Search Results (396)

Rapid socio-economic development and the impact of human activities have exerted tremendous pressure on the groundwater system of the Dawen River Basin (DRB), the largest tributary in the middle and lower reaches of the Yellow River. Hydrochemical studies on the DRB have largely centered on the upstream Muwen River catchment and downstream Dongping Lake, with some focusing solely on karst groundwater. Basin-wide evaluations suggest good overall groundwater quality, but moderate to severe contamination is confined to the lower Dongping Lake area. The hydrogeologically complex mid-reach, where the Muwen and Chaiwen rivers merge, warrants specific focus. This region, adjacent to populous areas and industrial/agricultural zones, features diverse aquifer systems, necessitating a thorough analysis of its hydrochemistry and origins. This study presents an integrated hydrochemical, isotopic investigation and EWQI evaluation of groundwater quality and formation mechanisms within the multiple groundwater types of the central DRB. Central DRB groundwater has a pH of 7.5–8.2 (avg. 7.8) and TDSs at 450–2420 mg/L (avg. 1075.4 mg/L) and is mainly brackish, with Ca²⁺ as the primary cation (68.3% of total cations) and SO₄²⁻ (33.6%) and NO₃⁻ (28.4%) as key anions. The Piper diagram reveals complex hydrochemical types, primarily HCO₃·SO₄-Ca and SO₄·Cl-Ca. Isotopic analysis (δ²H, δ¹⁸O) confirms atmospheric precipitation as the principal recharge source, with pore water showing evaporative enrichment due to shallow depths. The Gibbs diagram and ion ratios demonstrate that hydrochemistry is primarily controlled by silicate and carbonate weathering (especially calcite dissolution), active cation exchange, and anthropogenic influences. EWQI assessment (avg. 156.2) indicates generally “good” overall quality but significant spatial variability. Pore water exhibits the highest exceedance rates (50% > Class III), driven by nitrate pollution from intensive vegetable cultivation in eastern areas (Xiyangzhuang–Liangzhuang) and sulfate contamination from gypsum mining (Guojialou–Nanxiyao). Karst water (26.7% > Class III) shows localized pollution belts (Huafeng–Dongzhuang) linked to coal mining and industrial discharges. Compared to basin-wide studies suggesting good quality in mid-upper reaches, this intensive mid-reach sampling identifies critical localized pollution zones within an overall low-EWQI background. The findings highlight the necessity for aquifer-specific and land-use-targeted groundwater protection strategies in this hydrogeologically complex region. Full article

Phewa Lake, Nepal’s second-largest natural lake, is under increasing ecological stress due to sedimentation, shoreline encroachment, and water quality decline driven by rapid urban growth, fragile mountainous catchments, and changing climate patterns. This study employs an integrated approach combining sediment yield estimation from its catchment using RUSLE, shoreline encroachment analysis via satellite imagery and historical records, and identification of pollution sources and socio-economic factors through field surveys and community consultations. The results show that steep, sparsely vegetated slopes are the primary sediment sources, with Harpan Khola (a tributary of Phewa Lake) contributing over 80% of the estimated 339,118 tons of annual sediment inflow. From 1962 to 2024, the lake has lost approximately 5.62 sq. km of surface area, primarily due to a combination of sediment deposition and human encroachment. Pollution from untreated sewage, urban runoff, and invasive aquatic weeds further degrades water quality and threatens biodiversity. Based on the findings, this study proposes a way forward to mitigate sedimentation, encroachment, and pollution, along with a sustainable revitalization plan. The approach of this study, along with the proposed sustainability measures, can be replicated in other lake systems within Nepal and in similar watersheds elsewhere. Full article

The U.S. Environmental Protection Agency (EPA) developed the concept of Water Quality Volume (WQv) as a Best Management Practice (BMP) to treat the first 25.4 mm of rainfall in urban areas, aiming to capture approximately 90% of annual runoff. However, applying this urban-based standard—designed for areas with over 50% imperviousness—to rural regions with higher infiltration and pervious surfaces may result in overestimated facility capacities. In Korea, a uniform WQv criterion of 5 mm is applied nationwide, regardless of land use or hydrological conditions. This study examines the suitability of this 5 mm standard in rural catchments using the Hydrological Simulation Program–Fortran (HSPF). Eight sub-watersheds in the target area were simulated under varying cumulative runoff depths (1–10 mm) to assess pollutant loads and runoff characteristics. First-flush effects were most evident below 5 mm, with variation depending on land cover. Nature-based treatment systems for constructed wetlands were modeled for each sub-watershed, and their effectiveness was evaluated using Flow Duration Curves (FDCs) and Load Duration Curves (LDCs). The findings suggest that the uniform 5 mm WQv criterion may result in overdesign in rural watersheds and highlight the need for region-specific standards that consider local land-use and hydrological variability. Full article

