Search Results (116)

Subsurface mass concrete infrastructure—including immersed tunnels, dams, and nuclear waste containment systems—frequently faces calcium-leaching risks from prolonged groundwater exposure. An anisotropic stress-leaching damage model incorporating microcrack propagation is developed for underground concrete’s chemo–mechanical coupling. This model investigates stress-induced anisotropy in concrete through the evolution of oriented microcrack networks. The model incorporates nonlinear anisotropic plastic strain from coupled chemical–mechanical damage. Unlike conventional concrete rheology, this model characterizes chemical creep through stress-chemical coupled damage mechanics. The numerical model is incorporated within COMSOL Multiphysics to perform coupled multiphysics simulations. A close match is observed between the numerical predictions and experimental findings. Under high stress loads, calcium leaching and mechanical stress exhibit significant coupling effects. Regarding concrete durability, chemical degradation has a more pronounced effect on concrete’s stiffness and strength reduction compared with stress-generated microcracking. Full article

Underground brine as a liquid mineral resource available for development and utilization has attracted widespread attention. However, how the mining process affects the hydrochemical characteristics and evolution of underground brine has yet to be fully understood. Herein, 207 underground brine samples were collected from the Luobei mining area of the Lop Nur region during pre-exploitation (2006), exploitation (2019), and late exploitation (2023) to explore the dynamic change characteristics and evolution mechanisms of the underground brine hydrochemistry using the combination of statistical analysis, spatial interpolation, correlation analysis, and ion ratio analysis. The results indicated that Na⁺ and Cl⁻ were the dominant ionic components in the brine, and their concentrations remained relatively stable throughout the mining process. However, the content of Mg²⁺ increased gradually during the mining process (increased by 45.08% in the middle stage and 3.09% in the later stage). The elevation in Mg²⁺ concentration during the mining process could be attributed to the dissolution of Mg-bearing minerals, reverse cation exchange, and mixed recharge. This research furnishes a scientific foundation for a more in-depth comprehension of the disturbance mechanism of brine-mining activities on the groundwater chemical system in the mining area and for the sustainable exploitation of brine resources. Full article

The transformative trajectory of urban development in the contemporary era has engendered a substantial escalation in construction waste generation, particularly in China, where it constitutes approximately 40% of the total solid waste stream. Traditional landfill disposal methodologies pose formidable ecological challenges, encompassing soil contamination, groundwater pollution, and significant greenhouse gas emissions. Furthermore, the unsustainable exploitation of natural sandstone resources undermines energy security and disrupts ecological balance. In response to these pressing issues, an array of scholars and researchers have embarked on an exploratory endeavor to devise innovative strategies for the valorization of construction waste. Among these strategies, the conversion of waste into recycled aggregates has emerged as a particularly promising pathway. However, the practical deployment of recycled aggregates within the construction industry is impeded by their inherent physico-mechanical properties, such as heightened water absorption capacity and diminished compressive strength. To surmount these obstacles, a multitude of enhancement techniques, spanning physical, chemical, and thermal treatments, have been devised and refined. This paper undertakes a comprehensive examination of the historical evolution, recycling methodologies, and enhancement strategies pertinent to recycled aggregates. It critically evaluates the efficacy, cost–benefit analyses, and environmental ramifications of these techniques, while elucidating the microstructural and physicochemical disparities between recycled and natural aggregates. Furthermore, it identifies pivotal research gaps and prospective avenues for future inquiry, underscoring the imperative for collaborative endeavors aimed at developing cost-effective and environmentally benign enhancement techniques that adhere to the stringent standards of contemporary construction practices, thereby addressing the intertwined challenges of waste management and resource scarcity. Full article

