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16 pages, 2886 KiB  
Article
Incremental Capacity-Based Variable Capacitor Battery Model for Effective Description of Charge and Discharge Behavior
by Ngoc-Thao Pham, Sungoh Kwon and Sung-Jin Choi
Batteries 2025, 11(8), 300; https://doi.org/10.3390/batteries11080300 - 5 Aug 2025
Abstract
Determining charge and discharge behavior is essential for optimizing charging strategies and evaluating balancing algorithms in battery energy storage systems and electric vehicles. Conventionally, a sequence of circuit simulations or tedious hardware tests is required to evaluate the performance of the balancing algorithm. [...] Read more.
Determining charge and discharge behavior is essential for optimizing charging strategies and evaluating balancing algorithms in battery energy storage systems and electric vehicles. Conventionally, a sequence of circuit simulations or tedious hardware tests is required to evaluate the performance of the balancing algorithm. To mitigate these problems, this paper proposes a variable capacitor model that can be easily built from the incremental capacity curve. This model provides a direct and insightful R-C time constant method for the charge/discharge time calculation. After validating the model accuracy by experimental results based on the cylindrical lithium-ion cell test, a switched-capacitor active balancing and a passive cell balancing circuit are implemented to further verify the effectiveness of the proposed model in calculating the cell balancing time within 2% error. Full article
(This article belongs to the Special Issue Batteries: 10th Anniversary)
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21 pages, 3570 KiB  
Article
Performance Studies on a Scaled Model of Dual Oscillating-Buoys WEC with One Pneumatic PTO
by Peiyu Liu, Xiang Rao, Bijun Wu, Zhiwen Yuan and Fuming Zhang
Energies 2025, 18(15), 4151; https://doi.org/10.3390/en18154151 - 5 Aug 2025
Abstract
A hybrid wave energy conversion (WEC) system, integrating a backward bent duct buoy (BBDB) with an oscillating buoy (OB) via a flexible mooring chain, is introduced in this study. Unlike existing hybrid WECs, the proposed system dispenses with rigid mechanical linkages and enables [...] Read more.
A hybrid wave energy conversion (WEC) system, integrating a backward bent duct buoy (BBDB) with an oscillating buoy (OB) via a flexible mooring chain, is introduced in this study. Unlike existing hybrid WECs, the proposed system dispenses with rigid mechanical linkages and enables flexible offshore deployment. Flared BBDB and buoy models with spherical, cylindrical, and semi-capsule shapes are designed and tested experimentally in a wave flume using both regular and irregular wave conditions. The effects of nozzle ratio (NR), coupling distance, buoy draft, and buoy geometry are systematically examined to investigate the hydrodynamic performance and energy conversion characteristics. It is found that NR at 110 under unidirectional airflow produces an optimal balance between pressure response, free surface displacement, and energy conversion efficiency. Energy extraction is significantly influenced by the coupling distance, with the hybrid system achieving maximum performance at a specific normalized spacing. The semi-capsule buoy improves power extraction ability and expands effective bandwidth due to asymmetric shape and coupled motion. These findings provide valuable insights into the coupling mechanism and geometric optimization for hybrid WECs. Full article
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13 pages, 1674 KiB  
Article
Impact of Substrate Amount and Fruiting Induction Methods in Lentinula edodes Cultivation
by Bruno de Souza Rocha, Wagner Gonçalves Vieira Junior, Adriano Taffarel Camargo de Paula, Asser Botelho Santana, Marcos Antônio da Silva Freitas, Milton Mineo Hirai, Lucas da Silva Alves and Diego Cunha Zied
Horticulturae 2025, 11(8), 915; https://doi.org/10.3390/horticulturae11080915 (registering DOI) - 4 Aug 2025
Abstract
Mushroom production is a sustainable practice but requires improvements, such as in Lentinula edodes (Berk) Pegler cultivation, which has high water and labor demands. In this context, this study proposed replacing the traditional primordia induction method by submersion with a water injection method. [...] Read more.
