Search Results (899)

The development of anode-free sodium metal batteries (AFSMBs) offers a promising pathway to achieve ultrahigh energy density and cost efficiency inherent to conventional sodium ion/metal batteries. However, irreversible Na plating/stripping and dendritic growth remain critical barriers. Herein, we demonstrate that separator engineering is a pivotal strategy for stabilizing AFSMBs. Through systematic evaluation of four separators—2500 separator (PP), 2325 separator (PP/PE/PP), glass fiber (GF), and an Al₂O₃-coated PE membrane, we reveal that the Al₂O₃-coated separator uniquely enables exceptional interfacial kinetics and morphological control. Na||Na symmetric cells with Al₂O₃ coated separator exhibit ultralow polarization (4.5 mV) and the highest exchange current density (1.77 × 10⁻² mA cm⁻²), while the anode-free AlC-NFPP full cells retain 91.6% capacity after 150 cycles at 2C. Specifically, the Al₂O₃ coating homogenizes Na⁺ flux, promotes dense and planar Na deposition, and facilitates near-complete stripping with minimal “dead Na”. This work establishes ceramic-functionalized separators as essential enablers of practical high-energy AFSMBs. Full article

To further enhance the economic performance of fuel cell vehicles (FCVs), this study develops a model-adaptive model predictive control (MPC) strategy. This strategy leverages the dynamic relationship between proton exchange membrane fuel cell (PEMFC) output characteristics and temperature to track its optimal operating temperature (OOT), addressing challenges of temperature control accuracy and high energy consumption in the PEMFC thermal management system (TMS). First, PEMFC and TMS models were developed and experimentally validated. Subsequently, the PEMFC power–temperature coupling curve was experimentally determined under multiple operating conditions to serve as the reference trajectory for TMS multi-objective optimization. For MPC controller design, the TMS model was linearized and discretized, yielding a predictive model adaptable to different load demands for stack temperature across the full operating range. A multi-constrained quadratic cost function was formulated, aiming to minimize the deviation of the PEMFC operating temperature from the OOT while accounting for TMS parasitic power consumption. Finally, simulations under Worldwide Harmonized Light Vehicles Test Cycle (WLTC) conditions evaluated the OOT tracking performance of both PID and MPC control strategies, as well as their impact on stack efficiency and TMS energy consumption at different ambient temperatures. The results indicate that, compared to PID control, MPC reduces temperature tracking error by 33%, decreases fan and pump speed fluctuations by over 24%, and lowers TMS energy consumption by 10%. These improvements enhance PEMFC operational stability and improve FCV energy efficiency. Full article

Both ground source heat pumps (GSHPs) and energy underground structures are engineered systems that utilize shallow geothermal energy. However, due to the construction complexity and associated costs of energy tunnels, their heat exchange efficiency relative to GSHPs remains a topic worthy of in-depth investigation. In this study, a thermal–hydraulic (TH) coupled finite element model was developed based on a section of the Torino Metro Line in Italy to analyze the differences in and influencing factors of heat transfer performance between energy tunnels and GSHPs. The model was validated by comparing the outlet temperature curves under both winter and summer loading conditions. Based on this validated model, a parametric analysis was conducted to examine the effects of the tunnel air velocity, heat carrier fluid velocity, and fluid type. The results indicate that, under identical environmental conditions, energy tunnels exhibit higher heat exchange efficiency than conventional GSHP systems and are less sensitive to external factors such as fluid velocity. Furthermore, a comparison of different heat carrier fluids, including alcohol-based fluids, refrigerants, and water, revealed that the fluid type significantly affects thermal performance, with the refrigerant R-134a outperforming ethylene glycol and water in both heating and cooling efficiency. Full article

