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Search Results (627)

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Keywords = crack initiation energy

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24 pages, 8605 KB  
Article
Numerical Investigation on Rotational Cutting of Coal Seam by Single Cutting Pick
by Ying Tian, Shengda Zhang, Qiang Zhang, Yan Song, Yongliang Han, Long Feng, Huaitao Liu, Yingchun Zhang and Xiangwei Dong
Processes 2026, 14(3), 531; https://doi.org/10.3390/pr14030531 - 3 Feb 2026
Abstract
Shearers and roadheaders are critical equipment in coal mining and roadway excavation, where the rock-breaking performance of cutting picks directly influences operational efficiency and economic outcomes. Complex geological conditions, such as hard coal seams and embedded inclusions like gangue or pyrite nodules, pose [...] Read more.
Shearers and roadheaders are critical equipment in coal mining and roadway excavation, where the rock-breaking performance of cutting picks directly influences operational efficiency and economic outcomes. Complex geological conditions, such as hard coal seams and embedded inclusions like gangue or pyrite nodules, pose significant challenges to cutting efficiency and tool wear. This study presents a numerical investigation into the rotational cutting process of a single pick in heterogeneous coal seams using the Smoothed Particle Hydrodynamics (SPH) method integrated with a mixed failure model. The model combines the Drucker–Prager criterion for shear failure and the Grady–Kipp damage model for tensile failure, enabling accurate simulation of crack initiation, propagation, and coalescence without requiring explicit fracture treatments. Simulations reveal that cutting depth significantly influences the failure mode: shallow depths promote tensile crack-induced spallation of hard nodules under compressive stress, while deeper cuts lead to shear-dominated failure. The cutting pick exhibits periodic force fluctuations corresponding to stages of compressive-shear crack initiation, propagation, and spallation. The results provide deep insights into pick–rock interaction mechanisms and offer a reliable computational tool for optimizing cutting parameters and improving mining equipment design under complex geological conditions. A key finding is the identification of a critical transition in failure mechanism from tensile-dominated spallation to shear-driven fragmentation with increasing cutting depth, which provides a theoretical basis for practitioners to select optimal cutting parameters that minimize tool wear and energy consumption in field operations. Full article
(This article belongs to the Section Chemical Processes and Systems)
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22 pages, 9731 KB  
Article
Effects of Deviatoric Stress on Macro- and Meso-Mechanical Behavior of Granite for Water-Sealed Caverns Under True Triaxial Loading
by Liliang Han, Yu Cong, Xiaoshan Wang, Wenyang Du, Lixia Zhang, Jian Gao, Yuming Wang and Zhanchao Zhang
Geosciences 2026, 16(2), 66; https://doi.org/10.3390/geosciences16020066 - 3 Feb 2026
Abstract
Based on true triaxial loading experiments and particle flow numerical simulations (PFC3D), this study systematically analyzes the mechanical behavior and failure mechanisms of granite under the influence of stress difference (deviatoric stress). The experimental results indicate that increasing deviatoric stress reduces peak strength, [...] Read more.
Based on true triaxial loading experiments and particle flow numerical simulations (PFC3D), this study systematically analyzes the mechanical behavior and failure mechanisms of granite under the influence of stress difference (deviatoric stress). The experimental results indicate that increasing deviatoric stress reduces peak strength, axial strain, and lateral strain, promoting rock failure with less deformation and dilatancy. An energy analysis reveals that higher deviatoric stress suppresses peak energy accumulation, with a greater proportion of energy being dissipated through crack initiation and propagation. Macroscopic observations show that failure surfaces develop combined tensile-shear cracks, evolving into distinct “V” shapes as deviatoric stresses increase. Numerical simulations demonstrate that intermediate principal stress plays a dual role, initially facilitating, then inhibiting, and finally promoting rock failure with its continuous increase. Microscopically, tensile cracks dominate during pre-peak stages, while rapid crack coalescence in the post-peak stage leads to the formation of throughgoing V-shaped failure zones. Particle displacement analysis reveals that deformation concentrates along the minimum principal stress direction, with the displacement vectors ultimately forming a V-shaped boundary that delineates the failure zone. The research provides comprehensive insights into the macro-meso failure characteristics of hard rock under true triaxial conditions, offering valuable guidance for stability prediction and control in underground rock engineering projects such as water-sealed storage caverns. Full article
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24 pages, 863 KB  
Article
Energy Dissipation Analysis of Contact/Impact of Deformable Bodies Using Numerical Modelling
by Ondřej Holiš, Tomáš Dvořák, Matej Koiš, Ivan Němec, Miroslav Trcala and Jiří Vala
Buildings 2026, 16(3), 592; https://doi.org/10.3390/buildings16030592 - 31 Jan 2026
Viewed by 73
Abstract
The numerical analysis of dissipative energy in dynamic problems involving impact and contact phenomena relies on the physical principles of classical thermodynamics and on the constitutive equations of the material, supplemented by some additional considerations of potential contact interfaces. From the mathematical perspective, [...] Read more.
