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21 pages, 6166 KiB  
Article
Effect of Thermal Cycles on the Compressive Properties of 3D-Printed Polymeric Lattice-Reinforced Cement-Based Materials
by Can Tang, Yujie Zhou, Jing Qiao, Humaira Kanwal, Guoqian Song and Wenfeng Hao
Polymers 2025, 17(15), 2137; https://doi.org/10.3390/polym17152137 (registering DOI) - 4 Aug 2025
Abstract
Existing studies have shown that placing 3D-printed lattices in cement matrices can effectively improve the ductility of cement-based composites. However, the influence of thermal fatigue effect on the mechanical properties of 3D-printed lattice-reinforced cement-based composites during service remains to be studied. In this [...] Read more.
Existing studies have shown that placing 3D-printed lattices in cement matrices can effectively improve the ductility of cement-based composites. However, the influence of thermal fatigue effect on the mechanical properties of 3D-printed lattice-reinforced cement-based composites during service remains to be studied. In this paper, cement-based materials without lattices were used as the control group, and the uniaxial compressive mechanical properties of 3D-printed lattice-reinforced cement-based composites after thermal fatigue treatment under a temperature difference of 60 °C were tested. The number of thermal fatigue cycles was set to 45, 90, and 145 times, respectively. During the test, two non-destructive testing technologies, AE and DIC, were used to analyze the strength degradation and deformation law of 3D-printed lattice-reinforced cement-based composites with the increase in cycles. AE adopted the threshold triggering mode, and the channel threshold was 100 mv. The experiment showed that the compressive strength of the control group after 45, 90, and 145 thermal cycles decreased to 72.47% and 49.44% of that of the specimen after 45 thermal cycles, respectively. The strength of RO lattices decreased to 91.07% and 82.14% of that of the specimen after 45 thermal cycles, respectively, while the strength of SO lattices decreased to 83.27% and 77.96% of that of the specimen after 45 thermal cycles, respectively. The compressive strengths of the two types of lattices were higher than that of the control group after three cycles, indicating that 3D-printed lattices can effectively mitigate the influence of environmental thermal fatigue on the mechanical properties of cement-based materials. Full article
(This article belongs to the Special Issue Polymeric Materials and Their Application in 3D Printing, 2nd Edition)
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28 pages, 6199 KiB  
Article
Dual Chaotic Diffusion Framework for Multimodal Biometric Security Using Qi Hyperchaotic System
by Tresor Lisungu Oteko and Kingsley A. Ogudo
Symmetry 2025, 17(8), 1231; https://doi.org/10.3390/sym17081231 - 4 Aug 2025
Abstract
The proliferation of biometric technology across various domains including user identification, financial services, healthcare, security, law enforcement, and border control introduces convenience in user identity verification while necessitating robust protection mechanisms for sensitive biometric data. While chaos-based encryption systems offer promising solutions, many [...] Read more.
The proliferation of biometric technology across various domains including user identification, financial services, healthcare, security, law enforcement, and border control introduces convenience in user identity verification while necessitating robust protection mechanisms for sensitive biometric data. While chaos-based encryption systems offer promising solutions, many existing chaos-based encryption schemes exhibit inherent shortcomings including deterministic randomness and constrained key spaces, often failing to balance security robustness with computational efficiency. To address this, we propose a novel dual-layer cryptographic framework leveraging a four-dimensional (4D) Qi hyperchaotic system for protecting biometric templates and facilitating secure feature matching operations. The framework implements a two-tier encryption mechanism where each layer independently utilizes a Qi hyperchaotic system to generate unique encryption parameters, ensuring template-specific encryption patterns that enhance resistance against chosen-plaintext attacks. The framework performs dimensional normalization of input biometric templates, followed by image pixel shuffling