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Keywords = freeze-thaw (F–T) cycles

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22 pages, 9767 KiB  
Article
Freeze–Thaw-Induced Degradation Mechanisms and Slope Stability of Filled Fractured Rock Masses in Cold Region Open-Pit Mines
by Jun Hou, Penghai Zhang, Ning Gao, Wanni Yan and Qinglei Yu
Appl. Sci. 2025, 15(13), 7429; https://doi.org/10.3390/app15137429 - 2 Jul 2025
Viewed by 248
Abstract
In cold regions, the rock mass of open-pit mine slopes is continuously exposed to freeze–thaw (FT) environments, during which the fracture structures and their infilling materials undergo significant degradation, severely affecting slope stability and the assessment of service life. Conventional laboratory [...] Read more.
In cold regions, the rock mass of open-pit mine slopes is continuously exposed to freeze–thaw (FT) environments, during which the fracture structures and their infilling materials undergo significant degradation, severely affecting slope stability and the assessment of service life. Conventional laboratory FT tests are typically based on uniform temperature settings, which fail to reflect the actual thermal variations at different burial depths, thereby limiting the accuracy of mechanical parameter acquisition. Taking the Wushan open-pit mine as the engineering background, this study establishes a temperature–depth relationship, defines multiple thermal intervals, and conducts direct shear tests on structural plane filling materials under various FT conditions to characterize the evolution of cohesion and internal friction angle. Results from rock mass testing and numerical simulation demonstrate that shear strength parameters exhibit an exponential decline with increasing FT cycles and decreasing burial depth, with the filling material playing a dominant role in the initial stage of degradation. Furthermore, a two-dimensional fracture network model of the rock mass was constructed, and the representative elementary volume (REV) was determined through the evolution of equivalent plastic strain. Based on this, spatial assignment of slope strength was performed, followed by stability analysis. Based on regression fitting using 0–25 FT cycles, regression model predictions indicate that when the number of FT cycles exceeds 42, the slope safety factor drops below 1.0, entering a critical instability state. This research successfully establishes a spatial field of mechanical parameters and evaluates slope stability, providing a theoretical foundation and parameter support for the long-term service evaluation and stability assessment of cold-region open-pit mine slopes. Full article
(This article belongs to the Special Issue Rock Mechanics and Mining Engineering)
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16 pages, 5703 KiB  
Article
Understanding the Protective Effect of Liquid Nitrogen Freezing on Crayfish Quality During Transportation and Storage
by Gehao Lei, Peng Zhang, Limin Xu, Liuqing Wang, Xiaoyue He and Jiwang Chen
Foods 2025, 14(12), 2078; https://doi.org/10.3390/foods14122078 - 12 Jun 2025
Viewed by 546
Abstract
Freezing has been widely used to preserve the freshness and quality of crayfish (Procambarus clarkii). However, temperature fluctuations during transportation and storage inevitably affect the quality attributes of crayfish. In this study, the effect of liquid nitrogen freezing (LNF) on crayfish [...] Read more.
Freezing has been widely used to preserve the freshness and quality of crayfish (Procambarus clarkii). However, temperature fluctuations during transportation and storage inevitably affect the quality attributes of crayfish. In this study, the effect of liquid nitrogen freezing (LNF) on crayfish myofibrillar protein (MP) was investigated under freeze–thaw (FT) cycles. The small ice crystals formed by LNF could reduce the conversion of sulfhydryl groups to disulfide bonds, preventing the exposure of hydrophobic groups, thereby maintaining the functional properties of MP. LNF could prevent the degradation and oxidation of MP and maintain its compact and smooth microstructure. Compared to refrigerator freezing (RF), LNF showed a stronger protective effect on the secondary and tertiary structures of MP, alleviating their conformational changes. Therefore, LNF could be an alternative freezing method to preserve crayfish quality against FT cycles during transportation and storage. Full article
(This article belongs to the Section Food Packaging and Preservation)
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18 pages, 3601 KiB  
Article
Application of COMSOL Multiphysics Model in Studying Effects of Straw Addition on Dewatering Performance of Residual Sludge During Freeze–Thaw Cycles
by Zirui Guo, Jiawei Wang, Yao Wang, Riguang Chi, Xujin Gong and Zhiqiang Chen
Water 2025, 17(12), 1727; https://doi.org/10.3390/w17121727 - 7 Jun 2025
Viewed by 562
Abstract
Freeze–thaw (F/T) technology is an environmentally friendly and efficient method for residual sludge treatment. This study investigates the enhancement of sludge dewatering performance through the addition of straw during F/T cycles. A mathematical model was established using the Box–Behnken central composite design and [...] Read more.
