Search Results (1,383)

Phase-change materials (PCMs), such as paraffin wax, are widely used in latent heat storage (LHS) because they store substantial thermal energy at nearly constant temperature; however, their low thermal conductivity limits heat transfer and slows melting/solidification. In this work, two flat-plate solar collectors are coupled with a paraffin-based LHS unit for low-temperature solar heating, and the design is optimized by introducing improved fin-geometry combinations on both the heat transfer fluid (HTF) tube and shell side. The M-shaped fins combined with rectangular fins significantly enhanced convective heat transfer by generating localized vortices, while the extended surface area improved conduction within the solid PCM, facilitating efficient heat dissipation and accelerating the phase transition. The LHS unit without fins showed complete melting in 67 min. However, fin introduction remarkably mitigated charging duration to 44 min, 52.3% faster than bare tubes having no fins. The experimental melting process exhibited a 7 min delay by comparing experimental and numerical results, achieving complete melting in 51 and 44 min, respectively. Discharging was completed in 48 min. During PCM charging, sensible heating produces a rapid temperature rise with only a small energy increase, but once the PCM entered into the melting range (320–324 K), the energy changed more steeply. Adding fins boosts stored energy from 2.10 MJ to 3.25 MJ (54.8%) and exergy from 0.15 MJ to 0.27 MJ (80.0%), yet exergy remains far smaller than energy (92.9% lower without fins and 91.7% lower with fins), indicating fins enhance total heat storage more than recoverable work potential. Full article

This study analyzes four alternative cycle configurations for the traditional vapor compression system used in conventional, hybrid, and electric vehicles, taking low-GWP alternatives for the substitution of R134a. These are cycle with an internal heat exchanger and thermostatic expansion valve (IHX + TEV); cycle with an internal heat exchanger and short tube (IHX + ST); cycle with an ejector (EC); and cycle with an ejector and internal heat exchanger (EC + IHX). Similarly, the energy, exergy, exergoeconomic, and environmental impact of these configurations were analyzed using synthetic refrigerants with a GWP of less than 150. The results indicate that, using the EC + IHX configuration, the COP for refrigerants R1234yf, R1234ze(E), R1243zf, and R516A is the highest, increasing by more than 20%. Using R1243zf in the EC configuration can reduce the total cost ratio compared to other refrigerants. On the other hand, the use of IHX cycle configurations with R444A and R445A decreases the exergy efficiency and increases the total cost ratio by up to 35% and 70%, respectively. Additionally, the Total Equivalent Warming Impact (TEWI) analysis showed reductions up to 20% for ejector cycle configurations using R1234ze(E), R1234yf, R1243zf, and R516A. Full article

This study investigates the applicability of alternative low-global warming potential (GWP) refrigerant blends in water-source heat pump systems. Binary and ternary refrigerant mixtures were generated using REFPROP 10 to identify suitable candidates. Among 379 novel blends, 18 mixtures with glide temperatures below 10 °C, high critical temperatures, and GWP values lower than 750 were selected for analysis. Thermodynamic analyses were conducted for the selected refrigerants at target water outlet temperatures ranging from 35 to 75 °C, with a heat source temperature of 15 °C and an evaporation temperature of 5 °C. In addition, compressor discharge temperature, volumetric heating capacity, and coefficient of performance (COP) were evaluated. Among the refrigerants, MX1 was recommended for condenser temperatures of 40–80 °C in large-scale heat pump and district heating applications. For refrigerants with GWP values below 150, MX7 exhibited the highest COP and second-law efficiency (η_II) and is therefore suitable for small-capacity systems. In the GWP range of 150–750, MX16 demonstrated the highest COP and η_II values over the entire temperature range. Overall, MX7 achieved the highest COP and η_II among all refrigerants considered, while MX4 emerged as the most favorable mixture in terms of low GWP (below 150) and thermophysical performance. Full article

