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Keywords = agricultural plastic mulch

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20 pages, 6624 KiB  
Article
Visual Observation of Polystyrene Microplastics/Nanoplastics in Peanut Seedlings and Their Effects on Growth and the Antioxidant Defense System
by Yuyang Li, Xinyi Huang, Qiang Lv, Zhanqiang Ma, Minhua Zhang, Jing Liu, Liying Fan, Xuejiao Yan, Nianyuan Jiao, Aneela Younas, Muhammad Shaaban, Jiakai Gao, Yanfang Wang and Ling Liu
Agronomy 2025, 15(8), 1895; https://doi.org/10.3390/agronomy15081895 - 6 Aug 2025
Abstract
Peanut cultivation is widely practiced using plastic mulch film, resulting in the accumulation of microplastics/nanoplastics (MPs/NPs) in agricultural soils, potentially negatively affecting peanut growth. To investigate the effects of two polystyrene (PS) sizes (5 μm, 50 nm) and three concentrations (0, 10, and [...] Read more.
Peanut cultivation is widely practiced using plastic mulch film, resulting in the accumulation of microplastics/nanoplastics (MPs/NPs) in agricultural soils, potentially negatively affecting peanut growth. To investigate the effects of two polystyrene (PS) sizes (5 μm, 50 nm) and three concentrations (0, 10, and 100 mg L−1) on peanut growth, photosynthetic efficiency, and physiological characteristics, a 15-day hydroponic experiment was conducted using peanut seedlings as the experimental material. The results indicated that PS-MPs/NPs inhibited peanut growth, reduced soil and plant analyzer development (SPAD) values (6.7%), and increased levels of malondialdehyde (MDA, 22.0%), superoxide anion (O2, 3.8%) superoxide dismutase (SOD, 16.1%) and catalase (CAT, 12.1%) activity, and ascorbic acid (ASA, 12.6%) and glutathione (GSH, 9.1%) contents compared to the control. Moreover, high concentrations (100 mg L−1) of PS-MPs/NPs reduced the peanut shoot fresh weight (16.1%) and SPAD value (7.2%) and increased levels of MDA (17.1%), O2 (5.6%), SOD (10.6%), POD (27.2%), CAT (7.3%), ASA (12.3%), and GSH (6.8%) compared to low concentrations (10 mg L−1) of PS-MPs/NPs. Notably, under the same concentration, the impact of 50 nm PS-NPs was stronger than that of 5 μm PS-MPs. The peanut shoot fresh weight of PS-NPs was lower than that of PS-MPs by an average of 7.9%. Additionally, we found that with an increasing exposure time of PS-MPs/NPs, the inhibitory effect of low concentrations of PS-MPs/NPs on the fresh weight was decreased by 2.5%/9.9% (5 d) and then increased by 7.7%/2.7% (15 d). Conversely, high concentrations of PS-MPs/NPs consistently reduced the fresh weight. Correlation analysis revealed a clear positive correlation between peanut biomass and both the SPAD values as well as Fv/Fm, and a negative correlation with MDA, SOD, CAT, ASA, and GSH. Furthermore, the presence of PS-MPs/NPs in roots, stems, and leaves was confirmed using a confocal laser scanning microscope. The internalization of PS-MPs/NPs within peanut tissues negatively impacted peanut growth by increasing the MDA and O2 levels, reducing the SPAD values, and inhibiting the photosynthetic capacity. In conclusion, the study demonstrated that the effects of PS on peanuts were correlated with the PS size, concentration, and exposure time, highlighting the potential risk of 50 nm to 5 μm PS being absorbed by peanuts. Full article
(This article belongs to the Collection Crop Physiology and Stress)
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16 pages, 2656 KiB  
Article
Plastic Film Mulching Regulates Soil Respiration and Temperature Sensitivity in Maize Farming Across Diverse Hydrothermal Conditions
by Jianjun Yang, Rui Wang, Xiaopeng Shi, Yufei Li, Rafi Ullah and Feng Zhang
Agriculture 2025, 15(15), 1667; https://doi.org/10.3390/agriculture15151667 - 1 Aug 2025
Viewed by 205
Abstract
Soil respiration (Rt), consisting of heterotrophic (Rh) and autotrophic respiration (Ra), plays a vital role in terrestrial carbon cycling and is sensitive to soil temperature and moisture. In dryland agriculture, plastic film mulching (PM) is widely used to regulate soil hydrothermal conditions, but [...] Read more.
