Search Results (163)

Aluminum nitride (AlN) thin films were deposited on SiO₂ substrates by RF-magnetron sputtering at varying powers (110–140 W) and subsequently subjected to thermal annealing at 450 °C under nitrogen atmosphere. A comprehensive multi-technique investigation—including X-ray reflectometry (XRR), X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), optical profilometry, spectroscopic ellipsometry (SE), and electrical measurements—was performed to explore the physical structure, morphology, and optical and electrical properties of the films. The analysis of the film structure by XRR revealed that increasing sputtering power resulted in thicker, denser AlN layers, while thermal treatment promoted densification by reducing density gradients but also induced surface roughening and the formation of island-like morphologies. Optical studies confirmed excellent transparency (>80% transmittance in the near-infrared region) and demonstrated the tunability of the refractive index with sputtering power, critical for optoelectronic applications. The electrical characterization of Au/AlN/Al sandwich structures revealed a transition from Ohmic to trap-controlled space charge limited current (SCLC) behavior under forward bias—a transport mechanism frequently present in a material with very low mobility, such as AlN—while Schottky conduction dominated under reverse bias. The systematic correlation between deposition parameters, thermal treatment, and the resulting physical properties offers valuable pathways to engineer AlN thin films for next-generation optoelectronic and high-frequency device applications. Full article

This work presents a novel and comprehensive framework for optimizing fiber optic evanescent wave (FOEW) localized surface plasmon resonance (LSPR) sensors by investigating the unique interaction between evanescent waves and plasmonic nanoparticles. Unlike propagating light, the evanescent wave is a localized, non-propagating field that interacts exclusively with absorbing media near the fiber surface. This characteristic highlights the importance of prioritizing nanoparticle absorption over total extinction in FOEW sensor design. The optical response of silver nanoparticles was modeled across a size range of 10–100 nm, showing that absorption increases with particle number. Among the sizes tested, 30 nm silver nanoparticles exhibited the highest absorption efficiency, which was confirmed experimentally. An analytical adsorption kinetics model based on diffusion transport further predicted that smaller nanoparticles yield higher surface coverage, a result validated through atomic force microscopy (AFM) and scanning electron microscopy (SEM) imaging. Refractive index (RI) sensitivity tests conducted on sensors fabricated with 10 nm, 20 nm, and 30 nm silver nanoparticles revealed that while smaller nanoparticles produced higher initial absorption due to greater surface density, the 30 nm particles ultimately provided superior RI sensitivity due to their enhanced absorption efficiency. These findings underscore the significance of absorption-centered nanoparticle design in maximizing FOEW LSPR sensor performance. Full article

The development of high-performance electrochromic materials demands innovative approaches to simultaneously control the nanoscale architecture and the electronic structure. We present a dual-modification strategy that synergistically combines copper doping with the Langmuir–Blodgett (LB) assembly to overcome the traditional performance trade-offs in tungsten oxide-based electrochromic systems. Cu-doped W₁₈O₄₉ nanowires with varying Cu concentrations (0–12 mol%) were synthesized hydrothermally and assembled into thin films via the LB technique, with LB precursors characterized by contact angle, surface tension, viscosity, and thermogravimetric-differential scanning calorimetry (TG-DSC) analyses. The films were systematically evaluated using scanning electron microscopy, X-ray photoelectron spectroscopy, chronoamperometry, and transmittance spectroscopy. Experimental results reveal an optimal Cu-doping concentration of 8 mol%, achieving a near-infrared optical modulation amplitude of 76.24% at 1066 nm, rapid switching kinetics (coloring/bleaching: 5.0/3.0 s), and a coloration efficiency of 133.00 cm²/C. This performance is speculated to be a balance between Cu-induced improvements in ion intercalation kinetics and LB-ordering degradation caused by lattice strain and interfacial charge redistribution, while mitigating excessive doping effects such as structural deterioration and thermodynamic instability. The work establishes a dual-modification framework for designing high-performance electrochromic interfaces, emphasizing the critical role of surface chemistry and nanoscale assembly in advancing adaptive optoelectronic devices like smart windows. Full article