Mushroom production is a sustainable practice but requires improvements, such as in Lentinula edodes (Berk) Pegler cultivation, which has high water and labor demands. In this context, this study proposed replacing the traditional primordia induction method by submersion with a water injection method. Two primordia induction methods (submersion and injection) and two cultivation block formats were compared: rectangular cube (2 kg) and cylindrical (3.5 kg). The substrate, composed of eucalyptus sawdust (72%), wheat bran (12.5%), rice bran (12.5%), CaCO3 (1%), and CaSO4 (2%), was inoculated with strain LED 19/11 and incubated for 80 days at 26 ± 5 °C and 85 ± 15% humidity. After this period, the blocks were washed and transferred to the production environment. Fruiting was induced either by submersion or water injection, and production was evaluated over four harvest flushes. The 2 kg blocks had higher yields with submersion (16.62%), while the 3.5 kg blocks responded better to injection (13.01%), showing more homogeneous production. Increasing the substrate quantity contributes to greater harvest stability across production cycles. Water injections proved to be a viable alternative, reducing handling and facilitating large-scale production. The use of this technique demonstrates great importance in reducing water use and also the need for labor in cultivation. Full article
(This article belongs to the Section Vegetable Production Systems)
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27 pages, 11494 KiB  
Article
Establishment of Hollow Flexible Model with Two Types of Bonds and Calibration of the Contact Parameters for Wheat Straw
by Huinan Huang, Yan Zhang, Guangyu Hou, Baohao Su, Hao Yin, Zijiang Fu, Yangfan Zhuang, Zhijun Lv, Hui Tian and Lianhao Li
Agriculture 2025, 15(15), 1686; https://doi.org/10.3390/agriculture15151686 - 4 Aug 2025
Abstract
In view of the lack of accurate model in the discrete element study during straw comprehensive utilization (crushing, mixing, and baling), wheat straw was taken as the research object to calibrate the simulation parameters using EDEM 2023. The intrinsic and contact mechanical parameters [...] Read more.
In view of the lack of accurate model in the discrete element study during straw comprehensive utilization (crushing, mixing, and baling), wheat straw was taken as the research object to calibrate the simulation parameters using EDEM 2023. The intrinsic and contact mechanical parameters of wheat straw were measured, and a test of the angle of repose (AOR), extrusion test and bending test were carried out. On this basis, a discrete element model (DEM) of hollow flexibility by using cylindrical particles was developed. The optimal combination of contact mechanical parameters was obtained through AOR tests based on the Box–Behnken design (BBD), coefficients of static friction, rolling friction, and restitution between wheat straw and wheat straw-45 steel are separately 0.227, 0.136, 0.479, 0.271, 0.093, and 0.482, AOR is 18.66°. Meanwhile, optimal combinations of bond contact parameters were determined by the BBD. The calibrated parameters were used to conduct extrusion and bending tests. Results show that the average values of peak extrusion force and peak bending pressure are 23.20 N and 3.92 N, which have relative discrepancy of 3.25% and 3.59% compared to physical test measurements. The results can provide model reference for the optimization design such as feed processing equipment, baler, and mixer. Full article
(This article belongs to the Section Agricultural Technology)
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27 pages, 14083 KiB  
Article
Numerical Investigations and Hydrodynamic Analysis of a Screw Propulsor for Underwater Benthic Vehicles
by Yan Kai, Pengfei Xu, Meijie Cao and Lei Yang
J. Mar. Sci. Eng. 2025, 13(8), 1500; https://doi.org/10.3390/jmse13081500 - 4 Aug 2025
Abstract
Screw propulsors have attracted increasing attention for their potential applications in amphibious vehicles and benthic robots, owing to their ability to perform both terrestrial and underwater locomotion. To investigate their hydrodynamic characteristics, a two-stage numerical analysis was carried out. In the first stage, [...] Read more.