Engineering sizing of seasonal underground thermal energy storage (SUTES) systems remains constrained by the complex coupling of heat and moisture transport in unsaturated porous media. Neglecting these coupling effects can lead to significant errors in the design of borehole length and spacing. This study presents a three-dimensional numerical investigation of a coaxial borehole heat exchanger (CBHE) field over a full annual cycle, including storage, transition, extraction, and recovery stages. A coupled heat–moisture transfer model for the soil–CBHE system is developed and validated against experimental data, yielding mean relative errors of 6.8% for temperature and 7.7% for volumetric water content. The model is then used to quantify the sensitivity of SUTES performance to the initial volumetric water content (θ₀). Increasing θ₀ from 0.20 to 0.40 m³·m⁻³ enhances the average heat injection rate per unit depth by 6.6% (from 53.84 to 57.39 W·m⁻¹) and the heat extraction rate by 7.1% (from 23.73 to 25.41 W·m⁻¹). This enhancement is primarily attributed to increased effective thermal conductivity and heat capacity, together with moisture migration and the associated latent-heat effects within the soil matrix. While the variations in seasonal energy and exergy efficiencies are within 1 percentage point, radial soil-temperature uniformity and effective heat diffusion are significantly improved in moister soils. These findings clarify the coupled transport mechanisms in borehole seasonal storage and provide engineering guidance for sizing CBHE fields in unsaturated formations. Full article

There are numerous operating parameters that affect the thermodynamic and thermoeconomic performance of gas turbine cycles, and many studies based on energy, exergy, and economic analyses have been conducted in the literature by considering these parameters. However, the order of importance and contribution ratios of key operating parameters such as ambient temperature, compressor pressure ratio, combustion efficiency, regenerator effectiveness, and compressor and turbine isentropic efficiencies with respect to thermal efficiency, exergy efficiency, and the levelized cost of electricity (LCOE) have not been sufficiently investigated using statistical methods. Accordingly, a thermodynamic model of a gas turbine cycle improved with intercooling, reheating, and regeneration processes was developed in the study, and thermal efficiency, exergy efficiency, and LCOE values were calculated under different parameter levels. Taguchi analysis was carried out by using the L27 orthogonal array, in which six operating parameters were evaluated at three levels, and optimum parameter levels were determined for each performance indicator. Next, the contribution ratios of the parameters to the objective functions were calculated using the ANOVA method. The results showed that turbine isentropic efficiency was the most influential parameter in terms of thermal and exergy efficiencies, while compressor pressure ratio played the dominant role in terms of LCOE. Additionally, to simultaneously achieve the goals of maximizing thermal and exergy efficiencies and minimizing the LCOE value, the grey relational analysis (GRA) method was applied as a multi-objective optimization approach, and the optimum operating conditions were determined based on a single performance indicator. According to the GRA results, under the optimum conditions, the thermal efficiency was calculated as 0.5533, its exergy efficiency was 0.5772, and the LCOE value was 0.01751 USD/kWh. Full article

This study develops and optimizes a hybrid plant that couples a recompression sCO₂ Brayton cycle to a central-tower particle receiver with a bottoming Organic Rankine Cycle (ORC), including environmental and exergy balances. The two scenarios revealed Pareto points that raised the exergy efficiency to 0.65 in winter and reduced the fuel flow to 15 kg/s. Scenario number two achieves an overall thermal efficiency of 0.50 with total daily emissions of 2520 t CO₂ and 2850 kg NO_x, enabling nearly constant net power. Exergy destruction is concentrated in the high-temperature recuperator (HTR) and ORC turbines (27% each) and the ORC condenser (25%). Compared to a non-optimized baseline, the best solutions increased the ORC and Brayton efficiencies by 6.8–12.66% and 33.4–33.5%, respectively; cut gas-turbine power by 34% and ORC power to 10%; and lowered daily CO₂ and NO_x emissions by 52%. The gains stem from the coordinated adjustments of key levers: lower gas-turbine inlet temperature (about 10%), reduced Brayton mass flow (23%), and tuned ORC turbine inlet pressure. Full article

