Search Results (309)

The precise synthesis of non-precious metal single-atom electrocatalysts is crucial for enhancing the yield of highly active reactive oxygen species (ROSs). Conventional oxidation methods, such as Fenton or NaClO processes, suffer from poor efficiency, high energy demand, and secondary pollution. In contrast, heterogeneous electro-Fenton systems based on cascade oxygen reduction reactions (ORRs), which require low operational voltage and cause pollutant degradation through both direct electron transfer and ROS generation, have emerged as a promising alternative. Recent studies showed that carbon cathodes decorated with atomically dispersed transition metals can effectively integrate the excellent conductivity of carbon supports with the tunable surface chemistry of metal centers. However, the electronic structure of active sites intrinsically hinders the simultaneous achievement of high activity and selectivity in cascade ORRs. This review summarizes the advances, specifically from 2020 to 2025, in understanding the mechanism of cascade ORRs and the synthesis of transition metal-based single-atom catalysts in cathode electrocatalysis for efficient wastewater treatment, and discusses the key factors affecting treatment performance. While employing atomically engineered cathodes is a promising approach for energy-efficient wastewater treatment, future efforts should overcome the barriers in active site control and long-term stability of the catalysts to fully exploit their potential in addressing water pollution challenges. Full article

Pseudo-persistent organic pollutants, such as pharmaceuticals, personal care products (PPCPs), and organic dyes, are a major issue in current environmental engineering. Considering the limitations of traditional wastewater treatment plant methods and degradation technologies for organic pollutants, the search for new technologies more suitable for treating these new types of pollutants has become a research hotspot in recent years. Membrane filtration, adsorption, advanced oxidation, and electrochemical advanced oxidation technologies can effectively treat new organic pollutants. The electro-advanced oxidation process based on sulfate radicals is renowned for its non-selectivity, high efficiency, and environmental friendliness, and it can improve the dewatering performance of sludge after wastewater treatment. Therefore, in this study, octyl methoxycinnamate (OMC) was selected as the target pollutant. A new type of electrochemical filtration device based on the advanced oxidation process of sulfate radicals was designed, and a new type of modified carbon nanotube material electrode was synthesized to enhance its degradation effect. In a mixed system of water and acetonitrile, the efficiency of the electrochemical filtration device loaded with the modified electrode for degrading OMC is 1.54 times that at room temperature. The experimental results confirmed the superiority and application prospects of the self-designed treatment scheme for organic pollutants, providing experience and a reference for the future treatment of PPCP pollution. Full article

In this investigation, a hierarchical FeCo-layered double hydroxide (FeCo-LDH) electrochemical membrane material was prepared by a simple in situ hydrothermal method. The prepared material formed a 3D honeycomb-structured FeCo-LDH-modified carbon felt (FeCo-LDH/CF) catalytic layer with uniform open pores on a CF substrate with excellent catalytic activity and was served as the cathode in a flow-through electro-Fenton (FTEF) reactor. The electrocatalyst demonstrated excellent treatment performance (99%) in phenol simulated wastewater (30 mg L⁻¹) under the optimized operating conditions (applied voltage = 3.5 V, pH = 6, influent flow rate = 15 mL min⁻¹) of the FTEF system. The high removal rate could be attributed to (i) the excellent electrocatalytic oxidation performance and low interfacial charge transfer resistance of the FeCo-LDH/CF electrode as the cathode, (ii) the ability of the synthesized FeCo-LDH to effectively promote the conversion of H₂O₂ to •OH under certain conditions, and (iii) the flow-through system improving the mass transfer efficiency. In addition, the degradation process of pollutants within the FTEF system was additionally illustrated by the •OH dominant ROS pathway based on free radical burst experiments and electron paramagnetic resonance tests. This study may provide new insights to explore reaction mechanisms in FTEF systems. Full article