Soil respiration (Rt), consisting of heterotrophic (Rh) and autotrophic respiration (Ra), plays a vital role in terrestrial carbon cycling and is sensitive to soil temperature and moisture. In dryland agriculture, plastic film mulching (PM) is widely used to regulate soil hydrothermal conditions, but its effects on Rt components and their temperature sensitivity (Q10) across regions remain unclear. A two-year field study was conducted at two rain-fed maize sites: Anding (warmer, semi-arid) and Yuzhong (colder, drier). PM significantly increased Rt, Rh, and Ra, especially Ra, due to enhanced root biomass and improved microclimate. Yield increased by 33.6–165%. Peak respiration occurred earlier in Anding, aligned with maize growth and soil temperature. PM reduced Q10 of Rt and Ra in Anding, but only Ra in Yuzhong. Rh Q10 remained stable, indicating microbial respiration was less sensitive to temperature changes. Structural equation modeling revealed that Rt and Ra were mainly driven by soil temperature and root biomass, while Rh was more influenced by microbial biomass carbon (MBC) and dissolved organic carbon (DOC). Despite increased CO2 emissions, PM improved carbon emission efficiency (CEE), particularly in Yuzhong (+67%). The application of PM is recommended to enhance yield while optimizing carbon efficiency in dryland farming systems. Full article
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13 pages, 1373 KiB  
Article
A Comparative Plant Growth Study of a Sprayable, Degradable Polyester–Urethane–Urea Mulch and Two Commercial Plastic Mulches
by Cuyler Borrowman, Karen Little, Raju Adhikari, Kei Saito, Stuart Gordon and Antonio F. Patti
Agriculture 2025, 15(15), 1581; https://doi.org/10.3390/agriculture15151581 - 23 Jul 2025
Viewed by 332
Abstract
The practice in agriculture of spreading polyethylene (PE) film over the soil surface as mulch is a common, global practice that aids in conserving water, increasing crop yields, suppressing weed growth, and decreasing growing time. However, these films are typically only used for [...] Read more.
The practice in agriculture of spreading polyethylene (PE) film over the soil surface as mulch is a common, global practice that aids in conserving water, increasing crop yields, suppressing weed growth, and decreasing growing time. However, these films are typically only used for a single growing season, and thus, their use and non-biodegradability come with some serious environmental consequences due to their persistence in the soil and potential for microplastic pollution, particularly when retrieval and disposal options are poor. On the microscale, particles < 5 mm from degraded films have been observed to disrupt soil structure, impede water and nutrient cycling, and affect soil organisms and plant health. On the macroscale, there are obvious and serious environmental consequences associated with the burning of plastic film and its leakage from poorly managed landfills. To maintain the crop productivity afforded by mulching with PE film while avoiding the environmental downsides, the development and use of biodegradable polymer technologies is being explored. Here, the efficacy of a newly developed, water-dispersible, sprayable, and biodegradable polyester–urethane–urea (PEUU)-based polymer was compared with two commercial PE mulches, non-degradable polyethylene (NPE) and OPE (ox-degradable polyethylene), in a greenhouse tomato growth trial. Water savings and the effects on plant growth and soil characteristics were studied. It was found that PEUU provided similar water savings to the commercial PE-based mulches, up to 30–35%, while showing no deleterious effects on plant growth. The results should be taken as preliminary indications that the sprayable, biodegradable PEUU shows promise as a replacement for PE mulch, with further studies under outside field conditions warranted to assess its cost effectiveness in improving crop yields and, importantly, its longer-term impacts on soil and terrestrial fauna. Full article
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16 pages, 2657 KiB  
Article
Degradation of Biodegradable Mulch-Derived Microplastics and Their Effects on Bacterial Communities and Radish Growth in Three Vegetable-Cultivated Purple Soils
by Ruixue Ao, Zexian Liu, Yue Mu, Jiaxin Chen and Xiulan Zhao
Agriculture 2025, 15(14), 1512; https://doi.org/10.3390/agriculture15141512 - 13 Jul 2025
Viewed by 417
Abstract
Biodegradable mulch films (BDMs) are considered a promising solution for mitigating plastic residue pollution in agroecosystems. However, the degradation behavior and ecological impacts of their residues on soil–plant systems remain unclear. Here, a pot experiment was conducted using an acidic purple soil (AS), [...] Read more.
