Search Results (245)

This paper presents a novel, non-contact method for measuring capillary water uptake in porous materials based on the phenomenon of moisture-induced expansion. The proposed approach establishes a quantitative relationship between the amount of water absorbed by the material and the deformations measured on its surface. Digital Image Correlation (DIC) was used to track the displacements of reference points on gypsum specimens during capillary rise. The absorbed water mass was determined from the recorded displacements using a mechanical model that incorporates the moisture expansion coefficient. The method was validated by comparison with conventional continuous gravimetric measurements. The results demonstrate that the displacement-based approach accurately captures the capillary rise process, particularly in the initial phase, where the gravimetric method suffers from significant measurement errors due to surface tension effects. The proposed method eliminates these limitations, providing higher accuracy and temporal resolution. In addition, it enables the testing of larger samples and offers the potential for spatially resolved moisture analysis. The findings confirm that the method is suitable for studying moisture transport in porous materials and may serve as a valuable alternative to traditional gravimetric techniques. Full article

In order to elucidate the high-temperature reaction process of solid waste-based high belite sulphoaluminate cement containing residual gypsum in clinker (NHBSAC) and obtain the formation laws of each mineral in clinker, this article studied its high-temperature reaction kinetics. Through QXRD analysis and numerical fitting methods, the formation of C₄A₃$\overline{\mathrm{S}}$, β-C₂S, and CaSO₄ in clinker under different calcination systems was quantitatively characterized, the corresponding high-temperature reaction kinetics models were established, and the reaction activation energies of each mineral were obtained. The results indicate that the content of C₄A₃$\overline{\mathrm{S}}$ and β-C₂S increases with the prolongation of holding time and the increase in calcination temperature, while CaSO₄ is continuously consumed. Under the control mechanism of solid-state reaction, the formation and consumption of minerals follow the kinetic equation. C₄A₃$\overline{\mathrm{S}}$ and β-C₂S satisfy the D₄ equation under diffusion mechanism control, and CaSO₄ satisfies the R₃ equation under interface chemical reaction mechanism control. The activation energy required for mineral formation varies with different temperature ranges. The activation energies required to form C₄A₃$\overline{\mathrm{S}}$ at 1200–1225 °C, 1225–1275 °C, and 1275–1300 °C are 166.28 kJ/mol, 83.14 kJ/mol, and 36.58 kJ/mol, respectively. The activation energies required to form β-C₂S at 1200–1225 °C and 1225–1300 °C are 374.13 kJ/mol and 66.51 kJ/mol, respectively. This study is beneficial for achieving flexible control of the mineral composition of NHBSAC clinker, providing a theoretical basis and practical experience for the preparation of low-carbon cement and the optimization design of its mineral composition. Full article

Earth fill dams are susceptible to internal erosion and instability when founded over cavity-prone formations such as gypsum or karstic limestone. Subsurface voids can significantly compromise dam performance, particularly under seismic loading, by altering seepage paths, raising pore pressures, and inducing structural deformation. This study examines the influence of cavity presence, location, shape, and size on the behavior of zoned earth dams. A 1:25 scale physical model was tested on a uniaxial shake table under varying seismic intensities, and seepage behavior was observed under steady-state conditions. Numerical simulations using SEEP/W and QUAKE/W in GeoStudio complemented the experimental work. Results revealed that upstream and double-cavity configurations caused the greatest deformation, including crest displacements of up to 0.030 m and upstream subsidence of ~7 cm under 0.47 g shaking. Pore pressures increased markedly near cavities, with peaks exceeding 2.7 kPa. Irregularly shaped and larger cavities further amplified these effects and led to dynamic factors of safety falling below 0.6. In contrast, downstream cavities produced minimal impact. The excellent agreement between experimental and numerical results validates the modeling approach. Overall, the findings highlight that cavity geometry and location are critical determinants of dam safety under both static and seismic conditions. Full article