Geothermal systems play a crucial role in understanding Earth’s heat dynamics. The Yunkai Uplift in southern China exemplifies a geothermally rich region characterized by ancient lithologies and high heat flow. This study investigates the geochemical characteristics of geothermal waters in the Yunkai Uplift. Both geothermal and non-thermal water samples were collected along the Xinyi–Lianjiang (XL) Fault Zone and the Cenxi–Luchuan (CL) Fault Zone flanking the core of the Yunkai Mountains. Analytical techniques were applied to examine major ions, trace elements, and dissolved CO₂ and H₂, as well as isotopic characteristics of O, H, Sr, C, and He in water samples, allowing for an investigation of geothermal reservoir temperatures, circulation depths, and mixing processes. The findings indicate that most geothermal waters are influenced by water–rock interactions primarily dominated by granites. The region’s diverse lithologies, change from ancient Caledonian granites and medium–high-grade metamorphic rocks in the central hinterland (XL Fault Zone) to low-grade metamorphic rocks and sedimentary rocks in the western margin (CL Fault Zone). The chemical compositions of geothermal waters are influenced through mixing contacts between diverse rocks of varying ages, leading to distinct geochemical characteristics. Notably, δ¹³C_CO2 values reveal that while some samples exhibit significant contributions from metamorphic CO₂ sources, others are characterized by organic CO₂ origins. Regional heat flow results from the upwelling of mantle magma, supplemented by radioactive heat generated from crustal granites. Isotopic evidence from δ²H and δ¹⁸O indicates that the geothermal waters originate from atmospheric sources, recharged by precipitation in the northern Yunkai Mountains. After infiltrating to specific depths, meteoric waters are heated to temperatures ranging from about 76.4 °C to 178.5 °C before ascending through the XL and CL Fault Zones under buoyancy forces. During their upward migration, geothermal waters undergo significant mixing with cold groundwater (54–92%) in shallow strata. As part of the western boundary of the Yunkai Uplift, the CL Fault Zone may extend deeper into the crust or even interact with the upper mantle but exhibits weaker hydrothermal activities than the XL Fault Zone. The XL Fault Zone, however, is enriched with highly heat-generating granites, is subjected more to both the thermal and mechanical influences of upwelling mantle magma, resulting in a higher heat flow and tension effect, and is more conducive to the formation of geothermal waters. Our findings underscore the role of geotectonic processes, lithological variation, and fault zone activity in shaping the genesis and evolution of geothermal waters in the Yunkai Uplift. Full article

Pockmarks are globally distributed geomorphic features exhibiting diverse morphologies. Their geometric characteristics are commonly quantified by the radius-to-depth ratio. The evolutionary process of these features typically follows a cyclical pattern comprising initiation, expansion, stabilization, and decline. Submarine groundwater discharge (SGD), a seasonally modulated land–sea exchange process, exerts a significant influence on the formation and evolution of pockmarks. This influence is mediated through hydrodynamic forcing effects, sediment redistribution, and coupled chemical–biological interactions. This review systematically examines the formation mechanisms, evolutionary patterns, and primary controlling factors of pockmarks induced by SGD. It integrates recent research developments and global case studies to elucidate the dynamic interplay of multiple influencing factors. This study emphasizes the significance of interdisciplinary approaches in marine geological research and identifies key areas for future investigation. These insights aim to enhance risk assessment frameworks for marine hazards and inform marine spatial planning strategies. Full article