The numerical analysis of dissipative energy in dynamic problems involving impact and contact phenomena relies on the physical principles of classical thermodynamics and on the constitutive equations of the material, supplemented by some additional considerations of potential contact interfaces. From the mathematical perspective, we come to a weak form of partial differential equation(s) of evolution with initial, boundary, and interface conditions, whose numerical analysis is required using the method of discretisation in time and typically the finite element technique. Dissipative energy is an important metric for quantifying the portion of mechanical work that is permanently converted to plastic work and thermal energy, among other applications. Crucially, the localised accumulation of this energy, often expressed as the plastic work density, is the primary physical parameter driving microstructural changes, damage initiation, and crack propagation under intense loading. This paper demonstrates how the dissipative energy resulting from material nonlinearities can be evaluated in dynamic problems involving the impact of one body on another and provides a quantitative comparison of numerically calculated dissipated energy using three types of nonlinear constitutive material models, namely the plastic material model with Rankine–Hill criterion, the Mazars damage model, and the Kelvin–Voigt viscoelastic model. Full article
17 pages, 5297 KB  
Article
Mechanical Properties of Granite Residual Soil Reinforced by Permeable Water-Reactive Polyurethane
by Shuzhong Tan, Jinyong Li, Dingfeng Cao, Tao Xiao and Jiajia Zheng
Polymers 2026, 18(3), 381; https://doi.org/10.3390/polym18030381 - 30 Jan 2026
Viewed by 207
Abstract
Granite residual soil (GRS) is highly susceptible to water-induced softening, posing significant risks of slope instability and collapse. Conventional impermeable grouting often exacerbates these hazards by blocking groundwater drainage. This study investigates the efficacy of a permeable water-reactive polyurethane (PWPU) in stabilizing GRS, [...] Read more.
Granite residual soil (GRS) is highly susceptible to water-induced softening, posing significant risks of slope instability and collapse. Conventional impermeable grouting often exacerbates these hazards by blocking groundwater drainage. This study investigates the efficacy of a permeable water-reactive polyurethane (PWPU) in stabilizing GRS, aiming to resolve the conflict between mechanical reinforcement and hydraulic conductivity. Uniaxial compression tests were conducted on specimens with varying initial water contents (5%, 10%, and 15%) and PWPU contents (5%, 10%, and 15%). To reveal the multi-scale failure mechanism, synchronous acoustic emission (AE) monitoring and digital image correlation (DIC) were employed, complemented by scanning electron microscopy (SEM) for microstructural characterization. Results indicate that PWPU treatment significantly enhances soil ductility, shifting the failure mode from brittle fracturing to strain-hardening, particularly at higher moisture levels where failure strains exceeded 30%. This enhancement is attributed to the formation of a flexible polymer network that acts as a micro-reinforcement system to restrict particle sliding and dissipate strain energy. An optimal PWPU content of 10% yielded a maximum compressive strength of 4.5 MPa, while failure strain increased linearly with polymer dosage. SEM analysis confirmed the formation of a porous, reticulated polymer network that effectively bonds soil particles while preserving permeability. The synchronous monitoring quantitatively bridged the gap between internal micro-crack evolution and macroscopic strain localization, with AE analysis revealing that tensile cracking accounted for 79.17% to 96.35% of the total failure events. Full article
(This article belongs to the Section Polymer Processing and Engineering)
61 pages, 2678 KB  
Review
Technological Trends in Ammonia-to-Hydrogen Production: Insights from a Global Patent Review
by Miza Syahmimi Haji Rhyme, Dk Nur Hayati Amali Pg Haji Omar Ali, Hazwani Suhaimi and Pg Emeroylariffion Abas
Hydrogen 2026, 7(1), 16; https://doi.org/10.3390/hydrogen7010016 - 23 Jan 2026
Viewed by 416
Abstract
With rising demand for clean energy and uncertainty surrounding large-scale renewable deployment, ammonia has emerged as a viable carrier for hydrogen storage and transportation. This study conducts a global patent-based analysis of ammonia-to-hydrogen production technologies to determine technological maturity, dominant design pathways, and [...] Read more.