The rapid growth of Internet of Things (IoT) deployment has led to an unprecedented volume of interconnected, resource-constrained devices. Securing their communication is essential, especially in vehicular environments, where sensitive data exchange requires robust authentication, integrity, and confidentiality guarantees. In this paper, we present an empirical evaluation of TLS (Transport Layer Security)-enhanced MQTT (Message Queuing Telemetry Transport) on low-cost, quad-core Cortex-A72 ARMv8 boards, specifically the Raspberry Pi 4B, commonly used as prototyping platforms for On-Board Units (OBUs) and Road-Side Units (RSUs). Three MQTT entities, namely, the broker, the publisher, and the subscriber, are deployed, utilizing Elliptic Curve Cryptography (ECC) for key exchange and authentication and employing the AES_256_GCM and ChaCha20_Poly1305 ciphers for confidentiality via appropriately selected libraries. We quantify resource consumption in terms of CPU utilization, execution time, energy usage, memory footprint, and goodput across TLS phases, cipher suites, message packaging strategies, and both Ethernet and WiFi interfaces. Our results show that (i) TLS 1.3-enhanced MQTT is feasible on Raspberry Pi 4B devices, though it introduces non-negligible resource overheads; (ii) batching messages into fewer, larger packets reduces transmission cost and latency; and (iii) ChaCha20_Poly1305 outperforms AES_256_GCM, particularly in wireless scenarios, making it the preferred choice for resource- and latency-sensitive V2X applications. These findings provide actionable recommendations for deploying secure MQTT communication on an IoT platform. Full article

Creating a comfortable microclimate in the premises of buildings is currently becoming one of the priorities in the field of architecture, construction and engineering systems. The increased attention from the scientific community to this topic is due not only to the desire to ensure healthy and favorable conditions for human life but also to the need for the rational use of energy resources. This area is becoming particularly relevant in the context of global challenges related to climate change, rising energy costs and increased environmental requirements. Practice shows that any technical solutions to ensure comfortable temperature, humidity and air exchange in rooms should be closely linked to the concept of energy efficiency. This allows one not only to reduce operating costs but also to significantly reduce greenhouse gas emissions, thereby contributing to sustainable development and environmental safety. In this connection, this study presents a parametric assessment of the influence of climatic and geometric factors on the aerodynamic characteristics of the air cavity, which affect the heat exchange process in the ventilated layer of curtain wall systems. The assessment was carried out using a combined analytical calculation method that provides averaged thermophysical parameters, such as mean air velocity ($V_s$), average internal surface temperature ($t_{in.s}^{av}$), and convective heat transfer coefficient (${\alpha }_s$) within the air cavity. This study resulted in empirical average values, demonstrating that the air velocity within the cavity significantly depends on atmospheric pressure and façade height difference. For instance, a 10-fold increase in façade height leads to a 4.4-fold increase in air velocity. Furthermore, a three-fold variation in local resistance coefficients results in up to a two-fold change in airflow velocity. The cavity thickness, depending on atmospheric pressure, was also found to affect airflow velocity by up to 25%. Similar patterns were observed under ambient temperatures of +20 °C, +30 °C, and +40 °C. The analysis confirmed that airflow velocity is directly affected by cavity height, while the impact of solar radiation is negligible. However, based on the outcomes of the analytical model, it was concluded that the method does not adequately account for the effects of solar radiation and vertical temperature gradients on airflow within ventilated façades. This highlights the need for further full-scale experimental investigations under hot climate conditions in South Kazakhstan. The findings are expected to be applicable internationally to regions with comparable climatic characteristics. Ultimately, a correct understanding of thermophysical processes in such structures will support the advancement of trends such as Lightweight Design, Functionally Graded Design, and Value Engineering in the development of curtain wall systems, through the optimized selection of façade configurations, accounting for temperature loads under specific climatic and design conditions. Full article

This article presents an empirical evaluation of the technical and economic performance of a building-integrated photovoltaic (PV) system implemented at the Faculty of Architecture and Urbanism of the University of Cuenca, Ecuador. This study explores both stages of deployment, beginning with a 7.7 kWp pilot system and later scaling to a full 75.6 kWp configuration. This hourly monitoring of power exchanges with utility was conducted over several months using high-resolution instrumentation and cloud-based analytics platforms. A detailed comparison between projected energy output, recorded production, and real energy consumption was carried out, revealing how seasonal variability, cloud cover, and academic schedules influence system behavior. The findings also include a comparison between billed and actual electricity prices, as well as an analysis of the system’s payback period under different cost scenarios, including state-subsidized and real-cost frameworks. The results confirm that energy exports are frequent during weekends and that daily generation often exceeds on-site demand on non-working days. Although the university benefits from low electricity tariffs, the system demonstrates financial feasibility when broader public cost structures are considered. This study highlights operational outcomes under real-use conditions and provides insights for scaling distributed generation in institutional settings, with particular relevance for Andean urban contexts with similar solar profiles and tariff structures. Full article

