Search Results (57)

The impacts of the solar eclipse that occurred on 8 April 2024 over the United States on various atmospheric parameters are investigated. We analyzed surface and vertical profiles of temperature and humidity to understand how this eclipse affected the atmosphere from the ground to the stratosphere. Our findings show a significant response throughout the atmospheric range. The eclipse caused a decrease in shortwave radiation, leading to cooler Earth surfaces and a subsequent drop in surface temperature. This cooling effect also resulted in high relative humidity and lower wind speeds at the surface. Furthermore, GPS radio occultation data from COSMIC-2 revealed a decrease in tropospheric temperature and increase in stratospheric temperature during the eclipse. We also observed a reduction in both the temperature and height of the tropopause. The uniqueness of the present investigations lies in delineating the solar eclipse’s effects on the land and ocean. Our analysis indicates that land regions experienced a more pronounced temperature change compared to ocean regions. Full article

The rotational spectra of xanthene and its oxidation product xanthone were investigated by combining quantum chemical calculations with Fourier transform microwave spectroscopy in a jet-cooled environment. Xanthone was unexpectedly generated in the experiment when water was present in the reservoir of xanthene leading to the total disappearance of xanthene after few hours. Structurally, xanthone shows a near planar disposition, whereas xanthene exhibits a non-planar geometry with both benzene rings twisted out of the molecular plane. This geometry enables an inversion motion between two equivalent conformers, giving rise to a splitting in the ground vibrational state. A two-state analysis of the vibration–rotation interaction for the $v=0$ and $v=1$ states gives an energy separation between these states (inversion splitting) of $\Delta E_{01}=4689.7095\left(10\right)\mathrm{MHz}$. This large-amplitude motion leads to vibration–rotation coupling of energy levels. A symmetric double-minimum inversion potential function was determined, resulting in a barrier of about 45 cm⁻¹ in good agreement with that obtained by DFT quantum chemical calculations. Full article

The Autler–Townes (AT) doublet, a fundamental manifestation of quantum interference effects, serves as a critical tool for studying the dynamic behavior of Rydberg atoms. Here, we investigate the asymmetry of the Autler–Townes (AT) doublet in the trap-loss fluorescence spectroscopy (TLFS) of cesium (Cs) atoms confined in a magneto-optical trap (MOT) with single-step Rydberg excitation using a 319-nm ultraviolet (UV) laser. A V-type three-level system involving the ground state $6{\mathrm{S}}_{1/2}$ (F = 4), excited state $6{\mathrm{P}}_{3/2}$ (${\mathrm{F}}^{\prime }$ = 5), and Rydberg state ($n{\mathrm{P}}_{3/2}$ (${\mathrm{m}}_{\mathrm{J}}$ = +3/2)) is theoretically modeled to analyze the nonlinear dependence of the AT doublet’s asymmetry and interval on the cooling laser’s detuning. Experiments reveal that as the cooling laser detuning ${\mathsf{\Delta }}_1$ decreases from −15 MHz to −10 MHz, the AT doublet exhibits increasing symmetry, while its interval shows a nonlinear decrease. Theoretical simulations based on the density matrix equation and Lindblad master equation align closely with experimental data, confirming the model’s validity. This study provides insights into quantum interference dynamics in multi-level systems and offers a systematic approach for optimizing precision measurements in cold atom spectroscopy. Full article

