Search Results (282)

This study employs Western Anhui as a case study, establishing a three-dimensional quantitative analytical framework comprising ‘genetic map analysis—architectural feature coding—distribution pattern analysis’ to systematically describe and measure the cross-regional dissemination characteristics of Huizhou architectural culture within Western Anhui. Through field surveys and quantitative analysis of 20 traditional buildings (10 dwellings and 10 ancestral halls), this study employs order and law to determine feature weights and uses Spearman’s correlation coefficient to analyse feature associations, revealing the selective distribution pattern of Huizhou characteristics within Western Anhui architecture. Findings indicate: (1) the frequency of Huizhou features in ancestral halls (71%) significantly exceeds that in dwellings (36%), demonstrating typological differentiation; (2) plan-related features (plan form, courtyard configuration, compositional arrangement) appear most frequently in dwellings (60%), while stone carvings achieve comprehensive coverage in ancestral halls (100%); and (3) wood carvings and stone carvings co-occurred highly (ρ = 0.90), reflecting systematic application of decorative features; doors and plan forms showed a weak negative correlation (ρ = −0.17), potentially suggesting distinct adoption pathways, though not entirely mutually exclusive. The quantitative descriptive framework and feature database constructed in this study provide a replicable methodological reference for research into cross-regional architectural cultural transmission, while also offering scientific grounds for the conservation and restoration of traditional architecture in Western Anhui. Full article

Achieving natural esthetics has become essential for successful dental restorations and supports the use of modern non-metal materials. However, complexity in esthetic features of natural teeth, determined by both inherent color factors and hierarchical and gradient microstructures, makes recording, determination, and reproduction difficult. This often leads to misunderstanding during manufacturing and dissatisfaction with the final outcome, even when using advanced digital tools. The aim of this study was to investigate a new, easy-to-handle digital tool for determining the color of restorative materials. An industrial-level handheld color identifier, the NCS Colourpin SE, together with the corresponding NCS color system, was tested on three materials: dental resin nanocomposite, self-glazed zirconia (SGZ), and Decore zirconia pellets. The repeatability and impacts of geometrical contributions such as surface roughness and thickness on different colors were measured. The Colourpin SE offered promising repeatability. Decore zirconia showed more than 90% repeatability for most of the colors, independent of thickness. The NCS scanner showed slightly better repeatability than earlier in clinical trials with an intraoral scanner. The shades A3.5 and A3 had lower repeatability, varying from 50 to 90%. It identified effects of material thickness and surface roughness, where the thicker samples were identified with higher blackness levels, and surface roughness seemed to be coupled with a lower blackness level in color identification codes. Small but consistent differences between materials were detected, suggesting that material and manufacturing methods affect the final shade. The NCS Colourpin SE shows potential to be developed into an affordable and easy-to-handle scanner for the identification of a patient’s tooth color, enabling synchronization with digital workflows and improving the match between restoration and the patient’s natural teeth. Nevertheless, further research and development in customized applications for color identification in esthetic dentistry is still required through multidisciplinary collaboration. Full article

A DABCO-catalyzed one-pot synthesis of a novel pentacyclic heterocycle featuring an unprecedented benzo[4,5]imidazo[1,2-a]chromeno[3,2-e]pyridine scaffold from 2-(cyanomethyl)benzimidazole and 3-trifluoroacetyl-4-phenyl-4H-chromene has been developed. This hybrid architecture merges three privileged pharmacophores—benzimidazole, chromene, and pyridine—into a rigid, nearly planar π-extended system decorated with trifluoromethyl and nitrile groups. The structure of 8-phenyl-13a-(trifluoromethyl)-13aH-benzo[4,5]imidazo[1,2-a]chromeno[3,2-e]pyridine-6-carbonitrile was unambiguously confirmed through NMR spectroscopy and X-ray diffraction analysis. A plausible mechanism involves Michael addition, hemiaminal formation, ring opening, recyclization, and oxidation. Full article

This study presents a non-invasive, integrated and multidisciplinary diagnostic approach applied to the analysis of the altarpiece Coronation of the Virgin, attributed to Michele di Matteo (15th century). The investigation focused on the evaluation of a restoration intervention carried out in 2023 using quantitative colorimetric measurements to assess chromatic variations induced by surface treatments. Other non-invasive techniques, including multispectral imaging, hyperspectral imaging, Raman spectroscopy, and visible reflectance spectroscopy, were employed to investigate the painted surface, examine underlying features, and support the characterization and spatial distribution of pictorial materials through comparison with reference standards. Finally, the proteinaceous binding media used by the artist were investigated using nano-liquid chromatography coupled with tandem mass spectrometry (nLC-MS/MS), a sensitive, high-resolution analytical approach in the field of cultural heritage studies. Overall, the integrated approach documented chromatic changes induced by cleaning, revealed the preparatory drawing and previously unknown decorative elements by infrared reflectography, and confirmed the presence of pigments previously identified in earlier studies, allowing, in some cases, for an investigation of their distribution across the painted surface. The characterization of proteinaceous binding media further contributed to a deeper understanding of the materials and techniques employed by the artist. Full article

