Search Results (399)

Groundwater quality in arid and semi-arid regions is increasingly affected by salinization, evaporation, abstraction, and agricultural return flow. This study evaluates the hydrochemical evolution, isotopic characteristics, ²²²Rn activity, and water-use suitability of groundwater and associated waters in Karbala Governorate, central Iraq. Seventeen groundwater, lake water, and municipal supply water samples were analyzed for physicochemical parameters, major ions, δ¹⁸O, δ²H, and ²²²Rn. Hydrochemical, isotopic, and water-quality assessment methods were applied to evaluate groundwater evolution, salinization, and suitability for drinking and irrigation. The waters are near-neutral, with pH values of 6.18–7.35, but are strongly mineralized. Electrical conductivity ranges from 1440 to 16,305 µS/cm, and total dissolved solids (TDS) range from 592 to 10,191 mg/L. Most samples belong to a Ca–Mg–SO₄–Cl facies, indicating sulfate- and chloride-rich hard water evolution. The highest mineralization occurs near Karbala proper and lake-influenced sites. Ion ratios and chloro-alkaline indices indicate that evaporite dissolution, gypsum/anhydrite dissolution, carbonate interaction, evaporation, and local ion exchange jointly control groundwater chemistry. Stable isotopes indicate meteoric origin with variable evaporative enrichment; however, highly saline but isotopically depleted water, particularly W8, shows that evaporation alone cannot explain salinization. ²²²Rn activities range from below detection to 11.28 Bq/L and mainly reflect local aquifer contact and degassing. High TDS, sulfate, chloride, and very high hardness limit suitability for drinking-water use. For irrigation, the sodium hazard is low, but salinity, hardness, magnesium hazard, and permeability constraints make most samples unsuitable or restricted. Management should prioritize salinity and hardness control, treatment or blending before domestic use, restricted irrigation of the least saline wells under drainage and soil-salinity monitoring, protection of less mineralized recharge zones, and long-term monitoring of lake-adjacent and agriculturally influenced wells. Full article

Groundwater is an important resource for domestic, agricultural, and ecological use in the Surat Thani basin, southern Thailand, where increasing demand from agriculture, urbanization, and tourism is placing pressure on aquifer systems. This study investigates groundwater recharge and basin-scale flow dynamics using integrated numerical groundwater modeling, stable isotope analysis, and hydrochemical interpretation. A three-layer MODFLOW model representing floodplain (Qfd), terrace (Qt), and semi-consolidated aquifers was calibrated for 2018–2024 using PEST with pilot-point parameterization. Despite there being only four observation wells, the model achieved excellent agreement between simulated and observed heads (weighted RMSE = 0.0707 m). Simulated groundwater generally flows from western uplands toward the central floodplain and eastern coastal plain, with the Tapee River acting mainly as a gaining stream. Recharge rates range from 1.2 to 77.3 mm/yr (mean 23.7 mm/yr), representing only 1–4% of annual precipitation, while evapotranspiration is the dominant form of water loss. Stable isotope signatures (δ²H, δ¹⁸O) indicate recharge from direct monsoonal rainfall with minimal evaporation. Hydrochemical facies evolve from Ca–HCO₃ recharge waters to mixed facies along downgradient flow paths, reflecting increasing residence time and water–rock interaction. The results identify western and northern upland areas as key recharge zones requiring long-term protection and sustainable groundwater management. Full article