The event scale method, employed for assessing changes in nitrogen (N) dynamics pre- and post-rain, provides insights into its transport to surface water systems. However, the relationships between N discharge in catchments dominated by different land uses and water quality remain unclear. This study quantified variations in key N components in ponds across forest, paddy field, and orchard catchments before and after six rainfall events. The results showed that nitrate (NO₃⁻-N) was the main N component in the ponds. Post-rainfall, N concentrations increased, with ammonium (NH₄⁺-N) and particulate nitrogen (PN) exhibiting significant elevations in agricultural ponds. Orchard catchments contributed the highest N load to the ponds, while forest catchments contributed the lowest. Following a heavy rainstorm event, total nitrogen (TN) loads in the ponds within forest, paddy field, and orchard catchments reached 6.68, 20.93, and 34.62 kg/ha, respectively. These loads were approximately three times higher than those observed after heavy rain events. The partial least squares structural equation model (PLS-SEM) identified that rainfall amount and changes in water volume were the dominant factors influencing N dynamics. Furthermore, the greater slopes of forest and orchard catchments promoted more N loss to the ponds post-rain. In paddy field catchments, larger catchment areas were associated with decreased N flux into the ponds, while larger pond surface areas minimized the variability in N concentration after rainfall events. In orchard catchment ponds, pond area was positively correlated with N concentrations and loads. This study elucidates the effects of rainfall characteristics and catchment heterogeneity on N dynamics in surface waters, offering valuable insights for developing pollution management strategies to mitigate rainfall-induced alterations. Full article

The present study investigates the extent and spatial distribution of metal concentration in stream sediments that flow into Keban Dam Lake, Turkey. Sediment samples were analysed for trace and potentially toxic elements (PTEs), including V, Cr, Co, Ni, Cu, Zn, Pb, Tl, Th, and U. Enrichment Factor (EF), Contamination Factor (CF), Geo-accumulation Index (Igeo), and Pollution Load Index (PLI) were employed to assess contamination levels. Results reveal that Cr exhibited very high enrichment (EF = 15.95) in downstream urban samples, while Cu and Zn showed high enrichment in samples collected from the middle to lower reaches of the stream, probably indicating anthropogenic contributions. Most other elements, such as Pb, Tl, Th, and U, were within natural background levels. Sediment Quality Guidelines (SQGs) indicate that Cr, Ni, and Cu may pose potential ecological risks, especially in samples from urban-influenced and downstream areas where concentrations exceed the Probable Effect Levels (PEL; Cr: 160 mg/kg, Ni: 42.8 mg/kg, Cu: 108 mg/kg). Multivariate statistical analyses, including Pearson correlation and hierarchical clustering, reveal three distinct geochemical groupings. Among these, the most contaminated cluster—corresponding to midstream and downstream regions—is characterized by elevated Cu and Zn concentrations. Strong correlations among Cu–Zn, Ni–Cu, and Th–U suggest there is a combination of anthropogenic and lithogenic sources for most metals. While most sites showed low to moderate pollution, urban downstream locations exhibited significant metal accumulation, necessitating the region’s continued environmental monitoring and management strategies. Full article

High water quality in reservoirs used for drinking water supply and located within protected areas is of crucial importance for sustainable water-resource management. This study aims to evaluate the multi-depth water quality dynamics of the Ribnica Reservoir in western Serbia, combining two standardized assessment tools: the Serbian Water Quality Index (SWQI) and the Canadian Water Quality Index (CWQI). Data collected at various depths during 2021 and 2022 were analyzed to assess physico-chemical parameters and their impact on water quality, while the absence of microbiological data was noted as a limitation affecting the comprehensiveness of the assessment. The SWQI results indicated a general improvement in water quality over time, with values ranging from medium (82) to excellent (95) in 2021 and increasing from good (89) to excellent (98) in 2022. In contrast, the CWQI revealed specific risks, notably elevated concentrations of aluminum, mercury, and chromium, and reduced dissolved oxygen levels, with overall CWQI values ranging from poor (40) to good (88) depending on depth and parameter variability. The study highlights the necessity for continuous, comprehensive monitoring, including microbiological analyses and seasonal assessments, both within the reservoir and in the Crni Rzav River and its tributaries, to better understand pollutant sources and catchment influences. Strengthening microbiological and heavy metal monitoring, along with implementing proactive management strategies, is essential for preserving the Ribnica Reservoir’s ecological integrity and securing its long-term role in drinking water provision. Full article

