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16 pages, 1893 KB  
Article
Modeling and Optimization of Argon-Activated Electrohydraulic Plasma Discharge Process for p-Nitrophenol Remediation
by Anilkumar Krosuri, Yunfei Zhou, Muhammad Aamir Bashir, Robinson Junior Ndeddy Aka and Sarah Wu
Sustainability 2025, 17(20), 9275; https://doi.org/10.3390/su17209275 (registering DOI) - 19 Oct 2025
Abstract
This study presents a statistical modelling and optimization of an argon-activated electrohydraulic plasma discharge (EHPD) process for the degradation and mineralization of p-nitrophenol (p-NP) in water. The EHPD reactor design incorporated dual dielectric plates to initiate plasma discharge through a central orifice. A [...] Read more.
This study presents a statistical modelling and optimization of an argon-activated electrohydraulic plasma discharge (EHPD) process for the degradation and mineralization of p-nitrophenol (p-NP) in water. The EHPD reactor design incorporated dual dielectric plates to initiate plasma discharge through a central orifice. A fractional factorial design (FFD) was first employed to screen four operating variables, including argon flow rate, pH, applied power, and persulfate dosage, on the p-NP degradation efficiency and energy yield, revealing argon flow rate and applied power as two identified, significant process factors. These were then further optimized using a central composite design (CCD) and response surface methodology (RSM), with the optimal operating condition found to be 2.73 L/min and 128.6 W for argon flow rate and applied power, respectively. Under the optimal operating conditions, 10 min treatment of 50 mg/L p-NP achieved a degradation efficiency of 94.2% and 75.8% total organic carbon (TOC) removal, along with a first-order reaction rate constant of 0.296 min−1 and an energy efficiency of 0.22 g/kWh. The reaction mechanism for p-NP degradation by EHPD was proposed and confirmed with optical emission spectroscopy and radical scavengers. The optimized EHPD process proved both effective and energy-efficient in treating p-nitrophenol, highlighting its potential as a scalable and sustainable plasma-based technology for eliminating persistent organic pollutants and promoting greener water treatment practices. Full article
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12 pages, 2252 KB  
Article
Ultra-High Spectral Contrast Nanobeam Photonic Crystal Cavity on Bending Waveguide
by Ping Yu, Peihong Cheng, Zhuoyuan Wang, Jingrui Wang, Fangfang Ge, Huiye Qiu and Daniel Kacik
Photonics 2025, 12(10), 1031; https://doi.org/10.3390/photonics12101031 (registering DOI) - 17 Oct 2025
Viewed by 79
Abstract
In this article, one-dimensional photonic crystal cavities on bending waveguides (PCCoBW) used for achieving high-contrast spectra are proposed, analyzed, and experimentally verified on silicon on insulator (SOI). Both air and dielectric modes of the PCCoBW calculated by the finite-difference time-domain (FDTD) method show [...] Read more.
In this article, one-dimensional photonic crystal cavities on bending waveguides (PCCoBW) used for achieving high-contrast spectra are proposed, analyzed, and experimentally verified on silicon on insulator (SOI). Both air and dielectric modes of the PCCoBW calculated by the finite-difference time-domain (FDTD) method show finger-ring-like mode profiles with the achievement of high-quality factors (Q∼106), even when the bending radius is less than 50 times the lattice constant. Straight waveguides side-coupled to the cavity are used to access and measure mode resonances. The measured spectra show a high extinction ratio over 40 dB for dielectric modes and 20 dB for air modes, respectively. Both dielectric and air resonant modes are revealed with Q-factors over 3.3 × 104 and 7.9 × 104, respectively, for the coupled PCCoBWs. The proposed PCCoBW could be implemented as high-contrast notch filtering and would benefit a broad range of applications such as optical filters, modulators, sensors, or switches. Full article
(This article belongs to the Special Issue Recent Advancement in Microwave Photonics)
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8 pages, 1280 KB  
Case Report
From Technical Pitfall to Clinical Consequences: Leadless Pacing as a Rescue Solution
by Fulvio Cacciapuoti, Ciro Mauro, Flavia Casolaro, Antonio Torsi, Salvatore Crispo and Mario Volpicelli
Reports 2025, 8(4), 206; https://doi.org/10.3390/reports8040206 - 17 Oct 2025
Viewed by 138
Abstract
Background and Clinical Significance: Early lead failure after dual-chamber pacemaker implantation is rare but clinically significant, particularly when associated with thromboembolic complications. Technical pitfalls at the time of implantation, such as suture fixation without protective sleeves, may be predisposed to premature lead damage [...] Read more.