With ambitious targets set by the EU for the reduction of emissions from the energy sector by 2030, there is a need to design and develop more building projects using renewable energy sources. Even though in Europe, heating and cooling share from renewable resources is increasing, and in 2021, the total share in this sector in Croatia was at 38%, the share of heat production by heat pumps is rather low. One possibility to increase this share is to install energy piles when constructing a building, which is becoming an increasingly common practice. This case study focuses on such a system designed for a large, non-residential building in Zagreb, Croatia. The complex was designed as 13 separate dilatations, with central heating and cooling of all facilities, covered by 260 energy piles (130 pairs in serial connection), with a length of the polyethylene pipe of 20 m in a double loop inserted within the pile. The thermo-technical system was designed as a bivalent parallel system, with natural gas covering peak heating loads and a dry cooler covering cooling peak loads when the loads cannot be covered only by ground-source heat pumps. In the parallel bivalent system, the geothermal source will work with a much higher number of working hours at full load than is the case for geothermal systems that are dimensioned to peak consumption. Therefore, the thermal response test was conducted on two energy piles, connected in series, to obtain thermogeological parameters and determine the heat extraction and rejection rates. The established steady-state heat rate defines the long-term ability to extract heat energy during constant thermal load, with the inlet water temperature from the pile completely stabilized, i.e., no significant further sub-cooling is achieved in the function of the geothermal field operation time. Considering the heating and cooling loads of the building, modeling of the system was performed in such a manner that it utilized renewable energy as much as possible by finding a bivalent point where the geothermal system works efficiently. It was concluded that the optimal use of the geothermal field covers total heating needs and 70% for cooling, with dry coolers covering the remaining 30%. Additionally, based on the measured thermogeological parameters, simulations of the thermal response test were conducted to determine heat extraction and rejection rates for energy piles with various geometrical parameters of the heat exchanger pipe and fluid flow variations. Full article

For the deconfinement phase of an SU(2) Yang–Mills theory, we compute the axion mass $m_A$ by appealing to the Veneziano–Witten formula. The topological susceptibility $\chi$ arises (i) from a precisely computable thermal ground-state contribution due to a center of a relevant (anti)caloron, and (ii) from contributions due to free thermal quasi-particles in the effective theory. Both (i) and (ii) are derived by using standard Euclidean thermal field theory techniques. While contribution (i) is positive and $\propto T^4$, contribution (ii) is negative, as demanded by reflection positivity, but negligible compared to contribution (i). As a consequence, practically from the critical temperature $T_c$ onward, a real-valued axion mass $m_A\left(T\right)=\sqrt{{\displaystyle \frac{2}{3}}}\pi {\displaystyle \frac{T^2}{M_P}}$ emerges when the Peccei–Quinn scale is assumed to be the Planck mass $M_P$, independently of the Yang–Mills scale that the axion associates with. We discuss why our results deviate from those found in the dilute instanton gas and interacting instanton liquid approximations, and from results obtained in lattice simulations. Assuming the universe is dark sector to be based on such ultralight axion species, which are nonrelativistic for $T\ll M_P$, we investigate the cosmological conditions for their global Bose condensation as the very early universe cooled to temperatures of the order of ${10}^9$eV. Full article

The utilization of atomic or molecular spectroscopy for frequency locking of single-frequency laser to improve laser frequency stability plays an important role in the experimental investigation of optically pumped atomic magnetometers, atomic clocks, laser cooling and trapping of atoms, etc. We have experimentally demonstrated a technique for frequency stabilization of a single-frequency laser employing the bright state spectroscopy (BSS) with a rubidium atomic vapor cell. By utilizing the counter-propagating dual-frequency 795 nm laser beams with mutually orthogonal linear polarization and a frequency difference of 6.834 GHz, which is equal to the hyperfine splitting of rubidium-87 ground state 5$S_{1/2}$, an absorption-enhanced signal with narrow linewidth at the center of Doppler-broadened transmission spectroscopy is observed when continuous scanning the laser frequency over rubidium-87 D1 transition. This is the so-called BSS. Amplitude of the absorption-enhanced signal in the BSS is much larger compared with the conventional saturation absorption spectroscopy (SAS). The relationship between linewidth and amplitude of the BSS signal and laser beam intensity has been investigated. This high-contrast absorption-enhanced BSS signal has been employed for the laser frequency stabilization. The experimental results show that the frequency stability is $4.4\times {10}^{-11}$ with an integration time of 40 s, near one order of magnitude better than that for using the SAS. Full article