Understanding the impact of climate change on agricultural nonpoint source (NPS) pollution is crucial for developing effective adaptation strategies and reducing vulnerabilities where such challenges exist. This study evaluated the impact of precipitation and temperature variations on Total Inorganic Nitrogen (TIN), Total Inorganic Phosphorus (TIP), and sediment loads in the Sand River Catchment (SRC) using the Soil and Water Assessment Tool plus (SWAT+). One-way analysis of variance (ANOVA) was used to determine the significance (p < 0.05) of the relationships (R²) between precipitation and temperature on sediment, TIN, and TIP loads in the SRC. SWAT+ calibration and validation demonstrated that the statistical indices (NSE and R² ≥ 0.72; −17.30 ≤ PBIAS ≤ 14.74) fell within an acceptable range. Results indicated a significant influence of average monthly precipitation (p < 0.0001) and temperature (p ≤ 0.004) on sediment, TIN, and TIP loads. In addition, a decrease in average annual precipitation led to a decline in sediment, TIN, and TIP loads (R² ≥ 0.55), with the average annual temperature increasing in the same period (R² ≤ 0.23). This study confirms that climate change contributes to agricultural NPS pollution in the SRC and highlights the need to employ suitable adaptation strategies for pollution control in the catchment. Full article

Anthropogenic pollution of watersheds significantly threatens aquatic ecosystems, biodiversity, and human health. The present review examines the primary sources of contamination in river catchments, including industrial effluents, agricultural runoff, and urban wastewater discharge. The presence of pollutants degrades water quality, disrupting aquatic habitats and leading to adverse outcomes, including biodiversity loss, eutrophication, and declining fish populations. It also focuses on strategic mitigation approaches, including implementing stricter waste management regulations, adopting sustainable agricultural practices, improving wastewater treatment infrastructure, and public education initiatives. The article summarizes several biotechnological techniques developed to decrease the impact of farming activities on water quality. It also emphasises directions that could be followed concerning specific water chemical indicators, such as the residual quantity of heavy metals. Emphasis is placed on the need for integrated policy frameworks and cross-sector collaboration to safeguard freshwater systems and ensure long-term environmental sustainability. Full article

This article describes the reasons for and trends in the overgrowth of soft-water lakes in Belarus. Due to their unique water properties (low mineralization, pH, and nitrogen and phosphorus concentrations) and high water transparency, soft-water lakes are home to protected plant species like Lobelia dortmanna L., Isöetes lacustris L., and Littorella uniflora L. The purpose of this study was to analyze changes in aquatic vegetation distribution in seven soft-water Belarusian lakes and identify the causes of these changes. The initial data for this research were the results of field observations, the archive materials of the research laboratory of lake research conducted by the Belarusian State University for the period from 1971 to 2016, including morphometric and hydrochemical parameters, the characteristics of catchments and water exchange, and the results of studying the species composition and distribution of aquatic vegetation. The authors’ field studies were carried out in 2022–2024. We used expeditionary, hydrochemical, cartographic, and comparative research methods. The most significant changes in overgrowth were observed in Lakes Svityaz and Beloe (Luninets District). These lakes have high recreational loads. Significant negative trends were also noted in Lakes Bolshoe Ostrovito and Bredno. Over 35 years, the depth of distribution of submerged macrophytes in Lake Svityaz has decreased from 7 to 2 m, and the abundance and projective cover of semi-submerged macrophytes have increased. In Lake Beloe, I. lacustris, which forms a tier of submerged plants, has almost completely disappeared, and a previously absent strip of air-aquatic plants has formed. The total area of overgrowth in the lake has decreased from 35% of the water area to 3.2%. In Lake Bolshoe Ostrovito, Fontinalis sp., previously common at depths of up to 5 m, has practically disappeared. In Lake Bredno, the water moss Drepanocladus has spread to a depth of 4 m. In Lake Glubokoe, a new area of I. lacustris growth was discovered around an island at depths of up to 4 m. In Lake Cherbomyslo, the decrease in the species’ depth and area of distribution is associated with a weakening of the inflow of bog waters due to their backwater. The main causes of these changes are largely due to anthropogenic factors (water pollution by biogenic compounds) and, to a lesser extent, hydrological changes (decrease in the moisture content of lake catchments). Full article

