Search Results (2,298)

Rakı, a traditional distilled beverage produced from grapes, holds significant economic importance in Türkiye; however, comprehensive consumer-focused sensory research remains limited. This study aims to determine the aroma profile, sensory characteristics, and consumer preferences of commercial rakı to guide producers in aligning product characteristics with consumer expectations. Nine commercial rakı samples were evaluated. The aroma composition was analyzed using SBSE-GC-MS. Sensory attributes were assessed by a trained panel through descriptive analysis (DA) and by 100 consumers utilizing the Check-All-That-Apply (CATA) method alongside a liking test. Eighty-one aroma compounds were identified, predominantly the phenylpropanoids trans-anethole and estragole, with monoterpenes and sesquiterpenes dominating the secondary profile. Integrating instrumental data with DA evaluations suggests that anethole and sesquiterpenes likely contribute to the attributes related to visual coating, body, creamy, mastic, persistency, and complexity. Consumer profiling revealed two distinct preference groups. Older, frequent consumers preferred complex, high-alcohol profiles with trigeminal harshness and visual glass coating, whereas younger, casual consumers preferred smoother rakı with a traditional white appearance, reacting negatively to “boiled aniseed” flavors and the yellowish tint of oak-aged versions. The CATA technique effectively distinguished these profiles. To enhance overall product quality, producers should eliminate “boiled” defects and adjust sensory profiles: complex products for experienced consumers and visually traditional, smooth profiles for younger consumers. According to current knowledge, this is the first study to employ the CATA method alongside consumer profiling and preference mapping in the sensory evaluation of rakı. Full article

Previous studies on velvet antler processing have mainly evaluated single techniques, and systematic comparisons of processing combinations are limited. This study investigated the effects of different processing combinations on the nutritional composition and physicochemical properties of velvet antler from red deer and sika deer. A 2 × 2 factorial design was applied: Blood-Retained vs. Blood-Removed and Boiled/Fried (zhuzha; no deep-frying) vs. Vacuum Freeze-Dried. In this study, Boiled/Fried was treated as a single processing method. The four processing combinations were analyzed as independent groups using one-way ANOVA. Additionally, two-way ANOVA was conducted to evaluate the main effects of pretreatment, dehydration method, and their interaction on the measured indices. To account for species background, a three-way ANOVA (species × pretreatment × dehydration) was further conducted for key indices. Moisture, crude protein, ash, and crude fat contents were determined. All composition-related indices were evaluated on both wet-weight and dry-weight bases to distinguish moisture-driven concentration or dilution effects from processing-related retention changes. Principal component analysis (PCA) and orthogonal partial least squares discriminant analysis (OPLS-DA) were conducted for multivariate evaluation. Spearman’s rank correlation was used for association analysis, and Pearson’s correlation with linear regression was applied to quantify linear relationships (reported as r). Freeze-drying significantly reduced moisture content (p < 0.01) and increased crude protein content (p < 0.05). PCA and OPLS-DA demonstrated clear compositional separation among the four processing combinations, with moisture and crude protein as the main contributors (cumulative explained variance > 83%). The effects of Blood-Retained and Blood-Removed treatments differed between species. Three-way ANOVA indicated significant species-dependent effects (e.g., species × pretreatment and or species × dehydration interactions), while the pretreatment × dehydration interaction was significant for TAAs. In the Boiled/Fried groups, total amino acid content (TAA) decreased with increasing moisture. In the Freeze-Dried groups, moisture was significantly negatively correlated with TAAs in the Blood-Retained treatment (Pearson r = −0.886, p < 0.05), whereas no significant correlation was observed in the Blood-Removed treatment (r = 0.429, p > 0.05). Wet- versus dry-basis comparisons indicated that some between-treatment differences were attributable to moisture-related concentration or dilution effects, whereas differences persisting on a dry basis more directly reflected processing-related nutrient retention. Processing combinations produced species-dependent effects in velvet antler. The three-way ANOVA supported species-dependent pretreatment effects and confirmed that the influence of blood retention or removal on amino acid outcomes was contingent on the dehydration regime (pretreatment × dehydration for TAAs). From an application standpoint, no single processing route is universally optimal across all quality attributes; freeze-drying provides a robust baseline, whereas the choice of blood retention or removal should be made in a target-oriented manner (e.g., physicochemical stability versus protein and amino acid retention) while accounting for species background and interaction effects. Therefore, these findings provide a scientific basis for improving product quality, processing efficiency, and standardization in China’s velvet antler industry. Full article