Shallow groundwater systems of rural municipalities are highly vulnerable to long-term contamination from former on-site sanitation systems, while the hydrochemical response of the aquifer after sewerage network development may be delayed by several factors. In the present study, a total of 147 shallow groundwater samples collected during the summer sampling campaigns of 2018, 2019, 2023, and 2024 were analyzed for general water-quality parameters including pH, EC, NH₄⁺, NO₂⁻, NO₃⁻, PO₄⁻, Cl⁻, SO₄²⁻, microelements, and potentially toxic elements, including As, Pb, Cd, Ni, Cu, Zn, Fe, and Mn. The dataset was evaluated using descriptive statistics, Piper, Wilcox, and Gibbs diagrams, hierarchical cluster analysis, principal component analysis, and GIS-based spatial interpolation. The results indicate that, more than ten years after sewerage network development (2014), shallow groundwater in the study area still shows considerable contamination, primarily characterized by elevated mean concentrations of ammonium (0.836 mg/L), nitrate (177.43 mg/L), and chloride (313.26 mg/L), accompanied by high electrical conductivity (3115 µS/cm) and sodium enrichment (378.12 mg/L). Spatial and boxplot analyses of SAR further indicated increasing sodium-related heterogeneity after 2018, with higher local SAR values in 2023–2024. Hydrochemical diagrams revealed a shift towards Ca-Cl type to Na–Cl types, while multivariate analyses confirmed that salinity enrichment, nitrate contamination, water–rock interaction and redox-sensitive trace element mobilization act as overlapping but partly separable controls. The nitrate–chloride source plot indicated mixed contamination origins, dominated by residual sewage influence and manure-related inputs, with diffuse agricultural nitrogen leaching. Arsenic was used as a supporting indicator of mixing with wastewater; however, As was no longer detectable in most of the investigated wells, suggesting a marked reduction in the former wastewater leakage. These results support the slow attenuation of contamination in the shallow groundwater system affected by former wastewater infiltration and highlight the need for continuous monitoring. Full article

Karst terrains hold vital global groundwater reserves, underpinning regional water security and ecological stability. To elucidate groundwater hydrochemical patterns and formation mechanisms in Wuhan’s karst zone, this study adopted the Gibbs model, correlation analysis, principal component analysis and positive matrix factorization to explore water–rock interactions, hydrochemical origins, element migration, hydrogeochemical facies and genetic processes. The results show that water in both confined porous loose rock aquifers (CPLRAs) and karst fissure carbonate rock aquifers (KFCRAs) is mainly of HCO₃–Ca and HCO₃·SO₄–Ca types. Carbonate dissolution dominates hydrochemical evolution, with Ca²⁺, Mg²⁺, and HCO₃⁻ as major ions. Natural water–rock interactions control the ionic characteristics of both groundwater types. Silicate weathering exerts a greater influence on water in the KFCRA, while water in the CPLRA has more complex ion sources. Anthropogenic activities contribute 17.52% and 17.61% to their hydrochemical variations, suggesting moderate human influence. Water in the CPLRA is mainly affected by domestic sewage and soil organic nitrogen, locally superimposed with industrial and mining disturbances. Water in the KFCRA is primarily influenced by agricultural pollution, with minor domestic sewage input. These findings provide a scientific basis for sustainable development, protection, and targeted pollution control of groundwater resources in the Wuhan karst area, and offer a reference for hydrochemical studies in comparable karst regions. Full article

Groundwater contamination by redox-sensitive elements (RSEs) such as arsenic (As), chromium (Cr), vanadium (V), and selenium (Se) pose a critical challenge in alluvial aquifers, where seasonal hydrological forcing drives dynamic hydrogeochemical and redox conditions. This study investigates the seasonal evolution of groundwater hydrogeochemistry and multi-metal behavior in shallow aquifers of the Mid-Gangetic Plain, India, with particular emphasis on the role of seasonal redox decoupling. Monsoon conditions were dominated by strongly reducing environments (ORP: −150 to −70 mV), predominantly Ca–Mg–SO₄ and Na–Cl type facies. Under these conditions, significant correlations among RSEs in particular (As–V, As–Se) indicated coupled mobilization governed by the reductive dissolution of Fe–Mn (oxyhydr)oxides. Monsoon groundwater also exhibited strong associations between RSEs and agronomic indicators (NO₃⁻, SO₄²⁻), suggesting the influence of recharge-mediated agricultural inputs on redox-sensitive geochemical processes. In contrast, post-monsoon conditions showed a clear transition to sub-oxic states (ORP up to +121 mV) and were dominated by Ca–Mg–HCO₃ facies, accompanied by substantial increases in bicarbonate (~372%), electrical conductivity (~62%), and total dissolved solids (~21%). Despite the partial oxidation of the aquifer system, redox-sensitive metals did not respond uniformly. Instead, inter-element correlations weakened or disappeared, indicating a transition from coupled to decoupled contaminant behavior. Arsenic concentrations increased up to 20.8 µgL⁻¹, whereas Cr and V displayed variable enrichment controlled by alkali-induced desorption and carbonate-mediated surface interactions. This transition reflects seasonal redox decoupling, whereby seasonal redox shifts lead to metal-specific rather than coordinated multi-metal behavior. We propose a Seasonal Redox Decoupling Framework (SRDF) to explain the shift from coupled reductive release during monsoon conditions to selective mobilization pathways in the post-monsoon period. These findings demonstrate that seasonal redox shifts control not only metal concentrations but also inter-element relationships, leading to metal-specific risk profiles. This underscores the need for seasonally adaptive monitoring and management strategies in hydrologically dynamic alluvial aquifers. Full article