Background and Clinical Significance: Early lead failure after dual-chamber pacemaker implantation is rare but clinically significant, particularly when associated with thromboembolic complications. Technical pitfalls at the time of implantation, such as suture fixation without protective sleeves, may be predisposed to premature lead damage and abrupt device malfunction. This case highlights the role of device interrogation in diagnosing arrhythmia-related stroke, the challenges of reimplantation in the setting of venous occlusion and anticoagulation, and the value of leadless pacing as a safe rescue strategy. Case Presentation: A 78-year-old man with a history of complete atrioventricular block underwent dual-chamber pacemaker implantation one year earlier. He presented to the emergency department with acute aphasia, right-sided hemiparesis, and facial asymmetry. Stroke was diagnosed, and new-onset atrial fibrillation was documented. Device interrogation revealed an abrupt fall in lead impedance followed by a sharp rise consistent with lead insulation failure and premature battery depletion. Fluoroscopy demonstrated multiple focal narrowings of the leads and complete left subclavian vein occlusion, making conventional transvenous reimplantation unfeasible, while extraction was judged high risk. Right-sided reimplantation was avoided due to hemorrhagic risk under anticoagulation. A leadless pacemaker was implanted successfully in the apico-septal region of the right ventricle via ultrasound-guided femoral access. Hemostasis was secured with a figure-of-8 suture fixed inside a 3-way tap, providing constant compression and preventing hematoma. At two-months follow-up, device function was stable and neurological recovery was favorable (mRS = 2). Conclusions: This case underscores how multiple adverse factors—stroke, arrhythmia detection, early device failure, venous occlusion, and anticoagulation—may converge in a single patient, and demonstrates leadless pacing as a safe and effective rescue strategy in such complex scenarios. Full article
(This article belongs to the Section Cardiology/Cardiovascular Medicine)
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15 pages, 11023 KB  
Article
Aging Analysis of HTV Silicone Rubber Under Coupled Corona Discharge, Humidity and Cyclic Thermal Conditions
by Ming Lu, Shiyin Zeng, Chao Gao, Yuelin Liu, Xinyi Yan, Zehui Liu and Guanjun Zhang
Electronics 2025, 14(20), 4071; https://doi.org/10.3390/electronics14204071 - 16 Oct 2025
Viewed by 161
Abstract
High-temperature vulcanized silicone rubber (HTV-SR), widely used in composite insulators, experiences performance degradation when subjected to combined stresses such as corona discharge, humidity and temperature fluctuations. This degradation poses significant risks to the reliability of power grid operation. To investigate the aging behavior [...] Read more.