Freeze–thaw (F/T) technology is an environmentally friendly and efficient method for residual sludge treatment. This study investigates the enhancement of sludge dewatering performance through the addition of straw during F/T cycles. A mathematical model was established using the Box–Behnken central composite design and validated via COMSOL Multiphysics simulations. The optimal conditions were identified as freezing at −16 °C for 24 h, with 12.5 freeze–thaw cycles and a straw mixing ratio of 20%, reducing the sludge moisture content from 62.7% to 35.9%. The specific resistance to filtration (SRF) and cake moisture content decreased significantly with increasing straw addition, reaching a minimum SRF of 1.30 × 1012 m/kg at the optimal straw ratio. Straw conditioning also intensified the combustion stage of the sludge by increasing the maximum weight loss rate and elevating the thermal decomposition temperature. Numerical simulations confirmed the experimental results, demonstrating that straw addition significantly improves sludge dewaterability by modifying heat and mass transfer mechanisms. Full article
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19 pages, 9292 KiB  
Article
Research on the Anti-Erosion Capacity of Aeolian Sand Solidified with Enzyme Mineralization and Fiber Reinforcement Under Ultraviolet Erosion and Freeze–Thaw Erosion
by Jia Liu, Qinchen Zhu, Gang Li, Jing Qu and Jinli Zhang
Sustainability 2025, 17(11), 5053; https://doi.org/10.3390/su17115053 - 30 May 2025
Viewed by 535
Abstract
Aeolian sand is susceptible to wind and water erosion, which seriously restricts the ecological restoration and sustainable development in desert areas. Traditional solidification methods have characteristics of high cost, easy pollution, and unstable solidification. Enzyme-induced calcium carbonate precipitation (EICP) is an emerging method [...] Read more.
Aeolian sand is susceptible to wind and water erosion, which seriously restricts the ecological restoration and sustainable development in desert areas. Traditional solidification methods have characteristics of high cost, easy pollution, and unstable solidification. Enzyme-induced calcium carbonate precipitation (EICP) is an emerging method that has advantages in terms of cost-effectiveness, environmental friendliness, and durability, and, especially when coupled with fiber reinforcement (FR), it can significantly prevent brittle fracture. In this paper, ultraviolet (UV) erosion and freeze–thaw (FT) erosion tests were conducted to investigate the anti-erosion capacity of aeolian sand solidified by EICP and basalt fiber reinforcement (BFR) or wool fiber reinforcement (WFR). According to the analysis of the variation laws of sample appearance, quality losses, and unconfined compressive strength (UCS) during the UV and FT erosion process, the erosion mechanism was revealed, and the UCS models considering the damage effects were established. The research results indicated that the UCS of aeolian sand solidified by MICP and FR was significantly improved under UV and FT erosion. The strength loss rates of aeolian sand solidified by EICP, EICP–BFR, and EICP–WFR reached 45.4%, 46.6%, and 51.6%, respectively, under 90 h UV erosion. When the FT cycles reached 8, the strength loss rate of aeolian sand solidified by EICP, EICP–BFR, and EICP–WFR attained 41.0%, 49.2%, and 55.8%, respectively. The determination coefficients of the UCS models were all greater than 0.876, indicating that the experimental results were in good agreement with the predicted results, verifying the reliability of the established models. The research results can offer reference values for windproof and sand fixation in desert areas. Full article
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19 pages, 3522 KiB  
Article
The Influence of Freeze-Thaw Cycles on the Mechanical Properties of Loess Under Temperature Variations
by Fang Zheng, Xinle Xue, Zhanping Song, Yuwei Zhang and Hongke Liu
Buildings 2025, 15(11), 1806; https://doi.org/10.3390/buildings15111806 - 24 May 2025
Viewed by 422
Abstract
Freeze-thaw (F-T) cycle tests and triaxial shear tests are conducted under varying freezing ambient temperatures and different F-T cycles for remolded loess. The results indicate that nearly all stress–strain curves of remolded loess exhibit strain-hardening behavior under varying freezing ambient temperatures and different [...] Read more.
