Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

Article Types

Countries / Regions

Search Results (18)

Search Parameters:
Keywords = electroelastic materials

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
21 pages, 1400 KB  
Article
Frictional Contact of Functionally Graded Piezoelectric Materials with Arbitrarily Varying Properties
by Xiuli Liu, Kaiwen Xiao, Changyao Zhang, Xinyu Zhou, Lingfeng Gao and Jing Liu
Mathematics 2026, 14(3), 450; https://doi.org/10.3390/math14030450 - 27 Jan 2026
Viewed by 316
Abstract
This study investigates the two-dimensional (2D) steady-state frictional contact behavior of functionally graded piezoelectric material (FGPM) coatings under a high-speed rigid cylindrical punch. An electromechanical coupled contact model considering inertial effects is established, while a layered model is employed to simulate arbitrarily varying [...] Read more.
This study investigates the two-dimensional (2D) steady-state frictional contact behavior of functionally graded piezoelectric material (FGPM) coatings under a high-speed rigid cylindrical punch. An electromechanical coupled contact model considering inertial effects is established, while a layered model is employed to simulate arbitrarily varying material parameters. Based on piezoelectric elasticity theory, the steady-state governing equations for the coupled system are derived. By utilizing the transfer matrix method and the Fourier integral transform, the boundary value problem is converted into a system of coupled Cauchy singular integral equations of the first and second kinds in the frequency domain. These equations are solved semi-analytically, using the least squares method combined with an iterative algorithm. Taking a power-law gradient distribution as a case study, the effects of the gradient index, relative sliding speed, and friction coefficient on the contact pressure, in-plane stress, and electric displacement are systematically analyzed. Furthermore, the contact responses of FGPM coatings with power-law, exponential, and sinusoidal gradient profiles are compared. The findings provide a theoretical foundation for the optimal design of FGPM coatings and for enhancing their operational reliability under high-speed service conditions. Full article
Show Figures

Figure 1

11 pages, 2875 KB  
Article
Tb3+-Doped LGS Crystals: Crystal Growth and Electro-Elastic Features
by Nianlong Zhang, Jipeng Wu, Hengyuan Zhang, Feifei Chen, Fapeng Yu, Li Sun and Xian Zhao
Crystals 2025, 15(3), 269; https://doi.org/10.3390/cryst15030269 - 13 Mar 2025
Cited by 1 | Viewed by 1034
Abstract
Piezoelectric materials have garnered significant attention due to their diverse applications in technologies such as sensors, actuators, and energy-harvesting systems. This study focuses on the growth and characterization of Tb3+-doped La3Ga5SiO14 (LGS) crystals. A novel 10% [...] Read more.
Piezoelectric materials have garnered significant attention due to their diverse applications in technologies such as sensors, actuators, and energy-harvesting systems. This study focuses on the growth and characterization of Tb3+-doped La3Ga5SiO14 (LGS) crystals. A novel 10% Tb3+-doped single LGS crystal was successfully grown using the Czochralski method. The crystal structure and fluorescence properties were determined, and the electro-elastic properties were evaluated by the impedance method, which assessed dielectric, piezoelectric, and elastic constants. The Tb3+-doped crystal was observed to crystallize in the trigonal system, with the concentration of the Tb3+ ion in the crystal determined to be 2.50 wt%. The piezoelectric coefficients were measured as d11 = 5.41 pC/N and d14 = −5.52 pC/N, and the dielectric constants were found to be 19.60 and 52.75, respectively. The temperature-dependent behavior of Tb:LGS crystals was investigated, particularly concerning their elastic constants, demonstrating favorable thermal stability. This study provides valuable insights into the relationship between the crystals’ structural characteristics and performance. Additionally, the fluorescence properties were measured; a long lifetime (τ = 1.655 ms) indicated the potential applications of Tb:LGS crystals in laser technology. Full article
Show Figures