This study assesses the technical, operational, environmental, and economic feasibility of integrating alkaline water electrolysis (AEL) using on-site measured surplus electricity from two 20 MW natural-gas turbogenerators installed at a Central Processing Facility (CPF) in a Colombian oilfield. Unlike approaches based on modeled profiles, the analysis relies on more than 31,000 experimental records of gas consumption and active power, enabling an accurate characterization of the structural availability of energy surpluses under real operating conditions. A specialized industrial water treatment and purification company was consulted and provided with the physicochemical characterization results obtained from process water samples analyzed by an accredited laboratory. Based on these parameters, the technical supplier confirmed the feasibility of designing a multistage treatment train, including equalization, filtration, clarification, activated carbon, ultrafiltration, and reverse osmosis, capable of achieving final conductivities at or below 5 µS/cm. This water quality level is compatible with typical industrial alkaline electrolysis requirements and in line with technical specifications commonly aligned with ASTM and ISO standards for pressurized AEL systems. A strategic comparison between PEM and AEL technologies, supported by IFE/EFE matrices and sensitivity analyses, identified alkaline electrolysis as the optimal alternative under a stable electrical profile and capital expenditure constraints. Energy sizing for scenarios between 1.5 and 10 MW, assuming continuous 24 h operation and an average specific consumption of 50 kWh/kg H₂, yields productions between 0.5 and 3.5 t H₂/day, with electrical efficiencies above 70%. A 20-year financial analysis indicates a techno-economic threshold near 3 MW (NPV > 0; IRR > WACC), with optimal performance in the 6.5–10 MW range and payback periods between 2 and 4 years under internal valorization of the surplus electricity. From an environmental perspective, the produced hydrogen is classified as low-carbon rather than “green” due to its thermal origin; however, the integration improves the turbines’ operating regime and valorizes surplus electrical exergy that was previously unused, providing a replicable strategy for industrial assets with self-generation and treatable water availability. Full article

In multifunctional and high-energy-density integrated buildings, energy performance and environmental impacts are affected by the environmental conditions in which they are located. Entropy production, which is an output of exergy analysis in energy performance, offers a new evaluation area for energy management in this context. In the study developed for this purpose, the condensate line formed in the steam distribution lines of an integrated building was modeled, and the possible inefficiency potential of the condensate load formed and the usability of the approach developed over entropy production were suggested by energy management. Entropy production due to exergy destruction of distribution lines derived from condensate pump data in the integrated building was evaluated with two environmental indices developed. According to the analysis, the average exergy efficiency for the distribution lines of the integrated building system is 22%, with exergy extinction reaching 78%, indicating a high level of return level. The recovery potential associated with the total exergy flow was calculated as 50.8%, while the entropy generation potential due to the condensation load was 65.3%. From an environmental perspective, the potential for pollution based on entropy has reached 64.9%, while the target energy efficiency level associated with condensate management has been set at 33.5%. The findings suggest that this approach for energy management offers a quantitative evaluation opportunity between thermodynamic irreversibility and environmental performance in buildings. At the end of the study, a comparative analysis of this approach with the classical regression approach for energy management is also given. Full article

Vapour-compression refrigeration and cooling systems represent a significant share of global electricity consumption, being estimated to account for approximately 10% to 20% of the worldwide electricity demand, which highlights their critical impact on energy efficiency and sustainability. In this context, improving the thermodynamic and exergoeconomic performance of refrigeration cycles, as well as the appropriate selection of the refrigerant, has become a key research priority. Therefore, this work aims to comparatively evaluate the energy, exergy, exergy cost, and exergoeconomic performance of three vapour-compression refrigeration cycle configurations: a simple cycle, a two-stage cycle with a flash tank, and a two-stage cycle with a flash tank and a mixing chamber. Six refrigerants (R134a, R600a, R290, R1234yf, R1234ze (E), and R717) were analysed under evaporation temperatures of 228–238 K and condensation temperatures of 298–308 K. The performance evaluation was carried out using the Fuel–Product–Residue (FPR) methodology, considering the coefficient of performance (COP), exergy efficiency, system irreversibilities, and exergy and exergoeconomic costs. The results indicate that the incorporation of the mixing chamber increases the COP by up to 7% and the exergy efficiency by up to 6% compared to the simple cycle, while reducing exergoeconomic costs by up to 10% for the most favourable refrigerants. Among the working fluids analysed, R600a exhibits the best overall performance (COP up to 4.3 and an exergy efficiency of 33%), followed by R290 and R717, whereas R1234yf shows the lowest efficiencies (COP ≈ 3.7 and exergy efficiency ≈ 28%) and the highest exergoeconomic costs. These findings demonstrate that the design of vapour-compression refrigeration systems should involve the joint selection of the cycle configuration and the refrigerant based on integrated energy, exergy, and exergoeconomic criteria. Overall, the results highlight that both the refrigerant and the cycle configuration must be selected simultaneously, considering energy, exergy, and exergoeconomic criteria, to achieve more efficient and sustainable industrial applications. Full article

