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21 pages, 29238 KiB  
Article
Distributed Impulsive Multi-Spacecraft Approach Trajectory Optimization Based on Cooperative Game Negotiation
by Shuhui Fan, Xiang Zhang and Wenhe Liao
Aerospace 2025, 12(7), 628; https://doi.org/10.3390/aerospace12070628 - 12 Jul 2025
Viewed by 233
Abstract
A cooperative game negotiation strategy considering multiple constraints is proposed for distributed impulsive multi-spacecraft approach missions in the presence of defending spacecraft. It is a dual-stage decision-making method that includes offline trajectory planning and online distributed negotiation. In the trajectory planning stage, a [...] Read more.
A cooperative game negotiation strategy considering multiple constraints is proposed for distributed impulsive multi-spacecraft approach missions in the presence of defending spacecraft. It is a dual-stage decision-making method that includes offline trajectory planning and online distributed negotiation. In the trajectory planning stage, a relative orbital dynamics model is first established based on the Clohessy–Wiltshire (CW) equations, and the state transition equations for impulsive maneuvers are derived. Subsequently, a multi-objective optimization model is formulated based on the NSGA-II algorithm, utilizing a constraint dominance principle (CDP) to address various constraints and generate Pareto front solutions for each spacecraft. In the distributed negotiation stage, the negotiation strategy among spacecraft is modeled as a cooperative game. A potential function is constructed to further analyze the existence and global convergence of Nash equilibrium. Additionally, a simulated annealing negotiation strategy is developed to iteratively select the optimal comprehensive approach strategy from the Pareto fronts. Simulation results demonstrate that the proposed method effectively optimizes approach trajectories for multi-spacecraft under complex constraints. By leveraging inter-satellite iterative negotiation, the method converges to a Nash equilibrium. Additionally, the simulated annealing negotiation strategy enhances global search performance, avoiding entrapment in local optima. Finally, the effectiveness and robustness of the dual-stage decision-making method were further demonstrated through Monte Carlo simulations. Full article
(This article belongs to the Section Astronautics & Space Science)
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18 pages, 10208 KiB  
Article
Development of Ni-P-N-C/Nickel Foam for Efficient Hydrogen Production via Urea Electro-Oxidation
by Abdullah M. Aldawsari, Maged N. Shaddad and Saba A. Aladeemy
Catalysts 2025, 15(7), 662; https://doi.org/10.3390/catal15070662 - 7 Jul 2025
Viewed by 446
Abstract
Electrocatalytic urea oxidation reaction (UOR) is a promising dual-purpose approach for hydrogen production and wastewater treatment, addressing critical energy and environmental challenges. However, conventional anode materials often suffer from limited active sites and high charge transfer resistance, restricting UOR efficiency. To overcome these [...] Read more.
Electrocatalytic urea oxidation reaction (UOR) is a promising dual-purpose approach for hydrogen production and wastewater treatment, addressing critical energy and environmental challenges. However, conventional anode materials often suffer from limited active sites and high charge transfer resistance, restricting UOR efficiency. To overcome these issues, a novel NiP@PNC/NF electrocatalyst was developed via a one-step thermal annealing process under nitrogen, integrating nickel phosphide (NiP) with phosphorus and nitrogen co-doped carbon nanotubes (PNCs) on a nickel foam (NF) substrate. This design enhances catalytic activity and charge transfer, achieving current densities of 50 mA cm−2 at 1.34 V and 100 mA cm−2 at 1.43 V versus the reversible hydrogen electrode (RHE). The electrode’s high electrochemical surface area (235 cm2) and double-layer capacitance (94.1 mF) reflect abundant active sites, far surpassing NiP/NF (48 cm2, 15.8 mF) and PNC/NF (39.5 cm2, 12.9 mF). It maintains exceptional stability, with only a 16.3% performance loss after 35 h, as confirmed by HR-TEM showing an intact nanostructure. Our single-step annealing technique provides simplicity, scalability, and efficient integration of NiP nanoparticles inside a PNC matrix on nickel foam. This method enables consistent distribution and robust substrate adhesion, which are difficult to attain with multi-step or more intricate techniques. Full article
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16 pages, 5802 KiB  
Article
Enhancing the Mechanical Performance of Dual-Phase Steel Through Multi-Axis Compression and Inter-Critical Annealing
by Pooja Dwivedi, Aditya Kumar Padap, Sachin Maheshwari, Faseeulla Khan Mohammad, Mohammed E. Ali Mohsin, SK Safdar Hossain, Hussain Altammar and Arshad Noor Siddiquee
Materials 2025, 18(13), 3139; https://doi.org/10.3390/ma18133139 - 2 Jul 2025
Viewed by 413
Abstract
This study examines the microstructural evolution, mechanical properties, and wear behavior of medium-carbon dual-phase steel (AISI 1040) processed via Multi-Axis Compression (MAC). The DP steel was produced through inter-critical annealing at 745 °C, followed by MAC at 500 °C, resulting in a refined [...] Read more.