Biodegradable mulch films (BDMs) are considered a promising solution for mitigating plastic residue pollution in agroecosystems. However, the degradation behavior and ecological impacts of their residues on soil–plant systems remain unclear. Here, a pot experiment was conducted using an acidic purple soil (AS), a neutral purple soil (NS), and a calcareous purple soil (CS) to investigate the degradation of 1% (w/w) microplastics derived from polyethylene mulch film (PE-MPs) and polybutylene adipate terephthalate/polylactic acid (PBAT/PLA) mulch film (Bio-MPs), as well as their effects on soil properties, bacterial communities, and radish growth. PE-MPs degraded slightly, while the degradation of Bio-MPs followed the order of NS > CS > AS. PE-MPs and Bio-MPs enhanced the nitrification and radish growth in AS but had no significant effects on soil properties and radish growth in CS. Bio-MPs notably increased the relative abundance of PBAT/PLA degradation-related bacteria, such as Ramlibacter, Bradyrhizobium, and Microbacterium, across the three soils. In NS, Bio-MPs raised soil pH and enriched nitrogen-fixing and denitrifying bacteria, leading to a decrease in NO3-N content and radish biomass. Overall, the effects of Bio-MPs on soil–plant systems varied with soil properties, which are closely related to their degradation rates. These findings highlight the need to assess the ecological risks of BDM residues before their large-scale use in agriculture. Full article
(This article belongs to the Section Agricultural Soils)
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16 pages, 1059 KiB  
Review
Research Progress on Source Analysis, Ecological Effects, and Separation Technology of Soil Microplastics
by Kuan Chang, Yong Ma and Yulai Han
Microplastics 2025, 4(3), 39; https://doi.org/10.3390/microplastics4030039 - 2 Jul 2025
Viewed by 272
Abstract
Soil microplastic pollution poses a significant threat to the integrity of terrestrial ecosystems and agricultural sustainability. This review provides a comprehensive synthesis of recent progress on soil microplastic (MP) sources, ecological impacts, and separation technologies. Agricultural practices (e.g., residual plastic mulch and wastewater [...] Read more.
Soil microplastic pollution poses a significant threat to the integrity of terrestrial ecosystems and agricultural sustainability. This review provides a comprehensive synthesis of recent progress on soil microplastic (MP) sources, ecological impacts, and separation technologies. Agricultural practices (e.g., residual plastic mulch and wastewater irrigation) and atmospheric deposition serve as primary drivers of contamination accumulation, with pronounced spatial heterogeneity observed across regions. Predominant MP types such as polyethylene, polystyrene, and polypropylene disrupt soil structure and biogeochemical processes through three core mechanisms: physical interference, chemical toxicity, and biological accumulation. These particles further form carrier–pollutant complexes, exacerbating ecotoxicological impacts across trophic levels. While emerging separation techniques like magnetic separation and solvent extraction demonstrate enhanced efficiency, their implementation faces challenges stemming from soil matrix complexity and high operational costs. This article underscores the need for global collaborative efforts to accelerate innovation in biodegradable polymers, offering practical pathways for sustainable soil management. Full article
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21 pages, 3454 KiB  
Article
Yield Increase and Emission Reduction Effects of Alfalfa in the Yellow River Irrigation District of Gansu Province: The Coupling Mechanism of Biodegradable Mulch and Controlled-Release Nitrogen Fertilizer
by Wenjing Chang, Haiyan Li, Yaya Duan, Yi Ling, Jiandong Lu, Minhua Yin, Yanlin Ma, Yanxia Kang, Yayu Wang, Guangping Qi and Jianjun Wang
Plants 2025, 14(13), 2022; https://doi.org/10.3390/plants14132022 - 2 Jul 2025
Viewed by 367
Abstract
Agricultural production in Northwest China is widely constrained by residual plastic film pollution, excessive greenhouse gas emissions, and low productivity. Integrating biodegradable film with controlled-release nitrogen fertilizer offers a promising approach to optimize crop management, enhance yield, and improve environmental outcomes. In this [...] Read more.