With rising demand for clean energy and uncertainty surrounding large-scale renewable deployment, ammonia has emerged as a viable carrier for hydrogen storage and transportation. This study conducts a global patent-based analysis of ammonia-to-hydrogen production technologies to determine technological maturity, dominant design pathways, and emerging innovation trends. A statistically robust retrieval, screening, and classification process, based on the PRISMA guidelines, was employed to screen, sort, and analyze 708 relevant patent families systematically. Patent families were categorized according to synthesis processes, catalyst types, and technological fields. The findings indicate that electrochemical, plasma-based, photocatalytic, and hybrid systems are being increasingly investigated as alternatives to low-temperature processes. At the same time, thermal catalytic cracking remains the most established and widely used method. Significant advances in reactor engineering, system integration, and catalyst design have been observed, especially in Asia. While national hydrogen initiatives, such as those in Brunei, highlight the policy importance of ammonia-based hydrogen systems, the findings primarily provide a global overview of technological maturity and innovation trajectories, thereby facilitating long-term transitions to cleaner hydrogen pathways. Full article
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20 pages, 3919 KB  
Article
Mechanical Behavior and Energy Evolution of Coal–Rock Composites Under Mining-Induced Stress
by Hongqiang Song, Hong Li, Liang Du, Xiaoqing Zhao, Bingwei Gu, Jianping Zuo, Fuming Jia and Jinhao Wen
Buildings 2026, 16(3), 473; https://doi.org/10.3390/buildings16030473 - 23 Jan 2026
Viewed by 205
Abstract
To investigate the mechanical properties, energy evolution, and failure behavior of coal–rock composite structures under mining disturbances, a mining-induced stress path was designed based on the actual stress evolution ahead of a mining face. Triaxial tests were carried out under these stress conditions [...] Read more.
To investigate the mechanical properties, energy evolution, and failure behavior of coal–rock composite structures under mining disturbances, a mining-induced stress path was designed based on the actual stress evolution ahead of a mining face. Triaxial tests were carried out under these stress conditions on coal–rock composite samples at various confining pressures, supplemented by conventional triaxial compression tests for comparison. The results show that the coal–rock composite samples exhibited marked brittle failure under mining-induced stress, with no sign of the brittle–ductile transition observed in conventional triaxial tests as the confining pressure increased. Using dual circumferential extensometers, it was found that the circumferential deformation of the coal and rock was initially governed by their intrinsic mechanical properties and later controlled by crack propagation. At higher confining pressures, the growth rate of circumferential strain at failure increased significantly, indicating that deeper excavations result in more severe unloading-induced failure. Comparative analysis revealed that the coal component had a higher elastic energy density and faster energy accumulation and release rates than the rock, identifying coal as the dominant medium for elastic energy storage and release within the composite samples. Furthermore, at peak stress in mining-induced stress tests, the coal showed less circumferential deformation than in conventional tests, while the rock exhibited the opposite trend, confirming the presence of a bonding constraint effect at the coal–rock interface. These findings enhance our understanding of the mechanical behaviors and failure mechanisms of coal–rock composites under mining disturbances, thus providing practical guidance for ensuring safety and efficiency in deep coal mining. Full article
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14 pages, 1874 KB  
Article
Study on the Impact Resistance of PVA-Fiber-Reinforced Waste Glass Powder Concrete
by Yingjie Wang, Guanghui Chu, Aozhong Feng, Yi Zhao and Shidong Tang
Buildings 2026, 16(3), 469; https://doi.org/10.3390/buildings16030469 - 23 Jan 2026
Viewed by 99
Abstract
Under impact loading, the performance of ordinary waste glass powder concrete is lower than that of ordinary concrete. To enhance the impact resistance of waste glass powder concrete, renewable polyvinyl alcohol (PVA) fibers are introduced. Considering the effects of PVA fiber volume content [...] Read more.