Screw propulsors have attracted increasing attention for their potential applications in amphibious vehicles and benthic robots, owing to their ability to perform both terrestrial and underwater locomotion. To investigate their hydrodynamic characteristics, a two-stage numerical analysis was carried out. In the first stage, steady-state simulations under various advance coefficients were conducted to evaluate the influence of key geometric parameters on propulsion performance. Based on these results, a representative configuration was then selected for transient analysis to capture unsteady flow features. In the second stage, a Detached Eddy Simulation approach was employed to capture unsteady flow features under three rotational speeds. The flow field information was analyzed, and the mechanisms of vortex generation, instability, and dissipation were comprehensively studied. The results reveal that the propulsion process is dominated by the formation and evolution of tip vortices, root vortices, and cylindrical wake vortices. As rotation speed increases, vortex structures exhibit a transition from ordered spiral wakes to chaotic turbulence, primarily driven by centrifugal instability and nonlinear vortex interactions. Vortex breakdown and energy dissipation are intensified downstream, especially under high-speed conditions, where vortex integrity is rapidly lost due to strong shear and radial expansion. This hydrodynamic behavior highlights the fundamental difference from conventional propellers, and these findings provide theoretical insight into the flow mechanisms of screw propulsion. Full article
(This article belongs to the Section Ocean Engineering)
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50 pages, 9033 KiB  
Article
Heat Pipe Integrated Cooling System of 4680 Lithium–Ion Battery for Electric Vehicles
by Yong-Jun Lee, Tae-Gue Park, Chan-Ho Park, Su-Jong Kim, Ji-Su Lee and Seok-Ho Rhi
Energies 2025, 18(15), 4132; https://doi.org/10.3390/en18154132 - 4 Aug 2025
Abstract
This study investigates a novel heat pipe integrated cooling system designed for thermal management of Tesla’s 4680 cylindrical lithium–ion batteries in electric vehicles (EVs). Through a comprehensive approach combining experimental analysis, 1-D AMESim simulations, and 3-D Computational Fluid Dynamics (CFD) modeling, the thermal [...] Read more.
This study investigates a novel heat pipe integrated cooling system designed for thermal management of Tesla’s 4680 cylindrical lithium–ion batteries in electric vehicles (EVs). Through a comprehensive approach combining experimental analysis, 1-D AMESim simulations, and 3-D Computational Fluid Dynamics (CFD) modeling, the thermal performance of various wick structures and working fluid filling ratios was evaluated. The experimental setup utilized a triangular prism chamber housing three surrogate heater blocks to replicate the heat generation of 4680 cells under 1C, 2C, and 3C discharge rates. Results demonstrated that a blended fabric wick with a crown-shaped design (Wick 5) at a 30–40% filling ratio achieved the lowest maximum temperature (Tmax of 47.0°C), minimal surface temperature deviation (ΔTsurface of 2.8°C), and optimal thermal resistance (Rth of 0.27°C/W) under 85 W heat input. CFD simulations validated experimental findings, confirming stable evaporation–condensation circulation at a 40% filling ratio, while identifying thermal limits at high heat loads (155 W). The proposed hybrid battery thermal management system (BTMS) offers significant potential for enhancing the performance and safety of high-energy density EV batteries. This research provides a foundation for optimizing thermal management in next-generation electric vehicles. Full article
(This article belongs to the Special Issue Optimized Energy Management Technology for Electric Vehicle)
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17 pages, 6882 KiB  
Article
Development and Evaluation of a Solar Milk Pasteurizer for the Savanna Ecological Zones of West Africa
by Iddrisu Ibrahim, Paul Tengey, Kelci Mikayla Lawrence, Joseph Atia Ayariga, Fortune Akabanda, Grace Yawa Aduve, Junhuan Xu, Robertson K. Boakai, Olufemi S. Ajayi and James Owusu-Kwarteng
Solar 2025, 5(3), 38; https://doi.org/10.3390/solar5030038 - 4 Aug 2025
Abstract
In many developing African countries, milk safety is often managed through traditional methods such as fermentation or boiling over firewood. While these approaches reduce some microbial risks, they present critical limitations. Firewood dependency contributes to deforestation, depletion of agricultural residues, and loss of [...] Read more.