This paper highlights the findings of the emergency excavation carried out at Avenida Miguel de Cervantes No. 35 in Écija, conducted in two phases between 1999 and 2000 and in 2003. The investigation revealed a domus featuring valuable decorative elements, including pictorial wall paintings and two high-quality mosaics. Stylistic analysis of the wall decorations identified a scheme composed of wide and narrow panels, with a predominance of bright green in the central zone, along with traces of figurative representations. The evidence suggests a second construction phase in the latter half of the 2nd century AD, followed by renovations in the 3rd and 4th centuries. The use of green prevailing monochromy appears to be associated with high-status representational spaces. A total of six samples from the wall paintings and mortars were analysed. X-ray diffraction (XRPD) and X-ray fluorescence (XRF) were employed for a minimally destructive preliminary study of the mortars, while confocal microscopy was used to observe the sequence in which the pigments were applied, and Raman spectroscopy enabled the identification of the pigments, notably highlighting glauconite as the green pigment. Full article

This study identifies the technological signature of ancient and alternative “Chu” and “Kriab” gold glass mosaic mirrors from Thailand. Although these mirrors play an important role in Thai decorative heritage, their production routes and interfacial chemistry at the lead-to-glass interface have remained unclear. A survey of 154 sites across Thailand shows mosaic glass was widely distributed and likely produced during the Ayutthaya period (~300 years ago). Portable X-Ray Fluorescence (pXRF), Wavelength-Dispersive XRF (WD-XRF), scanning electron microscopy (SEM), and X-ray Photoelectron Spectroscopy (XPS) were used to examine the material properties of observed Chu mirrors. Most samples can be classified as a mixed lead–alkaline glass type, with a PbO content ranging from 4.28 to 48.17 wt%. Their yellow tone is controlled by iron and manganese redox states. Chemical and physical analyses distinguish between Chu from the northern part of Thailand and Kriab from the central part of Thailand, which share a silica source but rely on different fluxes, pointing to different glass workshops. Crucially, XPS depth profiling reveals a well-defined interfacial reaction zone extending to approximately 6 nm in the ancient mirrors, predominantly characterized by disordered, chain-like Pb–O–Pb linkages. These polymeric structures enable a “chemical bridging” mechanism that effectively accommodates interfacial strain arising from thermal expansion mismatch, thereby ensuring exceptional long-term adhesion. Furthermore, the depth-dependent distribution of hydrated lead species and the emergence of photoelectron energy-loss features beyond ~6 nm distinguish the superior metallic integrity of the ancient coatings from the alternative reproductions. This distinct stratification confirms that ancient artisans achieved a sophisticated balance between a chemically bonded interface and a coherent metallic bulk. These findings offer significant insights into the ingenuity of ancient Thai artisans, providing a scientific foundation for the conservation, restoration, and replication of these culturally significant artifacts. Full article

The carved lacquer horse-hoof-shaped box excavated from Yulin, Shaanxi Province, represents a typical example of lacquerware preservation in the arid environment of northern China, exhibiting multiple deterioration phenomena, including substrate deformation, lacquer film peeling, and pigment fading. To systematically analyze its structural composition and craftsmanship features, this study employed multiple analytical techniques, including ultra-depth microscopy, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), confocal laser micro-Raman spectroscopy (Raman), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Based on these analyses, a targeted conservation protocol was developed. Results revealed that the carved lacquer horse-hoof-shaped box has a wooden substrate structure, with the lacquer ash layer composed of mixed materials, including calcium carbonate (CaCO₃), quartz (SiO₂), and hydroxyapatite (Ca₁₀(PO₄)₆(OH)₂). The lacquer film layer contains Chinese lacquer and plant oils, with cinnabar applied as surface decoration. Based on these findings, a stratified reinforcement conservation strategy was proposed: under dynamic monitoring with optical fiber sensors and three-dimensional scanning, the wooden substrate was reinforced with moisture-curable polyurethane (MCPU), the lacquer ash layer was strengthened with acrylic emulsion (Primal AC33), aged areas were restored with nano calcium hydroxide (Ca(OH)₂) aqueous dispersion, and polyethylene glycol (PEG 400) poultice application was implemented to restore the flexibility of the lacquer film. This research significantly enhanced the integrity and stability of the carved lacquer horse-hoof-shaped box, providing practical evidence and technical references for the scientific conservation of lacquerware excavated from arid regions of northern China. Full article

