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19 pages, 15854 KiB  
Article
Failure Analysis of Fire in Lithium-Ion Battery-Powered Heating Insoles: Case Study
by Rong Yuan, Sylvia Jin and Glen Stevick
Batteries 2025, 11(7), 271; https://doi.org/10.3390/batteries11070271 - 17 Jul 2025
Viewed by 369
Abstract
This study investigates a lithium-ion battery failure in heating insoles that ignited during normal walking while powered off. Through comprehensive material characterization, electrical testing, thermal analysis, and mechanical gait simulation, we systematically excluded electrical or thermal abuse as failure causes. X-ray/CT imaging localized [...] Read more.
This study investigates a lithium-ion battery failure in heating insoles that ignited during normal walking while powered off. Through comprehensive material characterization, electrical testing, thermal analysis, and mechanical gait simulation, we systematically excluded electrical or thermal abuse as failure causes. X-ray/CT imaging localized the ignition source to the lateral heel edge of the pouch cell, correlating precisely with peak mechanical stress identified through gait analysis. Remarkably, the cyclic load was less than 10% of the single crush load threshold specified in safety standards. Key findings reveal multiple contributing factors as follows: the uncoated polyethylene separator’s inability to prevent stress-induced internal short circuits, the circuit design’s lack of battery health monitoring functionality that permitted undetected degradation, and the hazardous placement inside clothing that exacerbated burn injuries. These findings necessitate a multi-level safety framework for lithium-ion battery products, encompassing enhanced cell design to prevent internal short circuit, improved circuit protection with health monitoring capabilities, optimized product integration to mitigate mechanical and environmental impact, and effective post-failure containment measures. This case study exposes a critical need for product-specific safety standards that address the unique demands of wearable lithium-ion batteries, where existing certification requirements fail to prevent real-use failure scenarios. Full article
(This article belongs to the Section Battery Performance, Ageing, Reliability and Safety)
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9 pages, 212 KiB  
Communication
Are Mitochondria the True Origin of Cancer? A Hypothesis-Driven Perspective
by Sergio Da Silva
Onco 2025, 5(3), 32; https://doi.org/10.3390/onco5030032 - 1 Jul 2025
Viewed by 450
Abstract
Conventional wisdom holds that nuclear oncogenes and tumor suppressors initiate malignant transformation. However, mounting research suggests that mitochondrial dysfunction—rooted in the unique evolutionary history and genetic autonomy of mitochondria—may serve as a more fundamental driver of oncogenesis. This paper proposes a “mitochondria-first” hypothesis [...] Read more.
Conventional wisdom holds that nuclear oncogenes and tumor suppressors initiate malignant transformation. However, mounting research suggests that mitochondrial dysfunction—rooted in the unique evolutionary history and genetic autonomy of mitochondria—may serve as a more fundamental driver of oncogenesis. This paper proposes a “mitochondria-first” hypothesis of cancer, emphasizing the pivotal role of mitochondrial DNA (mtDNA) mutations, metabolic reprogramming, and immune evasion. By examining the evolutionary conflict between host and mitochondria, evaluating high mtDNA mutation rates, and highlighting the disruptive potential of mitochondrial transfer to immune cells, we outline robust mechanisms through which mitochondria could ignite cancer development. We also discuss emerging diagnostic and therapeutic approaches that target mitochondrial integrity, offering a potential paradigm shift in oncology. Full article
(This article belongs to the Special Issue The Evolving Landscape of Contemporary Cancer Therapies)
18 pages, 6782 KiB  
Article
Preparation, Reaction Kinetics, and Properties of Polyester Foams Using Water Produced by the Reaction as a Foaming Agent
by Fabian Weitenhagen and Oliver Weichold
Polymers 2025, 17(9), 1266; https://doi.org/10.3390/polym17091266 - 6 May 2025
Viewed by 576
Abstract
This study explores sustainable foamed polyester materials derived from natural or bio-based building blocks, including succinic, glutaric, and adipic acids, combined with trimethylolpropane and pentaerythritol. By precisely tuning the ratio of functional groups, the resulting polymers contain minimal free functionalities, leading to lower [...] Read more.