Biodiesel, a renewable and environmentally friendly alternative to fossil fuels, has attracted significant attention due to its potential to reduce greenhouse gas emissions. However, high production costs and complex processing remain challenges. Heterogeneous catalysts have shown promise in overcoming these barriers by offering benefits, such as easy separation, reusability, low-cost raw materials, and the ability to reduce reaction times and energy consumption. This review evaluates key classes of heterogeneous catalysts, such as metal oxides, ion exchange resins, and zeolites, and their performance in transesterification and esterification processes. It highlights the importance of catalyst preparation methods, textural properties, including surface area, pore volume, and pore size, activation techniques, and critical operational parameters, like the methanol-to-oil ratio, temperature, time, catalyst loading, and reusability. The analysis reveals that catalysts supported on high surface area materials often achieve higher biodiesel yields, while metal oxides derived from natural sources provide cost-effective and sustainable options. Challenges, such as catalyst deactivation, sensitivity to feedstock composition, and variability in performance, are discussed. Overall, the findings underscore the potential of heterogeneous catalysts to enhance biodiesel production efficiency, although further optimization and standardized evaluation protocols are necessary for their broader industrial application. Full article

Despite notable advancements in smart home technologies, residential energy management continues to face critical challenges. These include the complex integration of intermittent renewable energy sources, issues related to data latency, interoperability, and standardization across diverse systems, the inflexibility of centralized control architectures in dynamic environments, and the difficulty of accurately modeling and influencing occupant behavior. To address these challenges, this study proposes an intelligent multi-agent system designed to accurately estimate and control energy consumption in residential buildings, with the overarching objective of optimizing energy usage while maintaining occupant comfort and satisfaction. The methodological approach employed is a hybrid framework, integrating multi-agent system architecture with system dynamics modeling and agent-based modeling. This integration enables decentralized and intelligent control while simultaneously simulating physical processes such as heat exchange, insulation performance, and energy consumption, alongside behavioral interactions and real-time adaptive responses. The system is tested under varying conditions, including changes in building insulation quality and external temperature profiles, to assess its capability for accurate control and estimation of energy use. The proposed tool offers significant added value by supporting real-time responsiveness, behavioral adaptability, and decentralized coordination. It serves as a risk-free simulation platform to test energy-saving strategies, evaluate cost-effective insulation configurations, and fine-tune thermostat settings without incurring additional cost or real-world disruption. The high fidelity and predictive accuracy of the system have important implications for policymakers, building designers, and homeowners, offering a practical foundation for informed decision making and the promotion of sustainable residential energy practices. Full article

Hydrogen production through electrolysis of water can achieve efficient, stable and diversified utilization of renewable energy. To this end, a hybrid electrolyzer system for hydrogen production based on bi-layer optimization is constructed. Firstly, the wind and photovoltaic power is decomposed into high-frequency and low-frequency components by an adaptive wavelet packet. The low-frequency power is allocated to the alkaline electrolyzers (AWE) to ensure its stability, and the high-frequency power is allocated to the proton exchange membrane electrolyzers (PEM) with a faster response characteristic, thereby improving the energy utilization rate. This paper proposes a bi-layer optimization model, in which the upper-layer objective is to minimize the cost of mixed hydrogen production, and the lower-layer optimization objective is to maximize the utilization rate of renewable energy. The differential evolution algorithm optimizes the upper-layer objective, with results sent to the lower layer. Then, the YALMIP toolbox is used to solve the lower-layer objective. Through case analysis, the optimal proportion of AWE and PEM hydrogen electrolyzers obtained by this optimization method is 89.5 and 10.5, respectively. Compared with a single type of electrolyzer, the method proposed in this paper effectively improves the energy utilization efficiency and reduces the cost of hydrogen production. Full article

