Search Results (493)

Concrete is the most widely used construction material worldwide, yet its production and disposal pose significant environmental challenges due to high carbon emissions and limited recyclability. While microbial colonization of concrete is often associated with structural deterioration, recent research has highlighted the potential of microorganisms to contribute positively to concrete recycling and self-healing. In this study, we investigated the bacterial and fungal communities inhabiting urban concrete samples using amplicon-based taxonomic profiling targeting the 16S rRNA gene and internal transcribed spacer (ITS) region. Our analyses revealed a diverse assemblage of microbial taxa capable of surviving the extreme physicochemical conditions of concrete. Several taxa were associated with known metabolic functions relevant to concrete degradation, such as acid and sulphate production, as well as biomineralization processes that may support crack repair and surface sealing. These findings suggest that concrete-associated microbiomes may serve as a reservoir of biological functions with potential applications in sustainable construction, including targeted biodegradation for recycling and biogenic mineral formation for structural healing. This work provides a foundation for developing microbial solutions to reduce the environmental footprint of concrete infrastructure. Full article

The growing environmental effect of asphalt pavements has fueled interest in sustainable alternatives including the application of recycled materials and self-healing systems. This research investigates the synergistic possibilities of steel slag aggregates and steel wool fibers in hot-mix asphalt compositions to increase sustainability and let crack healing via electromagnetic induction heating. Using either recycled steel slag or natural porphyritic aggregates, two kinds of AC16 Surf S mixtures with 35/50 bitumen were created incorporating two levels of steel fiber content (2% and 4%). Based on repeated semi-circular bending (SCB) testing following regulated induction heating and confinement, a committed self-healing evaluation plan was developed. The results verified that combinations including recycled steel slag met or outperformed traditional mixes in terms of mechanical behavior. Induction heating successfully set off partial recovery of fracture toughness, with more fiber content and repeated heating cycles producing better healing values. Recovery levels ran from 14.6% to 40%, therefore proving the practicality of this approach. These results encourage the creation of asphalt mixtures with improved endurance and environmental advantages. The research offers both an approved approach for assessing healing and real-world recommendations for the construction of low-maintenance, round pavements utilizing induction-based techniques. Full article

Perovskite solar cells (PSCs) have emerged as a rising next-generational photovoltaic technology due to low fabrication costs through solution processing as compared to traditional silicon solar cells and high-power conversion efficiency. However, the poor long-term operational stability due to environmental and mechanical degradation remains a hindrance to commercialization. Herein, self-healing polymer additives are utilized by researchers to enhance the photovoltaic performance of PSCs by enabling self-restorative behavior from physical damage or chemical degradation. This review explores the design and application of self-healing polymers in both flexible and rigid PSCs, contrasting the two main reversible bonding mechanisms: physical bonds, such as hydrogen bonds, and chemical bonds, such as dynamic covalent disulfide bonds. Physical bonds provide passive healing at ambient conditions; meanwhile, chemical bonds offer a stronger restoration under external stimuli such as heat or light. These polymers are exceptionally effective at mitigating mechanical stress and cracks in flexible PSCs and combating moisture-induced degradation in rigid PSCs. The applications of self-healing polymers are categorized based on substrate type, healing mechanism, and perovskite composition, with the benefits and limitations of each approach highlighted. Additionally, the review explores the potential of multifunctional self-healing polymers to passivate defects at the grain boundaries and on surface of perovskite films, thereby enhancing the overall photovoltaic performance. Full article

To address the challenges of rutting and performance balance in asphalt pavements under high-temperature and heavy-load conditions, a novel polyolefin composite modifier (PCM-H) was developed from waste tire rubber powder, recycled ethylene vinyl acetate (EVA), acrylonitrile butadiene styrene (ABS), petroleum resin, and polymer additives. The chemical characteristics, thermal stability, and compatibility mechanisms of PCM-H were compared with those of two commercial modifiers (PCM-1 and PCM-2) using Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). PCM-H exhibited superior compatibility and thermal stability. In contrast, PCM-2 tends to crystallize and precipitate within the 180–200 °C range, which is detrimental to the stability of the composite system. At an optimal dosage of 10 wt% in styrene–butadiene–styrene (SBS) modified asphalt, PCM-H formed a uniform dispersion and, through crosslinking reactions, established a three-dimensional network structure. Subsequently, the performance of composite modified asphalts, prepared with each of the three modifiers at their respective optimal dosages, was evaluated comparatively. Performance evaluations demonstrated that all polyolefin-modified asphalts significantly outperformed the conventional SBS modified asphalt. The PCM-H modified asphalt (PCM-H MA) exhibited the most superior performance, achieving a performance grade (PG) exceeding 94 °C, along with exceptional high-temperature elasticity and creep resistance, superior low-temperature cracking resistance, and enhanced fatigue healing capability. The results indicated that the crosslinked network structure effectively enhances asphalt cohesion, thereby providing a synergistic improvement in both high- and low-temperature performance. This study provides an effective solution and theoretical basis for developing high-performance pavement materials resistant to high temperatures and heavy loads conditions. Full article