Agricultural production in Northwest China is widely constrained by residual plastic film pollution, excessive greenhouse gas emissions, and low productivity. Integrating biodegradable film with controlled-release nitrogen fertilizer offers a promising approach to optimize crop management, enhance yield, and improve environmental outcomes. In this study, three planting patterns (conventional flat planting, FP; ridge mulching with biodegradable film, BM; and ridge mulching with conventional plastic film, PM), two nitrogen fertilizer types (urea, U, and controlled-release nitrogen fertilizer, C), and four nitrogen application rates (0, 80, 160, and 240 kg·hm−2) were applied to systematically investigate their effects on alfalfa yield and N2O emissions from grasslands. The results showed that BM and PM increased alfalfa yield by 23.49% and 18.65%, respectively, compared to FP, while C increased yield by 8.46% compared to urea. The highest yield (24.84 t·hm−2) was recorded under the BMC2 treatment, which was 97.11% higher than that of FPN0. N2O emission flux and cumulative emissions increased with nitrogen application rate. Compared with U, C reduced cumulative N2O emissions and greenhouse gas emission intensity (GHGI) by 23.89% and 25.84%, respectively. Compared to PM, BM reduced cumulative N2O emissions and GHGI by 11.58% and 20.15%, respectively. Principal component analysis indicated that the combination of ridge mulching with biodegradable film and 160 kg·hm−2 of C was optimal for simultaneously increasing alfalfa yield and reducing N2O emissions, making it a suitable planting–fertilization strategy for the Yellow River irrigation district in Gansu and similar ecological regions. Full article
(This article belongs to the Special Issue Advances in Plant Nutrition and Novel Fertilizers—Second Edition)
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15 pages, 2621 KiB  
Article
The Effects of Different Plastic Film Mulches on the Physicochemical and Microbiological Properties of Soils for Protected Pepper Cultivation
by Guiliang Wang, Nannan He, Yulin Li, Wen Huang, Yifan Cao, Juanjuan Wang, Xiaoqing Qian, Li Yin and Xiaoping Zeng
Horticulturae 2025, 11(6), 710; https://doi.org/10.3390/horticulturae11060710 - 19 Jun 2025
Viewed by 387
Abstract
Plastic film mulching is widely used in protected agriculture. However, the residues of various types of plastic films, as a consequence, severely affect soil quality. The most widely promoted alternative strategy is the use of biodegradable plastic films. Nevertheless, the research on the [...] Read more.
Plastic film mulching is widely used in protected agriculture. However, the residues of various types of plastic films, as a consequence, severely affect soil quality. The most widely promoted alternative strategy is the use of biodegradable plastic films. Nevertheless, the research on the effects of different types of plastic films on soil properties remains insufficient. This study explored the impacts of different plastic film mulching on the physicochemical properties and microbial communities of soils for pepper cultivation, with three treatments: traditional polyethylene film (PE-Ctr), PBAT biodegradable film (PBAT bio), and reinforced polyethylene film (RPE). The results showed that the soil pH value was the highest in PE-Ctr treatment, and the soil organic matter content was higher in the biodegradable film treatment, while the electrical conductivity (EC), nitrate, and some cations (Ca2+, Mg2+) were higher in the RPE treatment. The contents of available trace element Zn, Fe, and Mn increased in the PBAT bio treatment. The bacterial richness and evenness indices were higher in PBAT bio treatment than those of other treatments. The fungal community had a relatively high richness, but a lower evenness, compared to the PE-Ctr and PBAT bio treatments. The use of different plastic films significantly affected the composition of soil bacteria, while differences in the composition of soil fungi were only observed between the PBAT bio and RPE treatments. Proteobacteria, Acidobacteriota, and Actinobacteriota were the most dominant bacterial phyla, and Ascomycota and Mortierellomycota were the dominant fungal phylum across all treatments. FAPROTAX functional prediction showed that the abundances of multiple functions of soil bacteria were higher in the RPE treatment, and the chemoheterotrophy function was higher in the PE treatment. FUNGuild analysis indicated that the trophic types and ecological function groups of soil fungi were more abundant in the PBAT bio treatment. Full article
(This article belongs to the Section Vegetable Production Systems)
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18 pages, 3417 KiB  
Article
Design and Preparation of Inherently Photostable Poly(Butylene Adipate-Co-Terephthalate) by Chemically Bonding UV-Stabilizing Moieties in Molecular Chains
by Xinpeng Zhang, Yan Ye, Yaqiao Wang, Hongli Bian, Jing Yuan, Jianping Ding, Wanli Li, Jun Xu and Baohua Guo
Polymers 2025, 17(11), 1567; https://doi.org/10.3390/polym17111567 - 4 Jun 2025
Viewed by 528
Abstract
Poly(butylene adipate-co-terephthalate) (PBAT) is a promising biodegradable polymer with balanced mechanical properties and excellent degradability, making it an ideal material to reduce plastic pollution. However, its susceptibility to ultraviolet (UV) degradation, due to photosensitive aromatic rings and carbonyl groups in its structure, limits [...] Read more.