In many developing African countries, milk safety is often managed through traditional methods such as fermentation or boiling over firewood. While these approaches reduce some microbial risks, they present critical limitations. Firewood dependency contributes to deforestation, depletion of agricultural residues, and loss of soil fertility, which, in turn, compromise environmental health and food security. Solar pasteurization provides a reliable and sustainable method for thermally inactivating pathogenic microorganisms in milk and other perishable foods at sub-boiling temperatures, preserving its nutritional quality. This study aimed to evaluate the thermal and microbial performance of a low-cost solar milk pasteurization system, hypothesized to effectively reduce microbial contaminants and retain milk quality under natural sunlight. The system was constructed using locally available materials and tailored to the climatic conditions of the Savanna ecological zone in West Africa. A flat-plate glass solar collector was integrated with a 0.15 cm thick stainless steel cylindrical milk vat, featuring a 2.2 cm hot water jacket and 0.5 cm thick aluminum foil insulation. The system was tested in Navrongo, Ghana, under ambient temperatures ranging from 30 °C to 43 °C. The pasteurizer successfully processed up to 8 L of milk per batch, achieving a maximum milk temperature of 74 °C by 14:00 GMT. Microbial analysis revealed a significant reduction in bacterial load, from 6.6 × 106 CFU/mL to 1.0 × 102 CFU/mL, with complete elimination of coliforms. These results confirmed the device’s effectiveness in achieving safe pasteurization levels. The findings demonstrate that this locally built solar pasteurization system is a viable and cost-effective solution for improving milk safety in arid, electricity-limited regions. Its potential scalability also opens avenues for rural entrepreneurship in solar-powered food and water treatment technologies. Full article
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21 pages, 4314 KiB  
Article
Panoptic Plant Recognition in 3D Point Clouds: A Dual-Representation Learning Approach with the PP3D Dataset
by Lin Zhao, Sheng Wu, Jiahao Fu, Shilin Fang, Shan Liu and Tengping Jiang
Remote Sens. 2025, 17(15), 2673; https://doi.org/10.3390/rs17152673 - 2 Aug 2025
Viewed by 189
Abstract
The advancement of Artificial Intelligence (AI) has significantly accelerated progress across various research domains, with growing interest in plant science due to its substantial economic potential. However, the integration of AI with digital vegetation analysis remains underexplored, largely due to the absence of [...] Read more.
The advancement of Artificial Intelligence (AI) has significantly accelerated progress across various research domains, with growing interest in plant science due to its substantial economic potential. However, the integration of AI with digital vegetation analysis remains underexplored, largely due to the absence of large-scale, real-world plant datasets, which are crucial for advancing this field. To address this gap, we introduce the PP3D dataset—a meticulously labeled collection of about 500 potted plants represented as 3D point clouds, featuring fine-grained annotations for approximately 20 species. The PP3D dataset provides 3D phenotypic data for about 20 plant species spanning model organisms (e.g., Arabidopsis thaliana), potted plants (e.g., Foliage plants, Flowering plants), and horticultural plants (e.g., Solanum lycopersicum), covering most of the common important plant species. Leveraging this dataset, we propose the panoptic plant recognition task, which combines semantic segmentation (stems and leaves) with leaf instance segmentation. To tackle this challenge, we present SCNet, a novel dual-representation learning network designed specifically for plant point cloud segmentation. SCNet integrates two key branches: a cylindrical feature extraction branch for robust spatial encoding and a sequential slice feature extraction branch for detailed structural analysis. By efficiently propagating features between these representations, SCNet achieves superior flexibility and computational efficiency, establishing a new baseline for panoptic plant recognition and paving the way for future AI-driven research in plant science. Full article
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21 pages, 4169 KiB  
Article
An Anisotropic Failure Characteristic- and Damage-Coupled Constitutive Model
by Ruiqing Chen, Jieyu Dai, Shuning Gu, Lang Yang, Laohu Long and Jundong Wang
Modelling 2025, 6(3), 75; https://doi.org/10.3390/modelling6030075 (registering DOI) - 1 Aug 2025
Viewed by 145
Abstract
This study proposes a coupled constitutive model that captures the anisotropic failure characteristics and damage evolution of nickel-based single-crystal (SX) superalloys under various temperature conditions. The model accounts for both creep rate and material damage evolution, enabling accurate prediction of the typical three-stage [...] Read more.