This study explores sustainable foamed polyester materials derived from natural or bio-based building blocks, including succinic, glutaric, and adipic acids, combined with trimethylolpropane and pentaerythritol. By precisely tuning the ratio of functional groups, the resulting polymers contain minimal free functionalities, leading to lower hygroscopicity and enhanced stability. The reaction is monitored by tracking the mass loss associated with water formation, the primary condensation by-product, which reveals a first-order kinetic behaviour. Infrared spectroscopy indicates that foaming occurs in a narrow time window, while esterification begins earlier and continues afterwards. Thermogravimetric analysis confirms thermal stability up to ~400 °C, with complete decomposition at 500 °C and no residue. Scanning electron microscopy images of test specimens with varying densities reveal dense, microporosity-free cell walls in both materials, indicating a homogeneous polymer matrix that contributes to the overall stabilisation of the foam structure. In flammability tests, the foams resist ignition during two 10 s methane flame exposures and, under prolonged flame, burn 40 times more slowly than conventional foams. These results demonstrate a modular system for creating bio-based foams with tunable properties—from soft and elastic to rigid—suitable for diverse applications. The materials offer a sustainable alternative to petrochemical foams while retaining excellent mechanical and thermal properties. Full article
(This article belongs to the Special Issue Designing Polymers for Emerging Applications)
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23 pages, 4424 KiB  
Article
Operational Conditions for an Internal Combustion Engine in a SOFC-ICE Hybrid Power Generation System
by Victor A. Reyes-Flores, Zachary Swartwout, Shane Garland, Daniel B. Olsen, Bret Windom, Robert Braun and Todd Bandhauer
Energies 2025, 18(7), 1838; https://doi.org/10.3390/en18071838 - 5 Apr 2025
Cited by 2 | Viewed by 576
Abstract
Hybrid power generation systems utilizing pressurized Solid Oxide Fuel Cells (SOFCs) have gained considerable attention recently as an effective solution to the increasing demand for cleaner electricity sources. Among the various hybridization options, gas turbines (GT) and internal combustion engines (ICE) running on [...] Read more.
Hybrid power generation systems utilizing pressurized Solid Oxide Fuel Cells (SOFCs) have gained considerable attention recently as an effective solution to the increasing demand for cleaner electricity sources. Among the various hybridization options, gas turbines (GT) and internal combustion engines (ICE) running on SOFC tail gas have been prominent. Although spark ignition (SI) tail gas engines have received less focus, they show significant potential for stationary power generation, particularly due to their ability to control combustion. This research experimentally characterized an SI engine fueled by simulated SOFC anode gas for five blends, which correspond to overall system power level and loads. The study aimed to optimize the engine operating conditions for each fuel blend and establish operational conditions that would sustain maximum performance. The results showed efficiencies as high as 31.4% at 1600 RPM, with a 17:1 compression ratio, equivalence ratio (φ) of 0.75, and a boost pressure of 165 kPa with low NOx emissions. The study also emphasizes the benefits of optimizing boost supply to minimize parasitic loads and improve brake thermal efficiency. Additionally, installing a catalytic oxidizer would enable the system to comply with new engine emission regulations. A proposed control scheme for automation includes regulating engine power by controlling the boost of the supercharger at a fixed throttle position. The results of this study help to promote the development of this SOFC-based clean energy technology. Full article
(This article belongs to the Special Issue Engine Combustion Characteristics, Performance, and Emission)
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28 pages, 9044 KiB  
Article
Strategies to Increase Hydrogen Energy Share of a Dual-Fuel Hydrogen–Kerosene Engine for Sustainable General Aviation
by Christian Reitmayr and Peter Hofmann
Hydrogen 2025, 6(1), 17; https://doi.org/10.3390/hydrogen6010017 - 19 Mar 2025
Cited by 1 | Viewed by 2022
Abstract
Reducing CO2 emissions in general aviation is a critical challenge, where battery electric and fuel cell technologies face limitations in energy density, cost, and robustness. As a result, hydrogen (H2) dual-fuel combustion is a promising alternative, but its practical implementation [...] Read more.
