Search Results (5,208)

Superhydrophobic magnetic nanomaterials (SHMNMs) are emerging as multifunctional platforms for efficient oil–water separation due to their combination of extreme water repellency, strong oil affinity, and external magnetic responsiveness. This review presents a comprehensive analysis of recent advances in the design, synthesis, and environmental application of SHMNMs. The theoretical foundations of superhydrophobicity and the physicochemical behavior of magnetic nanoparticles are first outlined, followed by discussion of their synergistic integration. Key fabrication techniques—such as sol–gel synthesis, electrospinning, dip-coating, laser-assisted processing, and the use of biomass-derived precursors—are critically assessed in terms of their ability to tailor surface morphology, chemical functionality, and long-term durability. The review further explores the mechanisms of oil adsorption, magnetic separation, and material reusability under realistic environmental conditions. Special attention is paid to the scalability, mechanical resilience, and environmental compatibility of SHMNMs in the context of water treatment technologies. Current limitations, including reduced efficiency in harsh media, potential environmental risks, and challenges in material regeneration, are discussed. This work provides a structured overview that could support the rational development of next-generation superhydrophobic materials tailored for sustainable and high-performance separation of oil and organic pollutants from water. Full article

Concrete cracks and sulfate degradation severely compromise structural durability, highlighting the need for sustainable solutions to enhance longevity and minimize environmental impact. This study assesses the efficacy of bacterial self-healing technology utilizing Bacillus megaterium (BM) and Bacillus sphaericus (BS) in enhancing the resistance of concrete to sulfate attacks and improving its mechanical properties. Bacterial suspensions (1% and 2.5% of cement weight) were mixed with concrete containing silica fume or fly ash (10% of cement weight) and cured in freshwater or sulfate solutions (2%, 5%, and 10% concentrations). Specimens were tested for compressive strength, flexural strength, and microstructure using a Scanning Electron Microscope (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), and X-ray diffraction (XRD) at various ages. The results indicate that a 2.5% bacterial content yielded the best performance, with BM surpassing BS, enhancing compressive strength by up to 41.3% and flexural strength by 52.3% in freshwater-cured samples. Although sulfate exposure initially improved early-age strength by 1.97% at 7 days, it led to an 8.5% loss at 120 days. Bacterial inclusion mitigated sulfate damage through microbially induced calcium carbonate precipitation (MICP), sealing cracks, and bolstering durability. Cracked specimens treated with BM recovered up to 93.1% of their original compressive strength, promoting sustainable, sulfate-resistant, self-healing concrete for more resilient infrastructure. Full article

Economic systems face critical challenges, including widening income inequality, unemployment driven by automation, mounting public debt, and environmental degradation. This study introduces Economocracy as a transformative framework aimed at addressing these systemic issues by integrating democratic principles into economic decision-making to achieve social equity, economic efficiency, and environmental sustainability. The research focuses on two core mechanisms: Economic Productive Resets (EPRs) and Economic Periodic Injections (EPIs). EPRs facilitate proportional redistribution of resources to reduce income disparities, while EPIs target investments to stimulate job creation, mitigate automion-related job displacement, and support sustainable development. The study employs a theoretical and analytical methodology, developing mathematical models to quantify the impact of EPRs and EPIs on key economic indicators, including the Gini coefficient for inequality, unemployment rates, average wages, and job displacement due to automation. Hypothetical scenarios simulate baseline conditions, EPR implementation, and the combined application of EPRs and EPIs. The methodology is threefold: (1) a mathematical–theoretical validation of the Cycle of Money framework, establishing internal consistency; (2) an econometric analysis using global historical data (2000–2023) to evaluate the correlation between GNI per capita, Gini coefficient, and average wages; and (3) scenario simulations and Difference-in-Differences (DiD) estimates to test the systemic impact of implementing EPR/EPI policies on inequality and labor outcomes. The models are further strengthened through tools such as OLS regression, and Impulse results to assess causality and dynamic interactions. Empirical results confirm that EPR/EPI can substantially reduce income inequality and unemployment, while increasing wage levels, findings supported by both the theoretical architecture and data-driven outcomes. Results demonstrate that Economocracy can significantly lower income inequality, reduce unemployment, increase wages, and mitigate automation’s effects on the labor market. These findings highlight Economocracy’s potential as a viable alternative to traditional economic systems, offering a sustainable pathway that harmonizes growth, social justice, and environmental stewardship in the global economy. Economocracy demonstrates potential to reduce debt per capita by increasing the efficiency of public resource allocation and enhancing average income levels. As EPIs stimulate employment and productivity while EPRs moderate inequality, the resulting economic growth expands the tax base and alleviates fiscal pressures. These dynamics lead to lower per capita debt burdens over time. The analysis is situated within the broader discourse of institutional economics to demonstrate that Economocracy is not merely a policy correction but a new economic system akin to democracy in political life. Full article

