Search Results (385)

Previous studies have extensively applied the generalized consolidation theory, which incorporates a two-stress state variable framework, to predict the volumetric behavior of unsaturated expansive soils under varying mechanical stress and matric suction. A key requirement for this approach is a constitutive surface that links the soil void ratio to both net stress and matric suction. A large number of fitting parameters are typically needed to accurately fit a two-variable void ratio surface equation to laboratory test data. In this study, a single-stress state variable framework was adopted to describe the void ratio as a function of effective stress for unsaturated soils. The proposed approach was applied to fit void ratio–effective stress constitutive curves to laboratory test data for two different expansive clays. Additionally, a finite element model coupling variably saturated flow and stress–strain analysis was developed to simulate the volume change behavior of expansive clay subjected to moisture fluctuations. The model utilizes suction stress to compute the effective stress field and incorporates the dependency of soil modulus on volumetric water content based on the proposed void ratio–effective stress relationship. The developed numerical model was validated against a benchmark problem in which a layer of Regina expansive clay was subjected to a constant infiltration rate. The results demonstrate the effectiveness of the proposed model in simulating expansive soil deformations under varying moisture conditions over time. Full article

Superplastic materials are characterised by extreme lightness and remarkable ductility. Instead of a punch, a gas is used to push the sheet into the die cavity, and it is precisely regulated to control the material’s strain rate. Forming a superplastic material while maintaining a high strain rate sensitivity index requires the forming gas to follow a precise pressure–time loading curve. This can be excellently predicted with the aid of the finite element method (FEM). Therefore, for the superplastic material to exhibit its best formability throughout the entire process, it is necessary to control the strain rate step by step to keep the maximum strain rate within the material’s optimal superplastic range. In this work, the results of a superplastic-forming process used to create a hemispherical shell are presented. This was carried out using both a circular blank of uniform thickness and a blank with a conical cross-section. The analysis was performed using finite element modelling. Specifically, the results obtained using 3D analysis were compared with those obtained using axisymmetric analysis for conditions of axial symmetry. Using the conical cross-section blank helped achieve a more uniform thickness distribution in the produced hemispherical shell. The success of the numerical activity was validated through results from appropriate experimental work conducted on the magnesium alloy AZ31. The results show that, by employing a blank characterised by a conical section profile, the thickness distribution appears more uniform than that of a constant-thickness blank. Full article

The extensive use of copper in thermal and electrical systems calls for constant performance enhancement by means of innovative material treatments. The effects on the microstructural, mechanical, and electrical characteristics of copper in deep cryogenic treatment (DCT) and deep cryogenic treatment followed by heat treatment (DCT + HT) are investigated in this work. Copper samples were treated for various soaking durations ranging from 6 to 24 h. Mechanical properties such as tensile strength, hardness, and wear rate were analyzed. In the DCT-treated samples, tensile strength increased, reaching a peak of 343 MPa at 18 h, alongside increased hardness (128 HV) and a refined grain size of 9.58 µm, primarily due to elevated dislocation density and microstrain. At 18 h of soaking, DCT + HT resulted in improved structural stability, high hardness (149 HV), a fine grain size (7.42 µm), and the lowest wear rate (7.73 × 10⁻¹⁰ mm³/Nm), consistent with Hall–Petch strengthening. Electrical measurements revealed improved electron mobility (52.08 cm²/V·s) for samples soaked for 24 h in DCT + HT, attributed to increased crystallite size (39.9 nm), reduced lattice strain, and higher (111) texture intensity. SEM–EBSD analysis showed a substantial increase in low-angle grain boundaries (LAGBs) in DCT + HT-treated samples, correlating with enhanced electrical conductivity. Overall, an 18 h soaking duration was found to be optimal for both treatments. However, the strengthening mechanism in DCT + HT is influenced by grain boundary stabilization and thermal recovery and is different to DCT, which is strain-induced enhancement. Full article

Underground production and injection operations result in mechanical compaction and mineral chemical reactions that alter porosity and permeability. These changes impact the flow and, eventually, the long-term sustainability of reservoirs utilized for CO₂ sequestration and geothermal energy. Even though mechanical and chemical deformations in rocks take place at the pore scale, it is important to investigate their impact at the continuum scale. Rock deformation can be examined using intergranular pressure solution (IPS) models, primarily for uniaxial compaction. Because the reaction rate parameters are estimated using empirical methods and the assumption of constant mineral saturation indices, these models frequently overestimate the rates of compaction and strain by several orders of magnitude. This study presents a new THMC algorithm by combining thermo-mechanical computation with a fractal approach and hydrochemical computations using PHREEQC to evaluate the pressure solution. Thermal stress and strain under axisymmetric conditions are calculated analytically by combining a derived hollow circle mechanical structure with a thermal resistance model. Based on the pore scale, porosity and its impact on the overall excessive stress and strain rate in a domain are estimated by applying the fractal scaling law. Relevant datasets from CO₂ core flooding experiments are used to validate the proposed approach. The comparison is consistent with experimental findings, and the novel analytical method allows for faster inspection compared to numerical simulations. Full article