The primary sources of widespread pollution in most river catchments are improperly treated final effluents from various wastewater treatment plants (WWTPs), affecting the physicochemical characteristics of the receiving water bodies. Wastewater discharge must be monitored regularly to ensure compliance with national and municipal water quality regulatory/standard restrictions. This study monitored the physicochemical parameters of two typical WWTPs (WWTP A = a peri-urban plant and WWTP B = a rural plant) for 5 months. The physicochemical parameters that were assessed included pH, temperature, total dissolved solids (TDSs), turbidity, chemical oxygen demand (COD), alkalinity, dissolved oxygen (DO), free chlorine, chloride, sulphate, phosphate, ammonium, and electrical conductivity (EC). The evaluation yielded the following results: temperature (14 to 21 °C and 14 to 23 °C), pH (7.2–8.2 and 7.3–8.4), EC (90–800 μs/cm and 80–750 μs/cm), TDSs (65–440 and 55–410 mg/L), alkalinity (2.6–20.9 mg/L), nitrate (0.24–26.5 mg/L), nitrite (0.01–90 mg/L), phosphate (0.0–18.0 mg/L and 0.0–21 mg/L), ammonia (0.2–75 mg/L and 0.8–70 mg/L), sulphate (0.0–18.0 mg/L and 0.0–21 mg/L), chloride (5.0–22.0 mg/L and 2.0–25 mg/L), COD (6.0–710 mg/L and 7.0–800 mg/L), and turbidity (0.4–150 NTU and 1.8–130 NTU) for wastewater treatment A and B, respectively. The results also showed that temperature, pH, TDSs, nitrite/nitrate, chloride, turbidity, alkalinity, sulphate, and free chlorine were among the parameters in the final effluent discharged that met the set guidelines. In contrast, parameters such as COD, EC, phosphate, and ammonia did not meet the guideline values for most of the sampling period for both WWTPs. Furthermore, this study found that WWTPs reduced nitrate, sulphate, phosphate, and COD pollutants by more than 90% while maintaining 60% alkalinity. Temperature, pH, TDSs, EC, Cl⁻, and other parameters were less than 40% for WWTP A and roughly less than 50% for WWTP B. Full article

Inland saline wetlands in the Ebro Basin (Spain) are protected by international regulations but are also threatened by the expansion of animal farms. We studied the input–output budgets of N from animal farms in four catchments of wetlands in the central Ebro Basin designated as Nitrate Vulnerable Zones. We used the N produced in animal farms as inputs and the N extracted by the crops on which manures and slurries are applied as outputs in each catchment. The balances considered the regulations concerning the slope of land where animal excreta may be applied and the doses of application. At a detailed scale, we applied the Water Erosion Prediction Program (WEPP) to the Farnaca catchment to assess the runoff and nutrients arriving to its wetland. While the Bujaraloz-Sástago basin showed a high excess of N load, in the Gallocanta basin, N extraction by crops was significantly higher than the N produced by the animal farms. Despite this lack of surplus of N from animal excreta, the groundwaters in the Gallocanta catchment are polluted by nitrates. The emphasis on N from animal farms in plans to prevent water pollution is missing the role of mineral fertilizers as the sources of pollution in basins with small N loads from animal farms. Agricultural plots in the Farnaca catchment produce significant amounts of sediments and nutrients that eventually pollute the wetland. Modelling approaches at detailed scales are required to assess the flows of materials to individual wetlands. Full article

Freshwater macroinvertebrates, often used as indicators of environmental quality for freshwater ecosystems, may be compromised by microplastics (MPs). We investigated MPs occurring in benthic filter feeder, predator, and grazer macroinvertebrates collected from the catchment-independent but adjacent Olifants and Sabie rivers of Kruger National Park as duplicates. We counted 369 MPs in 376 organisms (1.0 n/organism) with a mean of 8.8 n/organism, 8.5 n/organism, and 0.16 n/organism in filter feeders, predators, and grazers, respectively. Based on MP colour, size, and morphotype, significant differences in proportional compositions between predatorial macroinvertebrates and all other macroinvertebrates in both rivers preclude predatorial macroinvertebrates as a proxy indicator for the other macroinvertebrates. Proportional compositions of MP characteristics in macroinvertebrates differed in all respects between the two adjacent rivers, except for one aspect. Microplastic morphotypes occurred in equal proportions in macroinvertebrates of both rivers, suggesting biological selection based on morphotype but not MP colour or size. We found little evidence of trophic transfer between feeding guilds. Of the six polymer types observed (n = 50), butyl and chlorobutyl dominated. Waste mismanagement, single-use plastics, inefficient wastewater treatment plants, mining, and road transportation may be the major MP pollution sources that need mitigation. Microplastics in freshwater ecosystems of nature conservation areas need more attention due to high biodiversity that may be exposed. Full article