High-temperature vulcanized silicone rubber (HTV-SR), widely used in composite insulators, experiences performance degradation when subjected to combined stresses such as corona discharge, humidity and temperature fluctuations. This degradation poses significant risks to the reliability of power grid operation. To investigate the aging behavior and mechanisms of HTV-SR under the combined influences of corona, moisture and thermal cycling, a series of multi-factor accelerated aging tests are conducted. Comprehensive characterizations of surface morphology, structural, mechanical and electrical properties are performed before and after aging. The results reveal that corona discharge induces molecular chain scission and promotes oxidative crosslinking, leading to surface degradation. Increased humidity accelerates water diffusion and hydrolysis, enhancing crosslink density but reducing material flexibility, thereby further deteriorating structural integrity and electrical performance. Compared with constant temperature aging, thermal cycling introduces repetitive thermal stress, which significantly aggravates filler migration and leads to more severe mechanical and dielectric degradation. These findings elucidate the multi-scale degradation mechanisms of HTV-SR under the coupling effects of corona discharge, humidity and temperature cycling, providing theoretical support for the design of corona- and humidity-resistant silicone rubber for composite insulator applications. Full article
(This article belongs to the Special Issue Polyphase Insulation and Discharge in High-Voltage Technology)
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18 pages, 5113 KB  
Article
Theoretical Analysis and Experiments on the Sound Absorption Properties of Foam Sound Absorbers with Thin Membranes Naturally Present in Foams Using Nano-Computed Tomography Scan Images
by Shuichi Sakamoto, Takamasa Satoh, Kaito Tanabe, Koki Maruyama and Yusei Himori
Appl. Sci. 2025, 15(20), 11079; https://doi.org/10.3390/app152011079 - 16 Oct 2025
Viewed by 94
Abstract
Foam sound-absorbing materials develop a fine cellular structure during manufacturing, resulting in variations in porosity, cell size, and the proportion of naturally occurring thin membranes that obstruct skeletal openings. This membrane proportion significantly affects sound absorption. In this study, we utilized cross-sectional images [...] Read more.
Foam sound-absorbing materials develop a fine cellular structure during manufacturing, resulting in variations in porosity, cell size, and the proportion of naturally occurring thin membranes that obstruct skeletal openings. This membrane proportion significantly affects sound absorption. In this study, we utilized cross-sectional images obtained from a submicron resolution computer tomography (CT) scanner (nano-CT) that can capture membrane structures to theoretically assess the sound absorption of foam materials with membranes. We processed these cross-sectional images using techniques, including binarization, to extract the contours of the foam skeletons and the cross-sectional areas of the voids. By modeling the foam’s cross-section as the clearance between two planes, we were able to determine the propagation constant and characteristic impedance within this clearance. The effective density was adjusted based on measured tortuosity. The normal-incidence sound absorption coefficient (SAC), derived from the transfer matrix method, was then compared with experimental values obtained from a two-microphone impedance tube. Image processing techniques helped extract the skeleton cross-section and reduce residual noise, thereby minimizing the effect of variations in the binarization threshold on theoretical values. The accuracy of the theoretical model was enhanced by incorporating a correction factor for the skeleton surface area. Full article
(This article belongs to the Special Issue Advances in Architectural Acoustics and Vibration)
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18 pages, 6703 KB  
Article
Three-Dimensional Study of Contact Melting of a Molten Material Crust Against a Stainless Steel Plate During a Severe Reactor Accident
by Junjie Ma, Yuqing Chen, Wenzhen Chen and Hongguang Xiao
Processes 2025, 13(10), 3310; https://doi.org/10.3390/pr13103310 - 16 Oct 2025
Viewed by 198
Abstract
In severe reactor accidents, molten corium solidifies within the core to form a corium crust. Under decay heat, the high-temperature corium crust induces contact melting of internal reactor components. Given the narrow and limited dimensions of these components, this study investigated the contact [...] Read more.
In severe reactor accidents, molten corium solidifies within the core to form a corium crust. Under decay heat, the high-temperature corium crust induces contact melting of internal reactor components. Given the narrow and limited dimensions of these components, this study investigated the contact melting of a corium crust against a stainless steel plate. A three-dimensional plate contact melting model for plate-shaped corium is proposed, with its validity demonstrated through experimental verification. The patterns and factors influencing contact melting were analyzed. The results indicate that under constant heat flux boundary conditions, the melting rate depends solely on the magnitude of the heat flux density, while the effects of the contact surface geometry and heat source mass on the melting rate are negligible. The thickness of the molten liquid film is proportional to both the heat flux density and contact surface area, yet inversely proportional to both the heat source mass and aspect ratio of the contact surface. When the aspect ratio exceeds six, the model can be simplified to two dimensions. Full article
(This article belongs to the Section Energy Systems)
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29 pages, 6643 KB  
Article
Experimental and Machine Learning-Based Investigation on Forced Convection Heat Transfer Characteristics of Al2O3–Water Nanofluid in a Rotating Hypergravity Condition
by Zufen Luo, Gen Li, Jianxun Xie, Xiaojie Zhang, Yunbo Wang and Xiande Fang
Aerospace 2025, 12(10), 931; https://doi.org/10.3390/aerospace12100931 - 15 Oct 2025
Viewed by 182
Abstract
This study experimentally investigates single-phase forced convection heat transfer and flow characteristics of Al2O3-water nanofluids under rotating hypergravity conditions ranging from 1 g to 5.1 g. While nanofluids offer enhanced thermal properties for advanced cooling applications in aerospace and [...] Read more.