Electrocatalytic hydrogenation (ECH) represents an environmentally friendly pathway for converting 5-hydroxymethylfurfural (HMF) into the high-value chemical 2,5-bis(hydroxymethyl)furan (BHMF). However, its selectivity and Faradaic efficiency are often constrained by competitive hydrogen evolution at the cathode and insufficient supply of active hydrogen at the surface. To address this challenge, this study developed an Ir-decorated copper oxide nanowire catalyst (denoted as CuIr) featuring a hydrogen-rich adsorption (H_ads) surface. The incorporation of Ir significantly enhances the catalyst’s water dissociation capacity, creating abundant H_ads sources that selectively accelerate HMF hydrogenation while suppressing side reactions. Under a mild applied potential of −0.45 V vs. RHE and a current density of approximately −20 mA cm⁻², the optimal CuIr₄₀ catalyst achieved near-complete conversion of HMF (99%), a BHMF yield of 99%, and a high Faradaic efficiency of 97% within 120 min of electrolysis. Mechanistic studies reveal that this catalytic leap stems from the synergistic functional interaction between Cu and Ir sites in substrate activation and hydrogen supply. This work presents a novel strategy for designing efficient electrocatalysts for biomass hydrogenation by regulating surface H_ads concentration. Full article

The global production of dimension stones, that is, natural stones that can be processed into blocks and used as building and decorative materials, has grown steadily since the second half of the twentieth century. The rise of global markets and trade has also contributed to a rapid increase in imports of natural stones from distant locations. The introduction of dimension stones sourced from other continents can contribute significantly to geocultural heritage, defined as geological features that have acquired cultural, historical or symbolic meaning, as well as cultural elements embedded in a geological context. In the present contribution, the use of dimension stones in the city of Poznań (Poland, central Europe) is quantified. The study reveals dramatic changes in natural stone use between 1990 and 2019, with the number of dimension stone types increasing nearly threefold, and the mean distance to the stone source areas rising from 322 to 3885 km. Growing numbers and more diversified lithologies of natural stones can improve the urban landscape and contribute to the development of geotourism. On the other hand, increasing imports of dimension stones negatively affect local producers, threaten future conservation efforts, and have significant geoethical implications. Full article

Traditional villages, protected as cultural heritage in our country, are rich in historical information, cultural landscapes, and traditional domestic architecture. This article explores the spatial distribution of traditional villages and proposes a new paradigm for the sustainable development of traditional dwellings. It addresses the challenges these villages face, such as natural, social, and inherent issues, arising from rapid socioeconomic development and urbanization. This study analyzes the spatial distribution and architectural features of traditional villages and dwellings in Northern Shaanxi based on 179 national and provincial villages. Using ArcGIS 10.1, the geographic concentration index, kernel density analysis, and the analytic hierarchy process, this study applied both macro and micro level perspectives. The research shows that: (1) The traditional villages in northern Shaanxi exhibit a spatial distribution pattern of “overall aggregation, local dispersion, and uneven distribution.” This pattern is influenced by interactions between natural and human factors. (2) Traditional dwellings in these villages are primarily cave dwellings and courtyard buildings, each reflecting unique architectural features in terms of floor plan layout, facade form, structure, materials, and decoration. (3) Traditional village dwellings in northern Shaanxi face practical challenges related to protection, development, and governance. The top three challenges, based on weighted indicators, are issues related to inheritance, an imperfect protection mechanism, and inherent shortcomings of the buildings. Based on these findings, this study proposes three practical suggestions for the sustainable development of traditional village dwellings in Northern Shaanxi. These suggestions aim to enhance the comprehensive and multi-dimensional sustainable development of traditional village dwellings. Full article

In age-friendly furniture design, the visual characteristics of material surfaces play a crucial role in shaping the usage experience and preferences of elderly users. In response to the application requirements of decorative materials for furniture surfaces, this study focuses on polypropylene (PP) films, with the objective of investigating the visual perceptual preferences of elderly users concerning the surface color and glossiness attributes of these films. An eye-tracking experiment was initially conducted to identify color preferences among elderly participants, utilizing indicators including first fixation duration, total fixation duration, and total fixation count. Subsequently, a questionnaire survey was administered to assess user satisfaction with PP films featuring different glossiness levels—high-glossiness, semi-glossiness, and matte—and explored whether glossiness significantly influences color preference. The experimental results revealed the following: (1) red hues exhibited stronger initial visual attraction, while colors with low saturation and medium-to-high lightness sustained longer visual engagement; (2) the matte finishes received significantly higher satisfaction ratings than both semi-glossiness and high-glossiness finishes, with this preference remaining consistent across different color conditions; (3) glossiness does not exert a significant influence on color preference. The findings of this study provide consumer-oriented insights for the design of PP films that better accommodate the preferences of elderly users, while also offering guidance for the application and optimization of green and safe furniture materials. Full article