In the realm of click-type reactions and their application to bioorthogonal chemistry in living organisms, metal-free [3+2] cycloadditions involving mesoionic rings and strained cycloalkynes have gained increasing attention and potentiality in recent years. While there has been a significant accretion of experimental data, biological assays, and assessments of reaction mechanisms, some pieces of the tale are still missing. For instance, which structural and/or stereoelectronic effects are actually interlocked and which remain unplugged. With the advent of data-driven methods, including machine learning simulations, quantitative estimations of relevant observables and their correlations will explore better the chemical space of these transformations. Here we unveil a series of linear relationships, such as Hammett-type correlations, as well as deviations of linearity, using the case study of phenylsydnone (and its 4-aryl-substituted derivatives) with a highly reactive bicyclo[6.1.0]nonyne carbinol. Through accurate estimation of activation barriers and prediction of rate constants, our findings further increase the significance of integrating strain release and electronic effects in organic reactivity. Moreover, such results could pave the way to use mesoionics cycloadditions as probes for measuring the extent of delocalization-assisted strain release, which can be applied to related reactions involving dipoles and strained rings. Full article

This study presents a high-order shear deformation theory (HSDT)-based model for evaluating the energy harvesting performance of functionally graded material (FGM) beams integrated with a piezoelectric layer and subjected to a moving concentrated load at constant velocity. The governing equations are derived using Hamilton’s principle, and the dynamic response is obtained through the State Function Method with trigonometric mode shapes. The output voltage and harvested power are calculated based on piezoelectric constitutive relations. A comparative analysis with homogeneous isotropic beams demonstrates that HSDT yields more accurate predictions than the Classical Beam Theory (CBT), especially for thick beams; for instance, at a span-to-thickness ratio of h/L = 12.5, HSDT predicts increases of approximately 6%, 7%, and 12% in displacement, voltage, and harvested power, respectively, compared to CBT. Parametric studies further reveal that increasing the load velocity significantly enhances the strain rate in the piezoelectric layer, resulting in higher voltage and power output, with the latter exhibiting quadratic growth. Moreover, increasing the material gradation index n reduces the beam’s effective stiffness, which amplifies vibration amplitudes and improves energy conversion efficiency. These findings underscore the importance of incorporating shear deformation and material gradation effects in the design and optimization of piezoelectric energy harvesting systems using FGM beams subjected to dynamic loading. Full article

Tensile tests are a common method for characterizing plastic behavior for sheet metal forming applications. During tensile testing at the beginning of the deformation, the stress state is uniaxial; however, as the deformation proceeds, the state changes to triaxial, making the post-processing of experimental data challenging using analytical methods. In contrast, inverse approaches in which the behavior is represented by constitutive equations and the parameters are fitted using an iterative procedure are extremely dependent on the empirical equation chosen at the outset and can be computationally expensive. The inverse piecewise flow curve determination method, previously developed for compression tests, is extended in this paper to tensile testing. A stepwise approach is proposed to calculate constant strain rate flow curves accounting for the unique characteristics of tensile deformation. To capture the effects of localized strain rate variations during necking, a parallel flow curve determination strategy is introduced. Tensile test flow curves for manganese-boron steel 22MnB5, a material commonly used in hot stamping applications, are determined, and the approach is demonstrated for virtual force–displacement curves. It has been shown that these curves can replicate the virtual experimental flow curves data with a maximum deviation of 1%. Full article

This research investigates whether metakaolin can be used as a partial substitution for slag to mitigate significant volume changes in alkali-activated slags. Its effect on compressive strength and workability (as well as on isothermal calorimetry, autogenous strain, and coefficient of thermal expansion (CTE)) were found to depend on both the type and concentration of the alkaline activator. When using 8 M and 10 M sodium hydroxide (NaOH), increasing the substitution rate increased the compressive strength. With sodium silicate (Na₂SiO₃), compressive strength decreased as the substitution increased. Isothermal calorimetry revealed metakaolin’s dilution effect at 10% substitution. With 8 M NaOH, a third reaction peak appeared, whose magnitude increased with the substitution rate, while the second peak decreased. The swelling was increased at 10% substitution, followed by constant shrinkage in case of NaOH-activation. Shrinkage was mitigated with Na₂SiO₃-activation. Higher substitutions with 8 M NaOH resulted in a significant increase in the shrinkage rate and CTE, occurring when the third reaction peak appeared. A 10% substitution delayed the CTE increase but resulted in higher later-age values (dilution effect). The 20% substitution led to a similar final CTE value at 300 h, while 30% substitution resulted in a decrease in CTE after the initial increase. Full article

