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Search Results (274)

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Keywords = asymmetric geometry

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12 pages, 5607 KiB  
Article
Tunable Dual-Mode Resonant Excitation of Dumbbell-Shaped Structures in the Mid-Infrared Band
by Tao Jiang, Yafei Li, Zhuangzhuang Xu, Xike Qian, Rui Shi, Xiufei Li, Meng Wang and Ze Li
Nanomaterials 2025, 15(15), 1181; https://doi.org/10.3390/nano15151181 - 31 Jul 2025
Viewed by 45
Abstract
Metasurfaces have drawn extensive research attention for their unique optical properties and vast application potential. Among the various resonant modes induced in metasurfaces, BIC and electric anapole modes stand out as particularly interesting due to their distinctive physical characteristics. In this work, we [...] Read more.
Metasurfaces have drawn extensive research attention for their unique optical properties and vast application potential. Among the various resonant modes induced in metasurfaces, BIC and electric anapole modes stand out as particularly interesting due to their distinctive physical characteristics. In this work, we designed and investigated novel dimeric dumbbell-shaped metasurfaces incorporating two independently tunable asymmetric parameters. This structural innovation enables the simultaneous excitation of both electric anapole and QBIC modes under normally incident MIR illumination. More importantly, by adjusting these two asymmetric parameters, one can independently tune the resonance peaks of the two modes, thereby overcoming the performance limits of conventional single-peak modulation. This metasurface design demonstrates outstanding performance for dielectric environment-sensing applications. We conducted a comprehensive investigation of the sensing sensitivity for dumbbell-shaped metasurfaces of various geometries. Our simulation results show that the circular-shaped configuration achieved high sensitivity, reaching 20,930 GHz/RIU. This work offers a novel design paradigm for multi-mode control and functionalization of metasurface structures. Full article
(This article belongs to the Section Theory and Simulation of Nanostructures)
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34 pages, 12831 KiB  
Article
Behavior of Large-Diameter Circular Deep Excavation Under Asymmetric Surface Surcharge
by Ping Zhao, Youqiang Qiu, Feng Liu, Zhanqi Wang and Panpan Guo
Symmetry 2025, 17(8), 1194; https://doi.org/10.3390/sym17081194 - 25 Jul 2025
Viewed by 226
Abstract
Circular deep excavations, characterized by their symmetrical geometry, are commonly employed in constructing foundations for large-span suspension bridges and as launching shafts for shield tunneling. However, the mechanical behavior of such excavations under asymmetric surface surcharge remains inadequately understood due to a paucity [...] Read more.
Circular deep excavations, characterized by their symmetrical geometry, are commonly employed in constructing foundations for large-span suspension bridges and as launching shafts for shield tunneling. However, the mechanical behavior of such excavations under asymmetric surface surcharge remains inadequately understood due to a paucity of relevant investigations. This study addresses this knowledge gap by establishing a three-dimensional finite element model (3D-FEA) based on the anchor deep excavation project of a specific bridge. The model is utilized to investigate the influence of asymmetric surcharge on the forces and deformations within the supporting structure. The results show that both the internal force and displacement cloud diagrams of the support structure exhibit asymmetric characteristics. The distribution of displacement and internal forces has spatial effects, and the maximum values all occur in the areas where asymmetric loads are applied. The maximum values of the displacement, axial force, and shear force of underground continuous walls increase with the increase in the excavation depth. The total displacement curves all show the feature of a “bulging belly”. The maximum displacement is 13.3 mm. The axial force is mainly compression, with a maximum value of −9514 kN/m. The maximum positive and negative values of the shear force are 333 kN/m and −705 kN/m, respectively. The bending moment diagram of different monitoring points shows the characteristics of “bow knot”. The maximum values of the positive bending moment and negative bending moment are 1509.4 kN·m/m and −2394.3 kN·m/m, respectively. The axial force of the ring beam is mainly compression, with a maximum value of −5360 kN, which occurs in ring beams 3, 4, and 5. The displacement cloud diagram of the support structure under symmetrical loads shows symmetrical characteristics. Under different load conditions, the displacement curve of the diaphragm wall shows the characteristics of “bulge belly”. The forms of loads with displacements from largest to smallest at the same position are as follows: asymmetric loads, symmetrical loads, and no loads. These findings provide valuable insights for optimizing the structural design of similar deep excavation projects and contribute to promoting sustainable urban underground development. Full article
(This article belongs to the Special Issue Symmetry, Asymmetry and Nonlinearity in Geomechanics)
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11 pages, 2975 KiB  
Article
Crystallographic Combinations: Understanding Polymorphism and Approximate Symmetry in N-(1,3-Thiazol-2-yl)benzamide
by Johannes C. Voigt, Michael J. Hall and Paul G. Waddell
Crystals 2025, 15(7), 657; https://doi.org/10.3390/cryst15070657 - 18 Jul 2025
Viewed by 391
Abstract
A new polymorph of N-(1,3-thiazol-2-yl)benzamide crystallises in the monoclinic space group Pc with four crystallographically independent molecules (Z′ = 4) in the asymmetric unit. Where the previously reported polymorphs exhibit two distinct hydrogen-bonded dimer geometries exclusively, the asymmetric unit of the new [...] Read more.
