Search Results (250)

The maritime sector’s transition to sustainable energy is critical for achieving global carbon neutrality, with container terminals representing a key focus due to their high energy consumption and emissions. This study explores the potential of hydrogen energy as a decarbonization solution for port operations, using the Chuanshan Port Area of Ningbo Zhoushan Port (CPANZP) as a case study. Through a comprehensive analysis of hydrogen production, storage, refueling, and consumption technologies, we demonstrate the feasibility and benefits of integrating hydrogen systems into port infrastructure. Our findings highlight the successful deployment of a hybrid “wind-solar-hydrogen-storage” energy system at CPANZP, which achieves 49.67% renewable energy contribution and an annual reduction of 22,000 tons in carbon emissions. Key advancements include alkaline water electrolysis with 64.48% efficiency, multi-tier hydrogen storage systems, and fuel cell applications for vehicles and power generation. Despite these achievements, challenges such as high production costs, infrastructure scalability, and data integration gaps persist. The study underscores the importance of policy support, technological innovation, and international collaboration to overcome these barriers and accelerate the adoption of hydrogen energy in ports worldwide. This research provides actionable insights for port operators and policymakers aiming to balance operational efficiency with sustainability goals. Full article

The demand for anion exchange membranes (AEMs) is growing due to their applications in water electrolysis, CO₂ reduction conversion and fuel cells, as well as water treatment, driven by the increasing energy demand and the need for a sustainable future. However, current AEMs still face challenges, such as insufficient permeability and stability in strongly acidic or alkaline media, which limit their durability and the sustainability of membrane fabrication. In this study, polyvinyl alcohol (PVA) and chitosan (CS) biopolymers are selected for membrane preparation. Zinc oxide (ZnO) and porous organic polymer (POP) nanoparticles are also introduced within the PVA-CS polymer blends to make mixed-matrix membranes (MMMs) with increased OH⁻ transport sites. The membranes are characterized based on typical properties for AEM applications, such as thickness, water uptake, KOH uptake, Cl⁻ and OH⁻ permeability and ion exchange capacity (IEC). The OH⁻ transport of the PVA-CS blend is increased by at least 94.2% compared with commercial membranes. The incorporation of non-porous ZnO and porous POP nanoparticles into the polymer blend does not compromise the OH⁻ transport properties. On the contrary, ZnO nanoparticles enhance the membrane’s water retention capacity, provide basic surface sites that facilitate hydroxide ion conduction and reinforce the mechanical and thermal stability. In parallel, POPs introduce a highly porous architecture that increases the internal surface area and promotes the formation of continuous hydrated pathways, essential to efficient OH⁻ mobility. Furthermore, the presence of POPs also contributes to reinforcing the mechanical integrity of the membrane. Thus, PVA-CS bio-based membranes are a promising alternative to conventional ion exchange membranes for various applications. Full article

The aim of this study is to provide a comprehensive analysis of the outcome of two separate techno-economic studies that were conducted for the scaled-up and industrially relevant processes of a) synthetic natural gas (SNG) production from captured (cement-based) CO₂ and green-H₂ (via renewable-assisted electrolysis) and b) combined electricity and crude biofuel production through the integration of biomass pyrolysis, gasification, and solid oxide fuel cells. As was found, the SNG production process seems more feasible from an economic perspective as it can be comparable to current market values. Full article

This study presents preliminary findings from an experimental campaign conducted on a pilot-scale green hydrogen production plant powered by a photovoltaic (PV) system. The integrated setup, implemented at the University “Mediterranea” of Reggio Calabria, includes renewable energy generation, hydrogen production via electrolysis, on-site storage, and reconversion through fuel cells. The investigation assessed system performance under different configurations (on-grid and selective stand-alone modes), focusing on key operational phases such as inerting, purging, pressurization, hydrogen generation, and depressurization. Results indicate a strong linear correlation between the electrolyser’s power setpoint and the pressure rise rate, with a maximum gradient of 0.236 bar/min observed at 75% power input. The system demonstrated robust and stable operation, efficient control of shutdown sequences, and effective integration with PV input. These outcomes support the technical feasibility of small-scale hydrogen systems driven by renewables and offer valuable reference data for calibration models and future optimization strategies. Full article