Hydrogen (H₂) is becoming a meaningful way to store energy for long-term use and support thorough decarbonization in systems that use renewable energy. Underground hydrogen storage (UHS) has strategic benefits over above-ground systems because it can hold large volumes, is contained by geology, and is cheap to operate in cycles. This review compares four key geological formations for underground hydrogen storage (UHS): salt caverns, lined rock caverns, depleted hydrocarbon reservoirs, and saline aquifers. Each system is evaluated based on storage mechanisms, efficiency, safety, technological maturity, and economic feasibility. This review also introduces a unified cross-media evaluation framework, a TRL-risk matrix, a technology development roadmap, and novel insights into AI-based monitoring, offering prescriptive guidance for large-scale UHS implementation. Salt caverns have high injectivity, maintain their purity, and undergo 6 to 12 cycles per year at pressures of 60 to 180 bar; however, they are only found in certain places. Lined rock caverns can be built anywhere, but sealing and economic issues make them difficult to use. Depleted hydrocarbon reservoirs with TWh-scale capacity and already built infrastructure. Saline aquifers, on the other hand, have the most potential in the world but need enhanced management of microbiological responses and cushion gas optimization. A synthesis of current studies highlights key research gaps in cyclic geomechanics, hydrogen–rock–microbe interactions, and liner performance for high-pressure storage. The review concludes with techno-economic and safety considerations and identifies future directions for deploying geological UHS as a critical component of a net-zero hydrogen economy. Full article

We present a whole-rock geochemical dataset of late Variscan intrusive rocks and residual anatectic melts from the mid- and lower continental crust exposed in the Serre Massif of Calabria (southern Italy). A total of 74 samples were collected from the main plutonic units and from leucosomes of associated migmatitic metasediments. The composition of intrusive rocks varies from tonalites and quartz-diorites at deeper structural levels, to peraluminous granites at shallower levels. The dataset includes major, trace and rare earth element (REE) analyses obtained using X-ray fluorescence (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). The dataset integrates new and previously published geochemical data into a consistent and reusable format, including sample locations (WGS84), lithological classification and lithostratigraphic attribution. Sampling sites are also provided as a downloadable geospatial (.kmz) file for visualization in GIS platforms. The data are intended to support a wide range of applications, including studies on granitoid magmatism, water–rock interaction processes in crystalline aquifers and raw materials exploration. Therefore, the dataset represents a valuable resource for both fundamental and applied geoscientific research. Full article