Figure 1

18 pages, 3446 KB  
Review
Mechanics of Surface Instabilities in Soft Dielectrics Subject to Electromechanical Loading
by Jiangfei Li, Zehua Wang and Jianyou Zhou
Polymers 2024, 16(24), 3612; https://doi.org/10.3390/polym16243612 - 23 Dec 2024
Cited by 3 | Viewed by 1181
Abstract
As a category of polymeric materials, soft dielectrics, such as most elastomers and rubber-like materials, have shown great potential for extensive applications in various fields. Owing to their intriguing electromechanical coupling behaviors, the morphological instabilities in soft dielectrics have been an active research [...] Read more.
As a category of polymeric materials, soft dielectrics, such as most elastomers and rubber-like materials, have shown great potential for extensive applications in various fields. Owing to their intriguing electromechanical coupling behaviors, the morphological instabilities in soft dielectrics have been an active research field in recent years. In this work, the recent progress in experimental and theoretical research on their electromechanical morphological instabilities is reviewed, especially regarding the theoretical aspect. First, we revisit the theoretical framework for the electroelasticity of soft dielectrics. Then, the typical configurations of soft dielectric membranes used to generate two typical types of surface instabilities, namely wrinkles and creases, are introduced. Three commonly used modeling approaches (i.e., the stress balance method, the incremental method, and the energy method) for surface instabilities are reviewed with specific examples. Moreover, discussions on the difference between these methods and the corresponding critical loading conditions are presented. Furthermore, this review also covers the relation and transition between wrinkling and creasing phenomena. Full article
(This article belongs to the Special Issue Mechanic Properties of Polymer Materials)
Show Figures

Figure 1

24 pages, 4300 KB  
Review
Electromechanical Deformations and Bifurcations in Soft Dielectrics: A Review
by Yipin Su, Xudong Shen, Zinan Zhao, Bin Wu and Weiqiu Chen
Materials 2024, 17(7), 1499; https://doi.org/10.3390/ma17071499 - 26 Mar 2024
Cited by 8 | Viewed by 1849
Abstract
Dielectric elastomers have attracted considerable attention both from academia and industry alike over the last two decades due to their superior mechanical properties. In parallel, research on the mechanical properties of dielectrics has been steadily advancing, including the theoretical, experimental, and numerical aspects. [...] Read more.
Dielectric elastomers have attracted considerable attention both from academia and industry alike over the last two decades due to their superior mechanical properties. In parallel, research on the mechanical properties of dielectrics has been steadily advancing, including the theoretical, experimental, and numerical aspects. It has been recognized that the electromechanical coupling property of dielectric materials can be utilized to drive deformations in functional devices in a more controllable and intelligent manner. This paper reviews recent advances in the theory of dielectrics, with specific attention focused on the theory proposed by Dorfmann and Ogden. Additionally, we provide examples illustrating the application of this theory to analyze the electromechanical deformations and the associated bifurcations in soft dielectrics. We compared the bifurcations in elastic and dielectric materials and found that only compressive bifurcation modes exist in elastic structures, whereas both compressive and tensile modes coexist in dielectric structures. We summarize two proposed ways to suppress and prevent the tensile bifurcations in dielectric materials. We hope that this literature survey will foster further advancements in the field of the electroelastic theory of soft dielectrics. Full article
Show Figures