This study investigates the evolution characteristics of fissure networks in cohesive soils under wetting–drying cycle conditions with varying guar gum content. Four wetting–drying cycles were conducted under outdoor natural conditions, with real-time monitoring of changes in the surface crack network during drying and wetting. Geometric parameters—including surface crack density, width, connectivity coefficient, shape coefficient, and crack depth ratio—were quantitatively analyzed using digital image processing software. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were employed to reveal the mechanisms of microstructural improvement. Results indicate that as wetting–drying cycles increase, the fracture network progressively simplifies, with fracture density and fractal dimension decreasing while fracture width increases. The incorporation of guar gum reduced the crack depth ratio to approximately 0.62 times that of undamaged soil. The average crack width decreased from 2.69 mm to 2.16 mm during the fourth wet-dry cycle, whilst the connectivity coefficient and shape coefficient stabilized. SEM analysis indicated that guar gum promoted “bonded bridging” structures between soil particles, while XRD results confirmed no alteration in the mineral composition of the soil. The study demonstrates that the addition of guar gum enhances soil crack resistance and stability, providing theoretical support for the ecological protection of clayey slopes. Full article

Self-healing concrete provides an eco-efficient approach for restoring cracks through autonomous repair, reducing maintenance demands and enhancing long-term durability. This study evaluates concrete incorporating Bacillus subtilis bacteria and sisal fibers to examine their individual and combined effects on mechanical performance and microstructural development. Bacterial cells at a concentration of 2 × 10⁸ CFU/mL were introduced with calcium lactate as a nutrient source at varying dosages, while sisal fibers were added at a volume fraction of 0.9%. Concrete mixes containing 0%, 2.5%, and 5% bacterial content were tested under fresh-water curing. Compressive, splitting tensile, and flexural strengths were assessed at multiple ages, accompanied by SEM and EDS analyses to investigate healing products and microstructural alterations. Bacteria-enhanced mixes demonstrated improved long-term compressive behavior, with B5/5/1 reaching 50.1 MPa at 56 days, while higher bacterial content slightly reduced early-age strength but benefited later performance. Incorporating sisal fibers consistently improved mechanical resistance, notably in combination with bacteria. The SB5/5/1 mix achieved 55.2 MPa at 56 days, representing a 30% gain over the control. Tensile strength was particularly influenced by fibers, with SB10/5/1 recording 6.3 MPa at 56 days (≈70% increase). Flexural strength results similarly highlighted the superior behavior of hybrid systems, where SB10/5/1 attained 9.2 MPa (+67%), reflecting enhanced self-healing efficiency even under challenging curing conditions. Full article

To address brittle cracks in ceramic tools, an exogenous precursor ceramic repair agent was developed and applied to Al₂O₃/TiC/NiMo composite ceramic tools, which were treated by a two-step heat treatment process (heating at 3 °C/min to 300 °C for 60 min, heating the sample at 5 °C/min to 500, 600, 700, 800, and 900 °C, holding each for 60 min). The crack healing mechanism and temperature dependency of the repair agent were investigated. Cutting performance, including surface roughness, cutting force, and tool life, was optimized using an L9(34) orthogonal design. The results show that at 900 °C, the repair agent decomposed to form SiOC (Silicon Oxycarbide) amorphous phase and TiB₂ reinforced phase, filling the cracks and achieving atomic-level diffusion bonding. The flexural strength of the repaired sample recovered to 79.9% of the initial value (456.5 MPa), a 196.4% increase compared to the unrepaired sample. Optimal cutting parameters were found to be a cutting speed of 200 m/min, back draft of 0.1 mm, and feed of 0.1 mm/r. Under these conditions, surface roughness was 0.845 μm, cutting temperature was 258 °C, and stable tangential force was 70 N. The effective cutting distance of the repaired tool was increased from 1300 m to 1700 m. Wear was primarily abrasive and adhesive wear, and the SiOC phase formed by the repair agent helped to fill and repair the flank, thus extending tool life. Full article