Laser-boronized parts manufactured by a selective laser melting process from 18Ni to 300 maraging steel are investigated in this study. Two main issues are addressed, namely (i) the possibility to restore the hardness of the heat-affected zone (HAZ) formed during laser processing and (ii) the effect of re-aging on the hardness and wear resistance of the laser-boronized layer with a hypoeutectic structure. Optical microscopy, scanning electron microscopy, energy-dispersive spectroscopy, X-ray diffraction analysis, microhardness measurements, the “ball-on-plate” dry sliding test, and the two-body dry abrasive wear test were employed to answer the questions. The results confirmed that HAZ is formed with the dissolution of intermetallides formed before and undergo full (near the molten pool) or partial (at some distance from the molten pool) iron–base matrix recrystallization. The hardness of HAZ (350–550 HK0.05) has been restored after re-aging to the 550–600 HK0.05 level. Moreover, a certain positive effect of re-aging on the laser-boronized layer with a hardness of ~470–750 HK0.2 is established, associated with structural transformations induced by aging in the iron-based solid solution phase. The hardness increased by ~9–25%. The wear resistance of the hardest boronized samples (~750 HK0.2) under dry sliding and dry abrasive wear conditions was ~5.8 times and 3.7 times higher than that of the aged control sample, while re-aging provided further improvement of these characteristics. The presented results provide insights into the effectiveness of laser-boronized layers having a hypoeutectic structure in terms of increasing the wear resistance of maraging steel. Full article

This study investigates the use of spent coffee grounds (SCGs) as a biofiller in polypropylene (PP) composites, produced via injection molding, as a sustainable alternative to conventional materials. The effects of varying SCG content (1%, 5%, 7%, and 10% w/w) on the flow behavior, thermal stability, mechanical properties, structural integrity, and morphology of the composites were systematically evaluated. Analyses using optical microscopy (OM) and Fourier-transform infrared spectroscopy (FT-IR) revealed significant changes in morphology and structure with SCG addition. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) showed improved thermal stability with increasing SCG content. Mechanical characterization indicated an enhanced hardness and tensile modulus, a near-constant tensile strength, and a decreased toughness and elongation at break with increasing SCG content. Melt flow index (MFI) measurements confirmed suitable processing characteristics. Overall, the PP/SCG composites demonstrate promising performance regarding sustainability and mechanical properties, suggesting their viability as an alternative to traditional materials. Full article

The tunability of spectral lineshapes, ranging from Lorentzian to Fano profiles, is essential for advancing nanoscale photonic technologies. Conventional far-field techniques are insufficient for studying nanoscale phenomena, particularly within the terahertz (THz) range. In this work, we use a U-shaped resonant ring on a waveguide substrate to achieve precise modulation of Lorentzian, Fano, and antiresonance profiles. THz scattering scanning near-field optical microscopy (s-SNOM) reveals the underlying physical mechanism of these transitions, driven by time-domain phase shifts between the background excitation from the waveguide and the resonance of the U-shaped ring. Our approach reveals a pronounced asymmetry in the near-field response, which remains undetectable in far-field systems. The ability to control spectral lineshapes at the nanoscale presents promising applications in characterizing composite nanoresonators and developing nanoscale phase sensors. Full article

A high-temperature, high-cycle fatigue test was conducted on a nickel-based single-crystal superalloy with a pore structure. Optical and scanning electron microscopy were utilized to examine the crack propagation paths and fatigue fracture surfaces at the macro and micro scales. The analysis of crack initiation and propagation related to the pore structure facilitated the development of a crack shape factor reflecting these distinct fracture behaviors. Predictions about the high-cycle fatigue stress experienced by the specimen were made, accompanied by an error analysis, providing critical insights for precise stress calculations and structural optimization in engine blade design. The results reveal that high-cycle fatigue cracks originate from corner cracks at pore edges, with the initial propagation displaying smooth crystallographic plane features. Subsequent stages show clear fatigue arc patterns in the propagation zones. The fracture surface exhibits the significant layering of oxide layers, primarily composed of NiO, with traces of CoO displaying columnar growth. AL₂O₃ is predominantly found at the interfaces between the matrix and oxide layers. Short and straight dislocations near the oxide layers and within the matrix suggest that dislocation multiplication and planar slip dominate the slip mechanisms in this alloy. The orientation of the fracture surface is mainly perpendicular to the load direction, with minor inclined facets in localized areas. Correlations were established between the plastic zone dimensions at the crack tips and the corresponding fatigue stresses. Without grain boundaries in single-crystal alloys, these dimensions are easily derived as parameters for fatigue stress analysis. The selected crack shape factor, “elliptical corner crack at pore edges”, captures the initiation and propagation traits relevant to porous structures. Subsequent calculations, accounting for the impact of oxide layers on stress assessments, indicated an error ratio ranging from 1.00 to 1.21 compared to nominal stress values. Full article