Synthetic natural gas (SNG) production from biomass residues represents a promising strategy to reduce greenhouse gas emissions and enhance energy security in regions with abundant agricultural waste. This study evaluates the thermodynamic performance of SNG synthesis from rice husk (RH) and empty fruit bunches (EFB) bio-oils, major residues in the department of Bolívar, Colombia. The process was simulated in Aspen Plus^®, integrating syngas data and methanation under equilibrium conditions at 320 °C and 30 bar, complemented by hydrogen injection via alkaline electrolysis to maintain an H₂/CO ratio above 3. Energy and exergy analyses were performed to quantify efficiencies and irreversibilities. Results indicate carbon conversion rates of 48.3% for EFB and 47.4% for RH, producing SNG with 96% CH₄ suitable for grid injection. Energy efficiencies reached 71.9% and 71.0%, while exergy efficiencies were 87.2% and 82.9%, respectively, aligning with or surpassing literature benchmarks. The main irreversibilities occurred in methanation and CO₂ removal, highlighting thermal integration and gas recycling as key improvement strategies. These findings demonstrate the potential of leveraging local biomass for clean energy production and support the development of Power-to-Gas systems in Colombia. Full article

This study investigates the integration of a molten salt thermal energy storage (TES) system into a 330 MW coal-fired power unit to enhance its operational flexibility and exergy-based performance. Using EBSILON Professional (version 13) software, several heat storage and heat release schemes were modeled and analyzed to assess their effects on turbine performance, coal consumption rate, heat rate, and exergy losses under various load conditions. The results reveal that coupling TES with conventional thermal units can effectively decouple heat and power generation, enabling deep peak-shaving operation while maintaining system efficiency. The six heat storage schemes and seven heat release schemes considered in this study were selected based on the physical characteristics of the 330 MW reheat-steam cycle and the practical constraints of integrating a molten salt TES system into an existing coal-fired unit. Specifically, the schemes were designed to represent all feasible pathways for redirecting thermal energy within the boiler–turbine system, including steam extraction from different turbine stages, reheater-side interventions, and electric-heating-assisted charging options. These schemes also reflect the operational boundaries of the unit, such as allowable extraction fractions, steam temperature limits, and turbine safety margins. The findings demonstrate that molten salt TES can serve as a feasible and efficient pathway for retrofitting existing coal-fired power units to improve load-following capability, reduce fuel consumption, and support grid flexibility under renewable-dominated energy scenarios. Full article

Ammonia decomposition is one of the most used pathways for carbon-free hydrogen production, particularly in systems where ammonia is used as a hydrogen carrier. Modelling and simulation are critical for the general quantification of reaction kinetics, transport limitations, reactor performance, and system-level integration; however, simulation-based studies remain disjointed across modelling scales and synthesis routes. This systematic review examines modelling and simulation studies on ammonia decomposition published in the period between 2014 and 2025, identified through a structured Scopus search and screened using PRISMA methodology. A total of 70 modelling-focused studies were classified into five modelling categories: reactor-scale numerical and CFD modelling; kinetic and thermochemical mechanism modelling; thermodynamic, energy, and exergy-based process simulation; multiscale or cross-scale modelling; and conceptual or dimensionless modelling frameworks. The results show that reactor-scale CFD and kinetic models constitute most published studies, while integrated multiscale frameworks linking catalyst-scale phenomena to reactor and process-level performance remain limited. Furthermore, the inclusion of techno-economic analysis (TEA) and life-cycle assessment (LCA) is limited, restricting quantitative evaluation of scalability and system viability. Based on the reviewed literature, key methodological gaps are identified, and a multiscale modelling roadmap is proposed to support the design, optimisation, and scale-up of ammonia-to-hydrogen conversion systems. Full article