The hydrochemical characteristics and evolution mechanisms of groundwater are critical for accurately understanding the input–output budget of hydrochemical constituents in pristine groundwater. However, few studies have analyzed the changes in mineral precipitation and dissolution equilibrium along the groundwater flow path, especially in arid regions. This study integrated hydrochemical analysis, stable isotopes, and inverse hydrochemical modeling to identify groundwater recharge sources, hydrochemical evolution, and controlling mechanisms in an arid endorheic watershed, northwestern China. A stable isotope signature indicated that groundwater is primarily recharged by high-altitude meteoric precipitation and glacial snowmelt. The regional hydrochemical type evolved from HCO₃·Cl-Ca·Mg·Na types in phreatic aquifers to more complex HCO₃·Cl-Ca·Mg Na and HCO₃·Cl-Na Mg types in confined aquifers and a Cl-Mg·Na type in high-salinity groundwater. The dissolution of halite, gypsum, calcite, K-feldspar, and albite was identified as the primary source of dissolved substances and a key factor controlling the hydrochemical characteristics. Meanwhile, hydrochemical evolution is influenced by cation exchange, mineral dissolution–precipitation, and carbonate equilibrium mechanisms. Inverse hydrochemical modeling demonstrated that high-salinity groundwater has experienced intensive evaporation and quantified the transfer amounts of associated minerals. This study offers deeper insight into hydrochemical evolution in the Golmud River watershed and elucidates mineral transport and enrichment mechanisms, providing a theoretical basis for investigating hydrochemical metallogenic processes. Full article

Hyperspectral technology can non-destructively identify and analyze minerals. However, the quantitative inversion of different components in mixed minerals remains difficult in mineral spectral analysis. A set of mineral samples was prepared from dolomite and gypsum, varying in their components. Three improved spectral decomposition models were proposed: the Continuum Removal-Fully Constrained Linear Spectral Model (CR-FCLSM), the Natural Logarithm-Fully Constrained Linear Spectral Model (NL-FCLSM), and the Ratio Derivative Model (RDM). The unmixing Abundance Error (AE) was 0.161, 0.051, and 0.082 for CR-FCLSM, NL-FCLSM, and RDM. The results of the three improved linearized unmixing models are better than those of the traditional linear spectral unmixing model. The NL-FCLSM effectively enhanced the linear characteristics of the spectrum, making it more suitable for two mineral mixing scenarios. The systematic bias of CR-FCLSM may be due to its insufficient sensitivity to low-abundance signals. The stability of RDM depends on the selection of a strong linear band. The unmixing experiments of the measured spectra and the data from the USGS spectral library demonstrate that the improved linear unmixing model is more accurate than the traditional linear spectral model and simpler to calculate than the nonlinear spectral model, providing a new approach for demodulating hyperspectral images. Full article

The southeastern Hainan Island boasts abundant hydrothermal resources, most of which are exposed as thermal springs. Analyzing the hydrochemical characteristics, hydrochemical evolutionary mechanisms, and material transition of these resources is significant for their exploitation and utilization. This study investigated the Nanping geothermal field in southeastern Hainan Island, using five groups of geothermal water samples collected in 2022, as well as seven groups of geothermal water samples, one group of shallow groundwater samples, and one group of surface water samples taken in 2023. Specifically, this study examined water–rock interactions in the geothermal field using the Gibbs model, ion ratios, chloro-alkaline indices (CAIs), and the sodium adsorption ratio (SAR). Moreover, the mineral transfer process in groundwater was analyzed using inverse hydrogeochemical simulation. The results indicate that in the study area the geothermal water temperatures range from 64 °C to 80 °C, pH values from 8.32 to 8.64, and TDS concentrations from 431 mg/L to 623 mg/L. The primary hydrochemical types of geothermal water in the study area include Cl-Na and Cl·HCO₃-Na, suggesting low-temperature, slightly alkaline geothermal water. The hydrochemical components of geothermal water in the study area are primarily affected by water–rock interactions. Besides the dissolution of silicate minerals and halite, cation exchange reactions contribute greatly to the formation of Na⁺ and K⁺ in geothermal water. Geothermal water receives recharge from the atmospheric precipitation of the Diaoluo Shan area in the northwest of the study area, with the recharge elevation ranging from 967 to 1115 m. The inverse hydrogeochemical simulation results reveal that during the water–rock interactions, silicate minerals, clay minerals, gypsum, and halite dissolve, while quartz and carbonate minerals precipitate. Additionally, these processes are accompanied by cation exchange reactions dominated by the replacement of Na⁺ in surrounding rocks by Ca²⁺ in geothermal water. This study can provide a geological basis for the exploitation, utilization, and management of the Nanping geothermal field. Full article