Figure 1

14 pages, 2816 KB  
Article
Passive Damping of Longitudinal Vibrations of a Beam in the Vicinity of Natural Frequencies Using the Piezoelectric Effect
by Nelly Rogacheva, Vladimir Sidorov and Yulia Zheglova
Axioms 2023, 12(10), 981; https://doi.org/10.3390/axioms12100981 - 18 Oct 2023
Viewed by 1821
Abstract
To significantly reduce the amplitude of longitudinal vibrations of the beam in the vicinity of its natural frequencies, a fundamentally new method of damping vibrations is used. For this purpose, the beam surfaces are covered with layers of polarized piezoceramics with a strong [...] Read more.
To significantly reduce the amplitude of longitudinal vibrations of the beam in the vicinity of its natural frequencies, a fundamentally new method of damping vibrations is used. For this purpose, the beam surfaces are covered with layers of polarized piezoceramics with a strong piezoelectric effect. We will use two types of electrical conditions on the electrodes of the piezoelectric layers: short-circuited electrodes and disconnected electrodes. On short-circuited electrodes, the electric potential is zero. As a result of the piezoelectric effect, an electric charge appears on the disconnected electrodes when the beam is deformed. The electroelastic state of a beam with different electrical conditions is described by different boundary value problems. A new approach to damping vibrations in the vicinity of natural frequencies is based on the following rule for controlling the dynamic characteristics of a structure: when the beam vibration frequency approaches its natural vibration frequency, we change the electrical conditions on the electrodes of the piezoelectric layers, thereby changing the spectrum of its natural frequencies. Let, for example, the vibration frequency of a beam with short-circuited electrodes approach its natural frequency. In this case, the amplitudes of the sought quantities grow without limit. The natural frequency spectrum of a beam with disconnected electrodes will differ from the spectrum of a beam with short-circuited electrodes. As a result, the amplitudes of the sought quantities will decrease. It is shown that the efficiency of vibration damping can be significantly increased by choosing the direction of the preliminary polarization of the piezoelectric material and the location of its electrodes. Numerical examples are given that demonstrate the effectiveness of the proposed method. The advantage of the method lies in its simplicity and the low cost of the piezoelectric material, which serves as a non-inertial damper. Full article
(This article belongs to the Special Issue Applied Numerical Analysis in Civil Engineering)
Show Figures

Figure 1

29 pages, 4588 KB  
Review
FEM Modeling of Electro-Acoustic Nonlinearities in Surface Acoustic Wave Devices: A Methodological Review
by Andreas P. Mayer, Elena A. Mayer, Markus Mayer, Werner Ruile, Vikrant Chauhan, Thomas Forster and Karl C. Wagner
Acoustics 2023, 5(3), 759-787; https://doi.org/10.3390/acoustics5030045 - 7 Aug 2023
Cited by 4 | Viewed by 4186
Abstract
In the framework of electro-elasticity theory and the finite element method (FEM), a model is set up for the computation of quantities in surface acoustic wave (SAW) devices accounting for nonlinear effects. These include second-order and third-order intermodulations, second and third harmonic generation [...] Read more.
In the framework of electro-elasticity theory and the finite element method (FEM), a model is set up for the computation of quantities in surface acoustic wave (SAW) devices accounting for nonlinear effects. These include second-order and third-order intermodulations, second and third harmonic generation and the influence of electro-acoustic nonlinearity on the frequency characteristics of SAW resonators. The model is based on perturbation theory, and requires input material constants, e.g., the elastic moduli up to fourth order for all materials involved. The model is two-dimensional, corresponding to an infinite aperture, but all three Cartesian components of the displacement and electrical fields are accounted for. The first version of the model pertains to an infinite periodic arrangement of electrodes. It is subsequently generalized to systems with a finite number of electrodes. For the latter version, a recursive algorithm is presented which is related to the cascading scheme of Plessky and Koskela and strongly reduces computation time and memory requirements. The model is applied to TC-SAW systems with copper electrodes buried in an oxide film on a LiNbO3 substrate. Results of computations are presented for the electrical current due to third-order intermodulations and the displacement field associated with the second harmonic and second-order intermodulations, generated by monochromatic input tones. The scope of this review is limited to methodological aspects with the goal to enable calculations of nonlinear quantities in SAW devices on inexpensive and easily accessible computing platforms. Full article
(This article belongs to the Collection Featured Position and Review Papers in Acoustics Science)
Show Figures