A new polymorph of N-(1,3-thiazol-2-yl)benzamide crystallises in the monoclinic space group Pc with four crystallographically independent molecules (Z′ = 4) in the asymmetric unit. Where the previously reported polymorphs exhibit two distinct hydrogen-bonded dimer geometries exclusively, the asymmetric unit of the new polymorph comprises both. Approximate symmetry was observed to relate the molecules of these dimers. These approximate symmetry elements combine to form a structure with distorted P21/c space group symmetry, rationalising the unexpectedly high number of crystallographically independent molecules. Full article
(This article belongs to the Special Issue Celebrating the 10th Anniversary of International Crystallography)
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21 pages, 4628 KiB  
Article
Design and Performance Evaluation of a Sub-6 GHz Multi-Port Coupled Antenna for 5G NR Mobile Applications
by Cheol Yoon, Yunsub Lee, Wonmo Seong and Woosu Kim
Appl. Sci. 2025, 15(14), 7804; https://doi.org/10.3390/app15147804 - 11 Jul 2025
Viewed by 274
Abstract
This paper describes a compact multi-port sub-6 GHz multiple-input multiple-output (MIMO) antenna system tailored for 5G NR mobile terminals operating in the n77 (3.3–4.2 GHz), n78 (3.3–3.8 GHz), and n79 (4.4–5.0 GHz) frequency bands. The proposed design leverages a shared coupling approach that [...] Read more.
This paper describes a compact multi-port sub-6 GHz multiple-input multiple-output (MIMO) antenna system tailored for 5G NR mobile terminals operating in the n77 (3.3–4.2 GHz), n78 (3.3–3.8 GHz), and n79 (4.4–5.0 GHz) frequency bands. The proposed design leverages a shared coupling approach that exploits the smartphone metal frame as the radiating element, facilitating efficient integration within the spatial constraints of modern mobile devices. A two-stage method is used to mitigate the mutual coupling and correlation issues typically encountered when designing compact MIMO configurations. Initially, a four-port structure is used to evaluate broadband impedance and spatial feasibility. Based on the observed limitations in terms of isolation and the envelope correlation coefficient (ECC), the final configuration was reconfigured as an optimized two-port layout with a refined coupling geometry and effective current path control. The fabricated two-port prototype exhibited a measured voltage standing wave ratio below 3:1 across the n78 band on both ports, with the isolation levels attaining –12.4 dB and ECCs below 0.12. The radiation efficiency exceeded −6 dB across the operational band, and the radiation patterns were stable at 3.3, 3.5, and 3.8 GHz, confirming that the system was appropriate for MIMO deployment. The antenna supports asymmetric per-port efficiency targets ranging from −4.5 to −10 dB. These are the realistic layout constraints of commercial smartphones. In summary, this study shows that a metal frame integrated two-port MIMO antenna enables wideband sub-6 GHz operation by meeting the key impedance and system-level performance requirements. Our method can be used to develop a scalable platform assisting future multi-band antenna integration in mass-market 5G smartphones. Full article
(This article belongs to the Special Issue Antennas for Next-Generation Electromagnetic Applications)
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28 pages, 7820 KiB  
Review
Mechanisms and Performance of Composite Joints Through Adhesive and Interlocking Means—A Review
by Khishigdorj Davaasambuu, Yu Dong, Alokesh Pramanik and Animesh Kumar Basak
J. Compos. Sci. 2025, 9(7), 359; https://doi.org/10.3390/jcs9070359 - 10 Jul 2025
Viewed by 784
Abstract
Conventional adhesively bonded joints, such as single-lap, curved-lap, wavy-lap, double-lap, stepped-lap, and scarf joints, are widely used for aerospace, automotive, and medical applications. These adhesively bonded joints exhibit different load transfer mechanisms and stress distributions within adhesive layers, which depend primarily on their [...] Read more.