Wetland lakes are crucial ecosystems that serve as vital ecosystems that harbor rich biodiversity and provide essential ecological services, particularly in regulating regional water resources, purifying water quality, and maintaining ecological equilibrium. This study aims to conduct an in-depth investigation into the hydrochemical characteristics and their controlling factors during the dry season of the Hengshui Lake wetland system. By collecting water samples from the lake and shallow groundwater, and using water chemistry diagrams, ion ratios, mineral saturation indices, and multivariate statistical methods, the study systematically analyzes the hydrochemical characteristics of Hengshui Lake Wetland and its controlling factors. The results show: there is significant stratified differentiation in the water chemical composition: the lake water is weakly alkaline and fresh, while the shallow groundwater is highly mineralized and saline. Both are dominated by Na⁺, Mg²⁺, SO₄²⁻, and Cl⁻. Significant differences exist in water chemistry types between the lake and shallow groundwater. The lake water exhibits homogenized characteristics with a dominant SO₄·Cl·HCO₃-Na·Mg type, whereas shallow groundwater displays five distinct hydrochemical facies indicative of multi-source recharge processes. Evaporation–rock interaction mechanisms dominate the system, as evidenced by a Gibbs diagram analysis showing evaporation crystallization as the primary control. Ion ratio calculations demonstrate synergistic effects between silicate weathering and evaporite dissolution, while mineral saturation indices confirm cooperative processes involving calcite/dolomite oversaturation and ongoing gypsum dissolution. Cation exchange indexes combined with chloro-alkaline indices reveal unidirectional recharge from lake water to shallow groundwater accompanied by active cationic exchange adsorption. Although the wetland predominantly maintains natural hydrological conditions, elevated γ(NO₃⁻)/γ(Na⁺) ratios in nearshore zones suggest initial agricultural contamination infiltration. This study shows that, as a typical example of a closed wetland, the hydrochemistry evolution of Hengshui Lake during the dry season is primarily dominated by the coupled effects of evaporation and rock–water interaction, with silicate weathering and evaporation rock dissolution as secondary factors, and human activity having a weak influence. The findings provide new insights into the understanding of the hydrochemical evolution process and its controlling factors in closed lakes, offering valuable data support and theoretical basis for the ecological restoration and sustainable management of closed lakes. Full article

Extensive and unregulated groundwater extraction for irrigation in the arid inland basins of Northwest China has led to a continuous increase in groundwater depth in agricultural irrigation areas. This has significantly altered the distribution of soil ions, making it difficult to predict their evolution and dynamic patterns. In this study, we used a space-for-time substitution approach to elucidate the evolution of the soil ion distribution under changing groundwater depths. Experiments were conducted in three typical irrigation areas with varying groundwater depths, that is, below 5 m, 5–10 m, and above 10 m in Korla, Xinjiang, China. Soil samples were collected from five profiles at depths of 0–180 cm to measure the soil moisture, salinity, and major ion content. An innovative research framework was developed to examine the relationship between groundwater depth and soil ion distribution using ion ratios, principal components, hierarchical clustering, and correlation analyses. This framework aims to reveal the dynamics, correlations, and mechanisms of soil moisture, salinity, ion distribution, and representative ion composition as groundwater depth increases in the arid agricultural irrigation areas of Northwest China. The results showed that as groundwater depth increased, the soil chemical type shifted from Ca-SO₄ to Na-SO₄ and mixed types, with an increase in SO₄²⁻ and Na⁺ content in the soil profile. Soil moisture, salinity, sodium adsorption ratio (SAR), and total dissolved solids (TDS) were significantly higher in shallow groundwater than in deep groundwater. Groundwater depth was negatively correlated with soil moisture, salinity, and major cations and anions (K⁺, Na⁺, Ca²⁺, Mg²⁺, Cl⁻, SO₄²⁻, and NO₃⁻). Meanwhile, a positive correlation exists between groundwater depth and CO₃²⁻. The dynamic distribution of soil ions is primarily governed by groundwater depth and is influenced by multiple factors. Evaporation is the dominant factor in shallow groundwater areas, whereas the mineral composition of rocks plays a crucial role in deep groundwater areas. These findings provide scientific support for strategic agricultural water-resource management policies and sustainable development strategies in arid regions. Full article