Figure 1

20 pages, 1658 KB  
Article
Modelling of Electro-Viscoelastic Materials through Rate Equations
by Claudio Giorgi and Angelo Morro
Materials 2023, 16(10), 3661; https://doi.org/10.3390/ma16103661 - 11 May 2023
Cited by 4 | Viewed by 1578
Abstract
Models of dielectric solids subject to large deformations are established by following a thermodynamic approach. The models are quite general in that they account for viscoelastic properties and allow electric and thermal conduction. A preliminary analysis is devoted to the selection of fields [...] Read more.
Models of dielectric solids subject to large deformations are established by following a thermodynamic approach. The models are quite general in that they account for viscoelastic properties and allow electric and thermal conduction. A preliminary analysis is devoted to the selection of fields for the polarization and the electric field; the appropriate fields are required to comply with the balance of angular momentum and to enjoy the Euclidean invariance. Next, the thermodynamic restrictions for the constitutive equations are investigated using a wide set of variables allowing for the joint properties of viscoelastic solids, electric and heat conductors, dielectrics with memory, and hysteretic ferroelectrics. Particular attention is devoted to models for soft ferroelectrics, such as BTS ceramics. The advantage of this approach is that a few constitutive parameters provide a good fit of material behaviour. A dependence on the gradient of the electric field is also considered. The generality and the accuracy of the models are improved by means of two features. The entropy production is regarded as a constitutive property per se, while the consequences of the thermodynamic inequalities are made explicit by means of representation formulae. Full article
(This article belongs to the Special Issue Modelling of Viscoelastic Materials and Mechanical Behavior)
Show Figures

Figure 1

15 pages, 1224 KB  
Article
The Numerical Solution of Large-Scale Generalized Eigenvalue Problems Arising from Finite-Element Modeling of Electroelastic Materials
by Tatiana Martynova, Galina Muratova, Pavel Oganesyan and Olga Shtein
Symmetry 2023, 15(1), 171; https://doi.org/10.3390/sym15010171 - 6 Jan 2023
Cited by 3 | Viewed by 3133
Abstract
The generalized eigenvalue problem for a symmetric definite matrix pencil obtained from finite-element modeling of electroelastic materials is solved numerically by the Lanczos algorithm. The mass matrix is singular in the considered problem, and therefore the process proceeds with the semi-inner product defined [...] Read more.
The generalized eigenvalue problem for a symmetric definite matrix pencil obtained from finite-element modeling of electroelastic materials is solved numerically by the Lanczos algorithm. The mass matrix is singular in the considered problem, and therefore the process proceeds with the semi-inner product defined by this matrix. The shift-and-invert Lanczos algorithm is used to find multiple eigenvalues closest to some shift and the corresponding eigenvectors. The results of the numerical experiments are presented. Full article
(This article belongs to the Special Issue Mesh Methods—Numerical Analysis and Experiments II)
Show Figures

Figure 1

25 pages, 6864 KB  
Article
Electro-Elastic Modeling of Thermal Spin Transition in Diluted Spin-Crossover Single Crystals
by Karim Affes, Yogendra Singh and Kamel Boukheddaden
Int. J. Mol. Sci. 2022, 23(22), 13854; https://doi.org/10.3390/ijms232213854 - 10 Nov 2022
Cited by 4 | Viewed by 2422
Abstract
Spin-crossover solids have been studied for many years for their promising applications as optical switches and reversible high-density memories for information storage. This study reports the effect of random metal dilution on the thermal and structural properties of a spin-crossover single crystal. The [...] Read more.
Spin-crossover solids have been studied for many years for their promising applications as optical switches and reversible high-density memories for information storage. This study reports the effect of random metal dilution on the thermal and structural properties of a spin-crossover single crystal. The analysis is performed on a 2D rectangular lattice using an electro-elastic model. The lattice is made of sites that can switch thermally between the low-spin and high-spin states, accompanied by local volume changes. The model is solved by Monte Carlo simulations, running on the spin states and atomic positions of this compressible 2D lattice. A detailed analysis of metal dilution on the magneto-structural properties allows us to address the following issues: (i) at low dilution rates, the transition is of the first order; (ii) increasing the concentration of dopant results in a decrease in cooperativity and leads to gradual transformations above a threshold concentration, while incomplete spin transitions are obtained for big dopant sizes. The effects of the metal dilution on the spatiotemporal aspects of the spin transition along the thermal transition and on the low-temperature relaxation of the photo-induced metastable high-spin states are also studied. Significant changes in the organization of the spin states are observed for the thermal transition, where the single-domain nucleation caused by the long-range elastic interactions is replaced by a multi-droplet nucleation. As to the issue of the relaxation curves: their shape transforms from a sigmoidal shape, characteristic of strong cooperative systems, into stretched exponentials for high dilution rates, which is the signature of a disordered system. Full article
(This article belongs to the Special Issue Chemical Tuning of Molecular Magnetic and Optical Materials)
Show Figures