Conventional adhesively bonded joints, such as single-lap, curved-lap, wavy-lap, double-lap, stepped-lap, and scarf joints, are widely used for aerospace, automotive, and medical applications. These adhesively bonded joints exhibit different load transfer mechanisms and stress distributions within adhesive layers, which depend primarily on their geometries and mechanical properties of bonded materials. As such, joint geometry and material properties play a critical role in determining the capability of the joints to withstand high loads, resist fatigue, and absorb energy under impact loading. This paper investigates the effects of geometry and material dissimilarity on the performance of both conventional bonded and interlocking joints under tensile loading based on the information available in the literature. In addition, bonding and load transfer mechanisms were analysed in detail. It was found that stress concentration often occurs at free edges of the adhesive layer due to geometric discontinuities, while most of the load is carried by these regions rather than its centre. Sharp corners further intensify resulting stresses, thereby increasing the risk of joint failure. Adhesives typically resist shear loads better than peel loads, and stiffness mismatches between adherents induce an asymmetric stress distribution. Nonetheless, similar materials promote symmetric load sharing. Among conventional joints, scarf joints provide the most uniform load distribution. In interlocking joints such as dovetail, T-slot, gooseneck, and elliptical types, the outward bending of the female component under tension can lead to mechanical failure. Full article
(This article belongs to the Special Issue Mechanical Properties of Composite Materials and Joints)
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21 pages, 5159 KiB  
Article
Energy-Efficient AC Electrothermal Microfluidic Pumping via Localized External Heating
by Diganta Dutta, Lanju Mei, Xavier Palmer and Matthew Ziemke
Appl. Sci. 2025, 15(13), 7369; https://doi.org/10.3390/app15137369 - 30 Jun 2025
Viewed by 237
Abstract
In this study, we present a comprehensive numerical investigation of alternating-current electrothermal (ACET) pumping strategies tailored for energy-efficient microfluidic applications. Using coupled electrokinetic and thermal multiphysics simulations in narrow microchannels, we systematically explore the effects of channel geometry, electrode asymmetry and external heating [...] Read more.
In this study, we present a comprehensive numerical investigation of alternating-current electrothermal (ACET) pumping strategies tailored for energy-efficient microfluidic applications. Using coupled electrokinetic and thermal multiphysics simulations in narrow microchannels, we systematically explore the effects of channel geometry, electrode asymmetry and external heating on flow performance and thermal management. A rigorous mesh convergence study confirms velocity deviations below ±0.006 µm/s across the entire operating envelope, ensuring reliable prediction of ACET-driven flows. We demonstrate that increasing channel height from 100 µm to 500 µm reduces peak temperatures by up to 79 K at a constant 2 W heat input, highlighting the critical role of channel dimensions in convective heat dissipation. Introducing a localized external heat source beneath asymmetric electrode pairs enhances convective circulations, while doubling the fluid’s electrical conductivity yields a ~29% increase in net flow rate. From these results, we derive practical design guidelines—combining asymmetric electrode layouts, tailored channel heights, and external heat bias—to realize self-regulating, low-power microfluidic pumps. Such devices hold significant promises for on-chip semiconductor cooling, lab-on-a-chip assays and real-time thermal control in high-performance microelectronic and analytical systems. Full article
(This article belongs to the Section Applied Thermal Engineering)
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26 pages, 5112 KiB  
Article
Mixed Halide Isothiocyanate Tin(II) Compounds, SnHal(NCS): Signs of Tetrel Bonds as Bifurcated Extensions of Long-Range Asymmetric 3c-4e Bonds
by Hans Reuter
Molecules 2025, 30(13), 2700; https://doi.org/10.3390/molecules30132700 - 23 Jun 2025
Viewed by 395
Abstract
As part of a systematic study on the structures of the mixed halide isothiocyanates, SnIIHal(NCS), their single crystals were grown and structurally characterized. For Hal = F (1), the SnClF structure type was confirmed, while with Hal = Cl [...] Read more.