The increase in power generation facilities from nonprogrammable renewable sources is posing several challenges for the management of electrical systems, due to phenomena such as congestion and reverse power flows. In mitigating these phenomena, Power-to-Gas plants can make an important contribution. In this paper, a linear optimisation study is presented for the sizing of a Power-to-Hydrogen plant consisting of a PEM electrolyser, a hydrogen storage system composed of multiple compressed hydrogen tanks, and a fuel cell for the eventual reconversion of hydrogen to electricity. The plant was sized with the objective of minimising reverse power flows in a medium-voltage distribution network characterised by a high presence of photovoltaic systems, considering economic aspects such as investment costs and the revenue obtainable from the sale of hydrogen and excess energy generated by the photovoltaic systems. The study also assessed the impact that the electrolysis plant has on the power grid in terms of power losses. The results obtained showed that by installing a 737 kW electrolyser, the annual reverse power flows are reduced by 81.61%, while also reducing losses in the transformer and feeders supplying the ring network in question by 17.32% and 29.25%, respectively, on the day with the highest reverse power flows. Full article

This work addresses for the first time the effect of anode serpentine channel depth on Methanol Electrolysis Cells (MECs) and Direct Methanol Fuel Cells (DMFCs) for improving performance of both devices. Anode plates with serpentine flow fields of 0.5 mm, 1.0 mm and 1.5 mm depths are designed and tested in single-cells to compare their behaviour. Performance was evaluated through methanol crossover, polarization and power density curves. Results suggest shallower channels enhance mass transfer efficiency reducing MEC energy consumption for hydrogen production at 40 mA∙cm⁻² by 4.2%, but increasing methanol crossover by 30.3%. The findings of this study indicate 1.0 mm is the best depth among those studied for a MEC with 16 cm² of active area, while 0.5 mm is the best for a DMFC with the same area with an increase in peak power density of 14.2%. The difference in results for both devices is attributed to higher CO₂ production in the MEC due to its higher current density operation. This increased CO₂ production alters anode two-phase flow, partially hindering the methanol oxidation reaction with shallower channels. These findings underscore the critical role of channel depth in the efficiency of both MEC and DMFC single-cells. Full article

This study presents the design and techno-economic comparison of two standalone photovoltaic (PV) systems, each supplying a 1 kW critical load with 100% reliability under Cairo’s climatic conditions. These systems are modeled for both the constant and the night load scenarios, accounting for the worst-case weather conditions involving 3.5 consecutive cloudy days. The primary comparison focuses on traditional lead-acid battery storage versus green hydrogen storage via electrolysis, compression, and fuel cell reconversion. Both the configurations are simulated using a Python-based tool that calculates hourly energy balance, component sizing, and economic performance over a 21-year project lifetime. The results show that the PV/H₂ system significantly outperforms the PV/lead-acid battery system in both the cost and the reliability. For the constant load, the Levelized Cost of Electricity (LCOE) drops from 0.52 USD/kWh to 0.23 USD/kWh (a 56% reduction), and the payback period is shortened from 16 to 7 years. For the night load, the LCOE improves from 0.67 to 0.36 USD/kWh (a 46% reduction). A supplementary cost analysis using lithium-ion batteries was also conducted. While Li-ion improves the economics compared to lead-acid (LCOE of 0.41 USD/kWh for the constant load and 0.49 USD/kWh for the night load), this represents a 21% and a 27% reduction, respectively. However, the green hydrogen system remains the most cost-effective and scalable storage solution for achieving 100% reliability in critical off-grid applications. These findings highlight the potential of green hydrogen as a sustainable and economically viable energy storage pathway, capable of reducing energy costs while ensuring long-term resilience. Full article

Microbial electrochemical technologies (METs), such as microbial fuel cells (MFCs) and microbial electrolysis cells (MECs), show promise for sustainable energy generation from biomass waste and wastewater. However, further work is necessary for their practical use. In particular, it has been argued that process performances, such as those for organics removal and energy generation, should be substantially improved to catch up with those of existing processes, such as anaerobic digesters. Recent work has reported that bioaugmentation (BA) with electroactive microbes (EAMs) can significantly improve the performance of MFCs and MECs, while previous reports have also documented BA cases with limited impacts. In this article, after summarizing EAMs that have been isolated and characterized as possible BA agents, we comparatively analyze past BA trials for MET processes. Based on the information thus obtained, key factors that should be considered for successful BA are suggested. Full article