This study proposes a coupled constitutive model that captures the anisotropic failure characteristics and damage evolution of nickel-based single-crystal (SX) superalloys under various temperature conditions. The model accounts for both creep rate and material damage evolution, enabling accurate prediction of the typical three-stage creep curves, macroscopic fracture morphologies, and microstructural features under uniaxial tensile creep for specimens with different crystallographic orientations. Creep behavior of SX superalloys was simulated under multiple orientations and various temperature-stress conditions using the proposed model. The resulting creep curves aligned well with experimental observations, thereby validating the model’s feasibility and accuracy. Furthermore, a finite element model of cylindrical specimens was established, and simulations of the macroscopic fracture morphology were performed using a user-defined material subroutine. By integrating the rafting theory governed by interfacial energy density, the model successfully predicts the rafting morphology of the microstructure at the fracture surface for different crystallographic orientations. The proposed model maintains low programming complexity and computational cost while effectively predicting the creep life and deformation behavior of anisotropic materials. The model accurately captures the three-stage creep deformation behavior of SX specimens and provides reliable predictions of stress fields and microstructural changes at critical cross-sections. The model demonstrates high accuracy in life prediction, with all predicted results falling within a ±1.5× error band and an average error of 14.6%. Full article
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19 pages, 4156 KiB  
Article
Experimental and Numerical Analyses of Diameter Reduction via Laser Turning with Respect to Laser Parameters
by Emin O. Bastekeli, Haci A. Tasdemir, Adil Yucel and Buse Ortac Bastekeli
J. Manuf. Mater. Process. 2025, 9(8), 258; https://doi.org/10.3390/jmmp9080258 - 1 Aug 2025
Viewed by 103
Abstract
In this study, a novel direct laser beam turning (DLBT) approach is proposed for the precision machining of AISI 308L austenitic stainless steel, which eliminates the need for cutting tools and thereby eradicates tool wear and vibration-induced surface irregularities. A nanosecond-pulsed Nd:YAG fiber [...] Read more.
In this study, a novel direct laser beam turning (DLBT) approach is proposed for the precision machining of AISI 308L austenitic stainless steel, which eliminates the need for cutting tools and thereby eradicates tool wear and vibration-induced surface irregularities. A nanosecond-pulsed Nd:YAG fiber laser (λ = 1064 nm, spot size = 0.05 mm) was used, and Ø1.6 mm × 20 mm cylindrical rods were processed under ambient conditions without auxiliary cooling. The experimental framework systematically evaluated the influence of scanning speed, pulse frequency, and the number of laser passes on dimensional accuracy and material removal efficiency. The results indicate that a maximum diameter reduction of 0.271 mm was achieved at a scanning speed of 3200 mm/s and 50 kHz, whereas 0.195 mm was attained at 6400 mm/s and 200 kHz. A robust second-order polynomial correlation (R2 = 0.99) was established between diameter reduction and the number of passes, revealing the high predictability of the process. Crucially, when the scanning speed was doubled, the effective fluence was halved, considerably influencing the ablation characteristics. Despite the low fluence, evidence of material evaporation at elevated frequencies due to the incubation effect underscores the complex photothermal dynamics governing the process. This work constitutes the first comprehensive quantification of pass-dependent diameter modulation in DLBT and introduces a transformative, noncontact micromachining strategy for hard-to-machine alloys. The demonstrated precision, repeatability, and thermal control position DLBT as a promising candidate for next-generation manufacturing of high-performance miniaturized components. Full article
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28 pages, 3834 KiB  
Article
An Exact 3D Shell Model for Free Vibration Analysis of Magneto-Electro-Elastic Composite Structures
by Salvatore Brischetto, Domenico Cesare and Tommaso Mondino
J. Compos. Sci. 2025, 9(8), 399; https://doi.org/10.3390/jcs9080399 - 1 Aug 2025
Viewed by 104
Abstract
The present paper proposes a three-dimensional (3D) spherical shell model for the magneto-electro-elastic (MEE) free vibration analysis of simply supported multilayered smart shells. A mixed curvilinear orthogonal reference system is used to write the unified 3D governing equations for cylinders, cylindrical panels and [...] Read more.