As part of a systematic study on the structures of the mixed halide isothiocyanates, SnIIHal(NCS), their single crystals were grown and structurally characterized. For Hal = F (1), the SnClF structure type was confirmed, while with Hal = Cl (2), Br (3), and I (4), there are three isostructural compounds of a new structure type, and for Hal = Cl (5), there is a second modification of a third structure type. These structure types have been described with respect to the composition and coordination geometry of the first, second, and van der Waals crust coordination spheres and their dependence on the halogen size and thiocyanate binding modes. With respect to the first coordination spheres, all three structure types constitute one-dimensional coordination polymers. In 1, “ladder”-type double chains result from μ3-bridging fluorine atoms, and in 24, single-chains built up from μ2-halogen atoms are pairwise “zipper”-like interconnected via κ2NS-bridging NCS ligands, which manage the halogen-linked chain assembly in the double chains of 5. Based on the octet rule, short atom distances are interpreted in terms of 2c-2e and various (symmetrical, quasi-symmetrical, and asymmetrical) kinds of 3c-4e bonds. Weak contacts, the topology of which suggests the extension of the latter bonding concept, are identified as electron-deficient, bifurcated tetrel bonds. Full article
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13 pages, 3508 KiB  
Article
Increasing Nebulizer Spray Efficiency Using a Baffle with a Conical Surface: A Computational Fluid Dynamics Analysis
by Hung-Chieh Wu, Fu-Lun Chen, Yuan-Ching Chiang, Yi-June Lo, Chun-Li Lin, Wei-Jen Chang and Haw-Ming Huang
Bioengineering 2025, 12(7), 680; https://doi.org/10.3390/bioengineering12070680 - 20 Jun 2025
Viewed by 444
Abstract
Breath-actuated nebulizers used in aerosol therapy are vital to children and patients with disabilities and stand out for their ability to accurat ely deliver medication while minimizing waste. Their performance can be measured according to the mass output and droplet size. This study [...] Read more.
Breath-actuated nebulizers used in aerosol therapy are vital to children and patients with disabilities and stand out for their ability to accurat ely deliver medication while minimizing waste. Their performance can be measured according to the mass output and droplet size. This study aimed to analyze how the baffle impact surface geometries affect the pressure and flow streamlines inside the nebulizer using computational fluid dynamics (CFD). Computer-aided design models of conical symmetric, conical asymmetric, and arc-shaped baffle designs were analyzed using CFD simulations, with the optimal spray output validated through the differences in mass. Conical baffles exhibited superior pressure distribution and output streamlines at 0.25 cm protrusion, suggesting that the nebulizer spray performance can be enhanced by using such a conical baffle impact surface. This result serves as a valuable reference for future research. Full article
(This article belongs to the Section Biomedical Engineering and Biomaterials)
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17 pages, 698 KiB  
Article
A Generalized Helfrich Free Energy Framework for Multicomponent Fluid Membranes
by Hao Wu and Zhong-Can Ou-Yang
Membranes 2025, 15(6), 182; https://doi.org/10.3390/membranes15060182 - 17 Jun 2025
Viewed by 703
Abstract
Cell membranes contain a variety of biomolecules, especially various kinds of lipids and proteins, which constantly change with fluidity and environmental stimuli. Though Helfrich curvature elastic energy has successfully explained many phenomena for single-component membranes, a new theoretical framework for multicomponent membranes is [...] Read more.