Reducing CO2 emissions in general aviation is a critical challenge, where battery electric and fuel cell technologies face limitations in energy density, cost, and robustness. As a result, hydrogen (H2) dual-fuel combustion is a promising alternative, but its practical implementation is constrained by abnormal combustion phenomena such as knocking and pre-ignition, which limit the achievable H2 energy share. In response to these challenges, this paper focuses on strategies to mitigate these irregular combustion phenomena while effectively increasing the H2 energy share. Experimental evaluations were conducted on an engine test bench using a one-cylinder dual-fuel H2 kerosene (Jet A-1) engine, utilizing two strategies, including water injection (WI) and rising the air–fuel ratio (AFR) by increasing the boost pressure. Additionally, crucial combustion characteristics and emissions are examined and discussed in detail, contributing to a comprehensive understanding of the outcomes. The results indicate that these strategies notably increase the maximal possible hydrogen energy share, with potential benefits for emissions reduction and efficiency improvement. Finally, through the use of 0D/1D simulations, this paper offers critical thermodynamic and efficiency loss analyses of the strategies, enhancing the understanding of their overall impact. Full article
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9 pages, 4387 KiB  
Proceeding Paper
Designing and Testing of HDPE–N2O Hybrid Rocket Engine
by Triyan Pal Arora, Noah Buttrey, Peter Kirman, Sanmukh Khadtare, Eeshaan Kamath, Dario del Gatto and Adriano Isoldi
Eng. Proc. 2025, 90(1), 34; https://doi.org/10.3390/engproc2025090034 - 13 Mar 2025
Viewed by 680
Abstract
Hybrid Rocket Engines (HREs) combine the advantages of solid and liquid propellants, offering thrust control, simplicity, safety, and cost efficiency. Part of the research on this rocket architecture focuses on optimising combustion chamber design to enhance performance, a process traditionally reliant on time-consuming [...] Read more.
Hybrid Rocket Engines (HREs) combine the advantages of solid and liquid propellants, offering thrust control, simplicity, safety, and cost efficiency. Part of the research on this rocket architecture focuses on optimising combustion chamber design to enhance performance, a process traditionally reliant on time-consuming experimental adjustments to chamber lengths. In this study, two configurations of HREs were designed and tested. The tests aimed to study the impact of post-chamber lengths on rocket engine performance by experimental firings on a laid-back test engine. This study focused on designing, manufacturing, and testing a laid-back hybrid engine with two chamber configurations. The engine features a small combustion chamber, an L-shaped mount, a spark ignition, and nitrogen purging. Data acquisition includes thermocouples, pressure transducers, and a load cell for thrust measurement. Our experimental findings provide insights into thrust, temperature gradients, pressure, and plume characteristics. A non-linear regression model derived from the experimental data established an empirical relationship between performance and chamber lengths, offering a foundation for further combustion flow studies. The post-chamber length positively impacted the engine thrust performance by 2.7%. Conversely, the pre-chamber length negatively impacted the performance by 1.3%. Further data collection could assist in refining the empirical relation and identifying key threshold values. Full article
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19 pages, 4550 KiB  
Article
Research on the Fire Risk of Photovoltaic DC Fault Arcs Based on Multiphysical Field Simulation
by Zhenhua Xie, Linming Hou, Puquan He, Wenxin Hu, Yao Wang and Dejie Sheng
Energies 2025, 18(6), 1396; https://doi.org/10.3390/en18061396 - 12 Mar 2025
Viewed by 665
Abstract
With the rapid growth of photovoltaic power generation systems, fire incidents within the system have progressively increased. The lack of thorough studies on the temperature properties of direct current (DC) arc faults has resulted in an unclear ignition mechanism, significantly increasing the fire [...] Read more.