Understanding the characteristics of groundwater chemistry is essential for water resource development and utilization. However, few studies have focused on the chemical evolution processes of shallow groundwater in typical areas of the Huaibei Plain. We analyzed 28 water samples from the study area using hydrogeochemical mapping, multivariate statistical analysis, and other approaches. The study found that the hydrogeochemical facies of groundwater are mainly HCO₃-Ca·Mg (64.3%), mixed SO₄·Cl-Ca·Mg, and SO₄·Cl-Na. The hydrochemical composition is primarily controlled by natural water–rock interactions, including carbonate weathering and cation exchange processes. Correlation analysis and principal component analysis (PCA) revealed that mineral dissolution was the predominant source of Na⁺, Mg²⁺, Cl⁻, and SO₄²⁻ in shallow groundwater, significantly contributing to total dissolved solids (TDS) accumulation. Hierarchical cluster analysis (HCA) identified three characteristic zones: (1) agricultural/urban-influenced areas, (2) high-F⁻/low-hardness zones, and (3) nitrate-contaminated regions. These findings provide critical insights for assessing the geochemical status of groundwater in the Huaibei Plain and formulating targeted resource management strategies. Full article

Groundwater serves as a vital water source in Zhanjiang City. This study analyzed the chemical components of 35 samples to understand the hydrochemical characteristics and evolution mechanism of groundwater in Zhanjiang City. A comprehensive analysis was conducted using statistical methods, including the use of Piper trilinear diagrams, the Gibbs method, ion ratios, and other techniques, to investigate the sources and control factors of the main ions in groundwater in the area. The findings reveal that all the groundwater is freshwater, with the main cations and anions being Na⁺ and HCO₃⁻, respectively. Shallow water is mainly of the Cl•SO₄ mixed cation type, followed by the HCO₃•ClNa•Ca type. Middle and deep pore water is mainly of the HCO₃Na type, followed by the HCO₃Na•Mg type and HCO₃Na•Ca type. The hydrochemical classifications of pore and fissure water are Cl•HCO₃Mg•Na type and Cl•HCO₃Na type water. The primary hydrogeochemical process is water–rock interaction, particularly the dissolution of silicate minerals. Additionally, evaporation and concentration contribute significantly to the chemical composition of shallow water, and ion exchange is also an important hydrogeochemical process affecting middle and deep pore water. Shallow water commonly contains nitrates, with 37.5% of shallow water showing contamination with NO₃⁻. This study aims to provide insights into the development and utilization of local water resources. Full article

In this study, hydrogeochemistry and environmentally stable isotopes were employed to examine the processes involved in recharging aquifer systems and the changes in the groundwater chemistry caused by the interaction between the water and the aquifer matrix. Based on data derived from 113 groundwater wells, various tools and techniques, including stable environmental isotopes Oxygen-18 and Deuterium (δ¹⁸O and δD) for 33 samples and geochemical modeling with NETPATH, were used to evaluate the recharge mechanism and the evolution of the groundwater, combining GIS with hydrological and hydrochemical methods. The results revealed that groundwater from the Quaternary was the main source for irrigation; the water quality was categorized as relatively fresh to saline, with the total dissolved solids (TDSs) ranging from 261.3 to 8628.56 mg/L, exhibiting an average value of 2311.68 mg/L. The results of the environmental isotope analysis showed that the range of oxygen δ¹⁸O isotopes in the groundwater was from −5.65‰ to +0.39‰, while the range of hydrogen δD isotopes was from −32.60‰ to 4.73‰. Moreover, the δ¹⁸O–δD relationship indicated that the groundwater samples fell around the global meteoric precipitation line, showing a strong relationship, with a coefficient (R²) of approximately 0.82. The NETPATH model revealed that the dissolved chemical species within the groundwater system primarily originated from processes such as mineral weathering and dissolution, ion exchange, and evaporation. Full article

