Search Results (160)

In the present paper, impedance spectroscopy was employed to study the corrosion and anodic oxidation of stainless steel (AISI 316L at 280 °C/9 MPa) in contact with the boron-free primary coolant of a small modular reactor at two levels of KOH concentration. Analysis of impedance spectra with a distribution of relaxation times revealed contributions from the oxide layer and its interface with the coolant. Glow-Discharge Optical Emission Spectroscopy (GDOES) was used to estimate the thickness and elemental composition of the formed oxides. A quantitative interpretation of the impedance data using the Mixed-Conduction Model allowed us to estimate the kinetic and transport parameters of oxide growth and dissolution, as well as iron dissolution through oxide. The film thicknesses following exposure agreed with ex-situ analyses. The obtained corrosion and release rates were used for comparison with laboratory and industrial data in nominal pressurized water reactor primary coolants. Full article

Manganese (Mn) excess and low pH often coexist in some citrus orchard soils. Little information is known about the underlying mechanism by which raising pH reduces Mn toxicity in citrus plants. ‘Sour pummelo’ (Citrus grandis (L.) Osbeck) seedlings were treated with 2 (Mn2) or 500 (Mn500) μM Mn at a pH of 3 (P3) or 5 (P5) for 25 weeks. Raising pH mitigated Mn500-induced increases in Mn, iron, copper, and zinc concentrations in roots, stems, and leaves, as well as nitrogen, phosphorus, potassium, calcium, magnesium, sulfur, copper, iron, and zinc distributions in roots, but it mitigated Mn500-induced decreases in nitrogen, phosphorus, potassium, calcium, magnesium, sulfur, and boron concentrations in roots, stems, and leaves, as well as nutrient imbalance. Raising pH mitigated Mn500-induced necrotic spots on old leaves, yellowing of young leaves, decreases in seedling growth, leaf chlorophyll concentration, and CO₂ assimilation (A_CO2), increase in root dry weight (DW)/shoot DW, and alterations of leaf chlorophyll a fluorescence (OJIP) transients and related indexes. Further analysis indicated that raising pH ameliorated Mn500-induced impairment of nutrient homeostasis, leaf thylakoid structure by iron deficiency and competition of Mn with magnesium, and photosynthetic electron transport chain (PETC), thereby reducing Mn500-induced declines in A_CO2 and subsequent seedling growth. These results validated the hypothesis that raising pH reduced Mn toxicity in ‘Sour pummelo’ seedlings by (a) reducing Mn uptake, (b) efficient maintenance of nutrient homeostasis under Mn stress, (c) reducing Mn excess-induced impairment of thylakoid structure and PEPC and inhibition of chlorophyll biosynthesis, and (d) increasing A_CO2 and subsequent seedling growth under Mn excess. Full article

This paper presents the flow field reconstruction and prediction of powder fuel transport systems based on representative feature extraction from scattering images using deep learning techniques. A laboratory-built powder fuel supply system was used to conduct scattering spectroscopy experiments on boron-based fuel under various flow rate conditions. Based on the acquired scattering images, a prediction and reconstruction method was developed using a deep network framework composed of a Stacked Autoencoder (SAE), a Backpropagation Neural Network (BP), and a Long Short-Term Memory (LSTM) model. The proposed framework enables accurate classification and prediction of the dynamic evolution of flow structures based on learned representations from scattering images. Experimental results show that the feature vectors extracted by the SAE form clearly separable clusters in the latent space, leading to high classification accuracy under varying flow conditions. In the prediction task, the feature vectors predicted by the LSTM exhibit strong agreement with ground truth, with average mean square error, mean absolute error, and r-square values of 0.0027, 0.0398, and 0.9897, respectively. Furthermore, the reconstructed images offer a visual representation of the changing flow field, validating the model’s effectiveness in structure-level recovery. These results suggest that the proposed method provides reliable support for future real-time prediction of powder fuel mass flow rates based on optical sensing and imaging techniques. Full article