to permutate pixel positions before applying dual-key encryption using the Qi hyperchaotic system and XOR diffusion operations. Templates remain encrypted in storage, with decryption occurring only during authentication processes, ensuring continuous security while enabling biometric verification. The proposed system’s framework demonstrates exceptional randomness properties, validated through comprehensive NIST Statistical Test Suite analysis, achieving statistical significance across all 15 tests with p-values consistently above 0.01 threshold. Comprehensive security analysis reveals outstanding metrics: entropy values exceeding 7.99 bits, a key space of 10320, negligible correlation coefficients (<102), and robust differential attack resistance with an NPCR of 99.60% and a UACI of 33.45%. Empirical evaluation, on standard CASIA Face and Iris databases, demonstrates practical computational efficiency, achieving average encryption times of 0.50913s per user template for 256 × 256 images. Comparative analysis against other state-of-the-art encryption schemes verifies the effectiveness and reliability of the proposed scheme and demonstrates our framework’s superior performance in both security metrics and computational efficiency. Our findings contribute to the advancement of biometric template protection methodologies, offering a balanced performance between security robustness and operational efficiency required in real-world deployment scenarios. Full article
(This article belongs to the Special Issue New Advances in Symmetric Cryptography)
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29 pages, 7249 KiB  
Article
Application of Multi-Objective Optimization for Path Planning and Scheduling: The Edible Oil Transportation System Framework
by Chin S. Chen, Chia J. Lin, Yu J. Lin and Feng C. Lin
Appl. Sci. 2025, 15(15), 8539; https://doi.org/10.3390/app15158539 (registering DOI) - 31 Jul 2025
Viewed by 186
Abstract
This study proposes a multi-objective optimization scheduling method for edible oil transportation in smart manufacturing, focusing on centralized control and addressing challenges such as complex pipelines and shared resource constraints. The method employs the A* and Dijkstra pathfinding algorithm to determine the shortest [...] Read more.
This study proposes a multi-objective optimization scheduling method for edible oil transportation in smart manufacturing, focusing on centralized control and addressing challenges such as complex pipelines and shared resource constraints. The method employs the A* and Dijkstra pathfinding algorithm to determine the shortest pipeline route for each task, and estimates pipeline resource usage to derive a node cost weight function. Additionally, the transport time is calculated using the Hagen–Poiseuille law by considering the viscosity coefficients of different oil types. To minimize both cost and time, task execution sequences are optimized based on a Pareto front approach. A 3D digital model of the pipeline system was developed using C#, SolidWorks Professional, and the Helix Toolkit V2.24.0 to simulate a realistic production environment. This model is integrated with a 3D visual human–machine interface(HMI) that displays the status of each task before execution and provides real-time scheduling adjustment and decision-making support. Experimental results show that the proposed method improves scheduling efficiency by over 43% across various scenarios, significantly enhancing overall pipeline transport performance. The proposed method is applicable to pipeline scheduling and transportation management in digital factories, contributing to improved operational efficiency and system integration. Full article
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17 pages, 438 KiB  
Article
Analytic Solutions and Conservation Laws of a 2D Generalized Fifth-Order KdV Equation with Power Law Nonlinearity Describing Motions in Shallow Water Under a Gravity Field of Long Waves
by Chaudry Masood Khalique and Boikanyo Pretty Sebogodi
AppliedMath 2025, 5(3), 96; https://doi.org/10.3390/appliedmath5030096 (registering DOI) - 31 Jul 2025
Viewed by 72
Abstract
The Korteweg–de Vries (KdV) equation is a nonlinear evolution equation that reflects a wide variety of dispersive wave occurrences with limited amplitude. It has also been used to describe a range of major physical phenomena, such as shallow water waves that interact weakly [...] Read more.