Cell membranes contain a variety of biomolecules, especially various kinds of lipids and proteins, which constantly change with fluidity and environmental stimuli. Though Helfrich curvature elastic energy has successfully explained many phenomena for single-component membranes, a new theoretical framework for multicomponent membranes is still a challenge. In this work, we propose a generalized Helfrich free-energy functional describe equilibrium shapes and phase behaviors related to membrane heterogeneity with via curvature-component coupling in a unified framework. For multicomponent membranes, a new but important Laplace–Beltrami operator is derived from the variational calculation on the integral of Gaussian curvature and applied to explain the spontaneous nanotube formation of an asymmetric glycolipid vesicle. Therefore, our general mathematical framework shows a predictive capabilities beyond the existing multicomponent membrane models. The set of new curvature-component coupling EL equations have been derived for global vesicle shapes associated with the composition redistribution of multicomponent membranes for the first time and specified into several typical geometric shape equations. The equilibrium radii of isotonic vesicles for both spherical and cylindrical geometries are calculated. The analytical solution for isotonic vesicles reveals that membrane stability requires distinct elastic moduli among components (kAkBk¯Ak¯B), which is consistent with experimental observations of coexisting lipid domains. Furthermore, we elucidate the biophysical implications of the derived shape equations, linking them to experimentally observed membrane remodeling processes. Our new free-energy framework provides a baseline for more detailed microscopic membrane models. Full article
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16 pages, 12973 KiB  
Article
Study of Inlet Vortex Behavior in Dual-Pump Systems and Its Influence on Pump Operational Instability
by Wei Song, Jilong Lin, Yonggang Lu, Yun Zhao and Zhengwei Wang
Water 2025, 17(12), 1784; https://doi.org/10.3390/w17121784 - 14 Jun 2025
Viewed by 472
Abstract
This study addresses inlet flow distribution and pressure pulsation-induced vibration in LNG dual-pump parallel systems. We investigate an LNG dual-submerged pump tower system. Our approach combines computational fluid dynamics with vortex dynamics theory. We examine inlet flow characteristics under different flow conditions. Pressure [...] Read more.
This study addresses inlet flow distribution and pressure pulsation-induced vibration in LNG dual-pump parallel systems. We investigate an LNG dual-submerged pump tower system. Our approach combines computational fluid dynamics with vortex dynamics theory. We examine inlet flow characteristics under different flow conditions. Pressure pulsation propagation patterns are analyzed. System stability mechanisms are investigated. A 3D model incorporates inducers, impellers, guide vanes, outlet sections, and base structures. The SST k-ω turbulence model and Q-criterion vortex identification reveal key features. Results show minimal head differences during parallel operation. The inlet flow field remains uniform without significant vortices. However, local low-velocity zones beneath the base may cause flow separation at low flows. Pressure pulsations are governed by guide vane rotor–stator interactions. These disturbances propagate backward to impellers and inducers. Outlet sections show asymmetric pressure fluctuations. This asymmetry results from spatial positioning differences. Complex base geometries generate low-intensity vortices. Vortex intensity stabilizes at higher flows. These findings provide theoretical foundations for vibration suppression. Full article
(This article belongs to the Special Issue Hydrodynamics Science Experiments and Simulations, 2nd Edition)
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26 pages, 4773 KiB  
Article
LSE-CVCNet: A Generalized Stereoscopic Matching Network Based on Local Structural Entropy and Multi-Scale Fusion
by Wenbang Yang, Yong Zhao, Ye Gu, Lu Huang, Jianhua Li and Jianchuan Zhao
Entropy 2025, 27(6), 614; https://doi.org/10.3390/e27060614 - 9 Jun 2025
Viewed by 346
Abstract
This study presents LSE-CVCNet, a novel stereo matching network designed to resolve challenges in dynamic scenes, including dynamic feature misalignment caused by texture variability and contextual ambiguity from occlusions. By integrating three key innovations—local structural entropy (LSE) to quantify structural uncertainty in disparity [...] Read more.