Microbial fuel cells (MFCs) are bio-electrochemical systems that harness microorganisms to convert organic pollutants in wastewater directly into electricity, offering a dual solution for sustainable wastewater treatment and renewable energy generation. This paper presents a holistic techno-economic and environmental feasibility assessment of large-scale MFC deployment in Dhaka’s industrial zone, Bangladesh, as a relevant case study. Here, treating 100,000 cubic meters of wastewater daily would require a capital investment of approximately USD 500 million, with a total project cost ranging between USD 307.38 million and 1.711 billion, depending on system configurations. This setup has an estimated theoretical energy recovery of 478.4 MWh/day and a realistic output of 382 MWh/day, translating to a per-unit energy cost of USD 0.2–1/kWh. MFCs show great potential for treating wastewater and addressing energy challenges. However, this paper explores remaining challenges, including high capital costs, electrode and membrane inefficiencies, and scalability issues. Full article

This study introduces an advanced strategy for improving microbial fuel cell (MFC) performance in hexavalent chromium (Cr(VI)) wastewater treatment. A high-performance nano-iron sulfide (nano-FeS) hybridized biocathode was developed by regulating glucose concentration and applying an external voltage. The combination of a glucose concentration of 1000 mg/L and a 0.2 V applied voltage greatly promoted the in situ biosynthesis of nano-FeS, resulting in smaller particle sizes and increased quantities within the biocathode, leading to enhanced electrochemical performance. The MFC with the hybridized biocathode exhibited the highest power density (43.45 ± 1.69 mW/m²) and Cr(VI) removal rate (3.99 ± 0.09 mg/L·h), outperforming the control by 29% and 71%, respectively. The improvements were attributed to the following processes. (1) Nano-FeS provided additional active sites that enhanced electron transfer and electrocatalytic activity, reducing cathode passivation; (2) it protected microorganisms by reducing Cr(VI) toxicity, promoting redox-active substance enrichment and antioxidant enzyme secretion, which maintained microbial activity; (3) the biocathode selectively enriched electroactive and Cr(VI)-reducing bacteria (such as Brucella), fostering a stable and symbiotic microbial community. This study highlights the promising potential of regulating carbon source and external voltage to boost nano-FeS biosynthesis, offering a sustainable and efficient strategy for MFC-based Cr(VI) wastewater treatment with practical implications. Full article

Electrocatalytic urea oxidation reaction (UOR) is a promising dual-purpose approach for hydrogen production and wastewater treatment, addressing critical energy and environmental challenges. However, conventional anode materials often suffer from limited active sites and high charge transfer resistance, restricting UOR efficiency. To overcome these issues, a novel NiP@PNC/NF electrocatalyst was developed via a one-step thermal annealing process under nitrogen, integrating nickel phosphide (NiP) with phosphorus and nitrogen co-doped carbon nanotubes (PNCs) on a nickel foam (NF) substrate. This design enhances catalytic activity and charge transfer, achieving current densities of 50 mA cm⁻² at 1.34 V and 100 mA cm⁻² at 1.43 V versus the reversible hydrogen electrode (RHE). The electrode’s high electrochemical surface area (235 cm²) and double-layer capacitance (94.1 mF) reflect abundant active sites, far surpassing NiP/NF (48 cm², 15.8 mF) and PNC/NF (39.5 cm², 12.9 mF). It maintains exceptional stability, with only a 16.3% performance loss after 35 h, as confirmed by HR-TEM showing an intact nanostructure. Our single-step annealing technique provides simplicity, scalability, and efficient integration of NiP nanoparticles inside a PNC matrix on nickel foam. This method enables consistent distribution and robust substrate adhesion, which are difficult to attain with multi-step or more intricate techniques. Full article