The Korteweg–de Vries (KdV) equation is a nonlinear evolution equation that reflects a wide variety of dispersive wave occurrences with limited amplitude. It has also been used to describe a range of major physical phenomena, such as shallow water waves that interact weakly and nonlinearly, acoustic waves on a crystal lattice, lengthy internal waves in density-graded oceans, and ion acoustic waves in plasma. The KdV equation is one of the most well-known soliton models, and it provides a good platform for further research into other equations. The KdV equation has several forms. The aim of this study is to introduce and investigate a (2+1)-dimensional generalized fifth-order KdV equation with power law nonlinearity (gFKdVp). The research methodology employed is the Lie group analysis. Using the point symmetries of the gFKdVp equation, we transform this equation into several nonlinear ordinary differential equations (ODEs), which we solve by employing different strategies that include Kudryashov’s method, the (G/G) expansion method, and the power series expansion method. To demonstrate the physical behavior of the equation, 3D, density, and 2D graphs of the obtained solutions are presented. Finally, utilizing the multiplier technique and Ibragimov’s method, we derive conserved vectors of the gFKdVp equation. These include the conservation of energy and momentum. Thus, the major conclusion of the study is that analytic solutions and conservation laws of the gFKdVp equation are determined. Full article
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17 pages, 2495 KiB  
Article
Production Capacity and Temperature–Pressure Variation Laws in Depressurization Exploitation of Unconsolidated Hydrate Reservoir in Shenhu Sea Area
by Yuanwei Sun, Yuanfang Cheng, Yanli Wang, Jian Zhao, Xian Shi, Xiaodong Dai and Fengxia Shi
Processes 2025, 13(8), 2418; https://doi.org/10.3390/pr13082418 - 30 Jul 2025
Viewed by 227
Abstract
The Shenhu sea area is rich in unconsolidated hydrate reserves, but the formation mineral particles are small, the rock cementation is weak, and the coupling mechanism of hydrate phase change, fluid seepage, and formation deformation is complex, resulting in unclear productivity change law [...] Read more.
The Shenhu sea area is rich in unconsolidated hydrate reserves, but the formation mineral particles are small, the rock cementation is weak, and the coupling mechanism of hydrate phase change, fluid seepage, and formation deformation is complex, resulting in unclear productivity change law under depressurization exploitation. Therefore, a thermal–fluid–solid–chemical coupling model for natural gas hydrate depressurization exploitation in the Shenhu sea area was constructed to analyze the variation law of reservoir parameters and productivity. The results show that within 0–30 days, rapid near-well pressure drop (13.83→9.8 MPa, 36.37%) drives peak gas production (25,000 m3/d) via hydrate dissociation, with porosity (0.41→0.52) and permeability (75→100 mD) increasing. Within 30–60 days, slower pressure decline (9.8→8.6 MPa, 12.24%) and fines migration cause permeability fluctuations (120→90 mD), reducing gas production to 20,000 m3/d. Within 60–120 days, pressure stabilizes (~7.6 MPa) with residual hydrate saturation < 0.1, leading to stable low permeability (60 mD) and gas production (15,000 m3/d), with cumulative production reaching 2.2 × 106 m3. This study clarifies that productivity is governed by coupled “pressure-driven dissociation–heat limitation–fines migration” mechanisms, providing key insights for optimizing depressurization strategies (e.g., timed heat supplementation, anti-clogging measures) to enhance commercial viability of unconsolidated hydrate reservoirs. Full article
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31 pages, 11019 KiB  
Review
A Review of Tunnel Field-Effect Transistors: Materials, Structures, and Applications
by Shupeng Chen, Yourui An, Shulong Wang and Hongxia Liu
Micromachines 2025, 16(8), 881; https://doi.org/10.3390/mi16080881 - 29 Jul 2025
Viewed by 350
Abstract
The development of an integrated circuit faces the challenge of the physical limit of Moore’s Law. One of the most important “Beyond Moore” challenges is the scaling down of Metal-Oxide-Semiconductor Field-Effect Transistors (MOSFETs) versus their increasing static power consumption. This is because, at [...] Read more.