This study presents LSE-CVCNet, a novel stereo matching network designed to resolve challenges in dynamic scenes, including dynamic feature misalignment caused by texture variability and contextual ambiguity from occlusions. By integrating three key innovations—local structural entropy (LSE) to quantify structural uncertainty in disparity maps and guide adaptive attention, a cross-image attention mechanism (CIAM-T) to asymmetrically extract features from left/right images for improved feature alignment, and multi-resolution cost volume fusion (MRCV-F) to preserve fine-grained details through multi-scale fusion—LSE-CVCNet enhances disparity estimation accuracy and cross-domain generalization. The experimental results demonstrate robustness under varying lighting, occlusions, and complex geometries, outperforming state-of-the-art methods across multiple data sets. Ablation studies validate each module’s contribution, while cross-domain tests confirm generalization in unseen scenarios. This work establishes a new paradigm for adaptive stereo matching in dynamic environments. Full article
(This article belongs to the Section Multidisciplinary Applications)
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12 pages, 1401 KiB  
Article
Isolation and Preliminary X-Ray Crystallographic Characterisation of the Periplasmic Ligand-Binding Domain of the Chemoreceptor Tlp3 from Campylobacter hepaticus
by Diana Kovaleva, Yue Xin, Mohammad F. Khan, Yu H. Chin and Anna Roujeinikova
Crystals 2025, 15(6), 542; https://doi.org/10.3390/cryst15060542 - 6 Jun 2025
Viewed by 610
Abstract
The Campylobacter genus includes many pathogenic species, with Campylobacter hepaticus primarily implicated in spotty liver disease in poultry. Chemotaxis is one of the well-established mechanisms of pathogenesis of Campylobacter. The chemoreceptor Tlp3, previously studied in C. jejuni, mediates responses to diverse [...] Read more.
The Campylobacter genus includes many pathogenic species, with Campylobacter hepaticus primarily implicated in spotty liver disease in poultry. Chemotaxis is one of the well-established mechanisms of pathogenesis of Campylobacter. The chemoreceptor Tlp3, previously studied in C. jejuni, mediates responses to diverse ligands. Differences between the ligand-binding pockets of Tlp3s in C. hepaticus and C. jejuni may influence ligand specificity and niche adaptation. Here, we report a method for production of the ligand-binding domain of C. hepaticus Tlp3 (Ch Tlp3-LBD) in Escherichia coli inclusion bodies that yields crystallisable protein. Size-exclusion chromatography analysis showed Ch Tlp3-LBD is a monomer in solution. Ch Tlp3-LBD was crystallised using PEG 6000 and LiCl as the precipitants. The crystal lattice symmetry was P2221, with unit cell geometry of a = 82.0, b = 137.7, c = 56.1 Å, and α = β = γ = 90°. X-ray diffraction data have been acquired to 1.6 Å resolution using synchrotron radiation. Estimation of the Matthews coefficient (VM = 2.8 Å3 Da−1) and the outcome of molecular replacement suggested the asymmetric unit is composed of two protein molecules. This work lays the foundation for studies towards understanding the structural basis of ligand recognition by C. hepaticus Tlp3 and its role in pathogenesis. Full article
(This article belongs to the Section Biomolecular Crystals)
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22 pages, 2386 KiB  
Article
A Stochastic Framework for Saint-Venant Torsion in Spherical Shells: Monte Carlo Implementation of the Feynman–Kac Approach
by Behrouz Parsa Moghaddam, Mahmoud A. Zaky, Alireza Sedaghat and Alexandra Galhano
Symmetry 2025, 17(6), 878; https://doi.org/10.3390/sym17060878 - 4 Jun 2025
Viewed by 456
Abstract
This research introduces an innovative probabilistic method for examining torsional stress behavior in spherical shell structures through Monte Carlo simulation techniques. The spherical geometry of these components creates distinctive computational difficulties for conventional analytical and deterministic numerical approaches when solving torsion-related problems. The [...] Read more.