With the rapid growth of photovoltaic power generation systems, fire incidents within the system have progressively increased. The lack of thorough studies on the temperature properties of direct current (DC) arc faults has resulted in an unclear ignition mechanism, significantly increasing the fire risk associated with such faults. Hence, this work presents a proposed experimental scheme for detecting photovoltaic DC series arc faults (SAFs) and the corresponding detection standards. Additionally, the temperature characteristics of the DC arc fault are further analyzed. The magnetohydrodynamic (MHD) arc fault simulation model is developed to investigate the temperature-related aspects of photovoltaic DC arc faults. Finally, our experimental validation confirms the precision of the model in simulating arc temperature. It is verified that the research presented in this paper can provide a good explanation for the rise time of DC arc temperature and the characteristic distribution of arc distance. This study elucidates the impact mechanism of line current, power supply voltage, and arc gap size on arc temperature in a photovoltaic system. Additionally, it proposes an evaluation method for assessing the arc fault ignition risk level. This method is essential for safeguarding against arc fault ignition risk in photovoltaic DC series cells. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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24 pages, 1339 KiB  
Article
Bridging Neuroscience and Machine Learning: A Gender-Based Electroencephalogram Framework for Guilt Emotion Identification
by Saima Raza Zaidi, Najeed Ahmed Khan and Muhammad Abul Hasan
Sensors 2025, 25(4), 1222; https://doi.org/10.3390/s25041222 - 17 Feb 2025
Viewed by 976
Abstract
This study explores the link between the emotion “guilt” and human EEG data, and investigates the influence of gender differences on the expression of guilt and neutral emotions in response to visual stimuli. Additionally, the stimuli used in the study were developed to [...] Read more.
This study explores the link between the emotion “guilt” and human EEG data, and investigates the influence of gender differences on the expression of guilt and neutral emotions in response to visual stimuli. Additionally, the stimuli used in the study were developed to ignite guilt and neutral emotions. Two emotions, “guilt” and “neutral”, were recorded from 16 participants after these emotions were induced using storyboards as pictorial stimuli. These storyboards were developed based on various guilt-provoking events shared by another group of participants. In the pre-processing step, collected data were de-noised using bandpass filters and ICA, then segmented into smaller sections for further analysis. Two approaches were used to feed these data to the SVM classifier. First, the novel approach employed involved feeding the data to SVM classifier without computing any features. This method provided an average accuracy of 83%. In the second approach, data were divided into Alpha, Beta, Gamma, Theta and Delta frequency bands using Discrete Wavelet Decomposition. Afterward, the computed features, including entropy, Hjorth parameters and Band Power, were fed to SVM classifiers. This approach achieved an average accuracy of 63%. The findings of both classification methodologies indicate that females are more expressive in response to depicted stimuli and that their brain cells exhibit higher feature values. Moreover, females displayed higher accuracy than males in all bands except the Delta band. Full article
(This article belongs to the Section Intelligent Sensors)
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14 pages, 3845 KiB  
Article
Efficient Purification of Auto-Exhaust Soot Particles Using Hexagonal Fe2O3 Nanosheets Decorated with Non-Noble Metals (Ni)
by Haoqi Guo, Jing Xiong, Peng Zhang, Jian Liu, Zhen Zhao and Yuechang Wei
Nanomaterials 2025, 15(3), 233; https://doi.org/10.3390/nano15030233 - 1 Feb 2025
Viewed by 841
Abstract
Purification of soot particles from automobile exhaust has closely to do with the synergistic effect between catalyst metals. Here, several binary Ni-Fe oxide catalysts were elaborately prepared via a modified solvothermal method. A non-noble-metal (Ni)-modified hexagonal Fe2O3 nano-sheet catalyst (Ni−Fe [...] Read more.