Freeze-thaw (F-T) cycle tests and triaxial shear tests are conducted under varying freezing ambient temperatures and different F-T cycles for remolded loess. The results indicate that nearly all stress–strain curves of remolded loess exhibit strain-hardening behavior under varying freezing ambient temperatures and different F-T cycles. A decrease in freezing temperature alters the yield strain of loess and diminishes its resistance to deformation. As the freezing temperature decreases and the number of F-T cycles increases, the failure deviatoric stress of loess initially decreases, then increases, and eventually stabilizes. The most detrimental freezing temperature is −12 °C, which significantly exacerbates the adverse effects of F-T cycles on failure deviatoric stress. The strength indices initially decrease and then increase with decreasing freezing temperatures, while they first decrease and then stabilize with an increasing number of F-T cycles. Notably, the deterioration of cohesion is significantly greater than that of the internal friction angle. A quantitative analysis is conducted to examine the relationship between failure deviatoric stress, shear strength index, temperature, and freeze-thaw cycles. The fitting results effectively quantify the influence of different variables on the strength characteristics of loess. The findings of this research have significant theoretical implications for practical engineering applications in the northwest loess region. Full article
(This article belongs to the Special Issue Sustainable and Low-Carbon Building Materials in Special Areas)
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26 pages, 4077 KiB  
Article
Characterization of Mechanical Property Evolution and Durability Life Prediction of Engineered Cementitious Composites Under Frozen State
by Su Lu, Liqiang Yin, Shuguang Liu, Dandan Yin, Jiaxin Liu, Huifang Hou and Lin Li
Materials 2025, 18(10), 2375; https://doi.org/10.3390/ma18102375 - 20 May 2025
Viewed by 388
Abstract
Engineered cementitious composites (ECCs) exhibit superior mechanical properties (MPs) and excellent crack control capabilities, making them widely used in practical engineering applications. However, the MPs of ECCs in frozen states (FSs), particularly their flexural properties (FPs), still need to be better understood. MP [...] Read more.
Engineered cementitious composites (ECCs) exhibit superior mechanical properties (MPs) and excellent crack control capabilities, making them widely used in practical engineering applications. However, the MPs of ECCs in frozen states (FSs), particularly their flexural properties (FPs), still need to be better understood. MP tests were designed for frozen ECC samples to investigate the service performance of ECCs in an FS. The samples underwent 0 to 300 freeze–thaw cycles (FTs), followed by compressive and flexural tests at a constant freezing temperature of −18 °C. The compressive properties (CPs) and FPs of the samples and their influencing mechanisms were analyzed. Based on this analysis, a life prediction model (LPM) for freeze–thaw-damaged (FTD) ECCs was established using the entropy weight method and the GM(1,1) model to predict the durability changes of ECCs in FS. The results indicate that with an increasing number of FTs, the uniaxial compressive strength (CS), elastic modulus (E), initial crack strength, and ultimate strength of ECCs in the FS are higher than those in the thawed state (TS), with a notable increase in brittleness at ultimate failure. The overall stiffness of the specimens increased under high FTs. The established model effectively predicts the durability changes of ECCs in the FS. Full article
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16 pages, 9615 KiB  
Article
Shear Resistance Evolution of Geogrid Reinforced Expansive Soil Under Freeze–Thaw Cycles
by Zhongnian Yang, Jia Liu, Runbo Zhang, Wei Shi and Shaopeng Yuan
Appl. Sci. 2025, 15(10), 5492; https://doi.org/10.3390/app15105492 - 14 May 2025
Cited by 1 | Viewed by 516
Abstract
Expansive soils have significant characteristics of expansion by water absorption, contraction by water loss. Under the freeze–thaw (F-T) cycles, the engineering diseases are more significant, and the serious geotechnical engineering incidents are induced extremely easily. The aim is to investigate the mechanical response [...] Read more.