This study examines the microstructural evolution, mechanical properties, and wear behavior of medium-carbon dual-phase steel (AISI 1040) processed via Multi-Axis Compression (MAC). The DP steel was produced through inter-critical annealing at 745 °C, followed by MAC at 500 °C, resulting in a refined grain microstructure. Optical micrographs confirmed the presence of ferrite and martensite phases after annealing, with significant grain refinement observed following MAC. The average grain size decreased from 66 ± 4 μm to 18 ± 1 μm after nine MAC passes. Mechanical testing revealed substantial improvements in hardness (from 145 ± 9 HV to 298 ± 18 HV) and ultimate tensile strength (from 557 ± 33 MPa to 738 ± 44 MPa), attributed to strain hardening and the Hall–Petch effect. Fractographic analysis revealed a ductile failure mode in the annealed sample, while DP0 and DP9 exhibited a mixed fracture mode. Both DP0 and DP9 samples demonstrated superior wear resistance compared to the annealed sample. However, the DP9 sample exhibited slightly lower wear resistance than DP0, likely due to the fragmentation of martensite induced by high accumulated strain, which could act as crack initiation sites during sliding wear. Furthermore, wear resistance was significantly enhanced due to the combined effects of the DP structure and Severe Plastic Deformation (SPD). These findings highlight the potential of MAC processing for developing high-performance steels suitable for lightweight automotive applications. Full article
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22 pages, 25204 KiB  
Article
An Improved NSGA-II Algorithm for Multi-Objective Optimization of Irregular Polygon Patch Antennas
by Zhenyang Ma and Jiahao Liu
Micromachines 2025, 16(7), 786; https://doi.org/10.3390/mi16070786 - 30 Jun 2025
Viewed by 429
Abstract
This paper presents an improved NSGA-II algorithm for the multi-objective optimization of irregular polygon patch antennas (IPPAs), improving convergence efficiency and Pareto front quality. The algorithm integrates adaptive mechanisms that dynamically adjust crossover and mutation rates based on generational progression, accelerating convergence while [...] Read more.
This paper presents an improved NSGA-II algorithm for the multi-objective optimization of irregular polygon patch antennas (IPPAs), improving convergence efficiency and Pareto front quality. The algorithm integrates adaptive mechanisms that dynamically adjust crossover and mutation rates based on generational progression, accelerating convergence while preserving solution diversity. Furthermore, a simulated annealing-inspired acceptance criterion is embedded during offspring generation to mitigate local optima trapping and enhance evolutionary robustness. A dual-objective formulation simultaneously minimizes antenna volume and maximizes operational bandwidth within the X-band. Optimization is executed via HFSS co-simulation, with detailed electromagnetic models ensuring physical realizability and design fidelity. The optimized antenna achieves a compact volume of 2807.6 mm3 and an operational bandwidth of 2.7 GHz. Experimental validation of fabricated prototypes demonstrates agreement with simulations, confirming the accuracy and reliability of the proposed method. These results demonstrate the effectiveness of the improved NSGA-II algorithm in addressing complex multi-objective design challenges and underscore its potential in advanced broadband antenna applications. Full article
(This article belongs to the Section E:Engineering and Technology)
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15 pages, 5685 KiB  
Article
Microstructure and Mechanical Properties of Ultrafine-Grained Dual-Phase 0.1C3Mn Steel Processed by Warm Deformation
by Yongkang Wang, Chenglu Liu and Qingquan Lai
Metals 2025, 15(7), 699; https://doi.org/10.3390/met15070699 - 24 Jun 2025
Viewed by 342
Abstract
In this study, we have explored the thermomechanical processing on 0.1C3Mn steel to produce an ultrafine-grained (UFG) dual-phase (DP) microstructure. The composition was designed to allow a decrease in temperature for the warm deformation of austenite. It was found that the warm deformation [...] Read more.