This study experimentally investigates single-phase forced convection heat transfer and flow characteristics of Al2O3-water nanofluids under rotating hypergravity conditions ranging from 1 g to 5.1 g. While nanofluids offer enhanced thermal properties for advanced cooling applications in aerospace and rotating machinery, their performance under hypergravity remains poorly understood. Experiments employed a custom centrifugal test rig with a horizontal test section (D = 2 mm, L = 200 mm) operating at constant heat flux. Alumina nanoparticles (20–30 nm) were dispersed in deionized water at mass fractions of 0.02–0.5 wt%, with stability validated through transmittance measurements over 72 h. Heat transfer coefficients (HTC), Nusselt numbers (Nu), friction factors (f), and pressure drops were measured across Reynolds numbers from 500 to 30,000. Results demonstrate that hypergravity significantly enhances heat transfer, with HTC increasing by up to 40% at 5.1 g compared to 1 g, most pronounced at the transition from 1 g to 1.41 g. This enhancement is attributed to intensified buoyancy-driven secondary flows quantified by increased Grashof numbers and modified particle distribution. Friction factors increased moderately (15–25%) due to Coriolis effects and enhanced viscous dissipation. Optimal performance occurred at 0.5 wt% concentration, effectively balancing thermal enhancement against pumping penalties. Random forest (RF) and eXtreme gradient boosting (XGBoost) achieved R2 = 0.9486 and 0.9625 in predicting HTC, respectively, outperforming traditional correlations (Gnielinski: R2 = 0.9124). These findings provide crucial design guidelines for thermal management systems in hypergravity environments, particularly for aerospace propulsion and centrifugal heat exchangers, where gravitational variations significantly impact cooling performance. Full article
(This article belongs to the Special Issue Advanced Thermal Management in Aerospace Systems)
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20 pages, 5603 KB  
Article
Research on the Influence Mechanism of Regulating Capacity and Flow Recession Process in the Karst Vadose Zone
by Ruitong Liu, Jinguo Wang, Shumei Zhu, Yuting Zhang, Shiyu Zheng, Yongsheng Zhao, Fei Qiao and Dong Yang
Water 2025, 17(20), 2976; https://doi.org/10.3390/w17202976 - 15 Oct 2025
Viewed by 194
Abstract
Understanding the groundwater movement patterns and regulating functions of the karst vadose zone is essential in addressing water scarcity and protecting the ecological environment in the karst area of southwest China. A laboratory-scale experimental model of a typical karst vadose zone was constructed [...] Read more.