Under impact loading, the performance of ordinary waste glass powder concrete is lower than that of ordinary concrete. To enhance the impact resistance of waste glass powder concrete, renewable polyvinyl alcohol (PVA) fibers are introduced. Considering the effects of PVA fiber volume content (0.4%, 0.8%, 1.2%) and fiber length (6 mm, 12 mm, 18 mm), the basic mechanical properties and impact resistance of PVA-fiber-reinforced waste glass powder concrete are investigated through compression tests, flexural tests, and drop hammer impact tests. The results show that the incorporation of PVA fibers can effectively improve the impact resistance of waste glass powder concrete, and both the compressive and flexural strength are enhanced to varying degrees. The experimental results show that when the fiber volume content is 0.8% and the length is 12 mm, the flexural strength of the sample is the best. In addition, the impact of fiber length on performance varies by index; shorter fibers (6 mm) perform more prominently in enhancing impact toughness, while longer fibers (12 mm) are more conducive to the growth of flexural strength. There is a positive correlation between the impact resistance of the specimens and the fiber content; as the content of PVA fibers increases, both the initial crack impact number and the failure impact number show an increasing trend, and the energy absorbed by the concrete during initial cracking and failure gradually increases. The highest impact energy dissipation is achieved with the incorporation of 1.2% 6 mm fibers. Based on the experimental results, a functional relationship between fiber length, fiber content, and impact energy absorption is proposed for PVA-fiber-reinforced waste glass powder concrete. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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17 pages, 8142 KB  
Article
The Combined Influence of the Detonator Position and Anvil Type on the Weld Quality of Explosively Welded A1050/AZ31 Joints
by Bir Bahadur Sherpa, Shu Harada, Saravanan Somasundaram, Shigeru Tanaka and Kazuyuki Hokamoto
Metals 2026, 16(1), 128; https://doi.org/10.3390/met16010128 - 22 Jan 2026
Viewed by 101
Abstract
The present study systematically investigates, for the first time, the combined influences of detonator position (top-edge and bottom-edge initiations) and anvil material (steel and sand) on the interfacial microstructure and mechanical performance of explosively welded A1050/AZ31 dissimilar joints. When welding was conducted using [...] Read more.
The present study systematically investigates, for the first time, the combined influences of detonator position (top-edge and bottom-edge initiations) and anvil material (steel and sand) on the interfacial microstructure and mechanical performance of explosively welded A1050/AZ31 dissimilar joints. When welding was conducted using a steel anvil with the detonator positioned at the top edge, significant cracking occurred both at the surface and along the weld interface. In contrast, placing the detonator at the bottom edge noticeably reduced these defects. Moreover, the use of a sand anvil nullified these defects by damping the reflecting shockwaves and minimizing vibrations. Hardness measurements revealed substantial increase at the interface under all the conditions, with the highest value observed with the steel anvil. Welds subjected to top-edge detonation showed higher hardness values compared to those of welds subjected to bottom-edge detonation. Overall, the results suggest that sand anvils with bottom-edge detonation provide the optimal weld quality. The rigid steel anvil reflects the shockwave, generating high pressure and velocity at the interface, whereas the sand anvil absorbs a part of the shock energy, suppressing high-magnitude reflections. The position of the detonator influences the propagation dynamics of the detonation wave and the resulting collision velocity, which in turn, affect the interfacial morphology and overall quality of the weld. Full article
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22 pages, 6340 KB  
Article
Creep Instability and Acoustic Emission Responses of Bedded Coal Subjected to Compressive Loads and Acidic Water Saturation
by Zhenhua Zhao, Lin Han, Hongjie Sun, Hongtao Li, Rui Zhang, Xinyu Bai and Yu Wang
Appl. Sci. 2026, 16(2), 1005; https://doi.org/10.3390/app16021005 - 19 Jan 2026
Viewed by 119
Abstract
This study investigates the creep behavior and acoustic emission (AE) characteristics of bedded coal samples under acidic water environments. Uniaxial graded creep tests coupled with AE monitoring were conducted on samples with bedding angles of 0°, 30°, 60°, and 90°, respectively. The anisotropic [...] Read more.