Purification of soot particles from automobile exhaust has closely to do with the synergistic effect between catalyst metals. Here, several binary Ni-Fe oxide catalysts were elaborately prepared via a modified solvothermal method. A non-noble-metal (Ni)-modified hexagonal Fe2O3 nano-sheet catalyst (Ni−Fe2O3) was prepared. The introduced heteroatoms replace some of the Fe atoms, which take up the surface of the [FeO6] octahedron, and the synergistic effect formed between the heteroatoms which are on the surface and the adjacent Fe atoms promotes the formation of coordination unsaturated ions of the activated reactants. The optimal performance was obtained with the Ni-Fe2O3-20 composition, with catalytic soot oxidation resulting in T50, SCO2m, Ea and TOF of 366 °C, 99.1%, 72.7 kJ mol−1 and 0.156 min−1 (at 310 °C), respectively. The combination of Ni and Fe2O3 cells increases the ratio of Fe3+/Fe2+, making the interaction among electrons between the Ni, which was proved highly dispersed over the catalyst, and the Fe2O3 strong. Both exist on the catalyst surface in the form of NiFe2O4. Ni atoms and Fe2O3, which demonstrate a synergistic effect, promoting the formation of coordination unsaturated ions of the activated reactants and generating more oxygen vacancies, thus promoting the adsorption of NO and accelerating the ignition of soot in O2 at a low temperature. The novel Ni-Fe2O3-X oxide cocatalyst is an improved noble-free catalyst that promotes the synergistic effect between heteroatoms and metal oxides through surface regulation. This is of great significance for the further development of economic and efficient catalysts for soot particle removal from automobile exhaust. Full article
(This article belongs to the Special Issue Nanostructures for Enhanced Catalytic Activity)
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20 pages, 5507 KiB  
Article
Features of Hydrogen-Enriched Methane–Air Flames Propagating in Hele-Shaw Channels
by Sergey Yakush, Sergey Rashkovskiy, Maxim Alexeev and Oleg Semenov
Energies 2025, 18(2), 335; https://doi.org/10.3390/en18020335 - 14 Jan 2025
Viewed by 1302
Abstract
Mixtures of hydrogen with common hydrocarbon fuels are considered viable for reducing carbon footprint in modern industry, power production, and transportation. The addition of hydrogen alters the kinetics and thermophysical properties of the mixtures, as well as the composition and properties of combustion [...] Read more.
Mixtures of hydrogen with common hydrocarbon fuels are considered viable for reducing carbon footprint in modern industry, power production, and transportation. The addition of hydrogen alters the kinetics and thermophysical properties of the mixtures, as well as the composition and properties of combustion products, requiring detailed research into the features of flame propagation in hydrogen-enriched hydrocarbon–air mixtures. Of particular interest are also the safety aspects of such fuels. In this paper, experimental results are presented on the premixed laminar flame propagation in channels formed by two closely spaced plates (Hele-Shaw cell), with the internal straight walls forming a diverging (diffuser) channel with the opening angles between 5 and 25 degrees. Methane–hydrogen–air mixtures with the hydrogen relative contents of 0%, 25%, and 50% and global equivalence ratio of unity were ignited by a spark near the closed narrow end of the channel. Experiments were performed with the gap width of 3.5 mm; video recordings were processed in order to determine the quantitative features of the flame front propagation (leading and trailing point coordinate, coordinates of the cusps, cell sizes and shapes). The main features of flame propagation (fast initial expansion, development of cellular flame, self-induced longitudinal oscillations) are obtained and compared to clarify the effect of hydrogen contents in the fuel and channel geometry (gap width, opening angle). Full article
(This article belongs to the Special Issue Advanced Studies on Clean Hydrogen Energy Systems of the Future)
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14 pages, 11889 KiB  
Article
Thermal Propagation Test Bench for the Study of the Paschen Curve and Lightning Arcs of Venting Gas
by Björn Mulder, Kai Peter Birke, Björn Obry, Stefan Wigger, Ruslan Kozakov, Pavel Smirnov and Jochen Schein
Batteries 2024, 10(11), 397; https://doi.org/10.3390/batteries10110397 - 8 Nov 2024
Viewed by 1980
Abstract
Thermal propagation events are characterized by fire and thick black smoke, leading to propagation methods with a focus on preventing heat transfer and optimizing gas flow. Yet little attention is being paid to the electric conductivity of the gas, leading to possibly unexpected [...] Read more.