Alkaline lakes are thought to have facilitated prebiotic synthesis reactions on the early Earth because their modern analogs accumulate vital chemical feedstocks such as phosphate through the evaporation of dilute groundwaters. Yet, the conditions required for some building block synthesis reactions are distinct from others, and these conditions are generally incompatible with those permissible for nascent cellular function. However, because current scenarios for prebiotic synthesis have not taken account of the physical processes that drive the chemical evolution of alkaline lakes, the potential for the co-occurrence of both prebiotic synthesis and the origins and early evolution of life in prebiotic alkaline lake environments remains poorly constrained. Here, we investigate the dynamics of active, prebiotically relevant alkaline lakes using near-surface geophysics, aqueous geochemistry, and hydrogeologic modeling. Due to their small size, representative range of chemistry, and contrasting evaporation behavior, the investigated, neighboring Last Chance and Goodenough Lakes in British Columbia, Canada offer a uniquely tractable environment for investigating the dynamics of alkaline lake behavior. The results show that the required, extreme phosphate enrichments in alkaline lake waters demand geomorphologically-driven vulnerability to evaporation, while the resultant contrast between evaporated brines and inflowing groundwaters yields Rayleigh–Taylor instabilities and vigorous surface–subsurface cycling and mixing of lake and groundwaters. These results provide a quantitative basis to reconcile conflicting prebiotic requirements of UV light, salinity, metal concentration, and pH in alkaline lake environments. The complex physical and chemical processing inherent to prebiotic alkaline lake environments thus may have not only facilitated prebiotic reaction networks, but also provided habitable environments for the earliest evolution of life. Full article

The sustainable management of groundwater in the Jimma area is complicated by a lack of comprehensive studies on its chemical makeup and the geochemical processes influencing its hydrochemistry. This research aims to fill that gap by examining 51 groundwater samples from various sources, including deep groundwaters, shallow groundwaters, hand-dug well groundwaters, surface waters, and springs within the area primarily consisting of complex volcanic rocks. The goal is to describe the hydrogeochemical characteristics and determine the key processes affecting groundwater composition in this volcanic area. The study identifies clear patterns in cation and anion concentrations. For deep groundwaters, the average cation concentration is ranked as Na⁺ > Ca²⁺ > Mg²⁺ > K⁺, while shallow groundwaters, hand-dug well groundwaters, surface waters, and springs show a ranking of Ca²⁺ > Na⁺ > Mg²⁺ > K⁺. The major anions are typically ordered as HCO₃⁻ > NO₃⁻ > Cl⁻ > SO₄²⁻. The quantitative hydrogeochemical analysis indicates that the freshwater types in the region are primarily Ca-HCO₃ and Ca-Mg-HCO₃, with some highly mineralized Na-HCO₃ waters also detected. The weathering of silicate minerals mainly drives the geochemical processes affecting groundwater chemistry. An increase in mineralization, suggested by saturation indices, points to a longer residence time underground, with deep groundwaters exhibiting the highest saturation levels and springs the lowest. This mineralization is especially significant for Mg-silicates and carbonates. Stability diagrams for feldspar minerals further demonstrate groundwater evolution along flow paths, revealing that shallow systems are in equilibrium with minerals like gibbsite, whereas deeper systems achieve stability with albite, Ca-montmorillonite, and microcline. Higher CO₂ levels (10^−1.5 to 10^0.5 atm), likely from mantle-magma degassing, add more HCO₃⁻ to the deeper aquifers. This study offers the first thorough characterization of the groundwater composition in the Jimma area and provides important insights into the Jimma area’s hydrogeochemical development, establishing a basis for enhanced groundwater management within this intricate volcanic aquifer system. Full article

With the development of nuclear energy in China, the geological disposal of high-level radioactive waste (HLW) is increasingly receiving national attention. Among them, the study of nuclide migration is an important and complex technical system, which requires continuous in-depth research. Under the decay heat, radiation, and groundwater effects of HLW, buffer materials generate complex coupled thermo-hydro-mechanical-chemical (THMC) processes. The migration and diffusion of nuclides in buffer materials are controlled by the coupling effect of THMC. It is of great significance for the long-term safety of a HLW repository to study the long-term retarding effect of buffer material on nuclide strontium under the coupling effect of multiple factors. This study leverages the solving advantages of COMSOL Multiphysics 5.6, using a combination of the self-developed Mock-up experimental device as a geometric model and numerical simulations to study the multi-field coupling performance and radionuclide migration evolution characteristics of THMC buffer materials, which overcomes the difficulties due to the limitations of the experimental time and spatial scale. The simulation results can predict the migration range and distance variation of strontium in buffer materials at different time scales. In the initial stage, the migration and diffusion of nuclide in buffer materials are relatively slow, and the migration distance increases by about 0.03 m with time. In the mid-to-late stage, the migration distance increases by about 0.05 m over time; to ensure that, in 1000 years, core strontium does not penetrate the buffer material and migrate into the surrounding rock groundwater of the disposal facility, a buffer material thickness of 0.3 m needs to be set. The construction of THMC control equations for the migration and diffusion of nuclides in buffer materials under multi-field coupling conditions has been revealed, providing an important reference for a deeper understanding of the risk analysis of radionuclide contamination in disposal environments. Full article