In this study, we have explored the thermomechanical processing on 0.1C3Mn steel to produce an ultrafine-grained (UFG) dual-phase (DP) microstructure. The composition was designed to allow a decrease in temperature for the warm deformation of austenite. It was found that the warm deformation of austenite induced a dramatic ferrite transformation, in contrast to the absence of the formation of ferrite in the well-annealed state. Compression by 60% at 650 °C resulted in the generation of a UFG-DP microstructure with a ferrite grain size of 1.4 μm and a ferrite volume fraction of 62%. The UFG-DP 0.1C3Mn steel presents a good combination of strength, ductility and fracture resistance, and the fracture strain of the UFG-DP is higher than the as-quenched low-carbon martensite. The high fracture strain of the UFG-DP could be attributed to delayed void nucleation and constrained void growth, as revealed by the quantitative X-ray tomography. Full article
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37 pages, 6550 KiB  
Article
Multiphase Transport Network Optimization: Mathematical Framework Integrating Resilience Quantification and Dynamic Algorithm Coupling
by Linghao Ren, Xinyue Li, Renjie Song, Yuning Wang, Meiyun Gui and Bo Tang
Mathematics 2025, 13(13), 2061; https://doi.org/10.3390/math13132061 - 21 Jun 2025
Viewed by 407
Abstract
This study proposes a multi-dimensional urban transportation network optimization framework (MTNO-RQDC) to address structural failure risks from aging infrastructure and regional connectivity bottlenecks. Through dual-dataset validation using both the Baltimore road network and PeMS07 traffic flow data, we first develop a traffic simulation [...] Read more.
This study proposes a multi-dimensional urban transportation network optimization framework (MTNO-RQDC) to address structural failure risks from aging infrastructure and regional connectivity bottlenecks. Through dual-dataset validation using both the Baltimore road network and PeMS07 traffic flow data, we first develop a traffic simulation model integrating Dijkstra’s algorithm with capacity-constrained allocation strategies for guiding reconstruction planning for the collapsed Francis Scott Key Bridge. Next, we create a dynamic adaptive public transit optimization model using an entropy weight-TOPSIS decision framework coupled with an improved simulated annealing algorithm (ISA-TS), achieving coordinated suburban–urban network optimization while maintaining 92.3% solution stability under simulated node failure conditions. The framework introduces three key innovations: (1) a dual-layer regional division model combining K-means geographical partitioning with spectral clustering functional zoning; (2) fault-tolerant network topology optimization demonstrated through 1000-epoch Monte Carlo failure simulations; (3) cross-dataset transferability validation showing 15.7% performance variance between Baltimore and PeMS07 environments. Experimental results demonstrate a 28.7% reduction in road network traffic variance (from 42,760 to 32,100), 22.4% improvement in public transit path redundancy, and 30.4–44.6% decrease in regional traffic load variance with minimal costs. Hyperparameter analysis reveals two optimal operational modes: rapid cooling (rate = 0.90) achieves 85% improvement within 50 epochs for emergency response, while slow cooling (rate = 0.99) yields 12.7% superior solutions for long-term planning. The framework establishes a new multi-objective paradigm balancing structural resilience, functional connectivity, and computational robustness for sustainable smart city transportation systems. Full article
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23 pages, 925 KiB  
Article
Bi-Symmetric Polyhedral Cages with Nearly Maximally Connected Faces and Small Holes
by Bernard Piette
Symmetry 2025, 17(6), 940; https://doi.org/10.3390/sym17060940 - 12 Jun 2025
Viewed by 420
Abstract
Polyhedral cages (p-cages) provide a good description of the geometry of some families of artificial protein cages. In this paper we identify p-cages made out of two families of equivalent polygonal faces/protein rings, where each face has at least four neighbours and where [...] Read more.
