-degradable material that has a white color, better elastic properties and thermal stability, and a higher dissipation capacity of deformation energy. Full article

Orally disintegrating granules (ODGs) are a pharmaceutical form commonly used for the administration of NSAIDs because of their easy assumption and fast dispersion. The development of ODGs is not easy for drugs like dexketoprofen trometamol (DXKT), which have a bitter and burning taste. In this work, high-shear coating (HSC) was used as an innovative technique for DKXT taste masking. This study focused on coating DXKT granules using the HSC technique with a low-melting lipid excipient, glyceryl distearate (GDS). The HSC technique allowed for the coating to be developed through the thermal rise resulting from the friction generated by the granules movement inside the equipment, causing the coating excipient to soften. The design of the experiment was used to find the best experimental coating conditions in order to gain effective taste masking by suitably reducing the amount of drug released in the oral cavity. The influence of the granule dimensions was also investigated. Coating effectiveness was evaluated using a simulated saliva dissolution test. It was found that low impeller speed (300 rpm) and a 20% coating excipient were effective in suitably reducing the drug dissolution rate and then in taste masking. The coated granules were characterized for their morphology and solid-state properties by SEM, BET, XRPD, DSC, and NIR analyses. A human taste panel test confirmed the masking of DXKT taste in the selected batch granules. Full article

Friction is a pivotal factor influencing wrinkle formation in composite material shaping processes, particularly in novel thermoplastic composites like polyetheretherketone (PEEK) and low-melting polyaryletherketone (LM-PAEK) matrices reinforced with unidirectional carbon fibers. The aerospace sector lacks comprehensive data on the behavior of these materials under forming conditions, motivating this study’s objective to characterize the interlaminar friction of such high-performance thermoplastic composites across diverse temperatures and forming parameters. Differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) were employed to analyze the thermomechanical behaviors of PEEK and LM-PAEK. These data guided friction tests covering room-to-forming temperatures. Horizontal pull-out fixed-plies tests were conducted to determine the friction coefficient and shear stress dependency concerning temperature, pressure, and pulling rate. Below the melting point, both materials adhered to Coulomb’s law for friction behavior. However, above the melting temperature, PEEK’s friction decreased while LM-PAEK’s friction increased with rising temperatures. These findings highlight the distinct responses of these materials to temperature variations, pulling rates, and pressures, emphasizing the need for further research on friction characterization around glass transition and melting temperatures to enhance our understanding of this phenomenon. Full article

This study addresses the critical issue of traffic safety in winter, particularly focusing on the challenges posed by ice and snow on roads. Traditional methods of snow and ice removal are often labor-intensive, inefficient, and environmentally harmful. The objective is to develop a more effective solution for asphalt pavement deicing. Inspired by the anti-icing coating technology used in high-voltage conductors, this research develops an ice-suppressing material designed to reduce the adhesion between snow, ice, and pavement surfaces. The material’s performance is evaluated in terms of deicing efficiency, durability, adhesive properties, and its impact on pavement performance. Test results demonstrate that the developed ice-suppressing material significantly reduces the adhesion between the ice layer and the pavement, facilitating easier removal. This study concludes that the developed ice-suppressing material significantly enhances deicing efficiency on asphalt pavements. It exhibits strong hydrophobic properties, as evidenced by increased water droplet contact angles on coated surfaces (99.5° to 83.3°) compared to clean glass slides (39.2° to 29°). This hydrophobicity effectively reduces ice adhesion, decreasing tensile and shear strength of the ice layer by 38.2% and 63.6%, respectively. Additionally, the material demonstrates superior ice-melting capabilities in sub-zero temperatures, with coated ice cubes showing a higher mass reduction rate than uncoated ones. Importantly, its slow-release nature ensures sustained deicing performance over multiple cycles, maintaining effectiveness after seven test cycles. This study introduces an innovative ice-suppressing material that not only improves the efficiency and environmental impact of deicing methods but also contributes to enhancing road safety in winter conditions. The material’s novel composition and sustained effectiveness present a significant advancement in the field of winter road maintenance. Full article

In the context of polymer-based nanocomposites containing layered nanofillers, the achievement of good extents of dispersion and distribution of the embedded nanoparticles and, even more, the obtainment of intercalated and/or exfoliated structures through melt compounding still represents a persistent challenge, especially in the case of anionic layered double hydroxides (LDHs)-containing systems and non-polar polymeric matrices. In this work, a simulation approach is proposed to evaluate the influence of the processing conditions on the morphology of polypropylene (PP)-based nanocomposites containing organomodified LDHs. In particular, the effect of the screw rotation speed and the feed rate on the final microstructure of the materials formulated through melt compounding in a twin-screw extruder was assessed. The rheological and morphological characterizations demonstrated that a more homogeneous morphology was achieved when high levels of both exploited processing parameters are selected. The results coming from the simulation of the processing were used to establish some relationships between the flow parameters and the microstructure of the nanocomposites, demonstrating that low residence times coupled with high local shear rates are required to ensure the achievement of homogenous morphologies, likely involving the occurrence of intercalation phenomena. Full article

The incorporation of thermoplastics with pigments imparts diverse aesthetic qualities and properties to colored thermoplastic products. The selection of pigment type and content, along with specific processing conditions, plays a pivotal role in influencing color properties and overall product performance. This study focuses on optimizing these parameters to ensure the desired color quality and product functionality. Two types of polypropylene copolymer (PPCP) with different melt flow rates (MFRs) and acrylonitrile butadiene styrene (ABS) were compounded with ultramarine blue pigment masterbatch (MB) in concentrations ranging from 1 to 5 wt.% using a twin-screw extruder. The compounding process was conducted at a constant screw speed of 200 rpm and a die temperature of 210 °C. The effects of screw speed and die temperature were investigated at a constant MB of 3 wt.%. Colored samples were fabricated by injection molding. Microscopic analysis revealed a well-dispersed pigment within the PPCP matrix when using the MB. Rheological properties, assessed through the power law index, confirmed effective pigment dispersion, facilitated by shear thinning behavior and controlled shear rate via the manipulation of screw speed and die temperature. The effects of masterbatch contents and processing conditions on color spaces were evaluated using CIELAB and CIELCH, with one-way ANOVA employed to identify statistical significance. Higher opacity in high-MFR PPCP and ABS resulted in increased lightness and color strength, surpassing low-MFR PPCP by 15–40% at equivalent MB contents. Masterbatch content emerged as a significant factor influencing the color spaces of all colored thermoplastics. Further analysis, including Fisher pairwise comparisons of one-way ANOVA, revealed that screw speed influenced the redness and hue of low-MFR PPCP, whereas die temperature affected the lightness and hue of high-MFR PPCP and ABS. Interestingly, the blueness and chroma of colored thermoplastics were minimally affected by both screw speed and die temperature. Notably, regardless of processing conditions, the flexural properties of colored thermoplastics remained comparable to the neat polymer when incorporated with ultramarine blue pigment masterbatch. Full article