The transport properties of one-dimensional van der Waals nanodevices composed of carbon nanotubes (CNTs), hexagonal boron nitride (hBN) nanotubes, and molybdenum dichalcogenide (MoX₂) nanotubes were investigated within the framework of density functional theory (DFT). It was found that in nanodevices based on MoS₂(24,24) and MoTe₂(24,24), the effect of resonant tunneling is suppressed due to electron–phonon scattering. This suppression arises from the fact that these materials are semiconductors with an indirect band gap, where phonon participation is required to conserve momentum during transitions between the valence and conduction bands. In contrast, nanodevices incorporating MoSe₂(24,24), which possesses a direct band gap, exhibit resonant tunneling, as quasiparticles can tunnel between the valence and conduction bands without a change in momentum. It was demonstrated that the presence of vacancy defects in the CNT segment significantly degrades quasiparticle transport compared to Stone–Wales (SW) defects. Furthermore, it was revealed that resonant interactions between SW defects in MoTe₂(24,24)–hBN(27,27)–CNT(24,24) nanodevices can enhance the differential conductance under certain voltages. These findings may be beneficial for the design and development of nanoscale diodes, back nanodiodes, and tunneling nanodiodes. Full article

Titanium dioxide (TiO₂) is a wide-bandgap semiconductor material with broad application potential, known for its excellent photocatalytic performance, high chemical stability, low cost, and non-toxicity. These properties make it highly attractive for applications in photovoltaic energy, environmental remediation, and optoelectronic devices. For instance, TiO₂ is widely used as a photocatalyst for hydrogen production via water splitting and for degrading organic pollutants, thanks to its efficient photo-generated electron–hole separation. Additionally, TiO₂ exhibits remarkable performance in dye-sensitized solar cells and photodetectors, providing critical support for advancements in green energy and photoelectric conversion technologies. Boron-doped diamond (BDD) is renowned for its exceptional electrical conductivity, high hardness, wide electrochemical window, and outstanding chemical inertness. These unique characteristics enable its extensive use in fields such as electrochemical analysis, electrocatalysis, sensors, and biomedicine. For example, BDD electrodes exhibit high sensitivity and stability in detecting trace chemicals and pollutants, while also demonstrating excellent performance in electrocatalytic water splitting and industrial wastewater treatment. Its chemical stability and biocompatibility make it an ideal material for biosensors and implantable devices. Research indicates that the combination of TiO₂ nanostructures and BDD into heterostructures can exhibit unexpected optical and electrical performance and transport behavior, opening up new possibilities for photoluminescence and rectifier diode devices. However, applications based on this heterostructure still face challenges, particularly in terms of photodetector, photoelectric emitter, optical modulator, and optical fiber devices under high-temperature conditions. This article explores the potential and prospects of their combined heterostructures in the field of optoelectronic devices such as photodetector, light emitting diode (LED), memory, field effect transistor (FET) and sensing. TiO₂/BDD heterojunction can enhance photoresponsivity and extend the spectral detection range which enables stability in high-temperature and harsh environments due to BDD’s thermal conductivity. This article proposes future research directions and prospects to facilitate the development of TiO₂ nanostructured materials and BDD-based heterostructures, providing a foundation for enhancing photoresponsivity and extending the spectral detection range enables stability in high-temperature and high-frequency optoelectronic devices field. Further research and exploration of optoelectronic devices based on TiO₂-BDD heterostructures hold significant importance, offering new breakthroughs and innovations for the future development of optoelectronic technology. Full article

Although lithium-ion batteries are considered an ideal postulant for renewable energy harvesting, storage and applications, these batteries show promising performance; however, at the same time, these harvesting devices suffer from some major limitations, including scarce lithium resources, high cost, toxicity and safety concerns. Potassium ion batteries (PIBs) can be proven a favorable alternative to metal ion batteries because of their widespread potassium reserves, low costs and enhanced protection against sparks. In this study, DFT simulations were employed using the B3LYP/6-311⁺⁺g(d p) method to explore the application of graphene and its doped variants (N,B,P-graphene) as potential anode materials for PIBs. Various key parameters such as adsorption energy, Gibbs free energy, molecular orbital energies, non-covalent interactions, cell voltage, electron density distribution and density of states were computed as a means to evaluate the suitability of materials for PIB applications. Among the four structures, nitrogen- and phosphorus-doped graphene exhibited negative Gibbs free energy values of −0.020056 and −0.021117 hartree, indicating the thermodynamic favorability of charge transfer processes. Doping graphene with nitrogen and phosphorus decreases the HOMO-LUMO gap energy, facilitating efficient ion storage and charge transport. The doping of nitrogen and phosphorus increases the cell voltage from −1.05 V to 0.54 V and 0.57 V, respectively, while boron doping decreases the cell voltage. The cell voltage produced by graphene and its doped variants in potassium ion batteries has the following order: P-graphene (0.57 V) > N-graphene (0.54 V) > graphene (−1.05 V) > B-graphene (−1.54 V). This study illustrates how nitrogen- and phosphorus-doped graphene can be used as a propitious anode electrode for PIBs. Full article

