Search Results (3)

Establishing energy storage systems beyond conventional lithium ion batteries requires the development of novel types of electrode materials. Such materials should be capable of accommodating ion species other than Li⁺, and ideally, these ion species should be of multivalent nature, such as Al³⁺. Along this line, we introduce a highly porous aerogel cathode composed of reduced graphene oxide, which is loaded with nanostructured SnO₂. This binder-free hybrid not only exhibits an outstanding mechanical performance, but also unites the pseudocapacity of the reduced graphene oxide and the electrochemical storage capacity of the SnO₂ nanoplatelets. Moreover, the combination of both materials gives rise to additional intercalation sites at their interface, further contributing to the total capacity of up to 16 mAh cm⁻³ at a charging rate of 2 C. The high porosity (99.9%) of the hybrid and the synergy of its components yield a cathode material for high-rate (up to 20 C) aluminum ion batteries, which exhibit an excellent cycling stability over 10,000 tested cycles. The electrode design proposed here has a great potential to meet future energy and power density demands for advanced energy storage devices. Full article

Carbon monoxide (CO) gas is an odorless toxic combustion product that rapidly accumulates inside ordinary places, causing serious risks to human health. Hence, the quick detection of CO generation is of great interest. To meet this need, high-performance sensing units have been developed and are commercially available, with the vast majority making use of semiconductor transduction media. In this paper, we demonstrate for the first time a fabrication protocol for arrays of printed flexible CO sensors based on a printable semiconductor catalyst-decorated reduced graphene oxide sensor media. These sensors operate at room temperature with a fast response and are deposited using high-throughput printing and coating methods on thin flexible substrates. With the use of a modified solvothermal aerogel process, reduced graphene oxide (rGO) sheets were decorated with tin dioxide (SnO₂) nanoscale deposits. X-ray diffraction data were used to show the composition of the material, and high-resolution X-ray photoelectron spectroscopy (XPS) characterization showed the bonding status of the sensing material. Moreover, a very uniform distribution of particles was observed in scanning (SEM) and transmission electron microscopy (TEM) images. For the fabrication of the sensors, silver (Ag) interdigitated electrodes were inkjet-printed from nanoparticle inks on plastic substrates with 100 µm linewidths and then coated with the SnO₂-rGO nanocomposite by inkjet or slot-die coating, followed by a thermal treatment to further reduce the rGO. The detection of 50 ppm of CO in nitrogen was demonstrated for the devices with a slot-die coated active layer. A response of 15%, response time of 4.5 s, and recovery time of 12 s were recorded for these printed sensors, which is superior to other previously reported sensors operating at room temperature. Full article

SnO₂ aerogel/reduced graphene oxide (rGO) nanocomposites were synthesized using the sol–gel method. A homogeneous dispersion of graphene oxide (GO) flakes in a tin precursor solution was captured in a three-dimensional network SnO₂ aerogel matrix and successively underwent supercritical alcohol drying followed by the in situ thermal reduction of GO, resulting in SnO₂ aerogel/rGO nanocomposites. The chemical interaction between aerogel matrix and GO functional groups was confirmed by a peak shift in the Fourier transform infrared spectra and a change in the optical bandgap of the diffuse reflectance spectra. The role of rGO in 3D aerogel structure was studied in terms of photocatalytic activity with detailed mechanism of the enhancement such as electron transfer between the GO and SnO₂. In addition, the photocatalytic activity of these nanocomposites in the methyl orange degradation varied depending on the amount of rGO loading in the SnO₂ aerogel matrix; an appropriate amount of rGO was required for the highest enhancement in the photocatalytic activity of the SnO₂ aerogel. The proposed nanocomposites could be a useful solution against water pollutants. Full article