Poly(butylene adipate-co-terephthalate) (PBAT) is a promising biodegradable polymer with balanced mechanical properties and excellent degradability, making it an ideal material to reduce plastic pollution. However, its susceptibility to ultraviolet (UV) degradation, due to photosensitive aromatic rings and carbonyl groups in its structure, limits its use in outdoor settings like mulch films. Conventional methods of incorporating small-molecule UV stabilizers face challenges such as poor compatibility, uneven dispersion, and migration under environmental conditions, reducing their effectiveness over time. This study developed a novel strategy to enhance PBAT’s UV resistance by chemically bonding UV-stabilizing moieties directly into its molecular chains to address these limitations. A novel UV absorber containing a polymerizable group was synthesized and copolymerized with PBAT’s main chain, creating an intrinsically UV-stable PBAT. The UV-stable PBAT was evaluated for UV resistance, mechanical performance, and durability through accelerated aging and solvent extraction tests. The results demonstrated that UV-stable PBAT exhibited exceptional light stabilization effects, with no detectable UV absorber leaching in ethanol even after 114 h, whereas PBAT blends lost nearly 90% of UV-0 within 24 h. Furthermore, UV-stable PBAT maintained 67.1% tensile strength and 48.8% elongation at break after aging, which exhibited the best mechanical retention performance. Even when subjected to solvent extraction, the 42.6% tensile strength retention outperformed the PBAT blends. This innovative chemical modification overcomes the limitations of additive-based stabilization, offering improved durability, compatibility, and performance in outdoor applications. Our research provides key insights into the fundamental properties of PBAT films for UV resistance, demonstrating their potential for use in demanding fields such as agricultural films. Full article
(This article belongs to the Section Polymer Applications)
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16 pages, 1787 KiB  
Article
Drip Irrigation of Phosphorus Fertilizer Enhances Cotton Yield and Phosphorus Use Efficiency
by Yuwen Wu, Xiaoqian Wu, Jun Zhang, Leru Zhou and Bolang Chen
Agronomy 2025, 15(6), 1328; https://doi.org/10.3390/agronomy15061328 - 29 May 2025
Viewed by 547
Abstract
Root systems are pivotal for nutrient absorption, exhibiting high plasticity in phosphorus (P) acquisition, and significantly influencing soil phosphorus availability. However, the impacts of different P application methods on root parameters and P utilization efficiency in cotton (Gossypium hirsutum L.) under Xinjiang [...] Read more.