The rapid expansion of land reclamation necessitates a fundamental understanding of the strain rate effects on structured clays. While the rate effect has been widely studied in various soils, the interplay between bond structure and strain rate sensitivity remains unclear. This study investigates these mechanisms using artificially cemented kaolin (ACK) with controlled curing periods (2 and 30 days) to simulate naturally bonded clays. A series of undrained triaxial tests was conducted under low (100 kPa) and high (600 kPa) confining stresses, employing constant strain rates (0.01–5%/h) pre-peak and stepwise rate changes post-peak. The results reveal that the strain rate effects are governed by the bond structure maturity and drainage mechanisms. For the 30-day curing ACK, the pre-peak strength under low confining stress shows minimal rate sensitivity due to the rigid bond, while high confining stress induces a “negative” rate effect attributed to localised drainage along shear planes. The post-peak behaviour consistently exhibits a positive isotach-type rate effect (+3%/log-cycle) driven by viscous sliding. In contrast, the 2-day curing ACK displays negative rate effects pre-peak influenced by ongoing curing and post-peak strength reductions (−8%/log-cycle) linked to stick-slip dynamics. These findings establish a framework for predicting rate-dependent behaviour in structured clays, offering insights into land reclamation and subsequent construction work. Full article

Energy and environmental challenges are driving researchers to explore cost-effective and eco-friendly nanomaterial fabrication methods. In this study, Atmospheric Pressure Microplasma (AMP) was used to synthesize iron oxide nanoparticles at varying molar concentrations of ferrous sulfate (0.5 M, 1 M, and 1.5 M) under a 15 kV discharge voltage for 90 min. The X-ray diffraction (XRD) results confirmed the formation of mixed cubic and hexagonal phases of magnetite and hematite nanoparticles. The particle size, calculated using the Debye–Scherrer formula, ranged from 9 to 11 nm, depending on the precursor concentration. Scanning electron microscopy (SEM) images revealed spherical nanoparticles at 0.5 M, while agglomeration occurred at 1.5 M. The energy-dispersive X-ray spectroscopy (EDS) analysis confirmed the presence of iron and oxygen in the synthesized nanoparticles. Fourier-transform infrared (FTIR) and UV spectroscopy showed characteristic absorption bands of iron oxide. The impact of the particle size and lattice strain on the optical properties of the nanoparticles was also studied. Smaller nanoparticles exhibited an excellent specific capacitance (627) and a strong charge–discharge performance in a 3 M KOH solution, with a high energy density (67.72) and power density (2227). As photocatalysts, the nanoparticles demonstrated a 97.5% and 96.8% degradation efficiency against methylene blue (MB) and methyl orange (MO), respectively, with high rate constants. These results surpass previous reports. The enhanced electrochemical performance and photocatalytic activity are attributed to the high-quality iron oxide nanoparticles, showing an excellent cyclic stability, making them promising for supercapacitors and environmental remediation. Full article

Cis-1,4-polyisoprene is a widely used elastomer that demonstrates particular thermal and mechanical characteristics, in which the latter is influenced by temperature and strain rate. Molecular dynamic simulations were used to obtain thermal conductivities, glass transition temperatures (T_g), and tensile deformation. Thermal conductivities were calculated by applying the Green–Kubo method, and a decrease in thermal conductivity was observed with increasing temperature. Density–temperature relations were used to calculate T_g, which indicates the transition from the glassy to the rubbery state of the material, and this temperature influences mechanical properties. Investigation of the mechanical properties under uniaxial tensile deformation for constant strain rates indicates an increase in the stiffness and strength of the material at lower temperatures, while increasing molecular mobility at higher temperatures results in reducing these properties. The influence of strain rates at constant temperature highlighted the viscoelastic nature of the structure; increasing strain rates resulted in increases in stiffness, strength, elongation at maximum strength, and elongation at break because of restricted molecular relaxation time. The united-atom force field contributes to higher computational efficiency, which is suitable for large-scale simulations. These results provide important information on the thermo-mechanical properties and tunability of cis-1,4-polyisoprene, which supports applications in the production of interactive fiber rubber composites. Full article