This study presents an optimization approach for sizing photovoltaic (PV) and battery energy storage systems (BESSs) within a DC microgrid, aiming to enhance cost-effectiveness, energy reliability, and environmental sustainability. PV generation is modeled based on environmental parameters such as solar irradiance and ambient temperature, while battery charging and discharging operations are managed according to real-time demand. A simulation framework is developed in MATLAB 2021b to analyze PV output, battery state of charge (SOC), and grid energy exchange. For demand-side management, the Long Short-Term Memory (LSTM) deep learning model is employed to forecast future load profiles using historical consumption data. Moreover, a Multi-Layer Perceptron (MLP) neural network is designed for comparison purposes. The dynamic load prediction, provided by LSTM in particular, improves system responsiveness and efficiency compared to MLP. Simulation results indicate that optimal sizing of PV and storage units significantly reduces energy costs and dependency on the main grid for both forecasting methods; however, the LSTM-based approach consistently achieves higher annual savings, self-sufficiency, and Net Present Value (NPV) than the MLP-based approach. The proposed method supports the design of more resilient and sustainable DC microgrids through data-driven forecasting and system-level optimization, with LSTM-based forecasting offering the greatest benefits. Full article

This study systematically compares the environmental and economic performance of three wastewater treatment systems: constructed wetlands (CWs), microbial fuel cells (MFCs), and their integration (CW–MFC). Lab-scale units of each system were constructed using a multi-media matrix (gravel, zeolite, and granular activated carbon), composite native wetland species (Juncus effusus, Iris sp., and Typha angustifolia), carbon-based electrodes (graphite), and standard inoculum for CW and CW–MFC. The MFC system employed carbon-based electrodes and proton-exchange membrane. The experimental design included a parallel operation of all systems treating domestic wastewater under identical hydraulic and organic loading rates. Environmental impacts were quantified across construction and operational phases using life cycle assessment (LCA) with GaBi software 9.2, employing TRACI 2021 and ReCiPe 2016 methods, while techno-economic analysis (TEA) evaluated capital and operational costs. The key results indicate that CW demonstrates the lowest global warming potential (142.26 kg CO₂-eq) due to its reliance on natural biological processes. The integrated CW–MFC system achieved enhanced pollutant removal (82.8%, 87.13%, 78.13%, and 90.3% for COD, NO₃, TN, and TP) and bioenergy generation of 2.68 kWh, balancing environmental benefits with superior treatment efficiency. In contrast, the stand-alone MFC shows higher environmental burdens, primarily due to energy-intensive material requirements and fabrication processes. TEA results highlight CW as the most cost-effective solution (USD 627/m³), with CW–MFC emerging as a competitive alternative when considering environmental benefits and operational efficiencies (USD 718/m³). This study highlights the potential of hybrid systems, such as CW–MFC, to advance sustainable wastewater treatment technologies by minimizing environmental impacts and enhancing resource recovery, supporting their broader adoption in future water management strategies. Future research should focus on optimizing materials and energy use to improve scalability and feasibility. Full article

To alleviate the impact of economic and environmental detriments caused by the increased demands of electric vehicle battery production and disposal, the use of spent batteries in second-life stationary applications such as energy storage for renewable sources or backup power systems, offers many benefits. This paper focuses on reducing the energy consumption cost and greenhouse gas emissions of Internet-of-Things-enabled campus microgrids by installing solar photovoltaic panels on rooftops alongside energy storage systems that leverage second-life batteries, a gas-fired campus power plant, and a wind turbine while considering the potential loads of a prosumer microgrid. A linear optimization problem is derived from the system by scheduling energy exchanges with the Ontario grid through net metering and solved by using Python 3.11. The aim of this work is to support Sustainable Development Goals, namely 7 (Affordable and Clean Energy), 11 (Sustainable Cities and Communities), 12 (Responsible Consumption and Production), and 13 (Climate Action). A comparison between a base case scenario and the results achieved with the proposed scenarios shows a significant reduction in electricity cost and greenhouse gas emissions and an increase in self-consumption rate and renewable fraction. This research work provides valuable insights and guidelines to policymakers. Full article