The search for extraterrestrial life has traditionally focused on environments where liquid H₂O is stable over long timescales, such as subsurface aquifers, hydrothermal systems, or ice-rich deposits. However, many planetary bodies are characterized by active cycles of particulate transport involving either mineral dust or atmospheric aerosols. In planetary science, these are commonly distinguished as refractory particles (non-volatile mineral dust) and volatile or mixed aerosol particles, including condensates such as ices, organics, or acidic droplets. Here, we propose the concept of planetary aerobiomes, defined as distributed particle-associated microbial persistence and dispersal systems in extraterrestrial environments. In this framework, refractory mineral particles may act as mobile particle-associated microenvironments that could support microbial survival and dispersal, while in some cases also providing partial physical shielding from environmental stressors. Drawing on observations from terrestrial dust-associated microbiomes and mineral–microbe interactions, particle-associated systems may represent previously overlooked ecological substrates in planetary environments. Rather than replacing models centred on environments with persistent liquid H₂O, this perspective expands them by considering particle-associated microenvironments as transient but potentially relevant biosignature-preservation niches in arid, dust-dominated worlds such as Mars, as well as in aerosol-rich environments including Titan, Venus, and icy moons. We further discuss the implications for life-detection strategies, highlighting atmospheric particles as potential reservoirs of biosignatures, and consider their relevance for applied microbiology, including in situ resource utilization (ISRU) and bioregenerative life-support systems (BLSS). Beyond astrobiological implications, understanding microbial persistence within particle-associated extreme environments may provide useful models for applied microbiology, including stress-resilient microbial engineering, biomining, contamination control, and bioregenerative technologies for space exploration. Full article

Surface water–groundwater interactions play a critical role in regulating hydrological fluxes and sustaining water availability, yet they remain poorly understood in hydrogeologically complex terrains. This study employed an integrated modeling approach combining SWAT+ and MODFLOW to quantify water balance components, groundwater flow dynamics, and river–aquifer exchanges in the Chemoga watershed, a representative headwater system of the Upper Blue Nile Basin characterized by strong environmental and geological contrasts. Model results revealed substantial spatial heterogeneity in hydrological partitioning, with annual groundwater recharge ranging from 105 to 711 mm (mean = 296 mm; 24% of annual rainfall). Simulated groundwater flow exhibited a pronounced topographic control, with hydraulic heads declining from highland recharge zones toward deeply incised lowland gorges. River–aquifer interactions showed marked spatial variability, with the Chemoga river predominantly acting as a gaining stream in the highland and nick-point gorge sections (up to 2867 m³ d⁻¹), while transitioning to a losing stream in the midland floodplains and lowland gorge areas, with leakage reaching up to 75.0 m³ d⁻¹. These findings highlight the value of integrated, process-based modeling for resolving complex hydrological interactions, advancing understanding of groundwater flow regimes and supporting sustainable groundwater management in the Ethiopian highlands and other similar regions worldwide. Full article

Ningbo City is endowed with abundant mineral water resources. Investigating their chemical characteristics and formation mechanisms is essential for understanding hydrochemical evolution and supporting sustainable resource utilization. Based on hydrochemical data from 12 drinking natural mineral water sources in Ningbo City, this study investigates the hydrochemical features and genesis of mineral water by integrating statistical analysis, hydrochemical diagrams, ionic ratios, and mineral equilibrium modeling. The results indicate that metasilicic acid (as H₂SiO₃) and strontium (Sr) are the principal characteristic components of the drinking natural mineral water in Ningbo City, with concentrations of 32.87–60.8 mg/L and 0.05–4.59 mg/L, respectively. The mineral waters are neutral to slightly alkaline and weakly mineralized, with the pH values ranging from 6.70 to 8.16, and total dissolved solids (TDS) contents of 76.8–767.2 mg/L. The predominant hydrochemical facies are HCO₃-Ca-Na, HCO₃-Ca, HCO₃-Na-Ca. Their chemical composition is mainly governed by rock weathering, whilst also being influenced by cation exchange and mineral dissolution–precipitation equilibrium. H₂SiO₃ is mainly derived from the weathering and hydrolysis of silicate minerals such as plagioclase. Sr enrichment is associated with the dissolution of Sr-bearing silicate minerals and certain sulphate minerals, as well as prolonged water–rock interaction. The Sr- and Si-rich aquifers provide the material basis for the enrichment of Sr and H₂SiO₃ in groundwater. Structural fractures and weathering fractures provide transport pathways and storage spaces for groundwater, facilitating the migration and enrichment of these characteristic components. The mechanism of mineral water emergence can be summarized as of the tectonic fracture-controlled circulation-leaching type. Full article