Understanding the groundwater movement patterns and regulating functions of the karst vadose zone is essential in addressing water scarcity and protecting the ecological environment in the karst area of southwest China. A laboratory-scale experimental model of a typical karst vadose zone was constructed and used to simulate the water flow process under the influence of four factors: transfer zone thickness, surface slope, karstification degree, and rainfall intensity. A corresponding distributed model was subsequently developed to simulate the laboratory experiments. The discharge recession process, the regulating capacity, and the division of fast and slow flow were quantitatively analyzed by the recession coefficient, the regulating coefficient, and the percentage of fast flow and that of sinkhole flow. As the transfer zone thickness increases from 40 cm to 120 cm, the vadose zone regulating coefficient rises from 0.49 to 0.53, while fast flow decreases from 87.7% to 78.1%, indicating that the enhanced regulating capacity is mainly governed by the slow flow system. The evident difference in growth rates between the percentage of fast flow (an increase of 9.1%) and that of sinkhole flow (an increase of 48.7%) indicates that the decrease in regulating capacity resulting from an increase in surface slope is primarily due to enhanced water loss through sinkholes. When the structure of the karst vadose zone remains constant, the regulating coefficient decreases exponentially with increasing rainfall intensity and gradually approaches a constant value, which represents the maximum regulating capacity of the karst vadose zone under its current structural conditions. Full article
(This article belongs to the Special Issue Hydrogeological and Hydrochemical Investigations of Aquifer Systems)
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16 pages, 3146 KB  
Article
Predictive Control and Manufacturing of Rotation Accuracy of Angular Contact Ball Bearings (ACBBs)
by Chaojun Wang, Dongfeng Wang, Xiaofei Li, Huqiang Wang, Dengke Li, Gang Chen and Lai Hu
J. Manuf. Mater. Process. 2025, 9(10), 333; https://doi.org/10.3390/jmmp9100333 - 13 Oct 2025
Viewed by 210
Abstract
High-precision angular contact ball bearings (ACBBs) are critical components in advanced manufacturing equipment, where rotation accuracy directly determines system performance and stability. Considering error superposition and equipment processing capability comprehensively, this study establishes an error analysis and control model of the ACBBs, studies [...] Read more.
High-precision angular contact ball bearings (ACBBs) are critical components in advanced manufacturing equipment, where rotation accuracy directly determines system performance and stability. Considering error superposition and equipment processing capability comprehensively, this study establishes an error analysis and control model of the ACBBs, studies the error transmission law, and puts forward a rotation accuracy control strategy for batch manufacturing of precision ACBBs. The ACBBs 7020C/P4, 7020AC/P4, 7020A/P4, and 7020B/P4 (four conventional contact angles of 15°, 25°, 30°, 40°) were taken as examples to verify the experiment. The error of the calculation compared with actual test results was not more than 7.5%, which had good accuracy and practicability. The research shows that the roundness error of bearing raceway, the thickness difference in bearing ring wall, and the parallelism error of raceway to end face were the main influencing factors of bearing rotation accuracy Kia, Sia, Kea, and Sea. The influence coefficient of raceway roundness error on the axial runout of bearing (Sia, Sea) decreased rapidly with the increase in contact angle, while the influence coefficient on radial runout (Kia, Kea) remained constant. The rotation accuracy error of the outer ring was always greater than that of the inner ring, and this law was not affected by the contact angle. Moreover, with the increase in contact angle, the radial runout of the inner and outer rings of the bearing increased. During actual machining, bearings with larger contact angle place lower demands on the equipment process capability index (Cp), particularly on the parameter Cer. This reduction in required capability is equivalent to an effective Cp improvement of about 30%. Full article
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22 pages, 81961 KB  
Article
Synergistic Regulation of Vegetation Greening and Climate Change on the Changes in Evapotranspiration and Its Components in the Karst Area of China
by Geyu Zhang, Qiaotian Shen, Zijun Wang, Hao Li, Zongsen Wang, Tingyi Xue, Dangjun Wang, Haijing Shi, Yangyang Liu and Zhongming Wen
Agronomy 2025, 15(10), 2375; https://doi.org/10.3390/agronomy15102375 - 11 Oct 2025
Viewed by 241
Abstract
The fragile karst ecosystem in Southwest China faces severe water scarcity. Since 2000, large-scale ecological restoration programs (e.g., the “Grain for Green” Program) have substantially increased vegetation coverage. Concurrently, climate change has manifested as a distinct warming trend and heightened drought risk in [...] Read more.