In order to improve energy utilization efficiency and the flexibility of resource transfer in oceanic-island-group microgrids, a water–electricity–hydrogen flexible scheduling strategy based on a multi-rate hydrogen-powered ship is proposed. First, the characteristics of the seawater desalination unit (SDU), proton exchange membrane electrolyzer (PEMEL), and battery system (BS) in consuming surplus renewable energy on resource islands are analyzed. The variable-efficiency operation characteristics of the SDU and PEMEL are established, and the effect of battery life loss is also taken into account. Second, a spatio-temporal model for the multi-rate hydrogen-powered ship is proposed to incorporate speed adjustment into the system optimization framework for flexible resource transfer among islands. Finally, with the goal of minimizing the total cost of the system, a flexible water–electricity–hydrogen hybrid resource transfer model is constructed, and a certain island group in the South China Sea is used as an example for simulation and analysis. The results show that the proposed scheduling strategy can effectively reduce energy loss, promote renewable energy absorption, and improve the flexibility of resource transfer. Full article

The MENA region, with its high solar potential and increasing investments in renewable energy, is transitioning away from fossil fuels toward more sustainable energy systems. To fully benefit from this transition and address issues such as intermittency and energy storage, “green” hydrogen is emerging as a key parameter. When produced using simple and cost-effective technologies like linear Fresnel reflector (LFR), it offers a practical solution. Therefore, assessing the potential of hydrogen production from LFR technology is essential to support the development of the energy sector and promote local industrial growth. This study investigates “green” hydrogen production using a 50 MW concentrated solar power (CSP) system based on LFR technology, where the CSP system generates electricity to power a proton exchange membrane electrolyzer for hydrogen production for three locations, including Ain Beni Mathar in Morocco, Assiout in Egypt, and Tabuk in Saudi Arabia. The results show that Tabuk achieved the highest annual hydrogen production (45.02 kg/kWe), followed by Assiout (38.72 kg/kWe) and Ain Beni Mathar (32.42 kg/kWe), with corresponding levelized costs of hydrogen (LCOH₂) of 6.47 USD/kg, 6.84 USD/kg, and 7.35 USD/kg, respectively. In addition, several sensitivity analyses were conducted addressing the impact of thermal energy storage (TES) on the hydrogen production and costs, the effect of reduced investment costs resulting from the local manufacturing of LFR components, and the futuristic assumption of the electrolyzer cost drop. The integration of TES enhanced hydrogen output and reduced LCOH₂ by up to 9%. Additionally, a future PEM electrolyzer costs projected for 2030 showed that LCOH₂ could decrease by up to 1.3 USD/kg depending on site conditions. These findings demonstrate that combining TES with cost optimization strategies can significantly improve both technical performance and economic feasibility in the MENA region. Full article

This paper presents a distributed optimization strategy for reactive power–voltage control in distribution networks with high photovoltaic (PV) penetration under limited sensor deployment scenarios. To address voltage violations and minimize network power losses, a novel distributed optimization framework is developed that utilizes selective nodal measurements from PV-integrated nodes and critical T-junction locations, coupled with inter-node communication for information exchange. The methodology integrates an adaptive step size algorithm within a dynamic projected primal–dual distributed optimization framework, eliminating manual parameter tuning requirements while ensuring theoretical convergence guarantees through Lyapunov stability analysis. Comprehensive validation on the IEEE 33-bus distribution test system demonstrates that the proposed strategy achieves significant performance improvements. The distributed control framework reduces measurement infrastructure requirements while maintaining near-optimal performance, demonstrating superior economic efficiency and operational reliability. These results establish the practical viability of the proposed approach for real-world distribution network applications with high renewable energy integration, providing a cost-effective solution for voltage regulation under incomplete observability conditions. Full article