The development of an integrated circuit faces the challenge of the physical limit of Moore’s Law. One of the most important “Beyond Moore” challenges is the scaling down of Metal-Oxide-Semiconductor Field-Effect Transistors (MOSFETs) versus their increasing static power consumption. This is because, at room temperature, the thermal emission transportation mechanism will cause a physical limitation on subthreshold swing (SS), which is fundamentally limited to a minimum value of 60 mV/decade for MOSFETs, and accompanied by an increase in off-state leakage current with the process of scaling down. Moreover, the impacts of short-channel effects on device performance also become an increasingly severe problem with channel length scaling down. Due to the band-to-band tunneling mechanism, Tunnel Field-Effect Transistors (TFETs) can reach a far lower SS than MOSFETs. Recent research works indicated that TFETs are already becoming some of the promising candidates of conventional MOSFETs for ultra-low-power applications. This paper provides a review of some advances in materials and structures along the evolutionary process of TFETs. An in-depth discussion of both experimental works and simulation works is conducted. Furthermore, the performance of TFETs with different structures and materials is explored in detail as well, covering Si, Ge, III-V compounds and 2D materials, alongside different innovative device structures. Additionally, this work provides an outlook on the prospects of TFETs in future ultra-low-power electronics and biosensor applications. Full article
(This article belongs to the Special Issue MEMS/NEMS Devices and Applications, 3rd Edition)
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18 pages, 4643 KiB  
Article
The Effect of Non-Transferred Plasma Torch Electrodes on Plasma Jet: A Computational Study
by Sai Likitha Siddanathi, Lars-Göran Westerberg, Hans O. Åkerstedt, Henrik Wiinikka and Alexey Sepman
Appl. Sci. 2025, 15(15), 8367; https://doi.org/10.3390/app15158367 - 28 Jul 2025
Viewed by 178
Abstract
This study explores how different electrode shapes affect plasma flow in a non-transferred plasma torch. Various cathode geometries—including conical, tapered, flat, and cylindrical—were examined alongside stepped anode designs. A 2D axisymmetric computational model was employed to assess the impact of these shapes on [...] Read more.
This study explores how different electrode shapes affect plasma flow in a non-transferred plasma torch. Various cathode geometries—including conical, tapered, flat, and cylindrical—were examined alongside stepped anode designs. A 2D axisymmetric computational model was employed to assess the impact of these shapes on plasma behavior. The results reveal that different cathode designs require varying current levels to maintain a consistent power output. This paper presents the changes in electric conductivity and electric potential for different input currents across the arc formation path (from the cathode tip to the anode beginning) and relating to Ohm’s law. Significant variations in plasma jet velocity and temperature were observed, especially near the cathode tip. The study concludes by evaluating thermal efficiency across geometry configurations. Flat cathodes demonstrated the highest efficiency, while the anode shape had minimal impact. Full article
(This article belongs to the Section Applied Physics General)
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19 pages, 890 KiB  
Article
Finite Element Simulation for Fractional Allen–Cahn Equation with Regularized Logarithmic Free Energy
by Feng Wang and Huanzhen Chen
Fractal Fract. 2025, 9(8), 488; https://doi.org/10.3390/fractalfract9080488 - 24 Jul 2025
Viewed by 212
Abstract
This paper is focused on developing a Galerkin finite element framework for the fractional Allen–Cahn equation with regularized logarithmic potential over the Rd (d=1,2,3) domain, where the regularization of the singular potential extends beyond [...] Read more.
This paper is focused on developing a Galerkin finite element framework for the fractional Allen–Cahn equation with regularized logarithmic potential over the Rd (d=1,2,3) domain, where the regularization of the singular potential extends beyond the classical double-well formulation. A fully discrete finite element scheme is developed using a k-th-order finite element space for spatial approximation and a backward Euler scheme for the temporal discretization of a regularized system. The existence and uniqueness of numerical solutions are rigorously established by applying Brouwer’s fixed-point theorem. Moreover, the proposed numerical framework is shown to preserve the discrete energy dissipation law analytically, while a priori error estimates are derived. Finally, numerical experiments are conducted to verify the theoretical results and the inherent physical property, such as phase separation phenomenon and coarsening processes. The results show that the fractional Allen–Cahn model provides enhanced capability in capturing phase transition characteristics compared to its classical equation. Full article
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21 pages, 9288 KiB  
Article
Research on Deformation Mechanisms and Control Technology for Floor Heave in Deep Dynamic Pressure Roadway
by Haojie Xue, Chong Zhang, Yubing Huang, Ancheng Wang, Jie Wang, Kuoxing Li and Jiantao Zhang
Appl. Sci. 2025, 15(15), 8125; https://doi.org/10.3390/app15158125 - 22 Jul 2025
Viewed by 292
Abstract
Under deep, high-intensity mining conditions, a high mineral pressure develops at the working face, which can easily cause floor heave deformation of the roadway. In this paper, with the geological conditions of Buertai coal mine as the background, through on-site monitoring and numerical [...] Read more.