Conventional pesticides and fertilizers are frequently linked to high resource consumption, environmental damage, and poor nutrient usage efficiency in the production of broccoli. Nanofertilizers (e.g., iron, copper, zinc oxide, and boron NMs) and pesticide nanoparticles (NPs) are examples of nanotechnology that is mainly related to broccoli production. These technologies can increase the efficiency of nutrient uptake and utilization as well as broccoli’s resistance to drought, heavy metal stress, saline and alkaline stress, and other conditions. Through accurate fertilization and dosing, nanotechnology can reduce environmental contamination and the need for traditional chemical pesticides and fertilizers. Crops with nanomaterials have higher micronutrient content and better nutritional quality. This study examines the use of nanotechnology in the production of broccoli, which could improve crop yield and quality. However, much research is still required to determine how nanomaterials affect the environment and whether or not they might be hazardous to broccoli because of their minuscule particle size and unique physical and chemical characteristics. Researchers and agricultural professionals both within and outside the field of nanobiotechnology will be able to choose the right nanoparticles for broccoli production with the help of the information presented in this paper. The use of nanotechnology can reduce production costs and support sustainable agricultural growth. Additionally, it opens up new possibilities for the future production, transportation, and storage of cruciferous vegetables. Full article

Recent findings have demonstrated that the desalination and purification of contaminated water and the separation of ions and gases, besides solutions to other related issues, may all be achieved with the use of membranes based on artificial nanoporous materials. Before the expensive stages of production and experimental testing, the optimum size and form of membrane nanopores could be determined using computer-aided modeling. The notion that rectangular nanopores created in a multilayered hexagonal boron nitride (h-BN) membrane in a way that results in different inner lining atoms would exhibit unique properties in terms of the water penetration rate is put forth and examined in the current study. Nanopores in boron nitride sheets can be generated with the inner lining of boron atoms (B-edged), nitrogen atoms (N-edged), or both boron and nitrogen atoms (BN-edged). In this study, we compared the three different inner-lined nanopores of boron nitride nanosheets to a comparable-sized graphene nanopore and evaluated the water conduction. Full article

Nanotubes (NTs) are nanosized tube-like structured materials made from various substances such as carbon, boron, or silicon. Carbon nanomaterials (CNMs), including carbon nanotubes (CNTs), graphene/graphene oxide (G/GO), and fullerenes, have good interatomic interactions and possess special characteristics, exploitable in several applications because of the presence of sp2 and sp3 bonds. Among NTs, CNTs are the most studied compounds due to their nonpareil electrical, mechanical, optical, and biomedical properties. Moreover, single-walled carbon nanotubes (SWNTs) have, in particular, demonstrated high ability as drug delivery systems and in transporting a wide range of chemicals across membranes and into living cells. Therefore, SWNTs, more than other NT structures, have generated interest in medicinal applications, such as target delivery, improved imaging, tissue regeneration, medication, and gene delivery, which provide nanosized devices with higher efficacy and fewer side effects. SWNTs and multi-walled CNTs (MWCNTs) have recently gained a great deal of attention for their antibacterial effects. Unfortunately, numerous recent studies have revealed unanticipated toxicities caused by CNTs. However, contradictory opinions exist regarding these findings. Moreover, the problem of controlling CNT-based products has become particularly evident, especially in relation to their large-scale production and the nanosized forms of the carbon that constitute them. Important directive rules have been approved over the years, but further research and regulatory measures should be introduced for a safer production and utilization of CNTs. Against this background, and after an overview of CNMs and CNTs, the antimicrobial properties of pristine and modified SWNTs and MWCNTs as well as the most relevant in vitro and in vivo studies on their possible toxicity, have been reported. Strategies and preventive behaviour to limit CNT risks have been provided. Finally, a debate on regulatory issues has also been included. Full article