The cooling of a macroscopic mechanical oscillator to its quantum ground state is an important step for achieving coherent control over mechanical quantum states. Here, we theoretically study the cooling of a rotating mirror in a Laguerre–Gaussian (L-G) cavity optorotational system with a nonlinear cross-Kerr (CK) interaction. We discuss the effects of the nonlinear CK coupling strength, the cavity detuning, the power of the input Gaussian beam, the topological charge (TC) of the L-G cavity mode, the mass of the rotating mirror, and the cavity length on the cooling of the rotating mirror. We find that it is only possible to realize the improvement in the cooling of the rotating mirror by the nonlinear CK interaction when the cavity detuning is less than the mechanical frequency. Compared to the case without the nonlinear CK interaction, we find that the cooling of the rotating mirror can be improved by the nonlinear CK interaction at lower laser powers, smaller TCs of the L-G cavity mode, larger masses of a rotating mirror, and longer optorotational cavities. We show that the cooling of the rotating mirror can be enhanced by the nonlinear CK interaction by a factor of about 23.3 compared to that without the nonlinear CK interaction. Full article

The magnetic properties, band structure results, and magnetocaloric effect of GdCo_1.8M_0.2 with M = Fe, Mn, Cu, and Al are reported. The band structure calculations demonstrate that all the samples have a ferrimagnetically ordered ground state, in perfect agreement with the magnetic measurements. Calculated magnetic moments and variation with the alloy composition are strongly influenced by hybridisation mechanisms as sustained by an analysis of the orbital projected local density of states. The XPS measurements reveal no significant shift in the binding energy of the investigated Co core levels with a change in the dopant element. The Co 3s core-level spectra gave us direct evidence of the local magnetic moments on Co sites and an average magnetic moment of 1.3 µ_B/atom was found, being in good agreement with the theoretical estimation and magnetic measurements. From the Mn 3s core-level spectra, a value of 2.1 µ_B/Mn was obtained. The symmetric shapes of magnetic entropy changes, the Arrott plots, and the temperature dependence of Landau coefficients clearly indicate a second-order phase transition. The relative cooling power, RCP(S), normalized relative cooling power, RCP(∆S)/∆B, and temperature-averaged entropy change values indicate that these compounds could be promising candidates for applications in magnetic refrigeration devices. Full article

Geothermal energy piles or ground heat exchange (GHE) systems embrace a sustainable source of energy that utilizes the geothermal energy naturally found inside the ground in order to heat and/or cool buildings. GHE is a highly innovative system that consists of energy loops within foundation elements (shallow foundations or piles) through which a heat carrier fluid circulates, enabling heat extraction or storage in the ground. Despite the innovation and potential of GHE systems, there are significant challenges in harmonizing their thermal and mechanical designs due to the complex interactions involved. This review critically examines state-of-the-art design methodologies developed to address these complexities, providing insights into the most recent advancements in GHE performance and design. Key findings include innovative techniques such as advanced numerical modeling to predict thermomechanical behavior, the use of different pipe configurations to optimize heat transfer, and strategies to minimize thermal stress on the foundation. Additionally, this review identifies research gaps, including the need for more comprehensive full-scale experimental validations, the impact of soil properties on system performance, and the long-term effects of thermal cycling on pile integrity. These insights aim to contribute to a better understanding of the thermomechanical behavior of energy piles, ultimately facilitating more accurate and effective design solutions. Full article