The construction industry is the main consumer of mineral resources. At the same time, the Portland cement (PC) industry occupies a leading position, using expensive, high-quality raw materials. This is due to the high rate of construction in different areas (industrial, civil, road construction, etc.). The widespread application of PC is due primarily to the strength and durability of composite materials based on it. Taking into account their specific purpose, PC-based composites are usually optimized to achieve specified characteristics and rational use of raw materials. To reduce PC consumption and justify the possibility of its use in complex binders, this manuscript analyzes the composition of a functional polymer–mineral additive; the nature and mechanisms of its interaction with PC depend on the method of introducing the additive (dry mixing/joint grinding of the clinker–gypsum mixture with the additive at the stage of binder preparation). Based on the data of XRD, IR, and SEM analysis, as well as taking into account patent information, the composition of the additive was clarified. The combined application of the above methods allowed us to establish the uniformity of the additive distribution in the binder depending on the introduction method and to evaluate the effect of each additive component and its mutual impact on the processes occurring during cement hydration. As a result, it was established that the most effective introduction method is combined grinding. A phenomenological model of the structure formation of additives containing cement paste is proposed. The binder production by the combined grinding method promotes the intensification of the processes occurring during hydration, as evidenced by the data of qualitative and quantitative XRD, IR, and DTA analysis, differential scanning calorimetry (DSC), and TGA analysis. Full article

Gypsum and salt rocks have been proven to act as seals for abundant oil and gas reserves on a global scale, with significant potential for hydrocarbon preservation and evolution. Notably, the sedimentary dynamics of non-evaporitic gypsum in terrestrial half-graben basins remain underexplored, particularly regarding its genetic link to hydrocarbon accumulation in interbedded mudstones. This study is based on the Zhanhua Sag, in which thick-layered gypsum rocks with dark mudstone are deposited. The gypsum crystals show the intermittent deposition characteristics. The cumulative thickness of the gypsum-containing section reaches a maximum of over 110 m. The spatial distribution of gypsum thickness correlates strongly with the location of deep-seated faults. The strontium and sulfur isotopes of gypsum indicate deep hydrothermal fluids as mineral sources, and negative oxygen isotope excursions also suggest that gypsum layers precipitated in situ from hot brine. Total organic carbon and Rock-Eval data indicate that the deep-lake gypsum rock system has excellent hydrocarbon potential, especially in the mudstone interlayers. This study developed a depositional model of deep-lake gypsum rocks with thermal brine genesis in half-graben basins. The gypsum-bearing system is rich in mudstone interlayers. These gypsum–mudstone interbeds represent promising targets for shale oil exploration after the initial breakthrough during the extraction process. These insights provide a theoretical framework for understanding gypsum-related petroleum systems in half-graben basins across the globe, offering guidance for hydrocarbon exploration in analogous sedimentary environments. Full article

This study investigated the distribution and source of heavy metals and dispersed elements in the high-salinity brine of Qarhan Salt Lake. The brine with an average total dissolved solid content of 332.22 g/L, dominated by Cl⁻ (216.41 g/L) and Mg²⁺ (44.76 g/L), indicated strong evaporation and dolomite dissolution. As (6.57 ± 3.59 μg/L) and Hg (0.48 ± 0.14 μg/L) showed uniform distribution while Li (69.66 mg/L), B₂O₃ (317.80 mg/L), and Zn (5.69 mg/L) were highly enriched, highlighting the resource potential and geochemical complexity. Correlation analysis revealed that water–rock interaction played a key role in element differentiation, with Sr and Ca²⁺/Cl⁻ showing strong positive correlations (r = 0.693/0.768), reflecting isomorphic substitution and dissolution. Meanwhile, Na⁺ and Mg²⁺/Ca²⁺ showed negative correlations (r = −0.732/−0.889), suggesting cation exchange and gypsum precipitation. The self-organizing map yielded four clusters of elements and positive matrix factorization model identified four sources; the elements in the Salt Lake brine mainly came from the river water supply, weathering and leaching of minerals, and dissolution of salt-bearing layers and were locally influenced by human activities. The research provided valuable insights for future sustainable development and the environmental protection of the region. Full article