Root systems are pivotal for nutrient absorption, exhibiting high plasticity in phosphorus (P) acquisition, and significantly influencing soil phosphorus availability. However, the impacts of different P application methods on root parameters and P utilization efficiency in cotton (Gossypium hirsutum L.) under Xinjiang conditions are still not well understood. To identify optimal P fertilization strategies, a consecutive two-year field experiment (2023–2024) under mulched drip irrigation was conducted. Three P application methods were tested: no P (CK), basal P application (PB), and drip P application (PD). Results revealed that P application methods significantly affected cotton dry matter, P use efficiency, root morphology, and yield (p < 0.05). Over the two years, the optimized treatment (25% P applied at bud stage and 25% at flowering-boll stage, PD) increased yield by 13.62% and 9.50% compared to full basal application (PB), with P use efficiency improved by 22.04–31.51% and agronomic efficiency improved by 6.56–9.75 kg kg−1. PB significantly increased soil-available P in 0–20 cm (34.17–70.09%) and 20–40 cm layers (30.37–70.32%) compared to CK. During the bud stage, PD treatment exhibited higher soil-available P in the 20–40 cm layer than PB. PD enhanced P uptake and dry matter accumulation, with increases of 22.43–36.33% and 7.90–15.55% in reproductive organ P accumulation compared to other treatments. Root parameters followed PD > PB > CK across all treatments. At the seedling stage, PB increased total root length by 19.79% compared to CK, while PD increased root volume by 46.15% compared to PB. During the bud stage, PB increased root volume by 53.33% compared to CK, and PD enhanced root surface area and volume by 39.25% and 47.82% compared to PB. Root volume showed a significant positive correlation with phosphorus absorption across growth stages. The PD treatment significantly enhanced soil P availability and P use efficiency and optimized root spatial distribution. This treatment consistently increased cotton yield by 30.41–39.09% (p < 0.05) compared to CK, demonstrating stable positive effects. This study highlights that adjusting P application methods can establish sustainable, high-yield agricultural fertilization systems. Full article
(This article belongs to the Section Water Use and Irrigation)
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15 pages, 1830 KiB  
Article
Estimation of Maize Yield in Plastic Film Mulched Field Using UAV Multispectral Imagery
by Yue Wang, Min Hou, Zeyu Zhao, Kaiping Zhang, Jie Huang, Li Zhang and Feng Zhang
Agronomy 2025, 15(6), 1269; https://doi.org/10.3390/agronomy15061269 - 22 May 2025
Viewed by 551
Abstract
In precision agriculture research, it is important to monitor maize growth conditions in real time for effective field diagnosis, management, and accurate yield prediction. This study aimed to develop an inverse model of vegetation index and maize yield using Unmanned Aerial Vehicle (UAV) [...] Read more.
In precision agriculture research, it is important to monitor maize growth conditions in real time for effective field diagnosis, management, and accurate yield prediction. This study aimed to develop an inverse model of vegetation index and maize yield using Unmanned Aerial Vehicle (UAV) multispectral imagery. The objective was to investigate how the vegetation index, maize growth stages, and growth parameters respond to plastic film mulching on the Loess Plateau. Annual field trials (2019–2020) employed a factorial design to evaluate mulch and nitrogen regimes. The results show that vegetation index long-time series curves, combined with maize phenological growth stages, can be used to monitor maize growth and yield estimation (R2 > 0.9). The 13 vegetation indices (VIs) obtained by UAVs had a good regression relationship with the leaf area index, with the enhanced vegetation index 2 (EVI2) performing the best. The VIs obtained by UAVs at different stages of growth and development predicted yields, finding that EVI2 performed best with an R2 of 0.92 and an RMSE of 0.52 t ha-1 when maize entered the heading stage in 2019. The regression effect of VIs and yield based on maize without plastic film mulching management entering the heading stage was the best in 2020, with an R2 of 0.94 and an RMSE of 0.44 t ha−1. When maize enters the heading stage, the best simulation results can be obtained by using the VIs to establish a yield prediction model. Spectral signatures during reproductive transition (VT-R1) proved most indicative of the final yield. Convergence of UAV-based spectral phenotyping with crop developmental physiology enables high-resolution growth diagnostics, providing empirical support for precision farming adaptations. Full article
(This article belongs to the Section Precision and Digital Agriculture)
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16 pages, 3311 KiB  
Article
Microplastic Pollution in Tropical River: Fourier Transform Infrared Spectroscopy-Based Characterization of Abundance and Polymer Composition in Water and Sediments from Filobobos River, Mexico
by Gleybis Hernández-Morales, María Cristina López-Mendez, Alan Antonio Rico-Barragán, Jesús Pérez-Moreno, Carolina Peña-Montes, Luis Alberto Peralta-Pelaez and Humberto Raymundo González-Moreno
Hydrology 2025, 12(5), 124; https://doi.org/10.3390/hydrology12050124 - 21 May 2025
Viewed by 974
Abstract
Veracruz is a megadiverse state facing great water resource management challenges. The contamination of water bodies with external materials of anthropogenic origin stands out, including those derived from plastic products, which are deemed ubiquitous, emerging contaminants that have gained notoriety in recent decades [...] Read more.