This study investigates the creep behavior and acoustic emission (AE) characteristics of bedded coal samples under acidic water environments. Uniaxial graded creep tests coupled with AE monitoring were conducted on samples with bedding angles of 0°, 30°, 60°, and 90°, respectively. The anisotropic mechanical behavior and acoustic emission characteristics in terms of stress–strain, deformation, AE count, AE energy, and spectrum characteristics were revealed. The experimental results show that the strength of the coal samples gradually decreases as the saturation duration increases. At the same axial stress level, the axial deformation of the coal samples becomes larger with increasing saturation duration. The mechanical strength exhibits a distinct “U-shaped” relationship with the bedding angle, initially decreasing and then increasing. Correspondingly, axial deformation at a given stress level first increases and then decreases as the bedding angle increases. AE activity, particularly the AE ring count and energy, peaks at specimen failure, indicating significant fracture development. Spectral analysis revealed that under conditions of severe strength degradation (e.g., 0° bedding after 60-day saturation or 60° bedding after 30-day saturation), high-frequency, high-amplitude AE signals were absent. This suggests a shift in the dominant fracture mechanism from small-scale cracking to larger-scale fracture propagation in weakened samples. These findings offer valuable theoretical insights for the prevention and early warning of coal mine disasters. Full article
(This article belongs to the Topic Failure Characteristics of Deep Rocks, 3rd Edition)
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35 pages, 24420 KB  
Article
Rate-Dependent Fracturing Mechanisms of Granite Under Different Levels of Initial Damage
by Chunde Ma, Chenyang Li, Wenyuan Yang, Chenyu Wang, Qiang Gong and Hongbo Zhou
Appl. Sci. 2026, 16(2), 871; https://doi.org/10.3390/app16020871 - 14 Jan 2026
Viewed by 136
Abstract
Excavation of underground spaces often causes significant initial damage to surrounding rock, which can notably alter its mechanical properties. However, most studies on loading rate effects neglect the role of initial damage. This study investigates how initial damage and loading rate together affect [...] Read more.
Excavation of underground spaces often causes significant initial damage to surrounding rock, which can notably alter its mechanical properties. However, most studies on loading rate effects neglect the role of initial damage. This study investigates how initial damage and loading rate together affect granite’s mechanical behavior and fracturing characteristics. Granite specimens with different initial damage levels were subjected to uniaxial compression at varying loading rates to assess their mechanical parameters, stress thresholds, failure modes, energy evolution, and associated acoustic emission (AE) activity. Results indicate that granite’s mechanical behavior exhibits greater sensitivity to loading rate than to initial damage. As the loading rate increases, both strength and elastic modulus initially decrease and then rise, while the dissipated-to-input energy ratio reaches a maximum when the strength is at its lowest. This phenomenon occurs because, when cracks are allowed to fully develop, a relatively higher loading rate increases the likelihood of crack initiation and propagation, thereby reducing strength. The AE responses of initial damage granite samples (IDGSs), including counts, RA/AF value, b-value, and entropy, exhibit stage-dependent variations and contain precursory information before failure. Moreover, AE signals display multifractal characteristics across different loading rates. These findings reveal the mechanisms underlying granite’s mechanical response when both initial damage and loading rate act together: initial damage primarily affects the complexity and number of local microcracks, while loading rate determines the dominant crack initiation and propagation modes. Moreover, how the failure time of IDGSs varies with loading rate can be described by an inverse exponential function. These findings enhance insight into the coupling mechanism of initial damage and loading rate, with significant implications for failure warning and the cost-effectiveness of underground excavation. Full article
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16 pages, 6909 KB  
Article
A Novel Energy-Based Crack Resistance Assessment Method for Steel Fiber-Reinforced Lightweight Aggregate Concrete via Partially Restrained Ring Tests
by Binbin Zhang, Yongming Zhang and Wenbao Wang
Buildings 2026, 16(2), 299; https://doi.org/10.3390/buildings16020299 - 11 Jan 2026
Viewed by 150
Abstract
Early-age cracking limits the structural use of steel fiber-reinforced lightweight aggregate concrete (SFLWAC), and robust experimental evaluation methods are still needed. This study examines the influence of steel fiber volume fractions (i.e., 0%, 0.5%, 1.0%, and 2.0%) on the cracking performance of SFLWAC [...] Read more.