Thermal stratification strongly affects the efficiency and operational reliability of sensible thermal energy storage (TES) tanks in energy systems. This study numerically investigates the combined influence of inlet configuration and mass flow rate on the charging performance of a vertical cylindrical TES tank (H = 3 m, D = 1 m) using transient CFD simulations. Five inlet designs—open, orifice, groove, shower, and shower-groove are analyzed at three flow rates: $Q_1$ = 0.0003 m³/s, ${Q_2=Q}_1/2$, and $Q_3=Q_1/3$. System performance is evaluated using key thermal and stratification metrics. Increasing the flow rate from $Q_3$ to $Q_1$ enhances convective heat transfer and energy and exergy efficiencies, but significantly intensifies mixing and degrades thermal stratification. At $Q_1$, the groove inlet achieves the highest capacity ratio and exergy efficiency (0.87), while exhibiting increased mixing. Reducing the flow rate to $Q_2$ and $Q_3$ limits inlet-induced momentum, leading to improved stratification for all configurations. The shower-groove inlet reaches a maximum stratification level (tail factor) of 1.13 at $Q_3$, indicating superior thermal layering, albeit with lower energetic efficiency (≈0.40–0.45). The groove inlet provides the best overall compromise at $Q_2$, combining high efficiency with stable stratification. These results demonstrate a clear efficiency-stratification trade-off and highlight the importance of selecting inlet-flow combinations according to application-specific objectives. Full article

Dill is a valuable herb recognized for its rich nutritional composition and bioactive properties. Drying is an efficient preservation technique for maintaining its quality characteristics and ensuring longer storage stability. Incorporating ultrasonic pretreatment before the drying process can significantly reduce energy consumption (SEC) and greenhouse gas emissions. To the best of our knowledge, this is the first study to comprehensively evaluate ultrasound-assisted hybrid microwave–convective drying of dill (Anethum graveolens L.) leaves, focusing on the combined effects on drying kinetics, energetic and exergetic performance, providing an indirect emission estimate and multiple quality attributes. This study aimed to evaluate the drying kinetics, energy and exergy performance parameters, greenhouse gas emissions, quality properties (water activity, rehydration ratio and color) and antioxidant capacity of dill leaves dried by the microwave–hot-air (MW-HA) technique combined with ultrasonic (US) pretreatment. The experiments were conducted at MW power levels of 20%, 40%, and 60% (corresponding to a total output of 900 W), air temperatures of 40 and 60 °C, and US pretreatment durations of 0, 10, and 30 min. The results illustrated that rising MW power, air temperature and US duration significantly reduced the drying time, SEC and greenhouse gas emissions. At higher process conditions, specifically, 40% MW power, 60 °C drying temperature, and 30 min US pretreatment, the maximum energy efficiency (10.17%) and exergy efficiency (11.35%) were obtained. In terms of quality attributes, the best results were achieved at 40% MW power, 60 °C air temperature, and 10 min ultrasonic pretreatment, with reduced water activity (0.258), minimal color variation (ΔE = 11.44), improved rehydration ratio (3.88), and high retention of antioxidant activity. These findings demonstrate the potential of ultrasound pretreatment to enhance drying performance by reducing energy use and emissions while improving quality and antioxidant retention in dill, offering new guidelines for sustainable processing of this herb. Future studies should optimize microwave–hot-air-drying conditions to balance energy efficiency, exergy, and product quality. Full article

Thermochemical conversion of plastic waste to hydrogen and synthesis gas represents a potential pathway for energy recovery from heterogeneous waste streams. The feasibility and performance of such systems are fundamentally governed by thermodynamic constraints and heat-management requirements. This review critically examines the thermodynamic and heat-integration aspects of plastic waste conversion to hydrogen and syngas, with emphasis on pyrolysis, steam reforming, gasification, and system-level behaviour. Key thermodynamic features of plastic pyrolysis, reforming, and gasification are discussed, including reaction endothermicity, equilibrium limitations, temperature effects, and product distribution trends. The role of steam reforming and water–gas shift reactions in enhancing hydrogen yield is assessed from equilibrium and energy-demand perspectives. Heat integration emerges as a critical determinant of overall efficiency, with recoverable waste heat present at multiple process stages offering opportunities for internal heat recovery. Energy and exergy analyses identify dominant sources of irreversibility and enable comparison of plastic-derived hydrogen systems with conventional thermochemical hydrogen production routes. Quantitatively, conventional steam methane reforming achieves energy efficiencies of 65–75% and exergy efficiencies of 60–70%, whilst plastic-derived systems without extensive heat integration report 45–60% and 40–55%, respectively. Key challenges include limited thermodynamic property data for real plastic-derived mixtures, insufficient reconciliation of equilibrium and kinetic behaviour, incomplete system-level heat-integration analysis, and scarcity of comprehensive exergy-based evaluations. This review provides a thermodynamic framework for assessing the opportunities and limitations of hydrogen production from plastic waste. Full article