Numerical simulations quantify the transient impacts of implementing green infrastructure (GI) grass swales on unconfined aquifer storage and groundwater-surface water interactions around the Red Butte Creek (RBC) of Utah, USA. The Red Butte Creek Watershed (RBCW) transitions from undeveloped mountainous National Forest land to downstream urbanized areas within Salt Lake Valley (SLV). This reconnaissance-level study demonstrates that increasing stormwater infiltration in urbanized areas during the rainy months (April-June) can, until at least the subsequent March, (a) enhance aquifer recharge and support sustainable groundwater yields; and (b) improve surface water availability. Simulations predict hydrologic impacts of aquifer recharge resulting from hypothetical grass-swale implementation within a 704-acre area located around RBC. The employed model, HyperRBC, is an adaptation of a United States Geological Survey (USGS) transient numerical flow, MODFLOW, model implementation for SLV. Adaptations involved (a) uniformly refined horizontal discretization of seven aquifer layers within a sub-area encompassing parts of RBCW and an adjacent watershed; (b) updated input data; and (c) MODFLOW’s Streamflow-Routing (SFR) package to simulate RBC flow and aquifer-stream seepage. Model predictions indicated that by the end of next March: (a) about 3% of the GI-induced recharge would remain within the unconfined aquifer in the HyperRBC area; (b) 66.6% of the recharge would flow northward into the downgradient continuation of the unconfined aquifer; and (c) 30.3% would discharge to nearby stream and river. In summary, predicted hydrologic changes due to the short-term GI-induced recharge highlight increased groundwater availability within and outside the study area for at least the subsequent 12 months, including high-water-demand summer. These findings show the importance of GI in interim environmental management and in enhancing the effective use of water resources. Full article

The Yellow River Delta, a young alluvial plain in China, is experiencing severe land subsidence that threatens its ecological security and sustainable development. However, the driving mechanisms of this subsidence exhibit strong spatial heterogeneity, which traditional global models fail to capture. This study integrates high-precision subsidence measurements from Sentinel-1A imagery and SBAS-InSAR technology (2017–2023) with multi-source environmental factors (topography, geology, land use, precipitation) to propose a Spatially Adaptive Ensemble Learning Model with feature selection (SA-GSE). The model concatenates predictions from base learners (CatBoost, XGBoost, Random Forest) with spatial features (e.g., distance to salt pans, local topographic variance) to form meta-features, which are then input into a multilayer perceptron meta-learner. Through 5-fold spatial cross-validation, SA-GSE learns spatially dynamic base-model weights, implicitly adapting to regional variations in subsidence drivers. The model achieves an R² of 0.7810 and RMSE of 40.55 mm/yr on the test set, outperforming individual base models and ordinary stacking. Residual spatial autocorrelation is substantially reduced, with SA-GSE yielding the lowest Moran’s I (0.0334, p = 0.206) among all evaluated models, confirming effective capture of spatial heterogeneity. Driving force analysis reveals that distance to salt pans is the most important predictor (permutation importance: 0.4456), underscoring the dominant role of brine extraction-induced aquifer compaction. Lagged precipitation importance (0.3191) exceeds that of current precipitation (0.2453), indicating a recharge lag effect. SHAP interaction analysis uncovers a nonlinear “precipitation decoupling” mechanism in salt pan areas, where high precipitation paradoxically exacerbates subsidence. The resultant map of predicted subsidence rates highlights elevated rate zones in the northern salt pans and along the Guangli River. While the map does not represent a full risk assessment—as it does not include exposure or vulnerability—it provides a spatially explicit estimate of hazard likelihood. This ensemble framework yields novel perspectives on subsidence drivers in heterogeneous regions and can support land subsidence prevention and groundwater management planning. Full article