Early-age cracking limits the structural use of steel fiber-reinforced lightweight aggregate concrete (SFLWAC), and robust experimental evaluation methods are still needed. This study examines the influence of steel fiber volume fractions (i.e., 0%, 0.5%, 1.0%, and 2.0%) on the cracking performance of SFLWAC through mechanical testing, autogenous shrinkage measurements, and two types of partially restrained ring tests, with and without a clapboard. The performance of three crack resistance indices is compared: the strain-based ASTM C1581 index, a stress-based area index, and a newly proposed energy-based index defined as the strain energy accumulation degree (SEAD), i.e., the ratio between the accumulated and critical strain energy density. The 28-day splitting tensile strength was improved by 77.9% and autogenous shrinkage was diminished by 30.7% as steel fiber volume content increased from 0 to 2.0%, thereby improving the resistance to shrinkage-induced cracking. In the partially restrained ring tests, SEAD decreased with increasing fiber content, and crack initiation occurred when SEAD reached an approximately constant threshold, whereas ASTM C1581 and the area index could not consistently rank mixtures when some rings cracked and others remained intact. These results demonstrate that SEAD provides a physically meaningful and unified measure of cracking risk for SFLWAC under partially restrained shrinkage and has the potential to be extended to other fiber-reinforced concretes and shrinkage-related cracking problems. Full article
(This article belongs to the Section Building Structures)
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20 pages, 2746 KB  
Article
A Theoretical Model for Predicting the Blasting Energy Factor in Underground Mining Tunnels
by Alejandro Díaz, Heber Hernández, Javier Gallo and Luis Álvarez
Mining 2026, 6(1), 2; https://doi.org/10.3390/mining6010002 - 9 Jan 2026
Viewed by 316
Abstract
Optimizing the blast energy distribution is crucial for enhancing rock fragmentation, minimizing overexcavation, and boosting profitability in mining operations. This study introduces a theoretical model to predict the blasting Energy Factor (Fe) in mining tunnels, based on the Cracking Energy [...] Read more.