Figure 1

12 pages, 3067 KB  
Article
The Effect of the Doping Amount on Electroelastic Coupled-Wave Scattering and Dynamic Stress Concentration around Defects in BNT Doped FN Materials
by Jiawei Fan, Chuanping Zhou, Junqi Bao, Huawei Ji, Yongping Gong, Weihua Zhou and Jiang Lin
Materials 2022, 15(16), 5781; https://doi.org/10.3390/ma15165781 - 21 Aug 2022
Viewed by 2132
Abstract
Sodium bismuth titanate (Bi0.5Na0.5TiO3, BNT) has attracted much attention because of its excellent dielectric, piezoelectric and electromechanical properties. The microstructure of sodium bismuth titanate-doped ferrum niobium material (Bi0.5Na0.5TiO3 doped (Fe0.5Nb [...] Read more.
Sodium bismuth titanate (Bi0.5Na0.5TiO3, BNT) has attracted much attention because of its excellent dielectric, piezoelectric and electromechanical properties. The microstructure of sodium bismuth titanate-doped ferrum niobium material (Bi0.5Na0.5TiO3 doped (Fe0.5Nb0.5)4+, BNT-xFN) shows a triangle as its typical defect shape. Since piezoelectric devices usually operate under dynamic loads, they fail easily owing to dynamic stress concentration or dynamic fracture. Elastic waves can simulate many types of dynamic loads, and the dynamic stress concentration caused by an anti-plane shear wave is the basis for the calculation of the stress field strength factor of type Ⅲ-dynamic fractures. In this study, the electroelastic coupled-wave diffraction and dynamic stress concentration of BNT-xFN materials with triangular defects under the incidence of anti-plane shear waves were studied. Maxwell equations are decoupled by auxiliary functions, and the analytical solutions of the elastic wave field and electric field are obtained. Based on the conformal mapping method, the triangle defect was mapped to the unit circle defect, and the dynamic stress concentration coefficient around the triangle defect was obtained by calculating the undetermined mode coefficients in the expression through boundary conditions. The numerical calculation shows that the size of the triangular hole, the frequency of the applied mechanical load, the incidence angle of mechanical load and the amount of FN doping have a great influence on the stress concentration of BNT-xFN materials. Full article
(This article belongs to the Special Issue Smart Materials: Next Generation in Science and Technology)
Show Figures

Figure 1

12 pages, 1931 KB  
Article
Electroelastic Coupled-Wave Scattering and Dynamic Stress Concentration of Piezoceramics Containing Regular N-Sided Holes
by Jiang Lin, Chuanping Zhou, Xiao Han, Yongping Gong, Jiawei Fan, Junqi Bao, Huawei Ji, Jing Ni and Weihua Zhou
Actuators 2022, 11(7), 202; https://doi.org/10.3390/act11070202 - 19 Jul 2022
Cited by 1 | Viewed by 2323
Abstract
In this paper, the calculation method of dynamic stress concentration around piezoelectric ceramics containing regular n-sided holes under the action of electroelastic coupling wave was studied, and it was applied to promising barium calcium zirconate titanate material. First, electroelastic governing equations were [...] Read more.
In this paper, the calculation method of dynamic stress concentration around piezoelectric ceramics containing regular n-sided holes under the action of electroelastic coupling wave was studied, and it was applied to promising barium calcium zirconate titanate material. First, electroelastic governing equations were decomposed by using the auxiliary function method, and the solution forms of the elastic wave field and electric field were obtained by using the wave function expansion method. Then, the triangular boundary was simplified to a circular boundary using the mapping function, and the corresponding modal coefficients were determined according to simplified boundary conditions. Finally, the dynamic stress-concentration factor was calculated to characterize the dynamic stress concentration. We performed numerical simulations with a correlation coefficient of (1 − x)[(Ba0.94Ca0.06) (Ti0.92Sn0.08)]-xSm2O3-0.06 mol% GeO2 (abbreviated as (1 − x)BCTS-xSm-0.06G). The numerical calculation results show that the incident wave number, piezoelectric properties, shape parameters of the hole, and deflection angle have a great influence on the dynamic stress around the defect, and some significant laws are summarized through analysis. Full article
Show Figures