This study investigates the dripping and leakage problem in kitchenware known as the “teapot effect” through a multidisciplinary experimental approach encompassing fluid mechanics, material science, and ergonomic design. Unlike previous studies confined to idealized geometries and single-fluid analyses, this work systematically examines 32 distinct spout geometries from commercially available teapots, coffee pots, and milk jugs under realistic operating conditions. Experiments were performed using three fluids with contrasting rheological properties: boiling black tea, cow’s milk, and Turkish coffee on a precision rotating platform operating at quasi-static (1°/s) to isolate surface tension, gravitational, and geometric effects from inertial forces. Three quantitative parameters were measured for each specimen: capillary dome angle, teapot effect angle range, and optimum pouring angle. Results demonstrate that spout tip geometry is the dominant controlling parameter. Thin-lipped elliptical cross-sections effectively suppressed dripping, whereas triangular and wide curved geometries produced the teapot effect across broad pouring angle ranges reaching up to 70°. A spout outlet extension length of 4–5 mm combined with a spout tip radius below 4 mm was found necessary and sufficient for clean flow separation. Furthermore, suspended particles and proteins in milk and Turkish coffee were shown to intensify the teapot effect by disrupting contact line dynamics at the spout tip. These findings provide quantitative design thresholds directly applicable to industrial kitchenware development. Full article

The conversion of surplus electrical energy into thermal energy represents an effective pathway for increasing the flexibility of renewable-energy systems. This study presents an experimental and numerical assessment of a compact vapor-assisted sensible heat storage unit designed to transform electrical input into stored thermal energy using a controlled evaporation–condensation process inside a vertical steel cylinder. An 800 W immersion heater was employed to generate vapor, while nine temperature sensors monitored the thermal response of the evaporator, enclosure air, and storage medium. Two operating configurations, insulated and non-insulated, were investigated to characterize charging and discharging dynamics. In parallel, CFD simulations performed in ANSYS Fluent were used to analyze coupled heat transfer and phase-change mechanisms. The results demonstrate efficient electrical-to-thermal energy conversion, with rapid temperature rise during charging driven by vapor-assisted convection following the onset of boiling. Experimental data and numerical predictions consistently reveal a transition from conduction-dominated heating to a phase-change-enhanced regime, which accelerates heat distribution and thermal homogenization within the storage unit. Comparative tests further indicate that reduced external losses improve heat retention during discharge. Overall, the combined experimental–numerical approach confirms the capability of the proposed compact system to store electrically generated heat in a stable and repeatable manner, highlighting its potential for daily photovoltaic energy buffering and small-scale renewable-energy applications. Full article

A digital colorimetric method (ACETimage), which utilizes aldol condensation, crotonization, and resinification, was developed and validated to quantify acetaldehyde in the head fraction of Pisco distillation. The optimal conditions for the reaction were as follows: the head Pisco samples were placed in headspace vials, 20% w/w NaOH was added, and the mixture was boiled in water for 2 min. The Color Grab app was used to capture and analyze images of the reactions, with a screen brightness intensity of 0.5, within a maximum post-reaction time of 10 min. The Euclidean distance (ED-RGB) was the color parameter most sensitive to changes, showing a linear correlation with the square of acetaldehyde concentration, with R² values ranging from 0.9926 to 0.9976. The limit of detection (LOD) and limit of quantification (LOQ) for the ACETimage method were determined to be 30 and 95.3 mg/L, respectively. A significant correlation was observed between the acetaldehyde content measured using ACETimage and gas chromatography (Spearman’s r = 0.9373). Bland–Altman analysis indicated that the differences between the two methods were within the 95% limits of agreement. ACETimage offers a rapid, cost-effective, and user-friendly solution for monitoring acetaldehyde levels during Pisco distillation, enabling easy implementation in production environments, both artisanal and industrial, with minimal sample preparation and limited personnel training. Full article