Portuguese ceramic tile (azulejo) production has evolved significantly since its beginnings in the 16th century. While historic tiles reflect well-established traditional techniques and styles, modern and contemporary works began to explore new aesthetic and material possibilities, introducing textures, surface effects, and experimental approaches that challenge conventional conservation methods. This study examines a contemporary Portuguese tile panel dated from 1987, featuring decorative effect glazes with crater and crazing textures, which were characterized and reproduced. Analytical techniques, including optical microscopy, micro-X-ray fluorescence spectrometry, and Raman spectroscopy in microscopic mode, were employed to characterize material composition and formation mechanisms. Results showed that the crater-effect glazes were achieved with a silica-rich glaze recipe with MnO₂ and ZrO₂. The crazing effect developed in regions where unmelted crystalline silica induced internal stresses within a lead-silicate glaze, contributing to localized degradation. Experimental reproductions of the glazes, guided by analytical data, were conducted to better understand their formation and inform conservation strategies. The results provide essential insights for the technical assessment, documentation, and preservation of contemporary ceramic artworks featuring decorative effect glazes and contribute to the broader field of cultural heritage conservation. Full article

This study examines the traditional villages of the Tujia and Miao ethnic groups in Xiangxi Prefecture, western Hunan, and clarifies their spatial distribution and residential cultures through ArcGIS-based spatial analysis combined with extensive field investigation. On the basis of a systematic comparative framework, it explores differences in village patterns, architectural forms, and folk belief systems between the two groups. The results indicate that (1) in terms of spatial distribution, Miao villages are mainly located to the south of the Wuling Mountains, while Tujia villages are concentrated to the north, with the mountainous ranges of Baojing and Guzhang counties forming a clear transitional belt; (2) regarding village layout, Miao villages are generally clustered with “mountain-backed and water-adjacent”, whereas Tujia villages tend to adopt a more dispersed and defensive pattern than “mountain-anchored and water-distanced”; (3) in dwelling form, both groups share similar basic spatial organization, yet Miao dwellings exhibit greater diversity in construction materials, including timber, stone, and rammed earth; (4) in terms of belief and ritual, distinct folk practices and symbolic systems are embedded in the spatial organization and decorative features of each group’s villages. These findings deepen the understanding of cultural diversity among ethnic minorities in western Hunan and provide a theoretical basis for authenticity-oriented conservation and the sustainable development of traditional villages in ethnic regions. Full article

The growing demand for high-quality decorative polymer surfaces has increased interest in Out Mold Decoration (OMD), yet the combined influence of processing conditions and product geometry on film adhesion and deformation remains insufficiently defined. This study establishes an integrated framework that connects OMD process parameters with geometry-dependent deformation behavior using polycarbonate films printed with an ink grid. Adhesion and surface quality were evaluated using 2.5D specimens, while 3D models with varied fillet radii, slopes, and heights enabled quantitative assessment of grid-spacing evolution and thickness distribution. Results show that preheating smooths the film without improving adhesion, whereas increasing the forming environment temperature enhances both bonding and surface quality within the material’s thermal tolerance. Vacuum pressure strengthens film–substrate contact but requires moderation to prevent overstretching. An optimized condition of 100 °C preheating, 90 °C forming temperature, and 2.5 kg vacuum pressure provides a balanced performance. Geometric factors exert strong control over deformation, with small radii, steep slopes, and tall features producing greater strain and nonuniform thinning. These findings establish practical processing windows and geometry guidelines for achieving reliable OMD components that integrate high visual quality with stable adhesion performance. Full article

George Town, the capital of Penang, Malaysia, was inscribed as a UNESCO World Heritage Site in 2008 and is renowned for its multicultural architectural surfaces. However, these historic façades face significant deterioration challenges, particularly biodeterioration caused by weed growth on wall surfaces under hot and humid equatorial conditions. Root penetration is a critical surface defect, accelerating mortar decay and threatening structural integrity. To address this issue, this study proposes YOLOv11-SWDS (Surface Weed Detection System), a lightweight and interpretable deep learning framework tailored for surface defect detection in the form of weed intrusion on heritage buildings. The backbone network was redesigned to enhance the extraction of fine-grained features from visually cluttered surfaces, while attention modules improved discrimination between weed patterns and complex textures such as shadows, stains, and decorative reliefs. For practical deployment, the model was optimized through quantization and knowledge distillation, significantly reducing computational cost while preserving detection accuracy. Experimental results show that YOLOv11-SWDS achieved an F1 score of 86.0% and a mAP@50 of 89.7%, surpassing baseline models while maintaining inference latency below 200 ms on edge devices. These findings demonstrate the potential of deep learning-based non-destructive detection for monitoring surface defects in heritage conservation, offering both a reliable tool for sustaining George Town’s cultural assets and a transferable solution for other UNESCO heritage sites. Full article