Expansive soils have significant characteristics of expansion by water absorption, contraction by water loss. Under the freeze–thaw (F-T) cycles, the engineering diseases are more significant, and the serious geotechnical engineering incidents are induced extremely easily. The aim is to investigate the mechanical response characteristics of geogrid-reinforced expansive soils (GRES) under F-T cycles. Based on a series of large-scale temperature-controlled triaxial tests, influencing factors were considered, such as the number of F-T cycles, the geogrid layers, and the confining pressure. The results showed that: (1) Friction between the expansive soil and geogrid and the geogrid’s embedded locking effect indirectly provided additional pressure, limited shear deformation. With the increase in reinforced layers, the stress–strain curve changed from a strain-softening to a strain-hardening type. (2) Elastic modulus, cohesion, and friction angle decreased significantly with increasing number of F-T cycles, whereas dynamic equilibrium was reached after six F-T cycles. (3) The three-layer reinforced specimens showed the best performance of F-T resistance, compared to the plain soil, the elastic modulus reduction amount decreases from 35.7% to 18.3%, cohesion from 24.5% to 14.3%, and friction angle from 7.6% to 4.5%. (4) A modified Duncan–Zhang model with the confining pressure, the F-T cycles, and the geogrid layers was proposed; the predicted values agreed with the measured values by more than 90%, which can be used as a prediction formula for the stress–strain characteristics of GRES under freeze–thaw cycling conditions. The research results can provide important theoretical support for the practical engineering design of GRES in cold regions. Full article
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34 pages, 35649 KiB  
Review
Performance Degradation Law and Model Construction of Hydraulic Concrete Under Freeze-Thaw Cycles: A Comprehensive Review
by Xiangyi Zhu, Xiaohe Zhou, Yuxuan Xia and Xudong Chen
Buildings 2025, 15(10), 1596; https://doi.org/10.3390/buildings15101596 - 9 May 2025
Viewed by 716
Abstract
Hydraulic concrete structures in cold regions often suffer from the combined action of freeze-thaw (FT) cycles and external loads, indicating that these structures often depend on the combined effects of two or more factors. In recent years, researchers around the world have made [...] Read more.
Hydraulic concrete structures in cold regions often suffer from the combined action of freeze-thaw (FT) cycles and external loads, indicating that these structures often depend on the combined effects of two or more factors. In recent years, researchers around the world have made considerable efforts and explorations to solve this challenge, achieving fruitful research results. This article provides a comprehensive literature review on performance degradation law and model construction of hydraulic concrete under FT cycles. Firstly, the theory and characterization method of FT damage for concrete are introduced. Given the inherent deficiencies of traditional detection methodologies and the constraints imposed by extant computed tomography (CT) technology, there is an urgent need to develop a high-precision segmentation technique for concrete. By capitalizing on the resultant microstructure, a more accurate predictive model can be established. Thereafter, an in-depth discussion is conducted on the damage mechanism of hydraulic structures when subjected to freeze-thaw (FT) cycles in conjunction with external loading scenarios, namely fracture, direct tension, triaxial stress, and hydraulic wear. As the combined effects of different factors cause more serious damage to hydraulic structures than a single factor, the evolution law is more complex. Although researchers have attempted to reveal the deterioration mechanism of multi-factor interaction by means of numerical methods, there are still many fundamental issues that require further exploration and more in-depth research due to the limitations of constitutive models. Finally, the existing research results are summarized, and novel insights are proposed for future research directions. This study promptly identifies the gaps that urgently need to be filled, especially the insufficient understanding of the complex stress state of hydraulic concrete structures and the inadequate research on the performance deterioration law under multi-factor combined action. This investigation aims to determine the future research focus in relation to hydraulic concrete in cold regions that could advance the revelation of the deterioration mechanism caused by multi-factor interaction. By providing a detailed overview of the current hydraulic concrete structures in terms of the combined action of FT cycles and external loads, highlighting the research limitations, and suggesting future research directions, this review seeks to contribute to the safe operation of hydraulic concrete structures in cold regions. Full article
(This article belongs to the Section Building Structures)
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26 pages, 46466 KiB  
Article
Experimental Investigation of Mechanical Properties and Pore Characteristics of Hipparion Laterite Under Freeze–Thaw Cycles
by Tengfei Pan, Zhou Zhao, Jianquan Ma and Fei Liu
Appl. Sci. 2025, 15(9), 5202; https://doi.org/10.3390/app15095202 - 7 May 2025
Viewed by 505
Abstract
The Loess Plateau region of China has an anomalous climate and frequent geological disasters. Hipparion laterite in seasonally frozen regions exhibits heightened susceptibility to freeze–thaw (F-T) cycling, which induces progressive structural weakening and significantly elevates the risk of slope instability through mechanisms including [...] Read more.