The Dongqiyishan W-polymetallic deposit is a large porphyry deposit in the Beishan region, Inner Mongolia. Based on cross-cutting relationships of veins and distinct mineral assemblages, the hydrothermal evolution of the Dongqiyishan deposit can be divided into three mineralization stages, with corresponding characteristic alteration types: (1) early W mineralization stage, dominated by potassic–sodic alteration; (2) main W mineralization stage, characterized by extensive phyllic alteration; and (3) post-W-mineralization hydrothermal stage, associated with quartz–fluorite–calcite alteration. This study employs an integrated approach, including molybdenite Re-Os dating, microthermometry of fluid inclusions, and H-O-S isotopic analyses, to investigate the genesis of the deposit. The results show that: (1) the metallogenic age of the deposit is 222.2 ± 1.5 Ma (MSWD = 0.58; Middle Triassic), which was likely caused by the northward subduction of the Paleo-Tethys Ocean; (2) the metallogenic fluids of Stage I (homogenization temperature 350~400 °C, salinity 6.0~8.0 wt.% NaCl eqv.) and Stage II (homogenization temperature 300~350 °C, salinity 4.0~6.0 wt.% NaCl eqv.) are mainly from magmatic water, and Stage III (homogenization temperature 225~275 °C, salinity 4.0~8.0 wt.% NaCl eqv.) has a mixed fluid of magmatic water and meteoric water; (3) the ore-forming materials were mainly derived from magma, which is supported by the S isotopic results (δ³⁴S = −0.5‰~1.6‰, average 0.93‰); (4) mineralization depths calculated through fluid inclusions are 0.52–1.60 km (Stage I), 0.70–1.80 km (Stage II) and 0.10–0.49 km (Stage III); and (5) Stage I W precipitation was likely driven by fluid boiling and water–rock interaction, Stage II W precipitation by water–rock interaction principally, and Stage III fluorite precipitation by water–rock interaction plus fluid cooling. This research provides theoretical guidance for W-polymetallic prospecting in the Beishan of Inner Mongolia. Full article

Among the naturally abundant clays in the Earth’s crust, montmorillonite (MMT), a member of the smectite group, stands out for its versatility. Its interesting properties can be further improved by chemical processing with inorganic acids and reaction temperatures close to boiling. In this study, a Brazilian polycationic MMT was treated with a low-concentration (2M) aqueous solution of hydrochloric acid at 60 and 70 °C for 5 h. The resulting modified clay was then employed in the purification of post-consumption oil (PCO), specifically soybean oil. The effect of the modification variables of the clay and also the purification parameters (time and temperature) were investigated, comparing the adsorptive and purification capacities of the modified MMT with those of the natural and a commercial clay sample. The characterization of the MMT (raw and modified) was carried out by bulk density, moisture content, plasticity limit, BET, SEM/EDS, XRD, and FTIR, whereas the characterization of the PCO, as-received and after purification, involved the analyses of apparent density, relative flow time, UV-Vis spectrophotometry, and acid value. The results show that light acid activation, especially at 70 °C, promoted a significant increase in the surface area up to 96% and the adsorption capacity of the clay. The oil purification showed good results in all tests, with the best condition being 70 °C for 24 h with the C70 clay. Thus, the satisfactory results represent an economy of time and energy. Full article

This study proposes a CO₂ re-liquefaction system utilizing the cold energy of LNG and liquid hydrogen (LH₂) to efficiently manage boil-off gas in alternative fuel-based CO₂ carriers. Process simulations using Aspen HYSYS V11 under 100% and 70% propulsion loads evaluated the Specific Energy Consumption (SEC), Coefficient of Performance (COP), UA of heat exchangers, and Specific Life Cycle Cost (SLCC). The results demonstrate that under both 100% and 70% propulsion load conditions, the utilization of cold energy decreases the SEC by 24.5% and improves the COP by approximately 34% compared to the reference model without cold energy utilization. Sensitivity analysis on the minimum temperature approach indicates limited impact on performance. The UA of the heat exchangers decreased by up to 83% (LNG) and 87% (LH₂), offering significant downsizing advantages. Economically, SLCC was reduced by up to 14.8% and 15.9% for the LNG and H₂ models, respectively, due to lower Capital Expenditure (CAPEX) and Operating Expenditure (OPEX). Consequently, this study demonstrates that exploiting the cold energy of alternative fuels significantly improves both the thermodynamic performance and economic feasibility of CO₂ re-liquefaction systems, providing foundational data for future optimization. Full article