Enhancing the spatial resolution of gypsiferous soil detection, as a valuable baseline information layer, is beneficial for investigating agroecological processes and tackling land degradation in semi-arid environments. This study evaluates the performance of PRISMA (PRecursore IperSpettrale della Missione Applicativa) and EnMAP (Environmental Mapping and Analysis Program) satellites in estimating soil gypsum content and compares models trained on satellite imagery versus lab data. To this end, 242 bare-soil samples were collected from southeast Iran. Gypsum content was measured using acetone precipitation, and spectral reflectance was acquired using the ASD (Analytical Spectral Devices)-Fieldspec 3 spectroradiometer. The gypsum content was retrieved by optical data using three approaches: narrowband indices, spectral absorption features, and machine learning (ML) algorithms. Four machine learning algorithms, including PLSR (Partial Least Squares Regression), RF (Random Forest), SVR (Support Vector Regression), and GPR (Gaussian Process Regression), achieved excellent performance (RPD > 2.5). The results showcased that the difference soil index (DSI) achieved the highest R² scores of 0.96 (ASD), 0.79 (PRISMA), and 0.84 (EnMAP), slightly outperforming the normalized difference gypsum ratio (NDGI) and ratio soil index (RSI). Comparing the shape indices’, the slope parameter (SLP) index outperformed the half-area parameter (HAP) index. PRISMA, with SVR (R² ≥ 0.83), and EnMAP, with PLSR (R² ≥ 0.85), demonstrated that hyperspectral satellites proved reliable in detecting gypsum content, yielding results comparable to ASD with detailed algorithms. Full article

This study aims to develop fluid–solid coupled similar materials to enhance the reliability of geotechnical model tests simulating reservoir slope stability under water-level fluctuations. Using an orthogonal experimental method, materials were prepared with quartz sand and barite as aggregates, cement and gypsum as binders, and water as the regulator. Tests on density, uniaxial and triaxial compressive strength, and flow properties determined the relationships between material properties and raw components. Uniaxial compressive strength tests under dry–wet cycles revealed that cement-to-binder ratio primarily influenced density, uniaxial compressive strength, cohesion, and hydraulic conductivity, while the binder-to-aggregate ratio affected elastic modulus and internal friction angle. Uniaxial compressive strength continuously degraded with cycles but at a decreasing rate. A water-damage resistance coefficient was defined to quantify degradation. Multiple linear regression analysis established a robust model for uniaxial compressive strength prediction, providing a theoretical basis for material proportioning. These findings improve the simulation accuracy in hydrologically active zones, with applications in designing stable reservoir slopes. Full article

In response to the need for sustainable soil stabilization alternatives, this study explores the use of waste materials and biopolymers to improve the mechanical behavior of clay from Cartagena, Colombia. Crushed limestone waste (CLW), ground glass powder (GG), recycled gypsum (GY), xanthan gum (XG), and the combination of XG with polypropylene fibers (XG–PPF) were used as stabilizing agents. Samples were compacted at different dry densities and cured for 28 days. Unconfined compressive strength (UCS) and ultrasonic pulse velocity (UPV) tests were conducted to assess the strength and stiffness of the treated mixtures. Results were normalized using the porosity/binder index ($\mathrm{\eta }/B_{iv}$), leading to predictive equations with high determination coefficients (R² = 0.94 for UCS and R² = 0.96 for stiffness). However, XG-treated mixtures exhibited distinct behavior that prevented their inclusion in a unified predictive model, as the fitted exponent x in the porosity/binder index ($\mathrm{\eta }/B_{iv}^x$) differed markedly from the others. While an exponent of 0.28 was suitable for blends with mineral binders, the optimal x values for XG and XG–PPF mixtures were significantly lower at 0.02 and 0.03, respectively, reflecting their unique gel-like and fiber-reinforced characteristics. The analysis of variance (ANOVA) identified cement content and compaction density as the most influential factors, while some interactions involving the residues were not statistically significant, despite aligning with experimental trends. The findings support the technical viability of using sustainable additives to enhance soil properties with reduced environmental impact. Full article