We investigated the diatom communities and physicochemical water variables in the Abrud River catchment area (the Roșia Montană mining area, Romania) at 16 sampling sites, some of them impacted by acid mine drainage (AMD) and heavy metals. Diatoms serve as effective indicators of water characteristics owing to their ubiquity and sensitivity to environmental variables. This study aimed to enhance the understanding of the key environmental factors influencing the diatom flora of polluted rivers across various spatial and temporal scales, thereby informing the optimization of ecosystem management strategies. This work contributes to the knowledge of Romanian diatom flora through the identification of 274 taxa belonging to 63 genera, including 35 taxa recorded for the first time in the country. The spatial and temporal variations in the species richness patterns highlighted the effects of water pollution resulting from past mining activities, revealing distinctions between the main Abrud River stream and its tributaries, some of which exhibited extremely low species richness with few or no identified taxa. This contrasted sharply with the cleaner upstream waters of the Roșia Valley, where a notably rich diatom community (85 taxa) persisted, highlighting the severe localized impact of mining discharges on biodiversity. Full article

Nitrate (NO₃⁻) pollution resulting from anthropogenic activities represents one of the most prevalent environmental issues in karst spring catchments of northern China. In June 2021, a comprehensive study was conducted in the Jinan Spring Catchment (JSC), where 30 groundwater and surface water samples were collected. The sources and spatial distribution of nitrate pollution were systematically investigated through hydrochemical analysis combined with dual-isotope tracing techniques (δ¹⁵N_NO3 and δ¹⁸O_NO3). Analytical results revealed that the predominant anion and cation sequences were HCO₃⁻ > SO₄²⁻ > Cl⁻ > NO₃⁻ and Ca²⁺ > Na⁺ > Mg²⁺ > K⁺, respectively, with HCO₃·SO₄-Ca identified as the primary hydrochemical type. Notably, the average NO₃⁻ concentration in groundwater (46.62 mg/L) significantly exceeded that in surface water (4.96 mg/L). Among the water samples, 11 locations exhibited substantial nitrate pollution, demonstrating an exceedance rate of 42%. Particularly, the NO₃⁻-N concentrations in both the upstream recharge area and downstream drainage area were markedly higher than those in the runoff area. The spatial distribution of NO₃⁻ concentrations was primarily influenced by mixing processes, with no significant evidence of denitrification observed. The isotopic compositions ranged from −1.42‰ to 12.79‰ for δ¹⁵N_NO3 and 0.50‰ to 15.63‰ for δ¹⁸O_NO3. Bayesian isotope mixing model (MixSIAR) analysis indicated that domestic sewage and manure constituted the principal nitrate sources, contributing 37.1% and 56.9% to groundwater and surface water, respectively. Secondary sources included soil organic nitrogen, rainfall and fertilizer NH₄⁺, and chemical fertilizers, while atmospheric deposition showed the lowest contribution rate. Additionally, potential mixing of soil organic nitrogen with chemical fertilizer was identified. Full article

The present study focuses on the sources and spatial distribution of potentially toxic elements (PTEs) and organic pollutants in water, canal bed sediment, and soil in the Versiliana urban park, an inclusive green area near the coast in the densely populated Versilia Plain of Tuscany. Surface water and bed sediments from canals crossing the urban park were collected at 10 stations during four different surveys to account for hydrological seasonality. Groundwater was collected in a survey through 10 piezometers. Eleven shallow soil samples were also collected, with the aim of evaluating the potential release of pollutants. Groundwater ranged from Ca-HCO₃, to NaCl, CaCl₂, and Na-HCO₃ water types, indicating conservative mixing and cation exchange processes during seawater intrusion. Most waters from canals belonged to the Ca-HCO₃ hydrofacies; a salinization shift, due to hydraulic connection with saline groundwater and soil sea salt dissolution, is observed. The concentration of most PTEs in groundwater and canal water is below Italian regulatory thresholds, with the only exception being As, which exceeds the legal limit in some samples. In most sediments, Ni, Cr, Zn, and As exceed the threshold effect concentration, and in some cases, the probable effect concentration. Geogenic PTE sources are attributed to metalliferous mineralization that characterizes the upstream Versilia River basin catchment. However, local PTE inputs from vehicular emissions and local industrial activities have been highlighted. Arsenic in sediments originated from geogenic sources and from arsenical pesticides, as indicated by the analysis of organic compounds, highlighting the legacy of the use of organic pesticides that have settled in bed sediments, in particular malathion and metalaxyl. The arsenic risk-based screening level in soil is lower compared with the regulatory threshold and with the measured concentration. Full article