The effect of structure on the properties of cotton fibers is yet to be fully understood even after many years of research. This is due to the presence of convolutions that occur at various intervals in cotton fibers. An attempt was made in this investigation to remove these convolutions using liquid ammonia treatment. The optical and X-ray orientation angles of two varieties of G. hirsutum cotton fibers were investigated at various stages of maturity, and results were compared. An American upland variety was also studied. Four-hour treatment of cotton fibers in liquid ammonia at a temperature of −50 °C ensures a complete change of the lattice structure from cellulose I polymorph to cellulose III polymorph. The cellulose I lattice structure is restored by boiling it in distilled water for 24 h. X-ray diffractograms confirm these conversions. Mature fibers after treatments are devoid of convolutions and are rounded in appearance with no central lumen. The scanning electron micrographs revealed these morphological structures. A close correlation exists between the optical and X-ray orientation measurements and are both strongly dependent on fiber maturity. In all the varieties studied, a maturity ratio of at least 0.8 is required for a cotton fiber to be of commercial value, in terms of strength and durability The progressive build-up of both the primary and secondary walls as the fiber matures shows a gradual decrease in helix angles and, hence, an increase in the orientation of the fibrils, conforming to the constant pitch model. The effect of convolutions on both the optical and X-ray orientation angle is found to be higher than 10%. Full article

[¹¹¹In]In-diethylenetriaminepentaacetic acid-5,10,15,20-tetraphenylporphyrin ([¹¹¹In]In-DTPA-TPP) nanodroplets were developed for cancer theranostics, featuring ultrasound-sensitive properties. The designed nanodroplets that encapsulate the low-boiling-point liquid perfluorocarbon and IR-780 iodide, a near-infrared fluorescent dye, with surface conjugation of ¹¹¹In-labeled porphyrin derivative, were synthesized and evaluated by in vitro and in vivo experiments. The cellular uptake of [¹¹¹In]In-DTPA-TPP nanodroplets was significantly higher than that of control nanodroplets without TPP. Biodistribution experiments revealed greater tumor accumulation in mice injected with [¹¹¹In]In-DTPA-TPP nanodroplets than in those injected with control nanodroplets lacking TPP. Additionally, the accumulation of [¹¹¹In]In-DTPA-TPP nanodroplets in the tumor was visualized by single-photon emission computed tomography. Sonodynamic therapeutic experiments revealed that DTPA-TPP nanodroplets at 10 µmol total lipids/kg weight with a single ultrasound irradiation onto the tumor area significantly inhibited tumor growth. These results indicate that [¹¹¹In]In-DTPA-TPP nanodroplets would be promising cancer theranostic agents. Full article

This study investigates how porous structure formation influences the properties and safety characteristics of composite rocket propellants. Particular attention was given to approaches that may support more sustainable propellant formulations and processing methods. The work compares the efficiency of different sample-structuring and foaming methods, including a chemical foaming strategy based on two ammonium salts. Additionally, it evaluates the feasibility of generating porosity in propellants containing glycidyl azide polymer through the retention of a low-boiling solvent, remaining from synthesis. This approach is expected to reduce the number of processing steps and simplify them, translating into lessened environmental impact. Propellants incorporating this polymer were found to exhibit consistent low-level porosity and improved performance compared to other ammonium nitrate-based propellants, constituting a potential sustainable alternative to perchlorate-based propellants. The investigation encompassed decomposition kinetics (including decomposition activation energy), combustion product analysis, and exploratory nitrogen porosimetry. From a sustainability perspective, the investigated approach addresses key limitations of perchlorate-based propellants by eliminating chlorine-containing oxidising agents and reducing the need for auxiliary chemicals. In particular, the physical foaming strategy enables pore formation using residual solvent, which is already present in the system, supporting waste minimisation and inherently safer processing. These aspects are discussed in the context of selected principles of Green Chemistry and fundamental properties–sustainability trade-offs. Overall, the results highlight how foaming method selection affects not only propellant behaviour but also opportunities for more resource-efficient and environmentally conscious manufacturing routes. Full article

Aging drinking water infrastructure and persistent underinvestment have increased the frequency of service disruptions across public water systems in the United States, yet empirical evidence on the financial implications of such disruptions for water utilities remains limited. This study examines the relationship between boil water advisory (BWA) exposure and operating costs incurred by public water utilities using a cross-sectional dataset of 239 publicly owned community water systems in West Virginia during the 2023 fiscal year. Utility costs are measured using operating revenue deductions, an accounting measure capturing operating expenses, taxes, and depreciation. Regression results indicate a statistically significant positive association between cumulative BWA exposure and utility costs. Specifically, a one-day increase in advisory exposure is associated with approximately a 0.08% increase in operating deductions, implying an average cost increase of $1020 per utility for each day under advisory. Duration-based measures of BWA exposure explain cost variation more consistently than simple advisory counts, highlighting the importance of capturing persistence rather than frequency alone. These findings demonstrate that service reliability disruptions impose financial burdens on public water utilities and highlight the need to incorporate reliability considerations into infrastructure investment decisions, rate setting, and long-term financial planning, particularly for small and resource-constrained systems. Full article