The present paper proposes a three-dimensional (3D) spherical shell model for the magneto-electro-elastic (MEE) free vibration analysis of simply supported multilayered smart shells. A mixed curvilinear orthogonal reference system is used to write the unified 3D governing equations for cylinders, cylindrical panels and spherical shells. The closed-form solution of the problem is performed considering Navier harmonic forms in the in-plane directions and the exponential matrix method in the thickness direction. A layerwise approach is possible, considering the interlaminar continuity conditions for displacements, electric and magnetic potentials, transverse shear/normal stresses, transverse normal magnetic induction and transverse normal electric displacement. Some preliminary cases are proposed to validate the present 3D MEE free vibration model for several curvatures, materials, thickness values and vibration modes. Then, new benchmarks are proposed in order to discuss possible effects in multilayered MEE curved smart structures. In the new benchmarks, first, three circular frequencies for several half-wave number couples and for different thickness ratios are proposed. Thickness vibration modes are shown in terms of displacements, stresses, electric displacement and magnetic induction along the thickness direction. These new benchmarks are useful to understand the free vibration behavior of MEE curved smart structures, and they can be used as reference for researchers interested in the development of of 2D/3D MEE models. Full article
(This article belongs to the Special Issue Feature Papers in Journal of Composites Science in 2025)
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20 pages, 4765 KiB  
Article
Ultrasonic EDM for External Cylindrical Surface Machining with Graphite Electrodes: Horn Design and Hybrid NSGA-II–AHP Optimization of MRR and Ra
by Van-Thanh Dinh, Thu-Quy Le, Duc-Binh Vu, Ngoc-Pi Vu and Tat-Loi Mai
Machines 2025, 13(8), 675; https://doi.org/10.3390/machines13080675 - 1 Aug 2025
Viewed by 174
Abstract
This study presents the first investigation into the application of ultrasonic vibration-assisted electrical discharge machining (UV-EDM) using graphite electrodes for external cylindrical surface machining—an essential surface in the production of tablet punches and sheet metal-forming dies. A custom ultrasonic horn was designed and [...] Read more.
This study presents the first investigation into the application of ultrasonic vibration-assisted electrical discharge machining (UV-EDM) using graphite electrodes for external cylindrical surface machining—an essential surface in the production of tablet punches and sheet metal-forming dies. A custom ultrasonic horn was designed and fabricated using 90CrSi material to operate effectively at a resonant frequency of 20 kHz, ensuring stable vibration transmission throughout the machining process. A Box–Behnken experimental design was employed to explore the effects of five process parameters—vibration amplitude (A), pulse-on time (Ton), pulse-off time (Toff), discharge current (Ip), and servo voltage (SV)—on two key performance indicators: material removal rate (MRR) and surface roughness (Ra). The optimization process was conducted in two stages: single-objective analysis to maximize MRR while ensuring Ra < 4 µm, followed by a hybrid multi-objective approach combining NSGA-II and the Analytic Hierarchy Process (AHP). The optimal solution achieved a high MRR of 9.28 g/h while maintaining Ra below the critical surface finish threshold, thus meeting the practical requirements for punch surface quality. The findings confirm the effectiveness of the proposed horn design and hybrid optimization strategy, offering a new direction for enhancing productivity and surface integrity in cylindrical EDM applications using graphite electrodes. Full article
(This article belongs to the Section Advanced Manufacturing)
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12 pages, 2575 KiB  
Article
Simulation of Propagation Characteristics and Field Distribution in Cylindrical Photonic Crystals Composed of Near-Zero Materials and Metal
by Zhihao Xu, Dan Zhang, Rongkang Xuan, Shenxiang Yang and Na Wang
J. Low Power Electron. Appl. 2025, 15(3), 44; https://doi.org/10.3390/jlpea15030044 - 31 Jul 2025
Viewed by 91
Abstract
This study investigates the propagation characteristics and field distribution of photonic crystals composed of epsilon-near-zero (ENZ) materials and metal cylinders. The research reveals that the cutoff frequency of the photonic crystal formed by combining metal cylinders with an ENZ background is independent of [...] Read more.
This study investigates the propagation characteristics and field distribution of photonic crystals composed of epsilon-near-zero (ENZ) materials and metal cylinders. The research reveals that the cutoff frequency of the photonic crystal formed by combining metal cylinders with an ENZ background is independent of the volume fraction of the metal cylinders and exhibits a stop-band profile within the measured frequency range. This unique behavior is attributed to the scattering of long-wavelength light when the wavelength approaches the effective wavelength range of the ENZ material. Taking advantage of this feature, the study selectively filters specific wavelength ranges from the mid-frequency band by varying the ratio of cylinder radius to lattice constant (R/a). Decreasing the R/a ratio enables the design of waveguide devices that operate over a broader guided wavelength range within the intermediate-frequency band. The findings emphasize the importance of the interaction between light and ENZ materials in shaping the transmission characteristics of photonic crystal structures. Full article
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21 pages, 13539 KiB  
Article
Impact of Fiber Type on Chloride Ingress in Concrete: A MacroXRF Imaging Analysis
by Suânia Fabiele Moitinho da Silva, Wanderson Santos de Jesus, Thalles Murilo Santos de Almeida, Renato Quinto de Oliveira Novais, Laio Andrade Sacramento, Joaquim Teixeira de Assis, Marcelino José dos Anjos and José Renato de Castro Pessôa
Appl. Sci. 2025, 15(15), 8495; https://doi.org/10.3390/app15158495 (registering DOI) - 31 Jul 2025
Viewed by 85
Abstract
Chloride ion penetration is one of the most aggressive threats to reinforced concrete, as it triggers the electrochemical corrosion of steel reinforcement, compromising structural integrity and durability. Chloride ingress occurs through the porous structure of concrete, making permeability control crucial for enhancing structural [...] Read more.