The merging of pore designs is a potential strategy for achieving ultra-low lattice thermal conductivity (κ), for which phonon anharmonicity and size effect are indispensable for discovering novel functional materials in thermal applications. In this study, monolayer holey graphyne (HGY) and boron nitride holey graphyne (BN-HGY) were examined for their phonon thermal transport properties through first-principles calculation and phonon Boltzmann function. HGY exhibits an intrinsic lattice thermal conductivity (κ) of 38.01 W/mK at room temperature, which exceeds BN-HGY’s 24.30 W/mK but is much lower than 3550 W/mK for BTE graphene. The phonon–phonon scattering behavior of BN-HGY is obviously increased compared to HGY due to the enhancement of anharmonicity, which leads to a shorter phonon lifetime and lower κ. Additionally, at room temperature, the representative mean free path (rMFP) of BN-HGY is substantially higher than that of HGY, and the κ of BN-HGY decreases faster at a larger rMFP (within a unit nm). This work will be constructive to further the application of HGY and BN-HGY as thermal management materials. Full article

Boron (B) is an essential micronutrient for the growth, development, and maintenance of cellular integrity in vascular plants, and is especially important in cell wall synthesis and reproductive development. Rapeseed (Brassica napus L.), one of the dominant oil crops globally, has a high boron demand and its yield is dramatically decreased under B-deficiency conditions. Rapeseed, which is very sensitive to boron deficiency, suffers from reduced growth and reproductive development, ultimately causing severe yield losses. Here, we reviewed the present state of knowledge on the physiological function of boron in rapeseed, mechanisms of boron uptake and transport, specific effects of boron deficiency in rapeseed, and approaches to alleviate boron deficiency in rapeseed at the agronomical and molecular levels. A specific focus is given to recent molecular breakthroughs and agronomic approaches that may improve boron efficiency. The review focuses on practices that may alleviate the problems caused by boron-deficient soils by investigating the genetic and physiological mechanisms of boron tolerance. In summary, this review describes the integration of molecular information with practical agronomy as an important aspect of breeding future nutrient-efficient rapeseed cultivars that can sustain increasing yields while being cultivated in regions with boron-deficient soils. Full article

Calcium (Ca) and Boron (B) are structural components of the cell wall with limited phloem mobility. The absorption, movement, and distribution of these two nutrients have a greater effect on leaves than on fruits since their transport is dependent on transpiration flow. This research aimed to study the absorption and movement of ⁴⁵Ca applied to the soil and the fruit of sweet cherry trees under B-deficient and B-adequate soil conditions. In the first experiment, ⁴⁵Ca was applied to the soil surface before the occurrence of leaf senescence. Soil and tree components were sampled and analyzed 6 months after ⁴⁵Ca application. The second experiment involved a ⁴⁵Ca application to the surface of small fruits with 5 mm diameters, which were analyzed after 45 days. The tree Ca allocation in the B-deficient soil condition was significantly fewer in shoots and higher in roots, contrary to the B-adequate soil. On the other hand, the fruit evidenced significant differences in Ca levels in the edible portion of the fruit (i.e., the flesh and peel), which was higher in the B-adequate soil condition. Therefore, under B-deficient soil, Ca was ‘retained’ in the root system and in the fruit pit, suggesting a synergistic mechanism between Ca and B. This mechanism might indicate a survival ecological function where B triggers biological signals to restore Ca homeostasis. Full article