The Loess Plateau region of China has an anomalous climate and frequent geological disasters. Hipparion laterite in seasonally frozen regions exhibits heightened susceptibility to freeze–thaw (F-T) cycling, which induces progressive structural weakening and significantly elevates the risk of slope instability through mechanisms including pore water phase transitions, aggregate disintegration, and shear strength degradation. This study focuses on the slip zone Hipparion laterite from the Nao panliang landslide in Fugu County, Shaanxi Province. We innovatively integrated F-T cycling tests with ring-shear experiments to establish a hydro-thermal–mechanical coupled multi-scale evaluation framework for assessing F-T damage in the slip zone material. The microstructural evolution of soil architecture and pore characteristics was systematically analyzed through scanning electron microscopy (SEM) tests. Quantitative characterization of mechanical degradation mechanisms was achieved using advanced microstructural parameters including orientation frequency, probabilistic entropy, and fractal dimensions, revealing the intrinsic relationship between pore network anisotropy and macroscopic strength deterioration. The experimental results demonstrate that Hipparion laterite specimens undergo progressive deterioration with increasing F-T cycles and initial moisture content, predominantly exhibiting brittle deformation patterns. The soil exhibited substantial strength degradation, with total reduction rates of 51.54% and 43.67% for peak and residual strengths, respectively. The shear stress–displacement curves transitioned from strain-softening to strain-hardening behavior, indicating plastic deformation-dominated shear damage. Moisture content critically regulates pore microstructure evolution, reducing micropore proportion to 23.57–28.62% while promoting transformation to mesopores and macropores. At 24% moisture content, the areal porosity, probabilistic entropy, and fractal dimension increased by 0.2263, 0.0401, and 0.0589, respectively. Temperature-induced pore water phase transitions significantly amplified mechanical strength variability through cyclic damage accumulation. These findings advance the theoretical understanding of Hipparion laterite’s engineering geological behavior while providing critical insights for slope stability assessment and landslide risk mitigation strategies in loess plateau regions. Full article
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25 pages, 12927 KiB  
Article
Experimental and Numerical Analysis of Freeze–Thaw-Induced Mechanical Degradation in the Coarse-Grained Soil of the Southeastern Qinghai–Xizang Plateau
by Huan Niu, Peiqing Wang, Liang Chen, Ding Sang, Chao Li, Congyou Shi and Wengang Zhang
Appl. Sci. 2025, 15(9), 4900; https://doi.org/10.3390/app15094900 - 28 Apr 2025
Viewed by 358
Abstract
To investigate the effects of freeze–thaw (FT) cycles on the mechanical properties of coarse-grained soil in southeastern Xizang under different moisture contents, this study focuses on coarse-grained soil from a large landslide deposit in Linzhi City, Xizang. FT cycle tests, triaxial shear tests, [...] Read more.