Fuel cell electric vehicles (FCEVs) offer a promising solution for energy saving and emission reduction in transportation. However, several challenges must be addressed for their application. This study conducts a full life cycle assessment (LCA) of FCEVs, dividing it into the fuel cycle and vehicle cycle to separately assess energy consumption (EC) and emissions. The fuel cycle examined 18 hydrogen production–storage–transport pathways, while the vehicle cycle evaluates energy use and emissions associated with vehicle component production, assembly, disposal, battery production, and fluid consumption. Based on the GREET database, total energy consumption and emissions over a lifetime were calculated. Five environmental impact indicators were used for evaluation, and a comprehensive environmental assessment (CEA) indicator was established for different scenarios. Results indicate that nuclear thermochemical water splitting is the best hydrogen production method, and pipeline transportation is the most efficient for hydrogen transport. Additionally, water electrolysis for hydrogen production is only practical when paired with renewable energy. The study also identified that the Hydrogen production method, “Body”, “Proton Exchange Membrane Fuel Cells (PEMFCs) System”, “Chassis”, “Hydrogen Storage System” and lifetime significantly impact energy consumption and emissions. These stages or products represent high-impact leverage points for enhancing the lifecycle sustainability evaluation of FCEVs. Full article

An electrochemical reactions coupled multi-physics model is developed and applied to elucidate overall performance and thermal stress distributed in solid oxide electrolysis cells (SOECs) with graded fuel electrodes. Extending the conventional fuel electrode, the effects of various graded parameters are investigated and discussed in terms of porosity, pore size, and material composition, with the goal of identifying characteristics of the hydrogen production rate and maximum thermal stress. The results show that the application of the graded parameters is able to optimize the gas distribution and to improve reaction kinetics, avoiding local overheating. The generated hydrogen molar fraction is enhanced by 15.6% while the maximum thermal stress is decreased by 5.0% if the graded parameters are applied, while changing the material composition may increase the thermal stress under the same circumstances. These explorations elucidate the complex role of the graded fuel electrodes on the electrolysis and thermomechanical properties of SOECs. Full article

Interest in hydrogen is rapidly growing due to rising greenhouse gas emissions and the depletion of fossil fuel reserves. Additive manufacturing (AM) is extensively employed to produce high-quality components, with a strong focus on enhancing mechanical properties. The efficiency and cost-effectiveness of AM have further increased interest in its application to manufacturing components capable of withstanding demanding conditions, such as those encountered in hydrogen technology. In this study, 316L stainless steel specimens were fabricated using AM via the selective laser melting (SLM) technique. The specimens then underwent various post-processing heat treatments (PPHT). A subset of these specimens, measuring 50 × 50 × 3 mm³, was tested as electrodes in a water electrolysis cell for oxyhydrogen (HHO) gas production. The HHO gas flow rate and electrolyzer efficiency were evaluated at 60 °C under varying currents. The remaining AM specimens were evaluated for their susceptibility to hydrogen embrittlement under various hydrogen storage conditions, including testing at both room and cryogenic temperatures. Tensile and Charpy impact specimens were fabricated and tested before and after hydrogen charging. The fracture surfaces were analyzed using scanning electron microscopy (SEM) to assess the influence of hydrogen on fracture characteristics. Additionally, as-rolled stainless-steel specimens were examined for comparison with AM and PPHT 316L stainless steel. The primary objective of this study is to determine the most efficient alloy processing condition for optimal performance in each application. Results indicate that PPHT 316L stainless steel exhibits superior performance both as electrodes for HHO gas production and as a material for hydrogen storage vessels, demonstrating high resistance to hydrogen embrittlement. Full article

This review paper presents an overview of fuel cell electrochemical systems that can be used for clean large-scale power generation and energy storage as global energy concerns regarding emissions and greenhouse gases escalate. The fundamental thermochemical and operational principles of fuel cell power generation and electrolyzer technologies are discussed with a focus on high-temperature solid oxide fuel cells (SOFCs) and solid oxide electrolysis cells (SOECs) that are best suited for grid scale energy generation. SOFCs and SOECs share similar promising characteristics and have the potential to revolutionize energy conversion and storage due to improved energy efficiency and reduced carbon emissions. Electrochemical and thermodynamic foundations are presented while exploring energy conversion mechanisms, electric parameters, and efficiency in comparison with conventional power generation systems. Methods of converting hydrocarbon fuels to chemicals that can serve as fuel cell fuels are also presented. Key fuel cell challenges are also discussed, including degradation, thermal cycling, and long-term stability. The latest advancements, including in materials selection research, design, and manufacturing methods, are also presented, as they are essential for unlocking the full potential of these technologies and achieving a sustainable, near zero-emission energy future. Full article