The Sangu Spring Basin is located in an important economic area, and groundwater is the main source of water for local life and industry. Understanding the sources of chemical components in groundwater is important for the development and utilization of groundwater. In this paper, we analyzed the origin of the chemical components of groundwater and their evolution in the Sangu Spring Basin using statistical analysis, Piper diagrams, Gibbs diagrams, ion ratios, and combined hydrochemistry–isotope analyses. The results show that the groundwater in the Sangu Spring Basin is mainly derived from atmospheric precipitation, that the groundwater in stagnant and confined environment zones was formed under colder climatic conditions, and that the surface water (SW) has a close hydraulic relation with the groundwater. Water–rock interaction is the main factor controlling the composition of groundwater. The compositions of groundwater are mainly derived from carbonate weathering, silicate weathering, and dissolution of gypsum. Na⁺ and K⁺ in groundwater mainly come from the dissolution of albite and potassium feldspar, rather than rock salt. Ion exchange occurs in karst groundwater (KGW) and fissure groundwater (FGW), and ion exchange is dominated by the exchange of Mg²⁺ and Ca²⁺ in the groundwater with Na⁺ and K⁺ in the rock or soil. Sulfate in groundwater is derived from dissolution of gypsum, infiltration of atmospheric precipitation, and leakage of SW. Groundwaters with the highest sulfate content are located in the vicinity of SW, as a result of receiving recharge from SW seepage. Groundwaters with higher sulfate contents are located in the stagnant and deeply buried zones, where sulfate is mainly derived from the dissolution of gypsum. SW seepage recharges groundwater, resulting in increased levels of Cl⁻, NO₃⁻ and SO₄²⁻ in groundwater. These insights can provide assistance in the protection and effective management of groundwater. Full article

Zuogong County is located in the southeast of Tibet, which is rich in hot spring geothermal resources, but its development and utilization degree are low, and the genetic mechanism of the geothermal system is not clear. Hydrogeochemical characteristics of geothermal water are of great significance in elucidating the genesis and evolution of geothermal systems, as well as the sustainable development and utilization of geothermal resources. The hydrogeochemical characteristics and genesis of the geothermal water in Zuogong County were investigated using hydrogeochemical analysis, a stable isotope (δD, δ¹⁸O) approach, and an inverse simulation model for water–rock reactions using the PHREEQC. The results indicated that the Zuogong geothermal system is a deep circulation heating type without a magmatic heat source. The chemical types present in the geothermal water from the Zuogong area are HCO₃ and HCO₃·SO₄, and the main cations are Na⁺ and Ca²⁺. The groundwater is replenished by atmospheric precipitation and glacier meltwater. The salt content of geothermal water mainly comes from the interaction between water and surrounding rocks during the deep circulation process. The reservoir temperature of geothermal water in Zuogong is 120–176 °C before mixing with non-geothermal water and drops to 62–98 °C after mixing with 58 to 79% of non-geothermal water. According to the proposed conceptual model, geothermal water mainly produces water–rock interaction with aluminosilicate minerals in the deep formation, while in shallow areas it interacts mainly with sulfate minerals. These findings contribute to a better understanding of the geothermal system in Zuogong County, Tibet. Full article