Polyhedral cages (p-cages) provide a good description of the geometry of some families of artificial protein cages. In this paper we identify p-cages made out of two families of equivalent polygonal faces/protein rings, where each face has at least four neighbours and where the holes are contributed by at most four faces. We start the construction from a planar graph made out of two families of equivalent nodes. We construct the dual of the solid corresponding to that graph, and we tile its faces with regular or nearly regular polygons. We define an energy function describing the amount of irregularity of the p-cages, which we then minimise using a simulated annealing algorithm. We analyse over 600,000 possible geometries but restrict ourselves to p-cages made out of faces with deformations not exceeding 10%. We then present graphically some of the most promising geometries for protein nanocages. Full article
(This article belongs to the Special Issue Chemistry: Symmetry/Asymmetry—Feature Papers and Reviews)
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16 pages, 3899 KiB  
Article
Uncooled Insulated Monopole Antenna for Microwave Ablation: Improved Performance with Coaxial Cable Annealing
by Federico Cilia, Lourdes Farrugia, Charles Sammut, Arif Rochman, Julian Bonello, Iman Farhat and Evan Joe Dimech
Appl. Sci. 2025, 15(12), 6616; https://doi.org/10.3390/app15126616 - 12 Jun 2025
Viewed by 291
Abstract
There is growing interest in measuring the temperature-dependent dielectric properties of bio-tissues using dual-mode techniques (scattering measurements and thermal treatment). Uncooled coaxial antennas are preferred for their direct contact with the measured medium and reduced complexity; however, they exhibit structural changes during ablation [...] Read more.
There is growing interest in measuring the temperature-dependent dielectric properties of bio-tissues using dual-mode techniques (scattering measurements and thermal treatment). Uncooled coaxial antennas are preferred for their direct contact with the measured medium and reduced complexity; however, they exhibit structural changes during ablation due to the thermal expansion of polytetrafluoroethylene (PTFE). This paper presents an experimental study on PTFE expansion in an uncooled coaxial insulated monopole antenna in response to changes in the tissue’s thermal environment. Furthermore, it presents a methodology to mitigate these effects through coaxial annealing. The investigation consists of two distinct experiments: characterising PTFE expansion and assessing the effects of annealing through microwave ablation. This was achieved by simulating the thermal effects experienced during ablation by immersing the test antenna in heated peanut oil. PTFE expansion was measured through camera monitoring and using a toolmaker’s microscope, revealing two expansion modalities: linear PTFE expansion and non-linear plastic deformation from manufacturing processes. The return loss during ablation and consequential changes in the ablated lesion were also assessed. Antenna pre-annealing increased resilience against structural changes in the antenna, improving lesion ellipticity. Therefore, this study establishes a fabrication method for achieving an uncooled thermally stable antenna, leading to an optimised dual-mode ablation procedure, enabling quasi-real-time permittivity measurement of the surrounding tissue. Full article
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11 pages, 2750 KiB  
Article
Effect of Annealing on Vacancy-Type Defects and Heterogeneous Cu Precipitation Behavior in Fe60Cr12Mn8Cu15Mo3V2 Alloy
by Fengjiao Ye, Te Zhu, Peng Zhang, Peng Kuang, Haibiao Wu and Xingzhong Cao
Materials 2025, 18(11), 2613; https://doi.org/10.3390/ma18112613 - 3 Jun 2025
Viewed by 416
Abstract
This study systematically investigates the evolution of vacancy-type defects and heterogeneous Cu nanoprecipitates in an Fe60Cr12Mn8Cu15Mo3V2 (at%) multi-principal element alloy during thermal processing, utilizing Positron annihilation lifetime spectroscopy (PAS), coincidence Doppler broadening [...] Read more.
This study systematically investigates the evolution of vacancy-type defects and heterogeneous Cu nanoprecipitates in an Fe60Cr12Mn8Cu15Mo3V2 (at%) multi-principal element alloy during thermal processing, utilizing Positron annihilation lifetime spectroscopy (PAS), coincidence Doppler broadening (CDB) spectroscopy, and transmission electron microscopy (TEM). The results show that the alloy exhibited a dual-phase coexistence structure of Body-Centered Cubic (BCC) and Face-Centered Cubic (FCC). The CDB results show that the density of heterogeneous Cu precipitates gradually increases with annealing temperature. Compared to the as-cast alloy, the precipitates annealed at 773 K exhibit a significantly reduced size (approximately 33 nm) with higher density. The PAS results demonstrate that gradual migration and aggregation of monovacancies at 573 K form vacancy clusters, while contraction and dissociation of these clusters dominate at 673 K. Within the temperature range of 773–973 K, the dynamic equilibrium between the aggregation and decomposition of vacancy clusters maintains stable annihilation characteristics with minimal lifetime changes. Full article
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16 pages, 6095 KiB  
Article
Multi-Phase Design Strategy for Synergistic Strength–Ductility Optimization in V-Ti-Cr-Nb-Mo Refractory High-Entropy Alloys
by Xinwen Liang, Jiahao Zhu, Zhenjiao Tan, Ruikang Chen, Yun Chen and Xiaoma Tao
Materials 2025, 18(11), 2479; https://doi.org/10.3390/ma18112479 - 25 May 2025
Viewed by 575
Abstract
Controlling multiple phases by adjusting elemental ratios and applying heat treatments effectively balances the strength and ductility of refractory high-entropy alloys. In this study, five types of V-Ti-Cr-Nb-Mo alloys were designed by varying the contents of V, Ti, and Nb, followed by annealing [...] Read more.