Addressing climate change and advancing clean energy transitions demand holistic approaches that capture complex, interconnected system behaviors. This review focuses on the application of causal loop diagrams (CLDs) as a core systems-thinking methodology to understand and manage dynamic feedback within environmental, social, and technological domains. CLDs visually map the reinforcing and balancing loops that drive climate risks, clean energy adoption, and sustainable development, offering intuitive insights into system structure and behavior. Through a synthesis of empirical studies and case examples, this paper demonstrates how CLDs help identify leverage points in renewable energy policy, carbon management, and ecosystem resilience. Despite their strengths in simplifying complexity and enhancing stakeholder communication, challenges remain—including data gaps, model validation, and the integration of diverse knowledge systems. The review also examines recent innovations that improve CLD effectiveness, such as hybrid modeling approaches and digital tools that enhance transparency and decision support. By emphasizing CLDs’ unique capacity to reveal feedback mechanisms critical for climate action and energy planning, this study provides actionable recommendations for researchers, policymakers, and practitioners seeking to leverage systems thinking for transformative, sustainable solutions. Full article

The increasing demand for food necessitates that agri-food systems adopt innovative techniques to enhance food production while optimizing the use of limited resources, such as water. In agriculture, hydrogels are being increasingly used to enhance water retention and reduce irrigation requirements. However, most of these materials are based on synthetic polymers that are not biodegradable. This raises serious environmental and health concerns, highlighting the urgent need for sustainable, biodegradable alternatives. Biomass-derived from agro-industrial waste presents a substantial potential for producing hydrogels, which can effectively function as water collectors and suppliers for crops. This review article provides a comprehensive overview of recent advancements in the application of agro-industrial waste for the formulation of hydrogels. Additionally, it offers a critical analysis of the development of hydrogels utilizing natural and compostable materials. Agro-industrial and food waste, which are rich in hemicellulose and cellulose, have been utilized to enhance the mechanical properties and water absorption capacity of hydrogels. These biomaterials hold significant potential for the development of effective hydrogels in agricultural applications; they can be either hybrid or natural materials that exhibit efficacy in enhancing seed germination, improving water retention capabilities, and facilitating the controlled release of fertilizers. Natural hydrogels derived from agro-industrial waste present a sustainable technological alternative that is environmentally benign. Full article