Figure 1

12 pages, 1996 KB  
Article
Electroelastic Coupled-Wave Scattering and Dynamic Stress Concentration of Triangular Defect Piezoceramics
by Jiang Lin, Huawei Ji, Chuanping Zhou, Jiawei Fan, Xiao Han, Junqi Bao, Yongping Gong, Jing Ni and Weihua Zhou
Actuators 2022, 11(4), 106; https://doi.org/10.3390/act11040106 - 7 Apr 2022
Cited by 2 | Viewed by 3210
Abstract
In this paper, a method to calculate the dynamic stress concentration around the triangular defect of piezoelectric material under electroelastic coupling is studied and applied to the promising barium calcium zirconate titanate. Firstly, the electroelastic governing equation is decomposed by decoupling technique, and [...] Read more.
In this paper, a method to calculate the dynamic stress concentration around the triangular defect of piezoelectric material under electroelastic coupling is studied and applied to the promising barium calcium zirconate titanate. Firstly, the electroelastic governing equation is decomposed by decoupling technique, and the analytical solutions of elastic wave field and electric field are obtained by wave function expansion method. Then, the conformal transformation is used to simplify the triangle boundary into a circular boundary, and the corresponding modal coefficients are determined according to the simplified boundary conditions. Finally, the analytical solution of the dynamic stress concentration factor can be obtained according to the constitutive equation. Substitute the relevant material parameters of (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 and set different temperatures, Ce doping amount, and incident wave number for numerical simulation. The numerical results show that the incident wave number, piezoelectric properties, and the shape parameters and deflection angle of the triangular defect have a great influence on the dynamic stress around the defect, and some meaningful laws are summarized through analysis. Full article
Show Figures

Figure 1

7 pages, 2851 KB  
Article
Investigation of Electro-Elastic Properties for LN Single Crystals at Low Temperature
by Feifei Chen, Chao Jiang, Fapeng Yu, Xiufeng Cheng and Xian Zhao
Appl. Sci. 2021, 11(16), 7374; https://doi.org/10.3390/app11167374 - 11 Aug 2021
Cited by 2 | Viewed by 2867
Abstract
Lithium niobate crystals (LiNbO3, LN) are multifunctional crystal materials with many outstanding properties. In this work, the electro-elastic properties of LN single crystals were explored at temperatures from −150 °C to 150 °C. The temperature dependences of dielectric permittivities, elastic compliances, [...] Read more.
Lithium niobate crystals (LiNbO3, LN) are multifunctional crystal materials with many outstanding properties. In this work, the electro-elastic properties of LN single crystals were explored at temperatures from −150 °C to 150 °C. The temperature dependences of dielectric permittivities, elastic compliances, electromechanical coupling factors and piezoelectric coefficients were determined using the impedance method. The LN crystals possessed large dielectric permittivities, the ε11T/ε0 and ε33T/ε0 were 83.2 and 29.4 at room temperature, respectively. The elastic compliances s11, s13, s33 and s44 presented a positive increase as the temperature increased, and the variations were 5.0%, 8.2%, 4.6% and 5.4%, respectively, showing a good temperature stability. Moreover, the temperature dependence of the electromechanical coupling factors and piezoelectric coefficients for different vibration modes were studied with a temperature range from −150 °C to 150 °C, where the thickness shear vibration mode d15 presented a large piezoelectric response and minimal temperature variation. Full article
(This article belongs to the Special Issue Wireless and Passive Surface Acoustic Wave Sensor)
Show Figures