Thermal propagation events are characterized by fire and thick black smoke, leading to propagation methods with a focus on preventing heat transfer and optimizing gas flow. Yet little attention is being paid to the electric conductivity of the gas, leading to possibly unexpected battery casing openings due to lightning arcs as well as potentially providing the minimum ignition energy. This gas composition (omitting particles) was used at different temperatures and pressures in a lightning arc test bench, leading to the Paschen curve. Using a mini-module cell setup, filtered venting gas was flowed through another lightning arc test bench, allowing for in situ measurements. Full article
(This article belongs to the Special Issue Advances in Lithium-Ion Battery Safety and Fire)
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18 pages, 4926 KiB  
Article
The Influence of Helium Addition on the Combustion Process in a Hydrogen-Fueled Turbulent Jet Ignition Engine
by Dawid Mielcarzewicz and Ireneusz Pielecha
Appl. Sci. 2024, 14(19), 8996; https://doi.org/10.3390/app14198996 - 6 Oct 2024
Cited by 1 | Viewed by 1623
Abstract
There are considerably fewer requirements for the quality of hydrogen combusted in an engine than its quality for fuel cells. Therefore, the analysis was carried out on the combustion of hydrogen–helium mixtures in an engine with a two-stage combustion system (TJI—Turbulent Jet Ignition). [...] Read more.
There are considerably fewer requirements for the quality of hydrogen combusted in an engine than its quality for fuel cells. Therefore, the analysis was carried out on the combustion of hydrogen–helium mixtures in an engine with a two-stage combustion system (TJI—Turbulent Jet Ignition). A single-cylinder research engine with a passive and active prechamber was used. A hydrogen–helium mixture was supplied to the main chamber in proportions of 100:0, 90:10, 80:20, 30:70, and 60:40 volume fractions. The prechamber was fueled only with pure hydrogen. Combustion was carried out in the lean charge range (λ = 1.5–3) and at a constant value of the Center of Combustion (CoC = 8–10 deg aTDC). It was found that the helium concentration in the mixture affected the changes in combustion pressure, heat release rate and the amount of heat release. It was observed that increasing the proportion of helium in the mixture by 10% also reduces the IMEP by approximately 10% and reduces the rate of heat release by approximately 20%. In addition, helium influences knock combustion. Limits of MAPO = 1 bar mean assumed that knock combustion occurs in the main chamber at values of λ < 1.9. Increasing the excess air ratio results in a gradual reduction in the temperature of the exhaust gas, which has a very rapid effect on changes in the concentration of nitrogen oxides. Studies carried out on the helium addition in hydrogen fuel indicate that it is possible to use such blends with a partial deterioration of the thermodynamic properties of the two-stage combustion process. Full article
(This article belongs to the Special Issue Sustainable Alternative Fuels and Advanced Combustion Techniques)
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13 pages, 5765 KiB  
Article
The Characteristics of the Electro-Thermo-Convective Flow of a Dielectric Liquid Analyzed through the Electric Nusselt Number
by Dantchi Koulova, Philippe Traore and Hubert Romat
Fluids 2024, 9(10), 233; https://doi.org/10.3390/fluids9100233 - 3 Oct 2024
Cited by 1 | Viewed by 890
Abstract
This paper presents a fundamental study of electro-thermo-convective flows within a layer of dielectric liquid subjected to both an electric field and a thermal gradient. A low-conductivity liquid enclosed between two horizontal electrodes and subjected to unipolar charge injection is considered. The interplay [...] Read more.