Species and phylogenetic diversity play vital roles in sustaining the structure, function, and resilience of plant communities, particularly in tropical rainforests. However, the mechanisms according to which environmental filtering and competitive exclusion influence diversity across forest layers remain insufficiently understood. In this study, we investigated the species and phylogenetic diversity patterns in two representative tropical rainforest sites—Bawangling and Jianfengling—within Hainan Tropical Rainforest National Park, China, focusing on communities associated with the endangered species Hopea hainanensis. We employed a one-way ANOVA and Pearson’s correlation analyses to examine the distribution characteristics and interrelationships among diversity indices and used Mantel tests to assess the correlations with environmental variables. Our results revealed that the plant community in Jianfengling exhibited a significantly higher species richness at the family, genus, and species levels (a total of 288 plant species have been recorded, belonging to 82 families and 183 genera) compared to that in Bawangling (a total of 212 plant species, belonging to 75 families and 162 genera). H. hainanensis held the highest importance value in the middle tree layer across both sites (IV(BWL) = 12.44; IV(JFL) = 5.73), while dominant species varied notably among other forest layers, indicating strong habitat specificity. Diversity indices, including the Simpson index, the Shannon–Wiener index, and Pielou’s evenness, were significantly higher in the large shrub layer of Jianfengling, whereas Bawangling showed a relatively higher Shannon–Wiener index in the middle shrub layer. Phylogenetic diversity (PD) and the phylogenetic structure indices (NRI and NTI) displayed distinct vertical stratification patterns between sites. Furthermore, the PD in Bawangling’s large shrub layer was positively correlated with total phosphorus in the soil, while community evenness was influenced by soil organic carbon and total nitrogen. In Jianfengling, species richness was significantly associated with soil bulk density, altitude, and pH. These findings enhance our understanding of the ecological and evolutionary processes shaping biodiversity in tropical rainforests and highlight the importance of incorporating both species and phylogenetic metrics into the conservation strategies for endangered species such as Hopea hainanensis. Full article

The widespread use of pesticides in modern agriculture has significantly enhanced food production by managing pests and diseases; however, their degradation in soil can lead to unintended consequences for soil fertility and nutrient cycling. This review explores the mechanisms of pesticide degradation, both abiotic and biotic, and the soil factors influencing these processes. It critically examines how degradation products impact soil microbial communities, organic matter decomposition, and key nutrient cycles, including nitrogen, phosphorus, potassium, and micronutrients. This review highlights emerging evidence linking pesticide residues with altered enzymatic activity, disrupted microbial populations, and reduced nutrient bioavailability, potentially compromising soil structure, water retention, and long-term productivity. Additionally, it discusses the broader environmental and agricultural implications, including decreased crop yields, biodiversity loss, and groundwater contamination. Sustainable management strategies such as bioremediation, the use of biochar, eco-friendly pesticides, and integrated pest management (IPM) are evaluated for mitigating these adverse effects. Finally, this review outlines future research directions emphasizing long-term studies, biotechnology innovations, and predictive modeling to support resilient agroecosystems. Understanding the intricate relationship between pesticide degradation and soil health is crucial to ensuring sustainable agriculture and food security. Full article

Coal serves as the primary energy source for China, with production anticipated to reach 4.76 billion tons in 2024. However, the mining process generates a significant amount of gangue, with approximately 800 million tons produced in 2023 alone. Currently, China faces substantial gangue stockpiles, characterized by a low comprehensive utilization rate that fails to meet the country’s ecological and environmental protection requirements. The environmental challenges posed by the treatment and disposal of gangue are becoming increasingly severe. This review employs bibliometric analysis and theoretical perspectives to examine the latest advancements in gangue utilization, specifically focusing on the application of computational chemistry to elucidate the structural features and interaction mechanisms of coal gangue, and to collate how these insights have been leveraged in the literature to inform its potential utilization routes. The aim is to promote the effective resource utilization of this material, and key topics discussed include evaluating the risks of spontaneous combustion associated with gangue, understanding the mechanisms governing heavy metal migration, and modifying coal byproducts to enhance both economic viability and environmental sustainability. The case studies presented in this article offer valuable insights into the gangue conversion process, contributing to the development of more efficient and eco-friendly methods. By proposing a theoretical framework, this review will support ongoing initiatives aimed at the sustainable management and utilization of coal gangue, emphasizing the critical need for continued research and development in this vital area. This review uniquely combines bibliometric analysis with computational chemistry to identify new trends and gaps in coal waste utilization, providing a roadmap for future research. Full article