This study focuses on the design and optimization of a monopolar electrode configuration for the hybrid electrochemical treatment of real washing machine wastewater. A combined electrocoagulation (EC) and electro-oxidation (EO) system was optimized to maximize pollutant removal efficiency while minimizing energy consumption. The monopolar setup employed mixed metal oxide (MMO) and aluminum anodes, along with a stainless steel cathode, operating under controlled conditions with sodium chloride as the supporting electrolyte. An applied current density of 15 mA cm⁻² achieved 90% chemical oxygen demand (COD) removal, 98% surfactant degradation, complete turbidity reduction within 120 min, and pH stabilization near 8. Additionally, electrochemical disinfection achieved <2 MPN/100 mL, with no detectable phenols and the presence of organic anions such as oxalate and acetate. These results demonstrate the effectiveness of an optimized monopolar EC–EO system as a cost-efficient and sustainable strategy for wastewater treatment and potential water reuse. Further studies should focus on refining energy consumption and monitoring reaction by-products to enhance large-scale applicability. Full article

Microbial Fuel Cell (MFC) is a novel bioelectrochemical system that catalyzes the oxidation of chemical energy in organic waste and converts it directly into electrical energy through the attachment and growth of electroactive microorganisms on the electrode surface. This technology realizes the synergistic effect of waste treatment and renewable energy production. A CF-NiO-PANI capacitor composite anode was prepared by loading polyaniline on a CF-NiO electrode to improve the capacitance of a CF electrode. The electrochemical characteristics of the composite anode were evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), and the electrode materials were analyzed comprehensively by scanning electron microscopy (SEM), energy diffusion spectrometer (EDS), and Fourier transform infrared spectroscopy (FTIR). MFC system based on CF-NiO-PANI composite anode showed excellent energy conversion efficiency in potato starch wastewater treatment, and its maximum power density increased to 0.4 W/m³, which was 300% higher than that of the traditional CF anode. In the standard charge–discharge test (C1000/D1000), the charge storage capacity of the composite anode reached 2607.06 C/m², which was higher than that of the CF anode (348.77 C/m²). Microbial community analysis revealed that the CF-NiO-PANI anode surface formed a highly efficient electroactive biofilm dominated by electrogenic bacteria (accounting for 47.01%), confirming its excellent electron transfer ability. The development of this innovative capacitance-catalytic dual-function anode material provides a new technical path for the synergistic optimization of wastewater treatment and energy recovery in MFC systems. Full article

Titanium dioxide (TiO₂) is a wide-bandgap semiconductor material with broad application potential, known for its excellent photocatalytic performance, high chemical stability, low cost, and non-toxicity. These properties make it highly attractive for applications in photovoltaic energy, environmental remediation, and optoelectronic devices. For instance, TiO₂ is widely used as a photocatalyst for hydrogen production via water splitting and for degrading organic pollutants, thanks to its efficient photo-generated electron–hole separation. Additionally, TiO₂ exhibits remarkable performance in dye-sensitized solar cells and photodetectors, providing critical support for advancements in green energy and photoelectric conversion technologies. Boron-doped diamond (BDD) is renowned for its exceptional electrical conductivity, high hardness, wide electrochemical window, and outstanding chemical inertness. These unique characteristics enable its extensive use in fields such as electrochemical analysis, electrocatalysis, sensors, and biomedicine. For example, BDD electrodes exhibit high sensitivity and stability in detecting trace chemicals and pollutants, while also demonstrating excellent performance in electrocatalytic water splitting and industrial wastewater treatment. Its chemical stability and biocompatibility make it an ideal material for biosensors and implantable devices. Research indicates that the combination of TiO₂ nanostructures and BDD into heterostructures can exhibit unexpected optical and electrical performance and transport behavior, opening up new possibilities for photoluminescence and rectifier diode devices. However, applications based on this heterostructure still face challenges, particularly in terms of photodetector, photoelectric emitter, optical modulator, and optical fiber devices under high-temperature conditions. This article explores the potential and prospects of their combined heterostructures in the field of optoelectronic devices such as photodetector, light emitting diode (LED), memory, field effect transistor (FET) and sensing. TiO₂/BDD heterojunction can enhance photoresponsivity and extend the spectral detection range which enables stability in high-temperature and harsh environments due to BDD’s thermal conductivity. This article proposes future research directions and prospects to facilitate the development of TiO₂ nanostructured materials and BDD-based heterostructures, providing a foundation for enhancing photoresponsivity and extending the spectral detection range enables stability in high-temperature and high-frequency optoelectronic devices field. Further research and exploration of optoelectronic devices based on TiO₂-BDD heterostructures hold significant importance, offering new breakthroughs and innovations for the future development of optoelectronic technology. Full article