With the aim of reducing the environmental impact of buildings, the appropriate selection of building materials is essential, as a building is a complex system composed of various materials. With this background, a multi-criteria decision-making approach has recently gained traction. This study demonstrated the effect of building material selection on both environmental and economic parameters of a building in the context of Japan. A comparative analysis of five structural frame options was conducted utilizing a reference building model to assess the implication of material choices. The findings indicated that wooden frame options are advantageous in environmental aspects compared to non-wooden frames, provided that sustainable forestry practices and appropriate recycling scenarios are implemented. Conversely, it was found that a Cross Laminated Timber (CLT) frame is the most expensive option. This suggests that a hybrid approach, which combines various frame materials, could yield a more effective solution in terms of both environmental and economic sustainability. In addition, it was highlighted that building envelopes, such as foundation, exterior wall, and roof, should be prioritized to enhance the sustainability of a building from a material perspective. Furthermore, gypsum board, commonly used for sheathing building elements, should be selected with careful consideration of its environmental impact. Full article

Groundwater plays a leading role in ecological environment protection in semi-arid regions. The Huangshui River Basin is located in the Tibetan Plateau and Loess Plateau transition zone of semi-arid areas. Its ecological environment is relatively fragile, and there is an urgent need for systematic study of the basin to develop a groundwater environment and realize the rational and efficient development of water resources. In this study, methodologically, we combined the following: 1. Field sampling (271 groundwater samples across the basin’s hydrogeological units); 2. Comprehensive laboratory analysis of major ions and physicochemical parameters; 3. Multivariate statistical analysis (Pearson correlation, descriptive statistics); 4. Geospatial techniques (ArcGIS kriging interpolation); 5. Hydrochemical modeling (Piper diagrams, Gibbs plots, PHREEQC simulations). Key findings reveal the following: 1. Groundwater is generally weakly alkaline (pH 6.94–8.91) with TDS ranging 155–10,387 mg/L; 2. Clear spatial trends: TDS and major ions (Na⁺, Ca²⁺, Mg²⁺, Cl⁻, SO₄²⁻) increase along flow paths; 3. Water types evolve from Ca-HCO₃-dominant (upper reaches) to complex Ca-SO₄/Ca-Cl mixtures (lower reaches); 4. Water–rock interactions dominate hydrochemical evolution, with secondary cation exchange effects; 5. PHREEQC modeling identifies dominant carbonate dissolution (mean SIcalcite = −0.32) with localized evaporite influences (SIgypsum up to 0.12). By combining theoretical calculations and experimental results, this study reveals distinct hydrochemical patterns and evolution mechanisms. The groundwater transitions from Ca-HCO₃-type in upstream areas to complex Ca-SO₄/Cl mixtures downstream, driven primarily by dissolution of gypsum and carbonate minerals. Total dissolved solids increase dramatically along flow paths (155–10,387 mg/L), with Na⁺ and SO₄²⁻ showing the strongest correlation to mineralization (r > 0.9). Cation exchange processes and anthropogenic inputs further modify water chemistry in midstream regions. These findings establish a baseline for sustainable groundwater management in this ecologically vulnerable basin. Full article

The article investigates the characteristics of the phase composition and structure of supersulfated cement (SSC) during hardening using X-ray, electron microscopy, and ultrasonic analysis methods. The influence of different types of activators, hardening accelerators, and superplasticizers on the type and morphology of the newly formed phases during SSC hardening was studied. The effect of a polycarboxylate-type superplasticizer and calcium chloride on the standard consistency and setting times of SSC was experimentally determined. It was established that the introduction of the superplasticizer reduces the standard consistency by 10–16%. Experimental data showed higher effectiveness of phosphogypsum as a sulfate activator compared to gypsum stone. The strength increase of SSC at 7 days reached up to 35%, and at 28 days, up to 15%. Based on the kinetics of ultrasonic wave propagation during SSC hardening, the main stages of structure formation and the influence of cement composition on these stages were determined. The experimental results demonstrate the effect of SSC composition on its standard consistency, setting time, and mechanical properties. The impact of the type of activator and admixtures on the change in SSC strength during storage was investigated. It was found that the addition of a polycarboxylate-type superplasticizer significantly reduces the strength loss of SSC during long-term storage. Using mathematical modeling, experimentally obtained statistical models of strength were developed, which allow for the quantitative evaluation of individual and combined effects, as well as the determination of optimal SSC compositions. Full article