Under deep, high-intensity mining conditions, a high mineral pressure develops at the working face, which can easily cause floor heave deformation of the roadway. In this paper, with the geological conditions of Buertai coal mine as the background, through on-site monitoring and numerical simulation, the mechanism of strong dynamic pressure roadway floor heave is clarified and a cooperative control method for roadway floor heave deformation is proposed. The main conclusions are as follows: (1) The overall strength of the floor of this strong dynamic pressure roadway is low, which can easily cause roadway floor heave, and on-site multivariate monitoring of the mine pressure is carried out, which clarifies the evolution law of the mine pressure of the mining roadway and along-the-airway roadway. (2) Combined with FLAC3D numerical simulation software, we analyze the influence of coal seam depth and floor lithology on the stability of the roadway floor and find that both have a significant influence on the stability of the roadway. Under the condition of high-intensity mining, the floor will deteriorate gradually, forming a wide range of floor heave areas. (3) Based on the deformation and damage mechanism of the roadway floor, a synergistic control method of “roof cutting and pressure relief + floor anchor injection” is proposed and various technical parameters are designed. An optimized design scheme is designed for the control of floor heave in Buertai coal mine. Full article
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20 pages, 4023 KiB  
Article
Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling Model
by Xing Hu, Hu Xu, Chenglin Ding, Yupeng Tian and Kuo Yang
Batteries 2025, 11(7), 280; https://doi.org/10.3390/batteries11070280 - 21 Jul 2025
Viewed by 401
Abstract
The escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory and energy conservation principles. The model solves multi-physics [...] Read more.
The escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory and energy conservation principles. The model solves multi-physics equations such as Fick’s law, Ohm’s law, and the Butler–Volmer equation, to resolve coupled electrochemical and thermal dynamics, with temperature-dependent parameters calibrated via the Arrhenius equation. Simulations under varying discharge rates reveal that high-rate discharges exacerbate internal heat accumulation. Low ambient temperatures amplify polarization effects. Forced convection cooling reduces surface temperatures but exacerbates core-to-surface thermal gradients. Structural optimization strategies demonstrate that enhancing through-thickness thermal conductivity reduces temperature differences. These findings underscore the necessity of balancing energy density and thermal management in lithium-ion battery design, proposing actionable insights such as preheating protocols for low-temperature operation, optimized cooling systems for high-rate scenarios, and material-level enhancements for improved thermal uniformity. Full article
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21 pages, 4259 KiB  
Article
Transient Subcooled Boiling in Minichannels: Experimental Study and Numerical Modelling Using Trefftz Functions and ADINA
by Beata Maciejewska, Magdalena Piasecka and Paweł Łabędzki
Energies 2025, 18(14), 3865; https://doi.org/10.3390/en18143865 - 20 Jul 2025
Viewed by 368
Abstract
This study focuses on the phenomenon of boiling heat transfer during fluid flow (Fluorinert FC-72) in minichannels. The research stand was built around a specially designed test section incorporating sets of aligned minichannels, each 1 mm deep. These channel arrays varied in number, [...] Read more.
This study focuses on the phenomenon of boiling heat transfer during fluid flow (Fluorinert FC-72) in minichannels. The research stand was built around a specially designed test section incorporating sets of aligned minichannels, each 1 mm deep. These channel arrays varied in number, comprising configurations with 7, 15, 17, 19, 21, and 25 parallel channels. The test section was vertically orientated with upward fluid flow. To address the heat transfer problem associated with transient flow boiling, two numerical approaches grounded in the finite element method (FEM) were employed. One used the Trefftz function formulation, while the other relied on simulations performed using the commercial software ADINA (version 9.2). In both approaches, the heat transfer coefficient at the interface between the heated foil and the working fluid was determined by applying a Robin-type boundary condition, which required knowledge of the temperatures in both the foil and the fluid, along with the temperature gradient within the foil. The outcomes of both FEM-based models, as well as those of a simplified 1D method based on Newton’s cooling law, yielded satisfactory results. Full article
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12 pages, 2262 KiB  
Article
Long-Term Creep Mechanical and Acoustic Emission Characteristics of Water-Immersed Coal Pillar Dam
by Ersheng Zha, Mingbo Chi, Zhiguo Cao, Baoyang Wu, Jianjun Hu and Yan Zhu
Appl. Sci. 2025, 15(14), 8012; https://doi.org/10.3390/app15148012 - 18 Jul 2025
Viewed by 187
Abstract
This study conducted uniaxial creep tests on coal samples under both natural and water-saturated conditions for durations of about 180 days per sample to study the stability of coal pillar dams of the Daliuta Coal Mine underground reservoir. Combined with synchronized acoustic emission [...] Read more.