To investigate the effects of freeze–thaw (FT) cycles on the mechanical properties of coarse-grained soil in southeastern Xizang under different moisture contents, this study focuses on coarse-grained soil from a large landslide deposit in Linzhi City, Xizang. FT cycle tests, triaxial shear tests, and numerical simulations were employed to systematically examine the comprehensive impact of varying FT cycles, moisture content, and confining pressure on the soil’s mechanical characteristics. The results show that FT cycles significantly affect the stress–strain behavior of coarse-grained soil in southeastern Xizang. The degree of strain softening increased from approximately 11.6% initially to 31.2% after 15 FT cycles, with shear strength decreasing by an average of 31.8%. Specifically, cohesion decreased by 38% to 55% after 0 to 15 FT cycles, and the internal friction angle decreased by approximately 29% to 32%. Additionally, higher moisture content led to more pronounced strain softening and strength degradation, while increased confining pressure effectively mitigated these deteriorative effects. Numerical simulation results indicated that as moisture content increased from 7.6% to 11.6%, the number of FT cycles required to reach the critical instability state decreased from approximately 150 to 106, and finally to only 15, with the maximum equivalent plastic strain increasing from 0.20 to 2.47. The findings of this study provide key mechanical parameters for understanding the formation and evolution of FT landslide disasters in southeastern Xizang and lay a scientific foundation for the assessment and long-term prevention of cold-region geological hazards. Full article
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19 pages, 4223 KiB  
Article
Experimental Study on Mechanical Properties of Desert Sand Concrete Under Freeze–Thaw Cycles
by Wenjie Xi, Zhiqiang Li, Yang Zhou, Gang Li and Feng Ji
Materials 2025, 18(7), 1546; https://doi.org/10.3390/ma18071546 - 29 Mar 2025
Viewed by 609
Abstract
This study aims to explore the mechanical behavior of Desert Sand Concrete (DSC) under freeze–thaw (F-T) cycles. By adjusting the number of F-T cycles, the research analyzed the impact of various desert sand replacement ratios on the frost resistance of concrete. The study [...] Read more.
This study aims to explore the mechanical behavior of Desert Sand Concrete (DSC) under freeze–thaw (F-T) cycles. By adjusting the number of F-T cycles, the research analyzed the impact of various desert sand replacement ratios on the frost resistance of concrete. The study focused on the dynamic changes in mass loss of concrete specimens, relative dynamic elastic modulus, cubic compressive strength, splitting tensile strength, and axial compressive strength. Scanning electron microscopy was employed to analyze the micro-morphology of specimens after F-T cycles. This analysis aimed to predict the service life of DSC and provide practical recommendations for the maximum compressive strength loss rate within the designed service life. The results indicated that although the frost resistance of DSC was similar to that of ordinary concrete before 50 F-T cycles, it subsequently exhibited a nonlinear degradation trend correlated with increasing desert and replacement ratios, with both frost resistance and compactness reaching optimal levels at a 40% replacement rate. Additionally, the F-T damage model proposed in this study demonstrated high applicability and fitting accuracy. This model provided effective theoretical support for understanding and predicting the mechanical behavior of DSC. Full article
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22 pages, 5793 KiB  
Article
Concrete Durability Performance in Aggressive Salt and Deicing Environments—Case Study of Select Pavement and Bridge Concrete Mixtures
by Olaniyi S. Arowojolu, Milena Rangelov, Somayeh Nassiri, Fouad Bayomy and Ahmed Ibrahim
Materials 2025, 18(6), 1266; https://doi.org/10.3390/ma18061266 - 13 Mar 2025
Viewed by 715
Abstract
Transportation infrastructure such as concrete pavements, parapets, barriers, and bridge decks in cold regions are usually exposed to a heavy amount of deicing chemicals during the winter for ice and snow control. Various deicer salts can physically and chemically react with concrete and [...] Read more.