The fragile karst ecosystem in Southwest China faces severe water scarcity. Since 2000, large-scale ecological restoration programs (e.g., the “Grain for Green” Program) have substantially increased vegetation coverage. Concurrently, climate change has manifested as a distinct warming trend and heightened drought risk in recent decades. Therefore, understanding the synergistic and competing effects of climate change and vegetation restoration on regional evapotranspiration (ET) is critical for projecting water budgets and ensuring the sustainability of ecosystems and water resources within this vital ecological barrier region. This study employs a dual-scenario PT-JPL model (simulating natural vegetation dynamics versus constant coverage) integrated with Sen + MK trend analysis to quantify the spatiotemporal patterns of ET and its components—canopy transpiration (ETc), interception evaporation (ETi), and soil evaporation (ETs)—in Southwest China’s karst region (2000–2018). Furthermore, multiple regression analysis and SEM were utilized to investigate the driving mechanisms of vegetation and climatic factors (temperature, precipitation, radiation, and relative humidity) on changes in ET and its components. The key results demonstrate the following: (1) Vegetation restoration exerted a net positive effect on total ET (+0.44 mm/a) through enhanced ETi (+0.22 mm/a) and ETs (+0.37 mm/a), despite reducing ETc (−0.08 mm/a), revealing trade-offs in water allocation. (2) Radiation dominated ET variability (66.45% of the area exhibiting >50% contribution), while temperature exhibited the most extensive spatial dominance (44.02% of the region), and relative humidity exhibited drought-mediated dual effects (promoting ETi while suppressing ETc). (3) Precipitation exhibited minimal direct influence. Vegetation restoration and climate change collectively drive ET dynamics, with ETc declines indicating potential water stress. These findings elucidate the synergistic regulation of vegetation restoration and climate change on karst ecohydrology, providing critical insights for water resource management in fragile ecosystems globally. Full article
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17 pages, 3396 KB  
Article
Determinants of Odor-Related Perception: Analysis of Community Response
by Franciele Ribeiro Cavalcante, Milena Machado, Valdério Anselmo Reisen, Bruno Furieri, Elisa Valentim Goulart, Antonio Ponce de Leon, Neyval Costa Reis, Séverine Frère and Jane Meri Santos
Atmosphere 2025, 16(10), 1176; https://doi.org/10.3390/atmos16101176 - 11 Oct 2025
Viewed by 252
Abstract
This study intends to identify and quantify the individual, perceptual, and contextual factors associated with odor-related perception and to assess the perception of odor sources according to meteorological conditions. Two face-to-face seasonal community surveys were conducted using stratified random sampling with proportional allocation, [...] Read more.
This study intends to identify and quantify the individual, perceptual, and contextual factors associated with odor-related perception and to assess the perception of odor sources according to meteorological conditions. Two face-to-face seasonal community surveys were conducted using stratified random sampling with proportional allocation, yielding representative samples of residents in a southern Brazilian city, where mild constant temperatures throughout the year and shifting prevailing wind directions expose residents to different odor sources. Chi-Square tests were applied to assess associations between odor perception and qualitative variables, while logistic regression was used to identify predictors of higher annoyance. Results showed that prevailing wind direction influenced source attribution, with steel industry and sewage-related sites most frequently cited. Proximity to the steel plant increased both source recognition and annoyance levels. Reported impacts included closing windows and reducing outdoor activities. Self-reported respiratory problems consistently predicted higher annoyance levels in both surveys. The statistical methods were effective in analyzing the likelihood of odor-related perception and its relationship with explanatory variables. These findings highlight the value of a data-driven approach—specifically, integrating wind direction, source proximity, and community-based perception—to support urban environmental management and guide odor mitigation strategies. Full article
(This article belongs to the Special Issue Atmospheric Pollutants: Monitoring and Observation (2nd Edition))
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27 pages, 3885 KB  
Article
Experimental and Machine Learning-Based Assessment of Fatigue Crack Growth in API X60 Steel Under Hydrogen–Natural Gas Blending Conditions
by Nayem Ahmed, Ramadan Ahmed, Samin Rhythm, Andres Felipe Baena Velasquez and Catalin Teodoriu
Metals 2025, 15(10), 1125; https://doi.org/10.3390/met15101125 - 10 Oct 2025
Viewed by 453
Abstract
Hydrogen-assisted fatigue cracking presents a critical challenge to the structural integrity of legacy carbon steel natural gas pipelines being repurposed for hydrogen transport, posing a major barrier to the deployment of hydrogen infrastructure. This study systematically evaluates the fatigue crack growth (FCG) behavior [...] Read more.