Microwave-assisted depolymerization (MD) of heterogeneous postconsumer plastics was carried out in a quarter-scale reactor to evaluate product composition and the influence of feedstock type on oil quantity and quality. Various waste streams, including: PS, PP, ABS materials, keyboard housings, textile plastics, PCBs, and mixed electronic components, were processed in 3–6 kg batches using magnetron powers up to 2 × 1.55 kW. All experiments yielded a condensed liquid fraction, with color intensity correlating with aromatic content. FTIR spectroscopy showed that all oils consisted of hydrocarbon matrices dominated by aliphatic C-H stretching bands (2956–2850 cm⁻¹). Aromatic contributions varied significantly: PS produced oils rich in aromatic OOP C-H bands (900–650 cm⁻¹), PP yielded predominantly aliphatic oils with minor aromatic features, and ABS or electronics materials produced mixed aliphatic–aromatic profiles. Textile oils additionally exhibited carbonyl and O-H bands, indicating oxygenated decomposition products. Fractional distillation separated the oils into low-boiling aliphatic (<250 °C) and heavier aromatic (250–350 °C) fractions. These results suggest that MD reliably converts diverse plastic wastes into hydrocarbon oils whose spectroscopic characteristics reflect both feedstock composition and thermal pathways intrinsic to microwave heating. Full article

The purpose of this work is to investigate the binding state of inorganic elements to flavonoid components in aqueous extract of Silybum marianum (SM) seeds, as well as the antioxidant activity of the extract. This study employed reversed-phase high-performance liquid chromatography (RP-HPLC) to separate silymarin flavonoids in boiling water decoction of SM seeds, and collected the post-column effluent in the segments according to the retention time of seven main silymarin flavonoid components. Inductively coupled plasma mass spectrometry (ICP-MS) was subsequently utilized to quantify nine inorganic elements (As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Zn) in the collected HPLC fractions of the decoction. Meanwhile, electron paramagnetic resonance spectroscopy (EPR) was employed to assess the free radical scavenging activity of aqueous extract of SM seeds, using the signal intensity changes of 2,2-diphenyl-1-picrylhydrazyl (DPPH) and DMPO-OH• adducts as quantitative metrics. The results showed that essential trace elements (Cu, Fe, Mn, Zn) mainly existed as inorganic ions or strong polar forms in the tea-like infusion, with weak binding to flavonoid compounds. On the other hand, the aqueous extract exhibited significant •OH scavenging capacity, with a scavenging rate of 95% against •OH generated by continuous 5 min ultraviolet irradiation of H₂O₂ aqueous solution. This study provides experimental evidence for the development of SM as a food–medicine dual-purpose resource, proposing that consumption of SM seed tea represents a facile and effective approach to supplement trace elements and intake silymarin for enhancing endogenous antioxidant defense. Full article

Global water scarcity, intensified by population growth, economic development, and climate change, presents a significant challenge, with the cosmetics industry contributing heavily to water demand. Simultaneously, the cork industry generates substantial amounts of cork boiling wastewater (CBW), an acidic effluent with environmental hazards. This study explored CBW’s potential for cosmetic application, focusing on safety, physicochemical properties, and suitability for incorporation in cosmetic formulations. Three CBW samples (A, B and C) were analyzed for pH, conductivity, turbidity, density, 2,2-diphenyl-1-picrylhydrazyl (DPPH) scavenging activity, and total phenolic content. CBW A displayed suitable physicochemical properties and potential antioxidant activity and was selected for further investigation. Human keratinocyte viability was assessed using CBW A before and after adsorption treatment with silica (TCBW A) to reduce cytotoxicity. CBW A was more toxic to human keratinocytes compared to control water, but treatment improved cell viability. This treatment had minimal impact on physicochemical parameters, aside from reducing phenolic content. Metal concentrations in TCBW A remained within cosmetic safety limits. TCBW A was incorporated into an oil-in-water (O/W) cream, which was further evaluated for pH, droplet size, rheological behavior, textural properties, and stability. The resulting cream was homogeneous, woody-scented, with uniform droplet size and stable after centrifugation. TCBW A incorporation provided suitable rheological behavior and formulation stability after 90 days of storage at 25 °C. These findings indicate that TCBW A has low cytotoxicity, suitable physicochemical properties, and provides stable cosmetic formulations, highlighting its potential as a sustainable ingredient for the cosmetic industry. Full article