Mechanical friction offers a frequent approach for sustainable energy harvesting, as it can be captured and transformed into electricity by means of the triboelectric phenomenon. Theoretically, this electricity may subsequently be employed to drive electrochemical water purification processes. Herein, the experimental results confirm that the SiC particles effectively trigger the tribocatalytic decomposition of Rhodamine B (RhB). During the tribocatalytic decomposition of dye, mechanical friction is generated at the contact surface between the tribocatalyst and a custom-fabricated polytetrafluoroethylene (PTFE) rotating disk, under varying conditions of stirring speed, temperature, and pH value. Hydroxyl radicals and superoxide radicals are confirmed as the dominant reactive species participating in tribocatalytic dye decomposition, as demonstrated by reactive species inhibition experiments. Furthermore, the SiC particles demonstrate remarkable reusability, even after being subjected to five consecutive recycling processes. The exceptional tribocatalytic performance of SiC particles makes them potentially applicable in water purification by harnessing environmental friction energy. Full article

This study evaluates the effectiveness of the B Impact Assessment (BIA) as a catalyst for integrating sustainability into industrial firms through a qualitative case study of LC Paper, the first B Corp-certified tissue manufacturer globally and a pioneer in applying BIA in the pulp and paper sector. Based on semi-structured interviews, organizational documents, and direct observation, this study examines how BIA influences corporate governance, environmental practices, and stakeholder engagement. The findings show that BIA fosters structured goal setting and the implementation of measurable actions aligned with environmental stewardship, social responsibility, and economic resilience. Tangible outcomes include improved stakeholder trust, internal transparency, and employee development, while implementation challenges such as resource allocation and procedural complexity are also reported. Although the single-case design limits generalizability, this study identifies mechanisms transferable to other firms, particularly those in environmentally intensive sectors. The case studied also illustrates how leadership commitment, participatory governance, and data-driven tools facilitate the operationalization of sustainability. By integrating stakeholder and institutional theory, this study contributes conceptually to understanding certification frameworks as tools for embedding sustainability. This research offers both theoretical and practical insights into how firms can align strategy and impact, expanding the application of BIA beyond early adopters and into traditional industrial contexts. Full article

The growing disposal of used tyres and plastic waste in landfills poses a significant environmental challenge. This study investigates the potential of utilizing used tyre rubber and macro-synthetic fibres (MSFs) made from recycled plastics in fibre-reinforced rubberized concrete (RuFRC). Various percentages of tyre rubber shreds were used to replace coarse aggregates, calculated as 10%, 20%, and 30% of the volume of fine aggregates; fibre dosages (0%, 0.25%, 0.5%, 0.75%, and 1% by volume) were incorporated into the mix, and a series of physical, mechanical, and durability properties were evaluated. The results show that, as the fibre and rubber content increased, the slump of RuFRC decreased, with the lowest value obtained for concrete with 1% fibre and 30% rubber. The density of RuFRC decreases as the rubber percentage increases due to air voids and increased porosity caused by the rubber. The strength properties of RuFRC were found to decline with the increase in the rubber content, with mixes containing 30% rubber exhibiting reductions of about 60% in compressive strength, 27% in tensile strength, and 13% in flexural strength compared to the control specimen. Durability testing revealed that an increased rubber content led to higher water absorption, water penetration, and chloride ion permeability, with 30% rubber showing the highest values. However, lower rubber content (10%) and higher fibre dosages improved the durability characteristics, with water absorption reduced by up to 5% and shrinkage strains lowered by about 7%, indicating better compaction and bonding. These results indicate that RuFRC with moderate rubber and higher fibre content offers a promising balance between sustainability and performance. Full article

In modern agriculture, tractors play a crucial role in powering tools and implements. Proper operation of agricultural tractors in mechanized field operations can support sustainable agriculture and reduce emissions of pollutants such as carbon dioxide (CO₂). This has been a recurring concern associated with agricultural intensification for food production. This study aimed to evaluate the optimization of tractor gears and engine speed during crop operations to minimize CO₂ emissions and promote sustainability. The experiment was conducted using a strip plot design with subdivided sections and six replications, following a double factorial structure. The first factor evaluated was the type of agricultural implement (disc harrow, subsoiler, or sprayer), while the second factor was the engine speed setting (nominal or reduced). Operational and energy performance metrics were analyzed, including fuel consumption and CO₂ emissions, travel speed, effective working time, wheel slippage, and working depth. Optimized gear selection and engine speeds resulted in a 20 to 40% reduction in fuel consumption and CO₂ emissions. However, other evaluated parameters remain unaffected by the reduced engine speed, regardless of the implement used, ensuring the operation’s quality. Thus, optimizing operator training or configuring machines allows for environmental impact reduction, making agricultural practices more sustainable. Full article