This study conducted uniaxial creep tests on coal samples under both natural and water-saturated conditions for durations of about 180 days per sample to study the stability of coal pillar dams of the Daliuta Coal Mine underground reservoir. Combined with synchronized acoustic emission (AE) monitoring, the research systematically revealed the time-dependent deformation mechanisms and damage evolution laws of coal under prolonged water immersion and natural conditions. The results indicate that water-immersed coal exhibits a unique negative creep phenomenon at the initial stage, with the strain rate down to −0.00086%/d, attributed to non-uniform pore compaction and elastic rebound effects. During the steady-state creep phase, the creep rates under water-immersed and natural conditions were comparable. However, water immersion led to an 11.4% attenuation in elastic modulus, decreasing from 2300 MPa to 2037 MPa. Water immersion would also suppress AE activity, leading to the average daily AE events of 128, which is only 25% of that under natural conditions. In the accelerating creep stage, the AE event rate surged abruptly, validating its potential as an early warning indicator for coal pillar instability. Based on the identified long-term strength of the coal sample, it is recommended to maintain operational loads below the threshold of 9 MPa. This research provides crucial theoretical foundations and experimental data for optimizing the design and safety monitoring of coal pillar dams in CMURs. Full article
(This article belongs to the Section Civil Engineering)
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18 pages, 2807 KiB  
Article
The Nonlinear Vibration Response of Umbrella-Shaped Membrane Structure Under Heavy Rainfall Loads
by Zhongwei Luo, Zhoulian Zheng, Rui Yang and Peng Zhang
Buildings 2025, 15(14), 2529; https://doi.org/10.3390/buildings15142529 - 18 Jul 2025
Viewed by 160
Abstract
This paper investigates the vibration characteristics of tensioned umbrella-shaped membrane structures with complex curvature under heavy rainfall. To solve the geometrical problem of the complex curvature of a membrane surface, we set the rule of segmentation and simplify the shape by dividing it [...] Read more.
This paper investigates the vibration characteristics of tensioned umbrella-shaped membrane structures with complex curvature under heavy rainfall. To solve the geometrical problem of the complex curvature of a membrane surface, we set the rule of segmentation and simplify the shape by dividing it into multi-segment conical membranes. The generatrix becomes a polyline with a constant surface curvature in each segment, simplifying calculations. The equivalent uniform load of different rainfall intensity is determined by the theory of the stochastic process. The governing equations of the isotropic damped nonlinear forced vibration of membranes are established by using the theory of large deflection by von Karman and the principle of d’Alembert. The equations of the forced vibration of the membrane are solved by using Galerkin’s method and the small-parameter perturbation method, and the displacement function, vibration frequency, and acceleration of the membrane are obtained. At last, the influence of the height–span ratio, number of segments, pretension and load on membrane displacement, vibration frequency, and acceleration of the membrane surface are analyzed. Based on the above data, the general law of deformation of the umbrella-shaped membrane under heavy rainfall is obtained. Data and methods are provided for the design and construction of the membrane structure as a reference. Moreover, we propose methods to enhance calculation accuracy and streamline the computational process. Full article
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15 pages, 2521 KiB  
Article
Interface-Driven Electrothermal Degradation in GaN-on-Diamond High Electron Mobility Transistors
by Huanran Wang, Yifan Liu, Xiangming Dong, Abid Ullah, Jisheng Sun, Chuang Zhang, Yucheng Xiong, Peng Gu, Ge Chen and Xiangjun Liu
Nanomaterials 2025, 15(14), 1114; https://doi.org/10.3390/nano15141114 - 18 Jul 2025
Viewed by 298
Abstract
Diamond is an attractive substrate candidate for GaN high-electron-mobility transistors (HEMT) to enhance heat dissipation due to its exceptional thermal conductivity. However, the thermal boundary resistance (TBR) at the GaN–diamond interface poses a significant bottleneck to heat transport, exacerbating self-heating and limiting device [...] Read more.