This research introduces an innovative probabilistic method for examining torsional stress behavior in spherical shell structures through Monte Carlo simulation techniques. The spherical geometry of these components creates distinctive computational difficulties for conventional analytical and deterministic numerical approaches when solving torsion-related problems. The authors develop a comprehensive mesh-free Monte Carlo framework built upon the Feynman–Kac formula, which maintains the geometric symmetry of the domain while offering a probabilistic solution representation via stochastic processes on spherical surfaces. The technique models Brownian motion paths on spherical surfaces using the Euler–Maruyama numerical scheme, converting the Saint-Venant torsion equation into a problem of stochastic integration. The computational implementation utilizes the Fibonacci sphere technique for achieving uniform point placement, employs adaptive time-stepping strategies to address pole singularities, and incorporates efficient algorithms for boundary identification. This symmetry-maintaining approach circumvents the mesh generation complications inherent in finite element and finite difference techniques, which typically compromise the problem’s natural symmetry, while delivering comparable precision. Performance evaluations reveal nearly linear parallel computational scaling across up to eight processing cores with efficiency rates above 70%, making the method well-suited for multi-core computational platforms. The approach demonstrates particular effectiveness in analyzing torsional stress patterns in thin-walled spherical components under both symmetric and asymmetric boundary scenarios, where traditional grid-based methods encounter discretization and convergence difficulties. The findings offer valuable practical recommendations for material specification and structural design enhancement, especially relevant for pressure vessel and dome structure applications experiencing torsional loads. However, the probabilistic characteristics of the method create statistical uncertainty that requires cautious result interpretation, and computational expenses may surpass those of deterministic approaches for less complex geometries. Engineering analysis of the outcomes provides actionable recommendations for optimizing material utilization and maintaining structural reliability under torsional loading conditions. Full article
(This article belongs to the Section Engineering and Materials)
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9 pages, 1297 KiB  
Communication
Near-Infrared Emitting Chiral Tetranuclear Erbium Cluster Containing Soft-Base Bisthiazolate Linkers
by Vasily A. Ilichev, Anton F. Rogozhin, Roman V. Rumyantcev, Georgy K. Fukin and Mikhail N. Bochkarev
Molbank 2025, 2025(2), M2015; https://doi.org/10.3390/M2015 - 29 May 2025
Viewed by 1139
Abstract
A tetraerbium cluster containing soft-base dianionic 4,8-difluorobenzo [1,2-d:5,4-d′]bisthiazole-2,6-dithiol (H2L) ligands, μ-OH, and coordinated 1,2-dimethoxyethane (DME) of the general formula {Er4(μ-L)4(μ-OH)4(DME)4} (1) was synthesized using [...] Read more.
A tetraerbium cluster containing soft-base dianionic 4,8-difluorobenzo [1,2-d:5,4-d′]bisthiazole-2,6-dithiol (H2L) ligands, μ-OH, and coordinated 1,2-dimethoxyethane (DME) of the general formula {Er4(μ-L)4(μ-OH)4(DME)4} (1) was synthesized using a one-pot method. X-ray analysis revealed that 1 is an asymmetrical tetramer in which there are four μ2-bridging bisthiazole ligands and four μ2-bridging hydroxide anions per four erbium ions. The molecule of 1 has inherent chirality, and the geometry of intramolecular F…F short contacts implies the formation of a classical halogen bond. Upon excitation by a 375 nm diode laser, compound 1 shows the moderate metal-centered emission of Er3+ ions that peaked at 1530 nm. Full article
(This article belongs to the Section Structure Determination)
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29 pages, 15997 KiB  
Article
Conductivity of Filled Diblock Copolymer Systems: Identifying the Main Influencing Factors
by A. I. Chervanyov
Polymers 2025, 17(11), 1502; https://doi.org/10.3390/polym17111502 - 28 May 2025
Viewed by 278
Abstract
By developing and making use of the multi-scale theoretical approach, we identify the main factors that affect the conductivity of a composite composed of a diblock copolymer (DBC) system and conductive particles. This approach relies on the consistent phase-field model of DBC, Monte-Carlo [...] Read more.
By developing and making use of the multi-scale theoretical approach, we identify the main factors that affect the conductivity of a composite composed of a diblock copolymer (DBC) system and conductive particles. This approach relies on the consistent phase-field model of DBC, Monte-Carlo simulations of the filler localization in DBC, and the resistor network model that mimics the conductive filler network formed in DBC. Based on the described approach, we thoroughly explore the relation among the morphological state of the microphase-separated DBC, localization of fillers in DBC, and the electrical response of the composite. Good agreement with experimental results confirms the accuracy of our theoretical predictions regarding the localization of fillers in the DBC microphases. The main factors affecting the composite conductivity are found to be: (i) affinities of fillers for copolymer blocks; (ii) degree of the segregation of a host DBC system, driven by external stimuli; (iii) geometry of the microphases formed in the microphase-separated DBC; and (iv) interactions between fillers. The conductor-insulator transition in the filler network is found to be caused by the order-disorder transition in the symmetric DBC. The order-order transition between the ordered lamellae and cylindrical microphases of asymmetric DBC causes a spike in the composite conductivity. Full article
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