Controlling multiple phases by adjusting elemental ratios and applying heat treatments effectively balances the strength and ductility of refractory high-entropy alloys. In this study, five types of V-Ti-Cr-Nb-Mo alloys were designed by varying the contents of V, Ti, and Nb, followed by annealing at 1200 °C for 8 h. The alloys’ crystal structures, microstructure evolution, and mechanical properties were systematically investigated. The V-Ti-Cr-Nb-Mo alloys exhibited a typical dendritic structure with a dual-phase (BCC + HCP) matrix. When the Nb content was maintained at 35 at.% with increasing V content, the volume fraction of the HCP phase increased, and the C14 Laves phase emerged. The as-cast alloy V15Ti30Cr5Nb35Mo15, with a triple-phase (BCC + HCP + Laves) structure, exhibited excellent mechanical properties, including a compressive strength of 1775 MPa and a ductility of 18.2%. After annealing, the HCP phase coarsened and partially dissolved, the Laves phase precipitation reduced, and while the hardness and strength decreased, the ductility improved significantly. The annealed alloy V5Ti35Cr5Nb40Mo15, with a dual-phase (BCC + HCP) structure, achieved a ductility of 26.9% under a compressive strength of 1530 MPa. This work demonstrates that multi-phase refractory high-entropy alloys can significantly enhance the strength–ductility synergy, providing an experimental foundation for the compositional design and performance optimization of refractory high-entropy alloys. Full article
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18 pages, 7426 KiB  
Article
Evaluation of Thermal Damage Effect of Forest Fire Based on Multispectral Camera Combined with Dual Annealing Algorithm
by Pan Pei, Xiaojian Hao, Ziqi Wu, Rui Jia, Shenxiang Feng, Tong Wei, Wenxiang You, Chenyang Xu, Xining Wang and Yuqian Dong
Appl. Sci. 2025, 15(10), 5553; https://doi.org/10.3390/app15105553 - 15 May 2025
Viewed by 472
Abstract
In recent years, the frequency and severity of large-scale forest fires have increased globally, threatening forest ecosystems, human lives, and property while potentially triggering cascading ecological and social crises. Despite significant advancements in remote sensing-based forest fire monitoring, early warning systems, and fire [...] Read more.
In recent years, the frequency and severity of large-scale forest fires have increased globally, threatening forest ecosystems, human lives, and property while potentially triggering cascading ecological and social crises. Despite significant advancements in remote sensing-based forest fire monitoring, early warning systems, and fire risk zoning, post-fire thermal damage assessment remains insufficiently addressed. This study introduces an innovative approach combining multispectral imaging with a dual annealing constrained optimization algorithm to enable dynamic monitoring of fire temperature distribution. Based on this method, we develop a dynamic thermal damage assessment model to quantify thermal impacts during forest fires. The proposed model provides valuable insights for defining thermal damage zones, optimizing evacuation strategies, and supporting firefighting operations, ultimately enhancing emergency response and forest fire management efficiency. Full article
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19 pages, 4165 KiB  
Article
Tree Trunk Curvature Extraction Based on Terrestrial Laser Scanning Point Clouds
by Chenxin Fan, Yizhou Lan and Feizhou Zhang
Forests 2025, 16(5), 797; https://doi.org/10.3390/f16050797 - 9 May 2025
Viewed by 452
Abstract
The degree of tree curvature exerts a significant influence on the utilization of forestry resources. This study proposes an enhanced quantitative structural modeling (QSM) method, founded upon terrestrial laser scanning (TLS) point cloud data, for the precise extraction of 3D curvature characteristics of [...] Read more.