Optimizing the blast energy distribution is crucial for enhancing rock fragmentation, minimizing overexcavation, and boosting profitability in mining operations. This study introduces a theoretical model to predict the blasting Energy Factor (Fe) in mining tunnels, based on the Cracking Energy (Eg) of the rock mass, derived from the deformation energy of brittle materials (Young’s modulus) and adjusted by the Rock Mass Rating (RMR). The model was validated using 42 blasting datasets from horizontal galleries at El Teniente mine, Chile. Data included geometric parameters (tunnel sections, drilling length, diameter, number of holes, meters drilled), explosive type and consumption, and geomechanical properties, particularly the RMR. Results show that as rock mass quality improves (higher RMR), both Fe and %Eg increase, more competent rock masses require higher input energy to initiate and propagate cracks, and a greater portion of that energy is effectively utilized for crack formation. For instance, rock masses with an RMR of 66 exhibited an average Fe of 7.62 MJ/m3 and %Eg of 4.8%, while those with an RMR of 75 showed higher values (Fe = 8.47 MJ/m3, %Eg = 6.4%). This confirms that less fractured rock masses require higher Fe and %Eg for effective fragmentation. Lithology also plays a significant role in energy consumption. Diorite displayed the highest Fe (8.34 MJ/m3) and higher efficiency (%Eg = 7.0%), whereas andesite showed lower Fe (7.61 MJ/m3) and lower crack propagation efficiency (%Eg = 3.7%). Unlike traditional Fe prediction methods, which rely solely on explosive data and excavation volume, this model integrates RMR, enabling more precise energy allocation and fostering sustainable mining practices. This approach enhances decision-making in blast design, offering a more robust framework for optimizing energy use in mining operations. Full article
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14 pages, 3931 KB  
Article
Experimental Determination of Material Behavior Under Compression of a Carbon-Reinforced Epoxy Composite Boat Damaged by Slamming-like Impact
by Erkin Altunsaray, Mustafa Biçer, Haşim Fırat Karasu and Gökdeniz Neşer
Polymers 2026, 18(2), 173; https://doi.org/10.3390/polym18020173 - 8 Jan 2026
Viewed by 296
Abstract
Carbon-reinforced epoxy laminated composite (CREC) structures are increasingly utilized in high-speed marine vehicles (HSMVs) due to their high specific strength and stiffness; however, they are frequently subjected to impact loads like slamming and aggressive environmental agents during operation. This study experimentally investigates the [...] Read more.
Carbon-reinforced epoxy laminated composite (CREC) structures are increasingly utilized in high-speed marine vehicles (HSMVs) due to their high specific strength and stiffness; however, they are frequently subjected to impact loads like slamming and aggressive environmental agents during operation. This study experimentally investigates the Compression After Impact (CAI) behavior of CREC plates with varying lamination sequences under both atmospheric and accelerated aging conditions. The samples were produced using the vacuum-assisted resin infusion method with three specific orientation types: quasi-isotropic, cross-ply, and angle-ply. To simulate the marine environment, specimens were subjected to accelerated aging in a salt fog and cyclic corrosion cabin for periods of 2, 4, and 6 weeks. Before and following the aging process, low-velocity impact tests were conducted at an energy level of 30 J, after which the residual compressive strength was measured by CAI tests. At the end of the aging process, after the sixth week, the performance of plates with different layer configuration characteristics can be summarized as follows: Plates 1 and 2, which are quasi-isotropic, exhibit opposite behavior. Plate 1, with an initial toughness of 23,000 mJ, increases its performance to 27,000 mJ as it ages, while these values are around 27,000 and 17,000 mJ, respectively, for Plate 2. It is thought that the difference in configurations creates this difference, and the presence of the 0° layer under the effect of compression load at the beginning and end of the configuration has a performance-enhancing effect. In Plates 3 and 4, which have a cross-ply configuration, almost the same performance is observed; the performance, which is initially 13,000 mJ, increases to around 23,000 mJ with the effect of aging. Among the options, angle-ply Plates 5 and 6 demonstrate the highest performance with values around 35,000 mJ, along with an undefined aging effect. Scanning Electron Microscopy (SEM) and Energy-Dispersive X-ray Spectroscopy (EDS) analyses confirmed the presence of matrix cracking, fiber breakage, and salt accumulation (Na and Ca compounds) on the aged surfaces. The study concludes that the impact of environmental aging on CRECs is not uniformly negative; while it degrades certain configurations, it can enhance the toughness and energy absorption of brittle, cross-ply structures through matrix plasticization. Full article
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8 pages, 1868 KB  
Proceeding Paper
Experimental and Numerical Study of Mode II Fatigue Delamination via End-Loaded Split Specimens
by Johan Birnie, Maria Pia Falaschetti, Francesco Semprucci and Enrico Troiani
Eng. Proc. 2025, 119(1), 50; https://doi.org/10.3390/engproc2025119050 - 7 Jan 2026
Viewed by 156
Abstract
Delamination in fibre-reinforced polymer composites is a critical failure mechanism that can ultimately lead to a catastrophic failure. To characterise in-plane shear delamination (Mode II), several test setups have been proposed in the literature, with the End-Loaded Split (ELS) test being the most [...] Read more.