Diamond is an attractive substrate candidate for GaN high-electron-mobility transistors (HEMT) to enhance heat dissipation due to its exceptional thermal conductivity. However, the thermal boundary resistance (TBR) at the GaN–diamond interface poses a significant bottleneck to heat transport, exacerbating self-heating and limiting device performance. In this work, TCAD simulations were employed to systematically investigate the effects of thermal boundary layer (TBL) thickness (dTBL) and thermal conductivity (κTBL) on the electrothermal behavior of GaN-on-diamond HEMTs. Results show that increasing the TBL thickness (5–20 nm) or decreasing its thermal conductivity (0.1–1.0 W/(m·K)) leads to elevated hotspot temperatures and degraded electron mobility, resulting in a notable deterioration of IV characteristics. The nonlinear dependence of device performance on κTBL is attributed to Fourier’s law, where heat flux is inversely proportional to thermal resistance. Furthermore, the co-analysis of substrate thermal conductivity and interfacial quality reveals that interface TBR has a more dominant impact on device behavior than substrate conductivity. Remarkably, devices with low thermal conductivity substrates and optimized interfaces can outperform those with high-conductivity substrates but poor interfacial conditions. These findings underscore the critical importance of interface engineering in thermal management of GaN–diamond HEMTs and provide a theoretical foundation for future work on phonon transport and defect-controlled thermal interfaces. Full article
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15 pages, 2165 KiB  
Article
Study on the High-Temperature Reaction Kinetics of Solid Waste-Based High Belite Sulphoaluminate Cement Containing Residual Gypsum in Clinker
by Dunlei Su, Mingxin Yang, Yani Hao, Jiahui Wang, Xin Liu, Haojian Tang, Fengyuan Dong, Dejin Xing and Weiyi Kong
Materials 2025, 18(14), 3369; https://doi.org/10.3390/ma18143369 - 17 Jul 2025
Viewed by 336
Abstract
In order to elucidate the high-temperature reaction process of solid waste-based high belite sulphoaluminate cement containing residual gypsum in clinker (NHBSAC) and obtain the formation laws of each mineral in clinker, this article studied its high-temperature reaction kinetics. Through QXRD analysis and numerical [...] Read more.
In order to elucidate the high-temperature reaction process of solid waste-based high belite sulphoaluminate cement containing residual gypsum in clinker (NHBSAC) and obtain the formation laws of each mineral in clinker, this article studied its high-temperature reaction kinetics. Through QXRD analysis and numerical fitting methods, the formation of C4A3S¯, β-C2S, and CaSO4 in clinker under different calcination systems was quantitatively characterized, the corresponding high-temperature reaction kinetics models were established, and the reaction activation energies of each mineral were obtained. The results indicate that the content of C4A3S¯ and β-C2S increases with the prolongation of holding time and the increase in calcination temperature, while CaSO4 is continuously consumed. Under the control mechanism of solid-state reaction, the formation and consumption of minerals follow the kinetic equation. C4A3S¯ and β-C2S satisfy the D4 equation under diffusion mechanism control, and CaSO4 satisfies the R3 equation under interface chemical reaction mechanism control. The activation energy required for mineral formation varies with different temperature ranges. The activation energies required to form C4A3S¯ at 1200–1225 °C, 1225–1275 °C, and 1275–1300 °C are 166.28 kJ/mol, 83.14 kJ/mol, and 36.58 kJ/mol, respectively. The activation energies required to form β-C2S at 1200–1225 °C and 1225–1300 °C are 374.13 kJ/mol and 66.51 kJ/mol, respectively. This study is beneficial for achieving flexible control of the mineral composition of NHBSAC clinker, providing a theoretical basis and practical experience for the preparation of low-carbon cement and the optimization design of its mineral composition. Full article
(This article belongs to the Special Issue Characterization and Optimization of Cement-Based Materials)
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