Transportation infrastructure such as concrete pavements, parapets, barriers, and bridge decks in cold regions are usually exposed to a heavy amount of deicing chemicals during the winter for ice and snow control. Various deicer salts can physically and chemically react with concrete and result in damage and deterioration. Currently, Idaho uses four different types of deicers during the winter: salt brine, mag bud converse, freeze guard plus, and mag chloride. The most often utilized substance is salt brine, which is created by dissolving rock salt at a concentration of 23.3%. Eight concrete mixtures for paving and structural purposes were made and put through a battery of durability tests. Following batching, measurements were made of the unit weight, entrained air, slump, and super air meter (SAM) fresh characteristics. Rapid freeze–thaw (F-T) cycle experiments, deicing scaling tests, and surface electrical resistivity testing were used to test and assess all mixes. Tests with mag bud converse, freeze guard plus mag chloride, and acid-soluble chloride were conducted following an extended period of soaking in salt brine. Two different structural mixtures were suggested as a result of the severe scaling observed in the structural mixtures lacking supplemental cementitious materials (SCMs) and the moderate scaling observed in the other combinations. The correlated values of the SAM number with the spacing factor have been shown that mixture with no SCMs has a spacing factor of 0.24, which is higher than the recommended value of 0.2 and concentrations of acid soluble chloride over the threshold limit were discernible. In addition, the highest weight of calcium hydroxide using the TGA test was observed. For all examined mixes, the residual elastic moduli after 300 cycles varied between 76.0 and 83.3 percent of the initial moduli. Mixture M5 displayed the lowest percentage of initial E (76.0 percent), while mixtures M1 and M2 showed the highest percentage of residual E (83.3 and 80.0 percent, respectively) among the evaluated combinations. There were no significant variations in the percentage of maintained stiffness between the combinations. As a result, it was difficult to identify distinct patterns about how the air content or SAM number affected the mixture’s durability. Class C coal fly ash and silica fume were present in the suggested mixtures, which were assessed using the same testing matrix as the original mixtures. Because of their exceptional durability against large concentrations of chemical deicers, the main findings suggest altering the concrete compositions to incorporate SCMs in a ternary form. Full article
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16 pages, 4730 KiB  
Article
Effects of Expansive Clay Content on the Hydromechanical Behavior of Liners Under Freeze-Thaw Conditions
by Ahmed M. Al-Mahbashi and Muawia Dafalla
Minerals 2025, 15(3), 291; https://doi.org/10.3390/min15030291 - 12 Mar 2025
Cited by 1 | Viewed by 810
Abstract
In several geotechnical and geoenvironmental projects, fines containing expandable clay minerals such as expansive clay (EC) were added to sand as sealing materials to form liners or hydraulic barriers. Liner layers are generally exposed to different climatic conditions such as freeze-thaw (FT) during [...] Read more.
In several geotechnical and geoenvironmental projects, fines containing expandable clay minerals such as expansive clay (EC) were added to sand as sealing materials to form liners or hydraulic barriers. Liner layers are generally exposed to different climatic conditions such as freeze-thaw (FT) during their service lifetime. The hydromechanical behavior of these layers under such circumstances is of great significance. In this study, the impact of fine contents of expansive soil on swelling, consolidation characteristics, and hydraulic conductivity under FT conditions is examined. Different clay liners with 20%, 30%, and 60% of EC content were designed. The specimens were initially subjected to successive FT cycles up to 15 in close system criteria. The results revealed that volumetric strains attained during successive FT cycles are proportional to the content and nature of expanding minerals (i.e., montmorillonite) and reached a 4.5% magnitude value for the liner with 60% clay. Vertical strains during wetting conditions have been reduced by about 90% after the first FT cycles, which implies significant destruction in the soil structure. The yield stress indicated a 60% change, along with increasing FT cycles. The hydraulic conductivity during an extended period of 100 days shows significant changes and deterioration due to FT actions. The outcome of this study will help to predict the lifetime behavior and performance of the liner, taking into account the stability under frost conditions. Full article
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30 pages, 7205 KiB  
Review
The Effectiveness of Different Additives on Concrete’s Freeze–Thaw Durability: A Review
by Moutaman M. Abbas and Radu Muntean
Materials 2025, 18(5), 978; https://doi.org/10.3390/ma18050978 - 22 Feb 2025
Cited by 1 | Viewed by 1584
Abstract
Enhancing concrete’s resilience against freeze–thaw (F-T) cycles is a critical challenge in civil engineering, especially in cold climates, where repeated freezing and thawing lead to structural degradation. This review explores the effectiveness of various additives, including supplementary cementitious materials (SCMs) and chemical admixtures, [...] Read more.