Figure 1

28 pages, 2342 KB  
Article
Viscoelastic Effects on the Response of Electroelastic Materials
by Ricardo Diaz-Calleja, Damián Ginestar, Vícente Compañ Moreno, Pedro Llovera-Segovia, Clara Burgos-Simón, Juan Carlos Cortés, Alfredo Quijano and Joaquín Díaz-Boils
Polymers 2021, 13(13), 2198; https://doi.org/10.3390/polym13132198 - 1 Jul 2021
Cited by 5 | Viewed by 3540
Abstract
Electroelastic materials, as for example, 3M VHB 4910, are attracting attention as actuators or generators in some developments and applications. This is due to their capacity of being deformed when submitted to an electric field. Some models of their actuation are available, but [...] Read more.
Electroelastic materials, as for example, 3M VHB 4910, are attracting attention as actuators or generators in some developments and applications. This is due to their capacity of being deformed when submitted to an electric field. Some models of their actuation are available, but recently, viscoelastic models have been proposed to give an account of the dissipative behaviour of these materials. Their response to an external mechanical or electrical force field implies a relaxation process towards a new state of thermodynamic equilibrium, which can be described by a relaxation time. However, it is well known that viscoelastic and dielectric materials, as for example, polymers, exhibit a distribution of relaxation times instead of a single relaxation time. In the present approach, a continuous distribution of relaxation times is proposed via the introduction of fractional derivatives of the stress and strain, which gives a better account of the material behaviour. The application of fractional derivatives is described and a comparison with former results is made. Then, a double generalisation is carried out: the first one is referred to the viscoelastic or dielectric models and is addressed to obtain a nonsymmetric spectrum of relaxation times, and the second one is the adoption of the more realistic Mooney–Rivlin equation for the stress–strain relationship of the elastomeric material. A modified Mooney–Rivlin model for the free energy density of a hyperelastic material, VHB 4910 has been used based on experimental results of previous authors. This last proposal ensures the appearance of the bifurcation phenomena which is analysed for equibiaxial dead loads; time-dependent bifurcation phenomena are predicted by the extended Mooney–Rivlin equations. Full article
(This article belongs to the Section Polymer Physics and Theory)
Show Figures

Graphical abstract

29 pages, 8366 KB  
Article
Elastic Origin of the Unsymmetrical Thermal Hysteresis in Spin Crossover Materials: Evidence of Symmetry Breaking
by Mamadou Ndiaye, Nour El Islam Belmouri, Jorge Linares and Kamel Boukheddaden
Symmetry 2021, 13(5), 828; https://doi.org/10.3390/sym13050828 - 9 May 2021
Cited by 15 | Viewed by 3337
Abstract
The jungle of experimental behaviors of spin-crossover materials contains a tremendous number of unexpected behaviors, among which, the unsymmetrical hysteresis loops having different shapes on heating and cooling, that we often encounter in literature. Excluding an extra effect of crystallographic phase transitions, we [...] Read more.
The jungle of experimental behaviors of spin-crossover materials contains a tremendous number of unexpected behaviors, among which, the unsymmetrical hysteresis loops having different shapes on heating and cooling, that we often encounter in literature. Excluding an extra effect of crystallographic phase transitions, we study here these phenomena from the point of view of elastic modeling and we demonstrate that a simple model accounting for the bond lengths misfits between the high-spin and low-spin states is sufficient to describe the situation of unsymmetrical hysteresis showing plateaus at the transition only on cooling or on heating branches. The idea behind this effect relates to the existence of a discriminant elastic frustration in the lattice, which expresses only along the high-spin to low-spin transition or in the opposite side. The obtained two-step transitions showed characteristics of self-organization of the spin states under the form of stripes, which we explain as an emergence process of antagonist directional elastic interactions inside the lattice. The analysis of the spin state transformation inside the plateau on cooling in terms of two sublattices demonstrated that the elastic-driven self-organization of the spin states is accompanied with a symmetry breaking. Full article
Show Figures

Figure 1

Back to TopTop