Boron (B) is an essential micronutrient for the development of crops, and its reproductive stage is particularly sensitive to B deficiency. Brassica napus L., as an important oil-crop species, is extremely vulnerable to B deficiency. The typical B-deficient symptom of “flowering without seed setting” usually results in severe yield loss. However, few studies have focused on the response of the reproductive organs to B deficiency. In this study, the B-efficient variety “Zhongshuang 11” (ZS11) and the B-inefficient variety “Westar 10” (W10) of Brassica napus were selected to be cultivated at the developmental stage (BBCH15) in a pot experiment, both with and without B supply. Clear phenotype differences in B deficiency between the two varieties’ flowers appeared only at the reproductive stage, and only W10 showed symptoms of delayed flower opening, stigma exsertion, and resulted in abortion. Transcriptome analysis for the early buds of both varieties between B supply (+B) and free (−B) treatments revealed that W10 had more differentially expressed genes (DEGs) corresponding to its greater susceptibility to −B. As two potential mechanisms to improve B-efficient utilization, we focused on analyzing the expression profiles of B transporter-related genes and phytohormone metabolism-related genes. BnaC05.NIP7;1, BnaC08.NIP3;1, and BnaBOR2s were identified as the key genes which could enhance the capacity of B translocation to buds of ZS11. Additionally, combined with a phytohormone concentration measurement, we showed that a significant increase in IAA and a drastic decrease in JA could predominantly lead to the abnormal development of W10’s buds. BnaC02.NIT2 (Nitrilase 2) and BnaKAT5s (3-Ketoacyl-CoA Thiolase 5), which are IAA and JA biosynthesis genes, respectively, could be the key genes responsible for the changes in IAA and JA concentrations in W10’s buds under −B. These candidate genes may regulate the genotype differences in the response of the rapeseed reproductive stage to −B between different B-efficient varieties. It also has potential to breed rapeseed varieties with B-efficient utilization in the reproductive stage, which would improve the seed yield under −B condition. Full article

Lead (Pb) poses a significant risk to human health and the environment. Global Pb production and consumption have markedly risen due to unregulated development and urbanization, Pb smelting, and Pb-acid battery processing. This study addresses the issue of elevated heavy metal concentrations in dust, soil, and groundwater in Shubra Al Khaymah due to the Awadallah Pb smelter. Pb concentration in soil and groundwater escalates in proximity to the Awadallah smelter and diminishes with distance from it—the surface soil functions as a repository for heavy metals. The concentrations of Pb (50–1500 µg/L), manganese (Mn) (1–750 µg/L), iron (Fe) (200–1250 µg/L), and boron (B) (250–1750 µg/L) in the groundwater stratum exceeded drinking and irrigation standards. A solution to the groundwater system issue is proposed by employing pumping wells adjacent to the riverbed to recover the contaminated water from the hydrogeological environment. Processing Modflow Path (PMPATH) program may delineate groundwater protection zones according to the travel time of 150 days (Zones 1 and 2) and the whole watershed source (Zone 3). An injection well was constructed to replenish excellent water quality in the groundwater aquifer in the upstream region. A 3D model of dissolved matter transport was created to examine the concentration distribution across remediation time in the contaminated region. This model demonstrates that, after 365 days of injection, the C/Co concentration ratio exceeded 70% in the downstream area, rendering it appropriate for drinking and irrigation. The alternate strategy is to encapsulate the severely contaminated zone. All measures aim to decrease the piezometric pressure in the vicinity, directing groundwater flow towards the contaminated zone, as accomplished by Processing Modflow Windows (PMWIN). Full article

Brassinosteroids (BRs) are crucial plant hormones that play a significant role in regulating various physiological processes, including micronutrient homeostasis. This review delves into the complex roles of BRs in the uptake, distribution, and utilization of essential micronutrients such as iron (Fe), zinc (Zn), manganese (Mn), copper (Cu), and boron (B). BRs influence the expression of key transporter genes responsible for the absorption and internal distribution of these micronutrients. For iron, BRs enhance the expression of genes related to iron reduction and transport, improve root architecture, and strengthen stress tolerance mechanisms. Regarding zinc, BRs regulate the expression of zinc transporters and support root development, thereby optimizing zinc uptake. Manganese homeostasis is managed through the BR-mediated regulation of manganese transporter genes and chlorophyll production, essential for photosynthesis. For copper, BRs influence the expression of copper transporters and maintain copper-dependent enzyme activities crucial for metabolic functions. Finally, BRs contribute to boron homeostasis by regulating its metabolism, which is vital for cell wall integrity and overall plant development. This review synthesizes recent findings on the mechanistic pathways through which BRs affect micronutrient homeostasis and discusses their implications for enhancing plant nutrition and stress resilience. Understanding these interactions offers valuable insights into strategies for improving micronutrient efficiency in crops, which is essential for sustainable agriculture. This comprehensive analysis highlights the significance of BRs in micronutrient management and provides a framework for future research aimed at optimizing nutrient use and boosting plant productivity. Full article