Veracruz is a megadiverse state facing great water resource management challenges. The contamination of water bodies with external materials of anthropogenic origin stands out, including those derived from plastic products, which are deemed ubiquitous, emerging contaminants that have gained notoriety in recent decades due to the extent and effects of their presence, persistence and distribution in aquatic ecosystems. Being a significant environmental threat, their presence, persistence and distribution in aquatic ecosystems are deserving of a more detailed study. This research focused on analyzing microplastic (MP) retention and characterization in environmental matrixes (water and sediment) in the Bobos River’s lower basin, also taking into account other water physicochemical parameters, including a pH range from slightly acidic (5.17) to slightly alkaline (8.94) as the maximum value and an average temperature of 28.87 °C (83.96 °F). MPs are most frequently found in the form of blue-colored fibers. A polymer analysis by Fourier Transform Infrared Spectroscopy (FTIR) revealed that the most common polymer was polyethylene (PE), which is the main component of most agricultural mulch and agrochemical containers. This research aims to enhance the understanding of the plastic matter contamination of water bodies, pointing out the need for further and deeper research on this subject. Full article
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20 pages, 17772 KiB  
Article
Modification of Epoxidized Soybean Oil for the Preparation of Amorphous, Nonretrogradable, and Hydrophobic Starch Films
by Sara Dalle Vacche, Leandro Hernan Esposito, Daniele Bugnotti, Emanuela Callone, Sara Fernanda Orsini, Massimiliano D’Arienzo, Laura Cipolla, Simona Petroni, Alessandra Vitale, Roberta Bongiovanni and Sandra Dirè
Polysaccharides 2025, 6(2), 40; https://doi.org/10.3390/polysaccharides6020040 - 7 May 2025
Viewed by 574
Abstract
Starch was plasticized with epoxidized soybean oil (ESO) modified by reaction with cinnamic acid (CA), and films were prepared using solvent casting from water/ethanol solutions. They exhibited good hydrophobicity, reduced water sensitivity, and showed the same transparency as glycerol-plasticized counterparts, but with less [...] Read more.
Starch was plasticized with epoxidized soybean oil (ESO) modified by reaction with cinnamic acid (CA), and films were prepared using solvent casting from water/ethanol solutions. They exhibited good hydrophobicity, reduced water sensitivity, and showed the same transparency as glycerol-plasticized counterparts, but with less flexibility. Interestingly, modified ESO enhanced gelatinization and hindered retrogradation of the biopolymer. ESO was reacted with CA without the use of catalysts to obtain a β-hydroxyester; in order to optimize the synthesis process, different reaction conditions were explored, varying the stoichiometry and the heating cycles. Products were fully characterized by Fourier transform infrared (FTIR) spectroscopy, 1H and 13C nuclear magnetic resonance (NMR), and the different reactions following the opening of the oxirane ring were discussed. The properties of the novel starch-based films prepared with modified ESO highlight their use in food packaging, disposable devices, and agricultural mulching films. Full article
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17 pages, 4896 KiB  
Article
Urea–Formaldehyde Strengthened by Polyvinyl Alcohol: Impact on Mulch Film Properties and Cucumber Cultivation
by Tingting Shen, Yongjie Ma and Xueyan Zhang
Polymers 2025, 17(9), 1277; https://doi.org/10.3390/polym17091277 - 7 May 2025
Viewed by 874
Abstract
To address the problem of environmental pollution caused by the extensive use of low-density polyethylene (LDPE) mulch film, this study developed a novel sprayable mulch using natural fibers and biodegradable polymers. Urea–formaldehyde resin (UF), strengthened with polyvinyl alcohol (PVA), was used as a [...] Read more.