The Kingdom of Saudi Arabia is experiencing a surge in electricity demand, with power generation increasing 4 times in 25 years from 1990 to 2014. Despite the abundant primary renewable energy sources, the country has overlooked them in the past in national energy policies. However, in recent years, renewable energy has become a part of the Kingdom of Saudi Arabia’s energy conservation policy due to climate changes, technological progress, economies of scale, and increased competitiveness in supply chains. The Saudi government has created the King Abdullah City for Atomic and Renewable Energy (KACARE) to develop national strategies for effectively utilizing renewable and nuclear energy. This paper reviews the current state of the art of the renewable energy technologies available on the market and evaluates the installation of renewable energy plants near Saudi Arabia’s East Coast for a new town, focusing on technical rather than economic aspects. The paper provides a wide review of the possible technical solutions to exploit the producibility of different renewable sources, considering the challenging climate conditions typical of desert areas. The analysis of a real case study shows a high availability of wind and solar irradiance that allow a net energy production of 354 and 129 GWh, respectively. In addition, the comparison between a typical ground-mounted photovoltaic (PV) system and an emerging floating PV reveals that for the same installed power, occupied area, and environmental conditions, the latter has a 4% greater performance ratio due to the cooling effect of water. Full article

Thin films of carbazole (Cz) derivatives are frequently used in organic electronics, such as organic light-emitting diodes (OLEDs). Because of the proximity of the Cz units, the excited-state relaxation in such films is complicated, as intermolecular pathways, such as singlet–singlet annihilation (SSA), kinetically compete with the emission. Here, we provide an investigation of two benchmark systems employing neat carbazole and 3,6-di-tert-butylcarbazole (t-Bu-Cz) films and also their thin film blends with poly(methyl methacrylate) (PMMA). These are investigated by a combination of atomic force microscopy (AFM), femtosecond and nanosecond transient absorption spectroscopy (fs-TA and ns-TA) and time-resolved fluorescence. Excitonic J-aggregate-type features are observed in the steady-state absorption and emission spectra of the neat films. The S₁ state shows a broad excited-state absorption (ESA) spanning the entire UV–Vis–NIR range. At high S₁ exciton number densities of about 4 × 10¹⁸ cm⁻³, bimolecular diffusive S₁–S₁ annihilation is found to be the dominant SSA process in the neat films with a rate constant in the range of 1–2 × 10⁻⁸ cm³ s⁻¹. SSA produces highly vibrationally excited molecules in the electronic ground state (S₀*), which cool down slowly by heat transfer to the quartz substrate. The results provide relevant photophysical insight for a better microscopic understanding of carbazole relaxation in thin-film environments. Full article

The UK government has announced its ten-point plan to annually install 600,000 low-carbon heat pumps by 2028. However, there is a lack of evidence showing potential overheating risk in dwellings retrofitted with heat pumps. This paper examines the prevalence and magnitude of summertime overheating across 24 naturally ventilated social housing dwellings retrofitted with ground source heat pumps (GSHPs). The dwellings are located in a socially deprived area in Oxford (UK). The empirical study included longitudinal monitoring of indoor temperatures in the living rooms and bedrooms during the non-heating seasons of 2021 and 2022 (May–September), which included a record-breaking heatwave in July 2022. Indoor temperature and CO₂ levels in bedrooms were monitored across a subset of six dwellings alongside the monitoring of window opening state in three bedrooms to understand the effect of natural ventilation in removing excess heat. About 136 thermal comfort surveys were conducted to ascertain the subjective responses of residents. Overheating risk assessment was carried out using CIBSE static and adaptive methods, which revealed that summertime overheating was prevalent across half of the dwellings in the non-heating season of 2022, as compared to 17% overheated dwellings in 2021. Bungalows with upgraded cavity wall insulation and top floor flats facing south and south-west had a propensity to overheat. The variation in indoor temperature and CO₂ levels across a small sample also indicated the relationship between overheating and residents’ behaviour. Given that the majority of the dwellings were occupied by retired elderly people with low incomes who are vulnerable to heat and cannot afford active forms of cooling, it is vital to deploy passive design measures, such as appropriate shading devices that are suitable for a heating-dominated climate and enhanced ventilation, as part of home energy retrofits. Implementing reversible heat pumps coupled with solar PVs can provide cooling during heatwaves while delivering low-carbon heat in the winter. Full article