Calcareous sand, a critical construction material in reef engineering and building foundations, possesses unique internal microstructures and inherent mechanical properties. Given these characteristics, it is essential to thoroughly evaluate its strength under various loading conditions to ensure its reliability in building applications. This study examines the strength, deformation, and failure characteristics of calcareous sand through consolidated drained shear failure tests using a GDS stress path triaxial apparatus. The effects of shear rate, particle gradation, and compactness are systematically investigated to assess their impact on structural stability in building foundations and load-bearing applications. The results indicate that at low confining pressures, calcareous sand exhibits strain softening, whereas at higher confining pressures, strain hardening is observed. For samples with the same gradation, both peak deviatoric stress and failure strain increase linearly with confining pressure. The volume strain evolution during shear follows three stages: shear shrinkage, shear dilatancy, and stabilization. At low confining pressures, dilatancy is favored, while high confining pressures promote shrinkage. Additionally, under constant confining pressure, peak strength increases and failure strain decreases linearly with compactness. Increasing the loading rate from 0.01 to 0.1 mm/min results in a slight increase in the friction angle, with minimal impact on cohesion. Particle gradation plays a significant role in determining the shear strength of calcareous sand, as its effects vary depending on the combination of compactness and gradation. These findings provide valuable insights for the design and construction of stable building foundations, roadbeds, and other load-bearing structures in reef engineering and coastal developments, where calcareous sand is widely used. Full article

Listeria monocytogenes is an intracellular, Gram-positive, non-spore-forming, non-encapsulated, facultative anaerobic, rod-shaped, and psychrotrophic food-borne pathogen that causes the infection, listeriosis, thus it attracts great attention following listeriosis outbreaks, which are often associated with high mortality rates. The prevalence of listeriosis is quite low globally; however, the most recent and deadliest outbreak occurred in South Africa, during which 216 persons lost their lives. L. monocytogenes is endowed with the potential to multiply through a wide range of harsh environmental conditions, forming biofilms on varying surfaces in the food industry, as well as having persistent and antibiotic-resistant cells, which pose a major threat and burden to the ready-to-eat food industry. A more frustrating characteristic of this bacterium is its strain divergence, alongside an increased level of antibiotic resistance registered among the strains of L. monocytogenes recovered from food, humans, and environmental sources, especially to those antibiotics involved in the treatment of human listeriosis. Antibiotic resistance exerted by and among pathogenic food-borne microbes is an ongoing public health menace that continues to be an issue. Against this background, a thorough search into different databases using various search engines was performed, which led to the gathering of salient information that was organised, chronologically, based on Listeria monocytogenes and listeriosis. Altogether, the findings elaborated in this study present up-to date knowledge on different aspects of this pathogen which will improve our understanding of the mystery associated with it and the ways to prevent and control its dissemination through ready-to-eat foods. In addition, constant monitoring of the antibiotic resistance profiles of strains of L. monocytogenes from varying sources detected changes, giving an update on the trend in antibiotic resistance. Overall, monitoring of bacterial contamination serves as the key aspect in the control of the food safety output in the food industry. Full article

The shear strength and compression properties of stiff Boom clay from Belgium at a depth of about 16.5 to 28 m were investigated by means of cone penetration and laboratory testing. The latter consisted of index classification, constant rate of strain, triaxial, direct simple shear and unconfined compression tests. The Boom clay samples exhibited strong swelling tendencies. The suction pressure was measured via different procedures and was compared to the expected in situ stress. The undrained shear strength profile determined from cone penetration tests (CPTs) was not compatible with the triaxial and direct simple shear measurements, which gave significantly lower undrained shear strength values. Micro-computed tomography (μCT) scans of the samples showed the presence of pre-existing discontinuities which may cause inconsistencies in the comparison of the laboratory test results with in situ data. The experimental data gathered in this study provide useful information for analyzing the mechanical behaviour of Boom clay at shallow depths considering that most investigations in the literature have been carried out on deep Boom clay deposits. Full article

This study investigated Lacticaseibacillus paracasei GV17, a potentially probiotic strain, in association with the commercial culture Streptococcus thermophilus STI-12, in lactose-free fermented milk. Predictive modeling was used to estimate growth parameters and microbial viability and the technological characteristics of the fermented milk during storage. The initial concentrations of the strains were 9.80 log CFU/mL for Lc. paracasei GV17 and 9.50 log CFU/mL for S. thermophilus STI-12. After eight hours, the pH reached 4.6, and the concentrations of GV17 and STI-12 were 10.90 log CFU/mL and 11.20 log CFU/mL, respectively. The Baranyi model was fitted to the growth data, with correlation coefficients of 0.760 for Lc. paracasei GV17 and 0.852 for St. thermophilus STI-12. The maximum specific growth rates were 0.912 log CFU/h for GV17 and 0.882 log CFU/h for STI-12. Regarding technological characteristics, syneresis decreased by 8.90% after 28 days, indicating greater structural stability, while water retention capacity remained constant. The viability of LAB remained above 10.00 log CFU/mL. Lc. paracasei GV17 showed great potential for use in functional products, prompting further research. Full article