To address the problem of environmental pollution caused by the extensive use of low-density polyethylene (LDPE) mulch film, this study developed a novel sprayable mulch using natural fibers and biodegradable polymers. Urea–formaldehyde resin (UF), strengthened with polyvinyl alcohol (PVA), was used as a modifier to induce beneficial physicochemical structural changes in PVA-modified urea–formaldehyde (PUF) resins. Characterization of these resins was conducted using Fourier transformation infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). Preparation of the biodegradable mulch was conducted using Xuan paper waste residue (XP) as an enhancer, with PUF as the auxiliary agent. The resulting film (PUF-XP) was examined for differences in thickness, morphological characterization, and rate of weight loss, and the effects of different covering films on cucumber growth, root development, soil temperature, and weed control were evaluated. Characterization reveals that when the PVA content was 4% (W4UF), the film had the lowest free formaldehyde content (0.26%) and highest elongation at break (5.70%). In addition, W4UF could easily undergo thermal degradation at 278.4 °C and possessed a close-knit, three-dimensional structural network. W4UF was then mixed with paper powder and water in various proportions to produce three mulch films (BioT1, BioT2, and BioT3) that demonstrated excellent water retention and heat preservation and inhibited weed growth by 68.8–96.8%. Compared to no mulching (NM), BioT1 increased both the specific root length and root density, as well as improved the plant height, stem diameter, and total biomass of the cucumbers by 43.5%, 34.1%, and 33.9%, respectively. Therefore, a mass ratio of paper powder, water, and W4UF of 1:30:2 produced a biodegradable mulch film that could be used as an alternative to LDPE, mitigating the environmental pollution rendered by synthetic plastic mulch films and offering the potential for a sustainable agricultural application. Full article
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24 pages, 4011 KiB  
Article
Impact of Sustainable Agricultural Practices on Early Potato Yield Components
by Zorana Srećkov, Vesna Vasić, Anđelko Mišković, Vuk Vujasinović, Maja Radišić, Mladen Radišić and Gordana Racić
Sustainability 2025, 17(9), 4070; https://doi.org/10.3390/su17094070 - 30 Apr 2025
Viewed by 661
Abstract
Soil and plant covering methods offer sustainable agricultural benefits by improving soil health, water use efficiency, and reducing chemical inputs. A three-year split-plot experiment (2019–2021) evaluated the impact of various covering techniques on early potato production using two varieties (Cleopatra and Riviera). Treatments [...] Read more.
Soil and plant covering methods offer sustainable agricultural benefits by improving soil health, water use efficiency, and reducing chemical inputs. A three-year split-plot experiment (2019–2021) evaluated the impact of various covering techniques on early potato production using two varieties (Cleopatra and Riviera). Treatments included control, plastic mulch, agrotextile, low tunnels, and their combinations. The study assessed stem number, number of tubers per plant (including per stem), average tuber mass, tuber mass per plant, and tuber yield. Results demonstrate the significant positive impact of covering methods on early potato yield. The combination of agrotextile and low tunnels resulted in the highest increases, improving key yield components like tuber number and mass per plant. While varietal differences existed, the covering methods’ influence was paramount. These findings offer a basis for optimizing early potato production for higher yields and quality. Future research should investigate the economic viability of these methods and explore organic alternatives to plastic coverings for sustainable agriculture. Full article
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19 pages, 5134 KiB  
Article
A Garbage Detection and Classification Model for Orchards Based on Lightweight YOLOv7
by Xinyuan Tian, Liping Bai and Deyun Mo
Sustainability 2025, 17(9), 3922; https://doi.org/10.3390/su17093922 - 27 Apr 2025
Cited by 1 | Viewed by 703
Abstract
The disposal of orchard garbage (including pruning branches, fallen leaves, and non-biodegradable materials such as pesticide containers and plastic film) poses major difficulties for horticultural production and soil sustainability. Unlike general agricultural garbage, orchard garbage often contains both biodegradable organic matter and hazardous [...] Read more.
The disposal of orchard garbage (including pruning branches, fallen leaves, and non-biodegradable materials such as pesticide containers and plastic film) poses major difficulties for horticultural production and soil sustainability. Unlike general agricultural garbage, orchard garbage often contains both biodegradable organic matter and hazardous pollutants, which complicates efficient recycling. Traditional manual sorting methods are labour-intensive and inefficient in large-scale operations. To this end, we propose a lightweight YOLOv7-based detection model tailored for the orchard environment. By replacing the CSPDarknet53 backbone with MobileNetV3 and GhostNet, an average accuracy (mAP) of 84.4% is achieved, while the computational load of the original model is only 16%. Meanwhile, a supervised comparative learning strategy further strengthens feature discrimination between horticulturally relevant categories and can distinguish compost pruning residues from toxic materials. Experiments on a dataset containing 16 orchard-specific garbage types (e.g., pineapple shells, plastic mulch, and fertiliser bags) show that the model has high classification accuracy, especially for materials commonly found in tropical orchards. The lightweight nature of the algorithm allows for real-time deployment on edge devices such as drones or robotic platforms, and future integration with robotic arms for automated collection and sorting. By converting garbage into a compostable resource and separating contaminants, the technology is aligned with the country’s garbage segregation initiatives and global sustainability goals, providing a scalable pathway to reconcile ecological preservation and horticultural efficiency. Full article
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