The solid oxide electrolysis cell (SOEC) has potential application value in water electrolysis for hydrogen production. Here, we propose an integrated multi-scale optimization framework for the SOEC, addressing critical challenges in microstructure–property correlation and thermo-mechanical reliability. By establishing quantitative relationships between fuel support layer thickness, air electrode rib coverage, and Ni-YSZ volume ratio, we reveal their nonlinear coupling effects on the hydrogen production rate and thermal stress. The results show that when the fuel support layer thickness increases, the maximum principal stress of the fuel electrode decreases, and the hydrogen production rate and diffusion flux first increase and then decrease. The performance is optimal when the fuel support layer thickness is 5.4 mm. As the rib area decreases, the hydrogen production rate and thermal stress gradually decrease, but the oxygen concentration distribution becomes more uniform when the rib area portion is 42%. When the Ni volume fraction increases, the hydrogen production rate and the maximum principal stress gradually increase, but the uniformity of H₂O flow decreases. When the Ni volume fraction is lower than 50%, the uniformity of H₂O flow drops to 20%. As the volume fraction of nickel (Ni) increases, the fuel utilization gradually increases. When the volume fraction of Ni is between 50% and 60%, the fuel utilization reaches the range of 60–80%. This study indicates that the fuel support layer thickness, rib area, and Ni-YSZ ratio have different effects on the overall performance of the SOEC, providing guidance for the optimization of the flat-tube SOEC structure. Full article

Electro-fermentation (EF) is an emerging bioprocess with the ability to regulate the metabolism of electrochemically active microorganisms. In various fermentation processes, electrodes perform either as an electron acceptor or donor, facilitating the formation and movement of electrons and protons. The bioelectric activity created by external electrodes enhances the metabolic reactions, resulting in a higher yield of value-added chemicals. The conventional fermentation process has a number of limitations in terms of usability and economic feasibility, whereas electro-fermentation presents a hybrid technology, minimizing redox instabilities and enhancing the metabolic process in general to achieve increased product production and a higher biomass yield. Electrochemically active microorganisms such as Geobacter and Shewanella species can carry out the exchange of electrons with electrodes directly or indirectly by using electron mediators. Furthermore, the integration of microbial fuel cells (MFCs) with microbial electrolysis cells (MECs) precludes the need for external manipulation of the fermentation system as the required change in electrochemical gradient is provided by the MFC counterpart. The major beneficial aspects of electro-fermentation include its role as a potential tool for enhancing the production of value-added compounds. The mixed-culture system clearly had a favorable impact on the synthesis of butyric acid from rice straw. Furthermore, cathodic electro-fermentation (CEF) exhibited benefits over anaerobic fermentation, influencing NADH/NAD⁺, enabling a higher product titer, and reducing the accumulation of byproducts. Hence, in this review, we emphasize the importance of electro-fermentation over conventional fermentation for biofuel and biochemical production, covering its fundamentals, interactions, types, future challenges, and ability to provide several benefits to boost the fermentation process, such as the process efficiency and product yield, on an industrial scale. Full article

Additive manufacturing (AM) technologies have witnessed remarkable advancements, offering opportunities to produce complex components across various industries. This paper explores the potential of AM for fabricating bipolar plates (BPPs) in fuel cell or electrolysis cell applications. BPPs play a critical role in the performance and efficiency of such cells, and conventional manufacturing methods often face limitations, particularly concerning the complexity and customization of geometries. The focus here lies in two specific AM methods: the laser powder bed fusion of metals (PBF-LB/M) and material extrusion of metals (MEX/M). PBF-LB/M, tailored for high-performance applications, enables the creation of highly complex geometries, albeit at increased costs. On the other hand, MEX/M excels in rapid prototyping, facilitating the swift production of diverse geometries for real-world testing. This approach can facilitate the evaluation of geometries suitable for mass production via sinter-based manufacturing processes. The geometric deviations of different BPPs were identified by evaluating 3D scans. The PBF-LB/M method is more suitable for small features, while the MEX/M method has lower deviations for geometrically less complex BPPs. Through this investigation, the limits of the capabilities of these AM methods became clear, knowledge that can potentially enhance the design and production of BPPs, revolutionizing the energy conversion and storage landscape and contributing to the design of additive manufacturing technologies. Full article