The eruption of the Cumbre Vieja volcano on 19 September 2021 resulted in the deposition of over 20 million cubic meters of tephra, posing significant environmental and logistical challenges in the affected areas. This study aimed to explore the valorization of volcanic ash (VA) by evaluating its potential use in producing sustainable mortar by incorporating it as a replacement for cement or sand. Various experimental mixtures were prepared with different proportions of VA which substituted either cement or sand, and these mixes were characterized through a mechanical and microstructural campaign. Additionally, shrinkage was evaluated for the mixtures which showed good mechanical results. The results suggest that partially replacing cement with up to 15% ground VA as well as substituting sand with up to 25% VA are promising strategies for the production of sustainable mortar mixes. This research contributes to the understanding of the influence of VA in cementitious matrices and offers a novel approach for integrating locally available geomaterials into infrastructure design in volcanic active regions. Full article

Cutting beech plywood using abrasive water jet (AWJ) technology represents a significant area of research due to increasing demands for precision, quality, and environmental sustainability in manufacturing processes within the woodworking industry. AWJ technology enables non-contact cutting of materials without causing thermal deformation or mechanical damage, which is crucial for preserving the structural integrity and mechanical properties of the plywood. This article investigates cutting beech plywood using technical methods using an abrasive water jet (AWJ) at 400 MPa pressure, with Australian garnet (80 MESH) as the abrasive material. It examines how abrasive mass flow rate, traverse speed, and material thickness affect AWJ lag, which in turn influences both cutting quality and accuracy. Measurements were conducted with power abrasive mass flow rates of 250, 350, and 450 g/min and traverse speeds of 0.2, 0.4, and 0.6 m/min. Results show that increasing the abrasive mass flow rate from 250 g/min to 350 g/min slightly decreased the AWJ cut width by 0.05 mm, while further increasing to 450 g/min caused a slight increase of 0.1 mm. Changes in traverse speed significantly influenced cut width; increasing the traverse speed from 0.2 m/min to 0.4 m/min widened the AWJ by 0.21 mm, while increasing it to 0.6 m/min caused a slight increase of 0.18 mm. For practical applications, it is recommended to use an abrasive mass flow rate of around 350 g/min combined with a traverse speed between 0.2 and 0.4 m/min when cutting beech plywood with AWJ. This balance minimizes jet lag and maintains high surface quality comparable to conventional milling. For thicker plywood, reducing the traverse speed closer to 0.2 m/min and slightly increasing the abrasive flow should ensure clean cuts without compromising surface integrity. Full article

In recent years, growing concerns over environmental degradation and deepening awareness of the necessity of sustainable development have propelled green and low-carbon energy transition into a focal issue for both academia and policymakers. By decomposing energy transition into the transformation of energy structure and the upgrading of energy efficiency, this study investigates the impact and mechanisms of green finance on energy transition across 30 provinces (municipalities and autonomous regions) in China, with the exception of Tibet. In addition, the impact of climate change is incorporated into the analytical framework. Empirical results demonstrate that green finance development significantly accelerates energy transition, a conclusion robust to rigorous validation. Analysis of the mechanism shows that green finance promotes energy transition through the facilitation of technological innovation and the upgrade of industrial structures. Moreover, empirical evidence reveals that climate change undermines the promotional influence of sustainable finance on energy system transformation. The magnitude of this suppression varies nonlinearly across provincial jurisdictions with differing energy transition progress. Regional heterogeneity analyses further uncover marked discrepancies in climate–finance interactions, demonstrating amplified effects in coastal economic hubs, underdeveloped western provinces, and regions with mature eco-financial markets. According to these findings, actionable policy suggestions are put forward to strengthen green finance and accelerate energy transition. Full article