For the realization of an optical nuclear clock, the first isomeric excited state of thorium-229 (^229mTh) is currently the only candidate due to its exceptionally low-lying excitation energy ($8.338\pm 0.024$ eV). Such a nuclear clock holds promise not only to be a very precise metrological device but also to extend the knowledge of fundamental physics studies, such as dark matter research or variations in fundamental constants. Considerable progress was achieved in recent years in characterizing ^229mTh from its first direct identification in 2016 to the only recent observation of the long-sought-after radiative decay channel. So far, nuclear resonance as the crucial parameter of a nuclear frequency standard has not yet been determined with laser-spectroscopic precision. To determine another yet unknown basic property of the thorium isomer and to further specify the linewidth of its ground-state transition, a measurement of the ionic lifetime of the isomer is in preparation. Theory and experimental investigations predict the lifetime to be 10³–10⁴ s. To precisely target this property using hyperfine structure spectroscopy, an experimental setup is currently being commissioned at LMU Munich. It is based on a cryogenic Paul trap providing long-enough storage times for ^229mTh ions, that will be sympathetically cooled with ⁸⁸Sr⁺. This article presents a concept for an ionic lifetime measurement and discusses the laser-optical part of a setup specifically developed for this purpose. Full article

The ortho-isomer 2-furfural (2-FF), which is a primary atmospheric pollutant produced from biomass combustion, is also involved in oxidation processes leading to the formation of secondary organic aerosols. Its contribution to radiative forcing remains poorly understood. Thus, monitoring 2-FF directly in the atmosphere or in atmospheric simulation chambers to characterize its reactivity is merited. The present study reports an extensive jet-cooled rovibrational study of trans and cis conformers of 2-FF in the mid-IR region using two complementary setups: a continuous supersonic jet coupled to a high-resolution Fourier transform spectrometer on the IR beamline of the SOLEIL synchrotron (JET-AILES), and a pulsed jet coupled to a mid-IR tunable quantum cascade laser spectrometer (SPIRALES). Firstly, jet-cooled spectra recorded at rotational temperatures ranging between 20 and 50 K were exploited to derive reliable excited-state molecular parameters of trans- and cis-2-FF vibrational bands in the fingerprint region. The parameters were obtained from global fits of 11,376 and 3355 lines distributed over eight and three vibrational states (including the ground state), respectively, with a root mean square of 12 MHz. In a second step, the middle resolution spectrum of 2-FF recorded at 298.15 K and available in the HITRAN database was reconstructed by extrapolating the data derived from our low-temperature high-resolution analyses to determine the cross sections of each vibrational band of both 2-FF conformers in the 700–1800 $\mathrm{c}$$\mathrm{m}$⁻¹ region. Finally, we clearly demonstrated that the contribution of hot bands observed in the room temperature 2-FF spectrum, estimated between 40 and 63% of the fundamental band, must be imperatively introduced in our simulation to correctly reproduce the HITRAN vibrational cross sections of 2-FF with a deviation smaller than 10%. Full article

We present a systematic study of the structural and magnetic properties of a series of powder samples of SrYb${}_{2-x}$Er${}_x$O${}_4$ with different Yb/Er concentrations. Magnetometry and neutron diffraction have been used to study the magnetic ground states of the compound series, while inelastic neutron scattering was used to investigate the crystal field excitations for a chosen concentration. These results show that the crystal structure remains the same for all compositions, while the lattice parameters increase linearly with the Er content. All compounds showed some type of magnetic transition below 1 K, however, both the magnetic structure and nature of the phase transition vary throughout the series. The samples present a non-collinear magnetic structure with the moments lying on the ab plane for low Er content. For high Er content, the magnetic structure is collinear with the moments aligned along the c-axis. A critical concentration is found where there is a bifurcation between zero-field and field-cooled magnetic susceptibility. This irreversible process could be due to the random mixture of single-ion magnetic anisotropies. Full article