Chloride ion penetration is one of the most aggressive threats to reinforced concrete, as it triggers the electrochemical corrosion of steel reinforcement, compromising structural integrity and durability. Chloride ingress occurs through the porous structure of concrete, making permeability control crucial for enhancing structural longevity. Fiber-reinforced concrete (FRC) is widely used to improve durability; however, the effects of different fiber types on chloride resistance remain unclear. This study examines the influence of glass and polypropylene fibers on concrete’s microstructure and chloride penetration resistance. Cylindrical specimens were prepared, including a reference mix without fibers and mixes with 0.25% and 0.50% fiber content by volume. Both fiber types were tested for chloride resistance. The accelerated non-steady-state migration method was employed to determine the resistance coefficients to chloride ion penetration, while X-ray macrofluorescence (MacroXRF) mapped the chlorine infiltration depth in the samples. Compressive strength decreased in all fiber-reinforced samples, with 0.50% glass fiber leading to a 56% reduction in strength. Nevertheless, the XRF results showed that a 0.25% fiber content significantly reduced chloride penetration, with polypropylene fibers outperforming glass fibers. These findings highlight the critical role of fiber type and volume in improving concrete durability, offering insights for designing long-lasting FRC structures in chloride-rich environments. Full article
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17 pages, 6842 KiB  
Article
Inside the Framework: Structural Exploration of Mesoporous Silicas MCM-41, SBA-15, and SBA-16
by Agnieszka Karczmarska, Wiktoria Laskowska, Danuta Stróż and Katarzyna Pawlik
Materials 2025, 18(15), 3597; https://doi.org/10.3390/ma18153597 - 31 Jul 2025
Viewed by 222
Abstract
In the rapidly evolving fields of materials science, catalysis, electronics, drug delivery, and environmental remediation, the development of effective substrates for molecular deposition has become increasingly crucial. Ordered mesoporous silica materials have garnered significant attention due to their unique structural properties and exceptional [...] Read more.
In the rapidly evolving fields of materials science, catalysis, electronics, drug delivery, and environmental remediation, the development of effective substrates for molecular deposition has become increasingly crucial. Ordered mesoporous silica materials have garnered significant attention due to their unique structural properties and exceptional potential as substrates for molecular immobilization across these diverse applications. This study compares three mesoporous silica powders: MCM-41, SBA-15, and SBA-16. A multi-technique characterization approach was employed, utilizing low- and wide-angle X-ray diffraction (XRD), nitrogen physisorption, and transmission electron microscopy (TEM) to elucidate the structure–property relationships of these materials. XRD analysis confirmed the amorphous nature of silica frameworks and revealed distinct pore symmetries: a two-dimensional hexagonal (P6mm) structure for MCM-41 and SBA-15, and three-dimensional cubic (Im3¯m) structure for SBA-16. Nitrogen sorption measurements demonstrated significant variations in textural properties, with MCM-41 exhibiting uniform cylindrical mesopores and the highest surface area, SBA-15 displaying hierarchical meso- and microporosity confirmed by NLDFT analysis, and SBA-16 showing a complex 3D interconnected cage-like structure with broad pore size distribution. TEM imaging provided direct visualization of particle morphology and internal pore architecture, enabling estimation of lattice parameters and identification of structural gradients within individual particles. The integration of these complementary techniques proved essential for comprehensive material characterization, particularly for MCM-41, where its small particle size (45–75 nm) contributed to apparent structural inconsistencies between XRD and sorption data. This integrated analytical approach provides valuable insights into the fundamental structure–property relationships governing ordered mesoporous silica materials and demonstrates the necessity of combined characterization strategies for accurate structural determination. Full article
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