Transboundary basins in arid and semi-arid regions are increasingly stressed by groundwater depletion, drought, and competing upstream water-management policies. Quantifying surface–groundwater interactions in such systems remains challenging due to sparse hydroclimatic observations. This study develops and applies a fully coupled SWAT–MODFLOW model to the Tigris–Euphrates River Basin (TERB; ~900,000 km²), the largest transboundary basin in the Middle East, to evaluate spatiotemporal stream–aquifer interactions and basin-scale water balance. The model integrates SWAT 2012 with MODFLOW-NWT at daily and monthly time steps and was calibrated and validated against monthly streamflow records from 23 gauges and groundwater levels from four wells over 1981–2002, with a 1976–1980 warm-up period. A multi-stage calibration strategy was adopted, including standalone SWAT calibration using SUFI-2, standalone MODFLOW calibration using PEST, and subsequent coupled refinement. Model performance was satisfactory, with Nash–Sutcliffe efficiencies exceeding 0.5 for streamflow and strong agreement between simulated and observed groundwater levels (R² = 0.92). Basin-integrated total water storage anomalies showed reasonable agreement with GRACE-derived estimates for 2002–2013 (R² ≈ 0.72). The basin-averaged net stream–aquifer exchange was estimated at −7.08 × 10⁶ m³ yr⁻¹, indicating net river leakage to aquifers, with a marked intensification after 1987 consistent with major upstream reservoir developments. Recharge patterns were highest over permeable foothill formations and lowest over consolidated northern highlands. The integrated use of streamflow, groundwater, and GRACE observations within a fully coupled framework provides a transferable approach for water-resources assessment in data-scarce transboundary basins. Full article

This study investigates the role of longitudinal aquifer slope in controlling stream–aquifer interaction within bounded floodplain aquifer systems. A series of numerical simulations were conducted to analyze groundwater flow patterns, hyporheic exchange fluxes, and contaminant transport behavior under varying slope conditions. The results showed that increasing slope does not simply enhance hydraulic gradients but fundamentally reorganizes subsurface flow structure. As the slope increases, groundwater flow becomes progressively aligned with the stream, reducing lateral connectivity and confining exchange to a narrow corridor adjacent to the stream. This reorganization leads to the expansion of hydraulically inactive zones and a non-linear response in hyporheic exchange. Exchange flow rates initially increase at low to moderate slopes but decline beyond a threshold at higher slopes, despite higher local gradients. The transition begins at around a 2% slope and becomes pronounced within the range of approximately 3–7%, indicating a shift in flow regime rather than a continuous scaling of interaction intensity. Particle tracking analyses further reveal that slope controls the spatial distribution of contaminant vulnerability. While the overall extent of active transport zones decreases with increasing slope, localized transport potential intensifies near the stream boundary due to higher velocities and reduced residence times. These findings demonstrate that hydraulic gradient magnitude alone is insufficient to characterize stream–aquifer interaction and highlight the importance of flow geometry and connectivity. The results provide a process-based framework for understanding slope-controlled hyporheic exchange and offer insights for improving groundwater vulnerability assessment and management in alluvial systems. Full article

Groundwater-dependent communities such as De Aar require a better understanding of groundwater systems to ensure sustainable allocation. This study aims to trace recharge sources in unconfined and confined aquifers and identify processes controlling groundwater quality using hydrogeochemistry and environmental tracers. It argues that aquifer delineation and hydraulic parameters alone cannot fully identify recharge sources or geochemical processes; integrating them with hydrogeochemistry and environmental tracers provides stronger evidence to support groundwater allocation. To validate the argument, the study integrated hydrogeochemical analysis, stable isotopes, tritium, radon-222, and statistical methods supported by depth-specific groundwater sampling. The results, interpreted using Piper and Gibbs diagrams, PHREEQC modelling, and scatter plots, show that groundwater evolution is mainly controlled by rock–water interaction, ion exchange, evaporation, and mixing processes. Ca–HCO₃ water indicates recent recharge, while Na–Cl water reflects evaporation effects in both unconfined and confined aquifers, with halite dissolution contributing to Na and Cl enrichment. Isotope results indicate that unconfined aquifer water is isotopically enriched and linked to recent recharge, whereas confined aquifer and spring waters are depleted, suggesting recharge from higher elevations through fractured zones. Tritium dating reveals young (<30 years), intermediate (30–50 years), and old groundwater (60–109 years), while radon results indicate active groundwater flow path, particularly along fractures. These findings demonstrate that groundwater recharge is derived from both local meteoric sources and regional contributions, resulting in predominantly fresh groundwater; however, localized quality concerns should be considered for improved water allocation. Full article