Hydrogen-assisted fatigue cracking presents a critical challenge to the structural integrity of legacy carbon steel natural gas pipelines being repurposed for hydrogen transport, posing a major barrier to the deployment of hydrogen infrastructure. This study systematically evaluates the fatigue crack growth (FCG) behavior of API 5L X60 pipeline steel under varying hydrogen–natural gas (H2–NG) blending conditions to assess its suitability for long-term hydrogen service. Experiments are conducted using a custom-designed autoclave to replicate field-relevant environmental conditions. Gas mixtures range from 0% to 100% hydrogen by volume, with tests performed at a constant pressure of 6.9 MPa and a temperature of 25 °C. A fixed loading frequency of 8.8 Hz and load ratio (R) of 0.60 ± 0.1 are applied to simulate operational fatigue loading. The test matrix is designed to capture FCG behavior across a broad range of stress intensity factor values (ΔK), spanning from near-threshold to moderate levels consistent with real-world pipeline pressure fluctuations. The results demonstrate a clear correlation between increasing hydrogen concentration and elevated FCG rates. Notably, at 100% hydrogen, API X60 specimens exhibit crack propagation rates up to two orders of magnitude higher than those in 0% hydrogen (natural gas) conditions, particularly within the Paris regime. In the lower threshold region (ΔK ≈ 10 MPa·√m), the FCG rate (da/dN) increased nonlinearly with hydrogen concentration, indicating early crack activation and reduced crack initiation resistance. In the upper Paris regime (ΔK ≈ 20 MPa·√m), da/dNs remained significantly elevated but exhibited signs of saturation, suggesting a potential limiting effect of hydrogen concentration on crack propagation kinetics. Fatigue life declined substantially with hydrogen addition, decreasing by ~33% at 50% H2 and more than 55% in pure hydrogen. To complement the experimental investigation and enable predictive capability, a modular machine learning (ML) framework was developed and validated. The framework integrates sequential models for predicting hydrogen-induced reduction of area (RA), fracture toughness (FT), and FCG rate (da/dN), using CatBoost regression algorithms. This approach allows upstream degradation effects to be propagated through nested model layers, enhancing predictive accuracy. The ML models accurately captured nonlinear trends in fatigue behavior across varying hydrogen concentrations and environmental conditions, offering a transferable tool for integrity assessment of hydrogen-compatible pipeline steels. These findings confirm that even low-to-moderate hydrogen blends significantly reduce fatigue resistance, underscoring the importance of data-driven approaches in guiding material selection and infrastructure retrofitting for future hydrogen energy systems. Full article
(This article belongs to the Special Issue Failure Analysis and Evaluation of Metallic Materials)
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13 pages, 354 KB  
Article
Holographic Thermodynamics of Higher-Dimensional AdS Black Holes with CFT Rescaling
by Yahya Ladghami and Taoufik Ouali
Universe 2025, 11(10), 337; https://doi.org/10.3390/universe11100337 - 10 Oct 2025
Viewed by 247
Abstract
In this paper, we study the thermodynamic behavior of charged AdS black holes in higher-dimensional spacetimes within the framework of conformal holographic extended thermodynamics. This formalism is based on a novel AdS/CFT dictionary in which the conformal rescaling factor of the boundary conformal [...] Read more.
In this paper, we study the thermodynamic behavior of charged AdS black holes in higher-dimensional spacetimes within the framework of conformal holographic extended thermodynamics. This formalism is based on a novel AdS/CFT dictionary in which the conformal rescaling factor of the boundary conformal field theory (CFT) is treated as a thermodynamic parameter, while Newton’s constant is held fixed and the AdS radius is allowed to vary. We explore how variations in the CFT state, represented by its central charge, influence the bulk thermodynamics, phase structure, and stability of black holes in five and six dimensions. Our analysis reveals the emergence of Van der Waals-like phase transitions, critical phenomena governed by the central charge. Additionally, we find that the thermodynamic behavior of AdS black holes is affected by the dimensionality of the bulk spacetime, as we compare higher-dimensional black holes to lower-dimensional ones, such as the BTZ black holes. These findings provide new insights into the role of boundary degrees of freedom in shaping the thermodynamics of gravitational systems via holography. Full article
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16 pages, 374 KB  
Article
An Extended Complex Method to Solve the Predator–Prey Model
by Hongqiang Tu and Guoqiang Dang
Axioms 2025, 14(10), 758; https://doi.org/10.3390/axioms14100758 - 10 Oct 2025
Viewed by 222
Abstract
Through transformation and utilizing a novel extended complex method combining with the Weierstrass factorization theorem, Wiman–Valiron theory and the Painlevé test, new non-constant meromorphic solutions were constructed for the predator–prey model. These meromorphic solutions contain the rational solutions, exponential solutions, elliptic solutions, and [...] Read more.