Textile dyeing wastewater is one of the most challenging industrial effluents to treat due to its high concentrations of persistent organic compounds and nitrogenous substances. Conventional treatment methods often fall short in achieving both sufficient removal efficiency and environmental safety. In this study, we aimed to remove the total nitrogen (T-N) and total organic carbon (TOC) of dyeing wastewater from an industrial complex in D City, Korea, by applying bipolar and packed bipolar electrolysis using aluminum (Al) electrodes and activated carbon (AC). The system was operated for 60 min under varying conditions of applied voltage (5–15 V), electrolyte type and concentration (non-addition, NaCl 5 mM, NaCl 10 mM, Na₂SO₄ 5 mM, Na₂SO₄ 10 mM), and AC packing amount (non-addition or 100 g/L). The highest T-N and TOC removal efficiencies were observed at 15 V, reaching 69.53% and 63.68%, respectively. Electrolyte addition significantly improved initial treatment performance, with NaCl 10 mM showing the best results. However, Al leaching also increased, from 549.83 mg/L (non-addition) to 623.06 mg/L (NaCl 10 mM). When AC was used without electrolysis (control experiment), the T-N and TOC removal efficiencies were limited to 30.24% and 29.86%, respectively. In contrast, AC packing combined with 15 V electrolysis under non-addition achieved 86.04% T-N and 77.98% TOC removal, while also reducing Al leaching by 40.12%. These results suggested that electrochemical treatment with AC packing under non-addition conditions offers the best balance between high treatment efficiency and low environmental impact. These findings demonstrate that the synergistic use of packed activated carbon and electrochemical treatment under additive-free conditions can overcome the limitations of conventional methods. This study contributes to the development of more sustainable and effective technologies for treating high-strength industrial wastewater. Full article

This work shows a sustainable methodology for the synthesis of biogenic materials designed for the removal and photodegradation of rhodamine B (RhB), a highly dangerous environmental pollutant that induces reproductive toxicity. The classical synthesis of MCM-41-ordered mesoporous materials was modified using biocompatible rice husk as the silica template. Iron was incorporated and the so-prepared biogenic photocatalysts were characterized by X-ray diffraction, N₂ adsorption–desorption isotherms, transmission electron microscopy, diffuse reflectance UV-Vis, surface pH, cyclic voltammetry, and Fourier transform infrared spectral analysis of pyridine adsorption. The photocatalytic performance of the materials was evaluated following the removal by adsorption and the photon-driven degradation of RhB. The adsorption capacity and photocatalytic activity of the biogenic materials were correlated with their properties, including iron content, texture, surface content, and electrochemical properties. The best biogenic material boosted the degradation rates of RhB under UV irradiation up to 4.7 and 2.2 times greater than the direct photolysis and the benchmark semiconductor TiO₂-P25. It can be concluded that the use of rice husks for the synthesis of biogenic Fe-modified mesoporous materials is a promising strategy for wastewater treatment applications, particularly in the removal of highly toxic organic dyes. Full article