Delamination in fibre-reinforced polymer composites is a critical failure mechanism that can ultimately lead to a catastrophic failure. To characterise in-plane shear delamination (Mode II), several test setups have been proposed in the literature, with the End-Loaded Split (ELS) test being the most suitable for applications that require stable crack propagation (ISO 15114). This manuscript focuses on studying Mode II fatigue delamination in unidirectional carbon fibre-reinforced laminates using the ELS configuration. Experimental tests with varying displacement ratios and different initial energy levels were conducted to capture a wide range of stable crack propagation scenarios. To complement these experimental efforts, a numerical model based on cohesive zone models (CZM) was implemented in Abaqus, utilising a user-defined material subroutine (UMAT). The numerical results closely align with the experimental data, validating the model’s predictive capabilities. This combined approach deepens the understanding of Mode II fatigue delamination and provides a strong framework for designing and analysing composite structures. Full article
(This article belongs to the Proceedings of The 8th International Conference of Engineering Against Failure)
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51 pages, 4344 KB  
Review
Mechanistic Pathways and Product Selectivity in Pyrolysis of PE, PP and PVC: A Foundation for Applied Chemistry in Europe
by Tim Tetičkovič, Dušan Klinar, Klavdija Rižnar and Darja Pečar
Molecules 2026, 31(2), 202; https://doi.org/10.3390/molecules31020202 - 6 Jan 2026
Viewed by 692
Abstract
Plastic streams dominated by polyethylene (PE) including PE HD/MD (High Density/Medium Density) and PE LD/LLD (Low Density/Linear Low Density), polypropylene (PP), and polyvinyl chloride (PVC) across Europe demand a design framework that links synthesis with end of life reactivity, supporting circular economic goals [...] Read more.
Plastic streams dominated by polyethylene (PE) including PE HD/MD (High Density/Medium Density) and PE LD/LLD (Low Density/Linear Low Density), polypropylene (PP), and polyvinyl chloride (PVC) across Europe demand a design framework that links synthesis with end of life reactivity, supporting circular economic goals and European Union waste management targets. This work integrates polymerization derived chain architecture and depolymerization mechanisms to guide selective valorization of commercial plastic wastes in the European context. Catalytic topologies such as Bronsted or Lewis acidity, framework aluminum siting, micro and mesoporosity, initiators, and strategies for process termination are evaluated under relevant variables including temperature, heating rate, vapor residence time, and pressure as encountered in industrial practice throughout Europe. The analysis demonstrates that polymer chain architecture constrains reaction pathways and attainable product profiles, while additives, catalyst residues, and contaminants in real waste streams can shift radical populations and observed selectivity under otherwise similar operating windows. For example, strong Bronsted acidity and shape selective micropores favor the formation of C2 to C4 olefins and Benzene, Toluene, and Xylene (BTX) aromatics, while weaker acidity and hierarchical porosity help preserve chain length, resulting in paraffinic oils and waxes. Increasing mesopore content shortens contact times and limits undesired secondary cracking. The use of suitable initiators lowers the energy threshold and broadens processing options, whereas diffusion management and surface passivation help reduce catalyst deactivation. In the case of PVC, continuous hydrogen chloride removal and the use of basic or redox co catalysts or ionic liquids reduce the dehydrochlorination temperature and improve fraction purity. Staged dechlorination followed by subsequent residue cracking is essential to obtain high quality output and prevent the release of harmful by products within European Union approved processes. Framing process design as a sequence that connects chain architecture, degradation chemistry, and operating windows supports mechanistically informed selection of catalysts, severity, and residence time, while recognizing that reported selectivity varies strongly with reactor configuration and feed heterogeneity and that focused comparative studies are required to validate quantitative structure to selectivity links. In European post consumer sorting chains, PS and PC are frequently handled as separate fractions or appear in residues with distinct processing routes, therefore they are not included in the polymer set analyzed here. Polystyrene and polycarbonate are outside the scope of this review because they are commonly handled as separate fractions and are typically optimized toward different product slates than the gas, oil, and wax focused pathways emphasized here. Full article
(This article belongs to the Special Issue Applied Chemistry in Europe, 2nd Edition)
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