Through transformation and utilizing a novel extended complex method combining with the Weierstrass factorization theorem, Wiman–Valiron theory and the Painlevé test, new non-constant meromorphic solutions were constructed for the predator–prey model. These meromorphic solutions contain the rational solutions, exponential solutions, elliptic solutions, and transcendental entire function solutions of infinite order in the complex plane. The exact solutions contribute to understanding the predator–prey model from the perspective of complex differential equations. In fact, the presented synthesis method provides a new technology for studying some systems of partial differential equations. Full article
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20 pages, 6683 KB  
Article
Numerical Simulation Study on Shear Mechanical Properties of Unfilled Three-Dimensional Rough Joint Surfaces Under Constant Normal Stiffness Boundary Conditions
by Xinmu Xu, Kui Zhao, Liangfeng Xiong, Peng Zeng, Cong Gong and Yifan Chen
Appl. Sci. 2025, 15(19), 10827; https://doi.org/10.3390/app151910827 - 9 Oct 2025
Viewed by 171
Abstract
When jointed rock masses are in a high-stress environment, the roughness of the joints is the key factor controlling their shear strength. Their loading behavior is also different from the constant normal load (CNL) conditions controlled in conventional laboratories; rather, they follow the [...] Read more.
When jointed rock masses are in a high-stress environment, the roughness of the joints is the key factor controlling their shear strength. Their loading behavior is also different from the constant normal load (CNL) conditions controlled in conventional laboratories; rather, they follow the constant normal stiffness (CNS) conditions. To investigate the effects of normal stiffness and roughness on the shear mechanical properties of unfilled joint surfaces, shear tests were simulated using PFC3D (5.0) software under CNS conditions. The effects of normal stiffness of 0 (constant normal stress of 4 MPa), 0.028 GPa/m (low normal stiffness), 0.28 GPa/m (medium normal stiffness), and 2.8 GPa/m (high normal stiffness), and joint roughness coefficients (JRC) of 2~4 (low roughness), 10~12 (medium roughness), and 18~20 (high roughness) on the shear stress, normal stress, normal deformation, surface resistance index, and block failure characteristics of the joint surface were obtained. The results indicate that for different combinations of normal stiffness—JRC—the shear simulation process primarily exhibits three deformation stages: linear stage, yield stage, and post-peak stage. Shear stress increases initially and then decreases as shear displacement increases. When normal stiffness is no less than 0.28 GPa/m, both normal stress and JRC increase gradually with increasing JRC and normal stiffness. When the normal stiffness is no greater than 0.028 GPa/m, the normal stress shows no significant change. The normal displacement changes from “shear contraction” to “shear expansion” with increasing shear displacement and from positive to negative values while the displacement gradually increases; the maximum normal displacement decreases with increasing normal stiffness and increases with increasing JRC. The peak SRI value increases with increasing JRC and decreases with increasing normal stiffness. As normal stiffness increases, the number of tensile cracks for JRC 2~4 first decreases and then increases, while the number of shear cracks gradually increases; for JRC 10~12 and 18~20, both the number of shear cracks and tensile cracks increase with increasing normal stiffness. This paper simulates the actual mechanical environment of deep underground joints to expound the influence of normal stiffness and joint roughness on the stability of deep rock masses. The research results can provide certain theoretical references for predicting the stability of deep surrounding rocks and the stress of support structures. Full article
(This article belongs to the Section Earth Sciences)
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