Enhancing concrete’s resilience against freeze–thaw (F-T) cycles is a critical challenge in civil engineering, especially in cold climates, where repeated freezing and thawing lead to structural degradation. This review explores the effectiveness of various additives, including supplementary cementitious materials (SCMs) and chemical admixtures, in improving concrete durability under F-T conditions. Factors influencing F-T resistance include the type and percentage of SCM replacement, the water–cement ratio, pore structure refinement, and air entrainment. The mechanisms by which additives enhance the durability—such as reducing the permeability, improving the microstructure, and increasing the compressive strength—are examined through an extensive review of experimental studies. The findings indicate that manufactured additives, such as silica fume, metakaolin, nano-SiO2, and graphene oxide, significantly enhance the F-T durability by densifying the concrete matrix and mitigating internal damage. In contrast, natural additives, including rice husk ash and zeolite, show potential but require optimization to match the performance of industrial SCMs. Additionally, the preparation and treatment methods of these materials play a crucial role in their effectiveness. This review provides insights into optimizing concrete formulations to enhance the longevity and sustainability, offering practical recommendations for the use of SCMs in cold climates. Full article
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17 pages, 10527 KiB  
Article
Dynamics of Soil N2O and CO2 Emissions in Response to Freeze–Thaw Intensity and Moisture Variations: A Laboratory Experiment
by Yuhua Kong, Shanshan Gong, Longfei Zhu, Haohao Wu, Keji Duan, Weiguo Cheng, Dmitriy Khoroshaev, Yong Lai and Xingkai Xu
Forests 2025, 16(3), 380; https://doi.org/10.3390/f16030380 - 20 Feb 2025
Cited by 1 | Viewed by 800
Abstract
Climate warming has led to more frequent soil freeze–thaw (FT) events in high-latitude and high-altitude regions, leading to significant pulse releases of greenhouse gasses (GHGs) such as nitrous oxide (N2O) and carbon dioxide (CO2) into the atmosphere. These pulse [...] Read more.
Climate warming has led to more frequent soil freeze–thaw (FT) events in high-latitude and high-altitude regions, leading to significant pulse releases of greenhouse gasses (GHGs) such as nitrous oxide (N2O) and carbon dioxide (CO2) into the atmosphere. These pulse emissions exhibit unpredictable spatiotemporal variability, which are influenced by soil type, soil moisture and FT temperature. This study employed controlled laboratory experiments to investigate the effects of varying FT intensities (−10 °C/10 °C, −5 °C/5 °C, and a control at 0 °C/0 °C) and soil moisture levels (30%, 60%, and 90% water-filled pore space, WFPS) on the dynamics of soil N2O and CO2 emissions (measured daily), and the availability of carbon and nitrogen, microbial biomass, and enzyme activities (measured weekly) in the soils collected from two forest stands in the Changbai mountains of northeast China, a broadleaf and Korean pine (Pinus koraiensis Sieb. et Zucc.) mixed forest (BKPF) and an adjacent secondary white birch (Betula platyphylla Suk.) forest (WBF), where FT events frequently occur. Our findings reveal that a high FT intensity (−10 °C/10 °C) significantly increased N2O and CO2 emissions from BKPF and WBF soils. With increasing soil moisture, soil CO2 emissions peaked at 60% WFPS, while soil N2O emissions were the highest at 90% WFPS. Notably, pulse emissions of N2O were particularly intense under a high FT intensity and high moisture (i.e., 90% WFPS) in WBF soils, persisting for nearly 8 days during FT cycles. The emissions of N2O and CO2 under varying FT and moisture conditions are intricately regulated by soil substrate dynamics, including dissolved organic carbon, nitrogen mineralization, and nitrate concentrations. The results improve the understanding of the high variability of soil GHG emissions during the FT process and its underlying mechanisms, which are inadequately considered in current ecological and land surface process models. Consequently, it would contribute valuable insights into the interaction between soil GHG emissions and climate change in high-latitude and high-altitude zones. Full article
(This article belongs to the Section Forest Soil)
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Figure 1

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