This paper presents a fundamental study of electro-thermo-convective flows within a layer of dielectric liquid subjected to both an electric field and a thermal gradient. A low-conductivity liquid enclosed between two horizontal electrodes and subjected to unipolar charge injection is considered. The interplay between electric and thermal fields ignites complex physical interactions within the flows, all governed by a set of coupled electro-thermo-hydrodynamic equations. These equations include Maxwell, Navier–Stokes, and energy equations and are solved numerically using an in-house code based on the finite volume method. Electro-thermo-convective flows are driven by two dimensionless instability criteria: Rayleigh number Ra and the stability parameter T, and also by the dimensionless mobility parameter M and Prandtl number Pr. The electric Nusselt number (Ne) analogue to the Nusselt number (Nu) in pure thermal problems serves as an indicator to monitor the shift from a thermo- to an electro-convective flow and its eventual evolution into unsteady, and, later, chaotic flow. This change in regime is observed by tracking the electric Nusselt number’s behavior as a function of the stability parameter (T), for different values of the non-dimensional parameters (M, Ra, and Pr). The important role of mobility parameter M for the development of the flow is shown. The flow structure during different development stages in terms of the number of convective cells is also discussed. Full article
(This article belongs to the Special Issue Advances in Electrohydrodynamic Flow)
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12 pages, 3361 KiB  
Article
Investigation of the Effects Caused by Current Interruption Devices of Lithium Cells at High Overvoltages
by Jan Haß, Christina Schieber, Florian Meilinger, Yash Kotak, Serkan Sevinc, Philipp Lang and Hans-Georg Schweiger
Appl. Sci. 2024, 14(18), 8238; https://doi.org/10.3390/app14188238 - 12 Sep 2024
Viewed by 2275
Abstract
A faulty voltage measurement can lead to the overcharging of a Li-Ion cell, resulting in gas formation and heating inside the cell, which can trigger thermal runaway. To mitigate this risk, cylindrical cells are equipped with a Current Interrupt Device (CID), which functions [...] Read more.
A faulty voltage measurement can lead to the overcharging of a Li-Ion cell, resulting in gas formation and heating inside the cell, which can trigger thermal runaway. To mitigate this risk, cylindrical cells are equipped with a Current Interrupt Device (CID), which functions as a pressure relief valve, disconnecting the electrical circuit within the cell when internal pressure rises. However, this disconnection causes the cell to suddenly become highly resistant, posing a significant issue in series-connected cells. In such configurations, a portion or even the entire system voltage may drop across the disconnected cell, substantially increasing the likelihood of an electric arc. This arc could ignite any escaping flammable gases, leading to catastrophic failures. In a series of tests conducted on three different cell chemistries—NMC (Nickel Manganese Cobalt), NCA (Nickel Cobalt Aluminum), and LFP (Lithium Iron Phosphate)—it was found that the safe operation of the CID cannot be guaranteed for system voltages exceeding 120 V. Although comparative tests at double the nominal cell voltage did not exhibit the same behavior, these findings suggest that current safety standards, which recommend testing at double the nominal voltage, may not adequately address the risks involved. The tests further revealed that series connections of cells with CIDs are inherently dangerous, as, in the worst-case scenario, the entire system voltage can be concentrated across a single cell, leading to potential system failure. Full article
(This article belongs to the Section Energy Science and Technology)
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14 pages, 4206 KiB  
Article
Shear Thickening, Star-Shaped Polymer Electrolytes for Lithium-Ion Batteries
by Magdalena Słojewska, Arkadiusz Czerwiński, Marcin Kaczorowski and Ewa Zygadło-Monikowska
Molecules 2024, 29(16), 3782; https://doi.org/10.3390/molecules29163782 - 9 Aug 2024
Cited by 1 | Viewed by 1268
Abstract
The safety concerns associated with current lithium-ion batteries are a significant drawback. A short-circuit within the battery’s internal components, such as those caused by a car accident, can lead to ignition or even explosion. To address this issue, a polymer shear thickening electrolyte, [...] Read more.
The safety concerns associated with current lithium-ion batteries are a significant drawback. A short-circuit within the battery’s internal components, such as those caused by a car accident, can lead to ignition or even explosion. To address this issue, a polymer shear thickening electrolyte, free from flammable solvents, has been developed. It comprises a star-shaped oligomer derived from a trimethylolpropane (TMP) core and polyether chains, along with the inclusion of 20 wt.% nanosilica. Notably, the star-shaped oligomer serves a dual function as both the solvent for the lithium salt and the continuous phase of the shear thickening fluid. The obtained electrolytes exhibit an ionic conductivity of the order of 10−6 S cm−1 at 20 °C and 10−4 S cm−1 at 80 °C, with a high Li+ transference number (t+ = 0.79). A nearly thirtyfold increase in viscosity to a value of 1187 Pa s at 25 °C and a critical shear rate of 2 s−1 were achieved. During impact, this electrolyte could enhance cell safety by preventing electrode short-circuiting. Full article
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