Cracks can reduce the durability of concrete structures. To mitigate the damage caused, self-healing technologies using bacteria and cement-based materials can be utilized. For self-healing, bacteria contained within the matrix are advantageous because they can heal cracks upon introducing oxygen and water under favorable conditions. To our knowledge, this is the first study showing that Lysinibacillus fusiformis isolated from waste concrete induces calcite precipitation in a cement-based material. Replacing 5–20% of the mixing water with the bacterial solution increased mortar flow, and the initial compressive strength increased with the bacterial content. After long-term aging, the compressive strength of the sample with 20% bacterial solution was ~45.6 MPa, the highest among all samples. In terms of durability, the bacterial solution reduced the carbonation depth compared with that of a control sample without added bacteria, and the 20% sample showed 53% higher carbonation resistance than the control. In terms of the self-healing performance, the bacteria-loaded samples showed higher compressive strength recovery rates than the control sample, with the 20% sample showing the highest rate of approximately 131%. Therefore, L. fusiformis derived from waste concrete is a promising candidate bacterium for enhancing the durability and self-healing efficiency of cement composites. Full article

Concrete structure integrity is significantly compromised by the primary problem of cracking. Typically, surface cracking (predominantly shrinkage-induced and thermal microcracking) is rectified using costly and time-consuming repair methods involving mortar and other techniques. Research efforts have recently shifted towards developing smart materials to reduce concrete’s propensity for cracking, enhance its structural stability, and prevent damage to its framework. Concrete designs with self-healing capabilities can safeguard against degradation and enhance long-term durability. Despite extensive research, a consensus on the optimal preparation and mechanical properties of self-healing concrete has yet to be reached. Within self-healing concrete that utilizes microcapsules, repair agents are dispersed throughout the matrix to form a bond and seal cracks as damage develops. From the viewpoint of a sustainable society, this approach appears to promote the use of construction materials. This study examined the impact of Dawson/urea–formaldehyde microcapsule-based self-healing concrete using strength tests, where the effectiveness of different microcapsule quantities (0.5–2% microcapsule by weight of cement) was assessed. Following the data and data analysis, it becomes evident that among all samples, the 1% microcapsule sample yields outstanding results for both 7-day and 28-day compressive strength. Full article

Conductive hydrogels show great promise for wearable sensors but suffer from low sensitivity in small strain ranges. In this study, we developed a micropatterned composite hydrogel sheet (thickness: 1.2 ± 0.1 mm) by constructing a continuous electronic conductive network of carbon nanotubes (CNTs) on a highly crosslinked micropatterned hydrogel sheet. The sheet was fabricated via a two-step synthesis of a polyvinyl alcohol/polyacrylic acid polymer network—crosslinked by Zr⁴⁺ in a glycerol-water system—using sandpaper as the template. The first step ensured tight conformity to the template, while the second step preserved the micropattern’s integrity and precision. The reverse sandpaper micropattern enables secure bonding of CNTs to the hydrogel and induces localized stress concentration during stretching. This triggers controllable cracking in the conductive network, allowing the sensor to maintain high sensitivity even in small strain ranges. Consequently, the sensor exhibits ultra-high sensitivity, with gauge factors of 76.1 (0–30% strain) and 203.5 (30–100% strain), alongside a comfortable user experience. It can detect diverse activities, from subtle physiological signals and joint bending to complex hand gestures and athletic postures. Additionally, the micropatterned composite hydrogel sheet also demonstrates self-healing ability, adhesiveness, and conformability, while performing effectively under extreme temperatures and sweaty conditions. This innovative structure and sensing mechanism—leveraging stress concentration and controlled crack formation—provides a strategy for designing wearable electronics with enhanced performance. Full article

Criminal laws and their deserts-based punishments, particularly in Anglo-American systems, remain grounded in folk psychology assumptions about free will, willpower, and agency. Yet advances in neuropsychiatry, neuromicrobiology, behavioral genetics, multi-omics, and exposome sciences, are revealing how here-and-now decisions are profoundly shaped by antecedent factors. This transdisciplinary evidence increasingly undermines the folk psychology model: some argue it leaves “not a single crack of daylight to shoehorn in free will”, while others suggest the evidence at least reveals far greater constraints on agency than currently acknowledged. Historically, courts and corrections have marginalized brain and behavior sciences, often invoking prescientific notions of monsters and wickedness to explain harmful behavior—encouraging anti-science sentiment and protecting normative assumptions. Earlier disciplinary silos, such as isolated neuroscience or single-gene claims, did little to challenge the system. But today’s integrated sciences—from microbiology and toxicology to nutrition and traumatology, powered by omics and machine learning—pose a threat to the folk psychology fulcrum. Resistance to change is well known in criminal justice, but the accelerating pace of biopsychosocial science makes it unlikely that traditional assumptions will endure. In response to modern science, emergent concepts of reform have been presented. Here, we review the public health quarantine model, an emergent concept that aligns criminal justice with public health principles. The model recognizes human behavior as emergent from complex biological, social, and environmental determinants. It turns away from retribution, while seeking accountability in a way that supports healing and prevention. Full article