The degree of tree curvature exerts a significant influence on the utilization of forestry resources. This study proposes an enhanced quantitative structural modeling (QSM) method, founded upon terrestrial laser scanning (TLS) point cloud data, for the precise extraction of 3D curvature characteristics of tree trunks. The conventional approach operates under the assumption that the tree trunk constitutes an upright rotating body, thereby disregarding the tree trunk’s true curvature morphology. The proposed method is founded on the classical QSM algorithm and introduces two zoom factors that can dynamically adjust the fitting parameters. This improvement leads to enhanced accuracy in the representation of tree trunk curvature and reduced computational complexity. The study utilized 146 sample trees from 13 plots in Jixi, Anhui Province, which were collected and pre-processed by TLS. The study combines point cloud segmentation, manual labeling of actual curvature and dual-factor experiments, and uses quadratic polynomials and simulated annealing algorithms to determine the optimal model factors. The validation results demonstrate that the enhanced method exhibits a greater degree of concordance between the predicted and actual curvature values within the validation set. In the regression equation, the coefficient of the two-factor method for fitting a straight line is 0.95, which is substantially higher than the 0.75 of the one-factor method. Furthermore, the two-factor model has an R2 of 0.21, indicating that the two-factor optimization method generates a significantly smaller error compared to the one-factor model (with an R2 of 0.12). In addition, this study discusses the possible reasons for the error in the results, as well as the shortcomings and outlook. The experimental results demonstrate the augmented method’s capacity to accurately reconstruct the 3D curvature of tree trunks in most cases. This study provides an efficient and accurate method for conducting fine-grained forest resource measurements and tree bending studies. Full article
(This article belongs to the Section Forest Inventory, Modeling and Remote Sensing)
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16 pages, 3251 KiB  
Article
Ion Gel-Modulated Low-Temperature Field-Effect Phototransistors with Multispectral Responsivity for Artificial Synapses
by Junjian Zhao, Yufei Zhang, Di Guo and Junyi Zhai
Sensors 2025, 25(9), 2750; https://doi.org/10.3390/s25092750 - 26 Apr 2025
Viewed by 779
Abstract
We report an ion-gel-gated amorphous indium gallium zinc oxide (a-IGZO) optoelectronic neuromorphic transistors capable of synaptic emulation in both photoelectric dual modes. The ion-gel dielectric in the coplanar-structured transistor, fabricated via ink-jet printing, exhibits excellent double-layer capacitance (>1 μF/cm2) and supports [...] Read more.
We report an ion-gel-gated amorphous indium gallium zinc oxide (a-IGZO) optoelectronic neuromorphic transistors capable of synaptic emulation in both photoelectric dual modes. The ion-gel dielectric in the coplanar-structured transistor, fabricated via ink-jet printing, exhibits excellent double-layer capacitance (>1 μF/cm2) and supports low-voltage operation through lateral gate coupling. The integration of ink-jet printing technology enables scalable and large-area fabrication, highlighting its industrial feasibility. Electrical stimulation-induced artificial synaptic behaviors were successfully demonstrated through ion migration in the gel matrix. Through a simple and controllable oxygen vacancy engineering process involving low-temperature oxygen-free growth and post-annealing process, a sufficient density of stable subgap states was generated in IGZO, extending its responsivity spectrum to the visible-red region and enabling wavelength-discriminative photoresponses to 450/532/638 nm visible light. Notably, the subgap states exhibited unique interaction dynamics with low-energy photons in optically triggered pulse responses. Critical synaptic functionalities—including short-term plasticity (STP), long-term plasticity (LTP), and paired-pulse facilitation (PPF)—were successfully simulated under both optical and electrical stimulations. The device achieves low energy consumption while maintaining compatibility with flexible substrates through low-temperature processing (≤150 °C). This study establishes a scalable platform for multimodal neuromorphic systems utilizing printed iontronic architectures. Full article
(This article belongs to the Section Electronic Sensors)
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12 pages, 2211 KiB  
Article
Electrostatic Field Modification Enhances the Electrocatalytic Oxygen Evolution Reaction Stability of CoFe2O4 Catalysts
by Liwen Liang, Jiatong Miao, Xiyuan Feng, Yunlei Zhong and Wei Wang
Micromachines 2025, 16(5), 491; https://doi.org/10.3390/mi16050491 - 22 Apr 2025
Viewed by 503
Abstract
Enhancing the stability of oxygen evolution reaction (OER) catalysts is a critical challenge for realizing efficient water splitting. In this work, we introduce an innovative approach by applying an electric field during the annealing of a CoFe2O4/C catalyst. By [...] Read more.