A pilot-scale (4000 L) continuous flow electromethanogenic reactor (EMR), also known as a microbial electrochemical cell coupled with an anaerobic digester (MEC-AD), treating brewery wastewater was designed and installed at Hepworth’s Brewery, UK. This investigation presents a 4-fold increase in size compared to the next largest pilot-scale MEC-AD system presented in the literature, providing findings to inform the operation of a 52,000 L MEC-AD system (currently under construction). Housed in a 20 ft shipping container, the pilot system features four 1000 L reaction vessels arranged in series, each with a working volume of 900 L. Each reaction vessel contained 8 electrode modules. The system was tested over varying organic loading rates (OLRs), achieved through systematic reductions in hydraulic retention time (HRT). HRTs between 24 and 1.8 days were investigated to align with commercial viability targets. OLRs were observed from 0.4 to 7.5 kgCOD/m³/d. A maximum stable OLR of 6.75 kgCOD/m³/d at a HRT of 2.3 days was observed while maintaining COD removal of 65 and 88% over the first two vessels. This pilot demonstrated commercially viable performance of an EMR at a brewery, resulting in the purchase of the technology at commercial scale (52,000 L) to form part of a wastewater treatment system. Full article

Sludge-derived biochar (SDB) synthesized by the pyrolysis of sludge is gaining enormous interest as a sustainable solution to wastewater treatment and sludge disposal. Despite the proliferation of general biochar reviews, a focused synthesis on SDB-specific advances, particularly covering the recent surge in multifunctional wastewater treatment applications (2020–2025), receives little emphasis. In particular, a critical analysis of recent trends, application challenges, and future research directions for SDB is still limited. Unlike broader biochar reviews, this mini-review highlights the comparative advantages and limitations of SDB, identifies emerging integration strategies (e.g., bio-electrochemical systems, catalytic membranes), and outlines future research priorities toward enhancing the durability and environmental safety of SDB applications. Specifically, this review summarized the advances from 2020 to 2025, focusing exclusively on functional modifications, and practical applications of SDB across diverse wastewater treatment technologies involved in adsorption, catalytic oxidation, membrane integration, electrochemical processes and bio-treatment systems. Quantitative comparisons of adsorption capacities (e.g., >99% Cd2+ removal, >150 mg/g tetracycline adsorption) and catalytic degradation efficiencies are provided to illustrate recent improvements. The potential of SDB in evaluating traditional and emerging contaminant degradation among the Fenton-like, persulfate, and peracetic acid activation systems was emphasized. Integration with membrane technologies reduces fouling, while electrochemical applications, including microbial fuel cells, yield higher power densities. To improve the functionality of SDB-based systems in targeting contamination removal, modification strategies, i.e., thermal activation, heteroatom doping (N, S, P), and metal loading, played crucial roles. Emerging trends highlight hybrid systems and persistent free radicals for non-radical pathways. Despite progress, critical challenges persist in scalability, long-term stability, lifecycle assessments, and scale-up implementation. The targeted synthesis of this review offers valuable insights to guide the development and practical deployment of SDB in sustainable wastewater management. Full article

Accelerated urbanization and industrialization have significantly heightened water contamination risks, posing severe threats to public health and ecological balance. Polymeric membranes stand at the forefront of addressing this challenge, revolutionizing water and wastewater treatment. These membranes adeptly remove a broad spectrum of contaminants, including organic compounds and heavy metals, thereby playing a crucial role in mitigating environmental pollution. This research delves into the sophisticated mechanisms of polymeric membranes in filtering out pollutants, with a spotlight on the enhancements brought about by nanotechnology. This includes a detailed examination of their inherent antibacterial properties, showcasing their innovative design and potential for extensive application. The study further investigates advanced techniques like electrochemical processes and membrane distillation, particularly focusing on desalination. These methods are central to the advancement of water purification, emphasizing efficiency and environmental sustainability. However, challenges such as membrane fouling pose significant hurdles, necessitating ongoing research into surface modifications and antifouling strategies. This paper offers a comparative analysis of various membrane technologies, highlighting their manufacturing complexities and efficiency benchmarks. In summation, the paper underscores the importance of continuous innovation in membrane technology, aiming to develop sustainable and effective water treatment solutions. By bridging the gap between basic science and technological advancements, this review aims to guide practitioners and researchers towards a future where clean water is universally accessible, ensuring the preservation of our ecosystems. Full article