Biomineralized self-healing concrete is a type of concrete that, during its service life, induces the generation of calcium carbonate through the participation of microorganisms or active enzymes, thereby achieving self-repair of cracks at different times. Self-healing concrete based on biomineralization can achieve sustainable crack repair and could enhance the strength and extend the service life of buildings. This article comprehensively analyzes the latest progress in bio-self-healing concrete, including microbial-based self-healing, enzyme-induced calcium carbonate precipitation (EICP), microcapsule-loaded microbial in situ remediation, and bio-inorganic mineral synergist self-healing technology. The maximum repairable width of the crack is 2.0 mm, and concrete strength can be increased by 135%. These methods offer new insights and strategies for the repair of concrete cracks, providing fundamental knowledge for the later application of intelligent engineering of bio-self-healing concrete and the analysis of micro-interface mechanisms. At the same time, they clarify the practical possibility of microbial technology in building materials science and engineering and offer key theoretical support for the long-term development of China’s construction industry. Full article

Reinforced concrete durability depends on a passive oxide film protecting embedded steel, sustained by high-alkalinity pore solutions. Cracking fundamentally alters transport, allowing rapid chloride and carbon dioxide ingress, which undermines passivity and accelerates corrosion. Self-healing concrete technologies aim to autonomously restore transport barriers and reestablish electrochemical stability. This review critically synthesizes evidence on healing effectiveness for corrosion mitigation through a dual framework of barrier restoration and interface stabilization, integrating depth-resolved chloride profiles with electrochemical performance indices. Critically, visual crack closure proves an unreliable indicator of corrosion protection. Healing mechanisms exhibit characteristic spatial signatures: autogenous and microbial approaches preferentially seal surface zones with diminishing effectiveness at reinforcement depth, while encapsulated low-viscosity polymers achieve greater depth continuity. However, electrochemical recovery consistently lags transport recovery, with healed specimens achieving only partial restoration of intact corrosion resistance. Recovery effectiveness depends on crack geometry, moisture conditions, and healing mechanism characteristics, with systems performing effectively only within narrow, condition-specific windows. Effective corrosion protection requires coordinated barrier and interface strategies targeting both bulk transport and steel surface chemistry. The path forward demands rigorous field validation emphasizing electrochemical outcomes over appearance metrics, long-term durability assessment, and performance-based verification frameworks to enable predictable service life extension. Full article

Cracks in laser-cladded coatings represent a critical challenge that severely limits their industrial deployment. In this study, high-frequency pulsed direct current-assisted electrically assisted heat treatment (EAHT) was applied to repair cracks in laser-cladded Ni60/WC coatings deposited on 45# medium carbon steel. The influence of current density and treatment duration on crack arrest and healing behavior was systematically investigated. Dye penetrant testing and scanning electron microscopy (SEM) were employed to characterize the morphology and evolution of cracks before and after EAHT, while hardness, fracture toughness, and wear resistance tests were conducted to evaluate the mechanical properties. The results revealed that the crack repair process proceeds through three distinct stages: internal filling, nucleation and growth of healing points, and complete crack closure. The combined effects of Joule heating and current crowding induced by EAHT significantly facilitated progressive crack healing from the bottom upward. Optimal crack arrest and healing were achieved at a current density of 6.25 A/mm², resulting in a maximum fracture toughness of 10.74 MPa·m^1/2 and a transition of the wear mechanism from spalling to abrasive wear. This study demonstrates that EAHT promotes selective crack-tip heating and microstructural regulation through thermo-electro-mechanical coupling, thereby markedly enhancing the comprehensive performance of Ni-based WC coatings. Full article

This study aimed to examine the calcite precipitation potential of non-ureolytic bacterial strains of two species, Viridibacillus arenosi (A₆) and Bacillus zhangzhouensis (D₂₅), as compared to the known ureolytic bacterial strain, Sporosarcina pasteurii (SP), within geopolymer mortar. Tests were carried out after 56 days of injection treatment to confirm the precipitation process, incorporating healing efficiency measured by ImageJ software, recovery of UPV, water permeability, capillary water absorption, and microstructural and mineralogical analysis SEM/EDS and XRD. The non-ureolytic isolates D₂₅ and A₆ showed the highest healing efficiencies, at 96.9% and 91.9%, respectively, followed by the ureolytic bacteria SP at 77.8%. A₆ exhibited the most substantial reduction in permeability at 97.3%, indicating extensive crack healing, followed by D₂₅ at 92.9% and SP at 82.1%. Furthermore, SEM and EDS analyses confirmed the formation of calcite crystals and calcium depositions in the bacteria-treated samples. Complementary evidence was provided by XRD, which revealed distinct calcium carbonate peaks in the treated specimens, peaks that were entirely absent in the control samples, thus strongly confirming the role of bacterial activity in the precipitation process. The results confirm that non-ureolytic bacteria can efficiently boost calcite precipitation in geopolymer mortars, offering superior healing performance and a more sustainable alternative to ureolytic strains. Full article