Enhancing the stability of oxygen evolution reaction (OER) catalysts is a critical challenge for realizing efficient water splitting. In this work, we introduce an innovative approach by applying an electric field during the annealing of a CoFe2O4/C catalyst. By controlling the electric field strength (100 mV) and treatment duration (1 h), we achieved dual optimization of the catalyst’s microstructure and electronic environment, resulting in a significant improvement in catalytic stability. The experimental results demonstrate that the electric field-treated catalyst exhibits a reduced overpotential decay (only 0.8 mV) and enhanced stability (retaining 89.1% of its initial activity after 24 h) during extended OER testing. This performance significantly surpasses that of the untreated sample, which showed an overpotential decay of 1.5 mV and retained only 72.5% of its activity after 24 h. X-ray photoelectron spectroscopy (XPS) analysis confirmed that the electric field treatment promoted the formation of oxygen vacancies, substantially improved electron transfer efficiency, and optimized the local electronic environment of Co2+/Co3+ and Fe2+/Fe3+, leading to a decrease in charge transfer resistance (Rct) from 58.2 Ω to 42.9 Ω. This study not only presents a novel strategy for modulating catalyst stability via electric fields but also broadens the design concepts for OER catalytic materials by establishing a structure–activity relationship between electric field strength, microstructure, and catalytic performance, ultimately providing a theoretical foundation and experimental guidance for the development of highly efficient and stable water splitting catalysts. Full article
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11 pages, 5152 KiB  
Article
Heterogeneous Deformation-Induced Strengthening Achieves the Synergistic Enhancement of Strength and Ductility in Mg–Sc Alloys
by Wei Zhao, Mengyu Zhang, Ruxia Liu and Jian Zhang
Metals 2025, 15(4), 457; https://doi.org/10.3390/met15040457 - 18 Apr 2025
Viewed by 401
Abstract
Magnesium alloys are essential lightweight materials for engineering applications. However, conventional single-phase hexagonal close-packed (HCP) magnesium alloys exhibit poor cold workability and insufficient strength at room temperature, which limits their engineering applications. Compared to HCP structures with limited slip systems at room temperature, [...] Read more.
Magnesium alloys are essential lightweight materials for engineering applications. However, conventional single-phase hexagonal close-packed (HCP) magnesium alloys exhibit poor cold workability and insufficient strength at room temperature, which limits their engineering applications. Compared to HCP structures with limited slip systems at room temperature, body-centered cubic (BCC) structures possess 12 independent slip systems, enabling better plasticity. Therefore, Mg–Sc alloys with a dual-phase structure (HCP + BCC) exhibit superior plasticity compared to single-phase HCP magnesium alloys. In this study, the deformation behavior of dual-phase Mg-19.2 at.% Sc alloy was investigated, revealing its deformation characteristics and multiscale strengthening mechanisms. Experimental findings indicate that with the rise in annealing temperature, the volume fraction of the α phase progressively declines, while that of the β phase expands. Moreover, the grain size of the α phase first grows and then reduces, whereas the β phase grain size consistently enlarges. When the annealing temperature reaches 600 °C, the alloy exhibits an optimal strength–ductility combination, with an ultimate tensile strength of 329 MPa and an elongation of 20.5%. At this condition, the α phase volume fraction is 20%, while the β phase volume fraction is 80%, with corresponding grain sizes of 5.9 µm and 30.1 µm, respectively. Microstructural analysis indicates that the plastic incompatibility between the α and β phases induces significant heterogeneous deformation-induced (HDI) strengthening. Moreover, the unique bimodal grain size distribution, where the α phase grains are significantly smaller than the β phase grains, enhances the “hard phase harder, soft phase softer” heterogeneous structural effect, further amplifying the HDI strengthening contribution. This study provides new theoretical insights into multiphase interface engineering for designing high-performance dual-phase magnesium alloys. Full article
(This article belongs to the Special Issue Light Alloy and Its Application (2nd Edition))
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