The interaction of ultra-short laser pulses (USLP) with Nickel/Titanium (Ni/Ti) thin film has been presented. The nano layer thin film (NLTF), composed of ten alternating Ni and Ti layers, was deposited on silicon (Si) substrate by ion-sputtering. A single and multi-pulse irradiation was performed in air with focused and linearly polarized laser pulses. For achieving selective ablation of one or more surface layers, without reaching the Si substrate, single pulse energy was gradually increased from near the ablation threshold value to an energy value that caused the complete removal of the NLTF. In addition to single-pulse selective ablation, the multi-pulse USLP irradiation and production of laser-induced periodic surface structures (LIPSSs) were also studied. In the presented experiment, we found the optimal combination of accumulated pulse number and pulse energy to achieve the LIPSS formation on the thin film. The laser-induced morphology was examined with optical microscopy, scanning electron microscopy, and optical profilometry. To interpret the experimental observations, a theoretical simulation has been performed to explore the thermal response of the NLTFs after irradiation with single laser pulses. Full article

This paper reports on the successful preparation of a low absorption–emission thermal control coating on the surface of LAZ933 magnesium–lithium alloy using the micro-arc oxidation method. This study analyzed the microstructure, phase composition, and thermal control properties of the coating using Scanning Electron Microscopy (SEM), X-ray diffraction (XRD), UV–visible near-infrared spectroscopy (UV-VIS-NIR) and infrared emissivity measurements. The results indicate that the hemispherical emissivity of the coating remains unaffected with an increase in temperature and holding time, while the solar absorption ratio gradually increases. The thermal control performance of the coating after a high-temperature experiment was found to be related to the diffusion of the Li metal element in the magnesium lithium alloy matrix, as determined by X-ray photoelectron spectroscopy (XPS), flame graphite furnace atomic absorption spectrometry (GFAAS) and Glow Discharge Optical Emission Spectroscopy (GD-OES). As the holding time is extended, the coating structure gradually loosens under thermal stress. The Li metal element in the substrate diffuses outward and reacts with O₂, H₂O and CO₂ in the air, forming LiO₂, LiOH, Li₂CO₃ and other products. This reaction affects the coating’s solar absorption ratio in the end. Full article

A series of Sr_1−xDy_xTi_1−yNb_yO_3−δ (0.05 ≤ x, y ≤ 0.10) samples were fabricated using cold compaction, followed by sintering in a (95% N₂ + 5% H₂) reducing atmosphere. We studied the crystal structure and optical properties of Sr_1−xDy_xTi_1−yNb_yO_3−δ using X-ray diffraction (XRD) with Rietveld refinement, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and ultraviolet−visible−near-infrared (UV−VIS−NIR) spectroscopy. The sintered Sr_1−xDy_xTi_1−yNb_yO_3−δ had a tetragonal structure (I4/mcm space group). In the sintered samples, Ti ions existed as a mixture of Ti³⁺ and Ti⁴⁺, and Nb ions existed as a mixture of Nb⁴⁺ and Nb⁵⁺. The band-gap energies decreased with increasing Dy/Nb concentrations. The incorporation of Ti and Nb ions, the formation of both Ti³⁺ and Nb⁴⁺ ions, and the reduction in band-gap energies are likely highly effective for increasing the electron concentration and the corresponding electrical conductivity. Sr_1−xDy_xTi_1−yNb_yO_3−δ with high electrical conductivity is suitable for energy and electronics applications. Full article

Using liquid crystals in near-infrared applications suffers from effects related to processes like parasitic absorption and high sensitivity to UV-light exposure. One way of managing these disadvantages is to use deuterated systems. The combined ¹H and ²H nuclear magnetic resonance relaxometry method (FFC NMR), dielectric spectroscopy (DS), optical microscopy (POM), and differential scanning calorimetry (DSC) approach was applied to investigate the influence of selective deuteration on the molecular dynamics, thermal properties, self-organization, and electric-field responsiveness to a 4′-pentyl-4-biphenylcarbonitrile (5CB) liquid crystal. The NMR relaxation dispersion (NMRD) profiles were analyzed using theoretical models for the description of dynamics processes in different mesophases. Obtained optical textures of selectively deuterated 5CB showed the occurrence of the domain structure close to the I/N phase transition. The dielectric measurements showed a substantial difference in switching fields between fully protonated/deuterated 5CB and selectively deuterated molecules. The DSC thermograms showed a more complex phase transition sequence for partially deuterated 5CB with respect to fully protonated/deuterated molecules. Full article

The focus of this research is to examine the feasibility of using laser texturing as a method for surface preparation prior to thermal spraying. The experimental part includes the thermal spraying of a Stellite 6 coating by High Velocity Oxygen Fuel (HVOF) technology on laser-textured substrates. The thermal spraying of this coating was deposited both on conventional substrate material (low carbon steel) and on substrates that had been previously heat treated (nitrided steel). The properties of the coatings were analysed using scanning electron microscopy (SEM), optical microscopy (OM) and Raman spectroscopy. Adhesion was assessed through a tensile adhesion test. The results showed the usability of laser texturing in the case of carbon steel, which was comparable or even better than traditional grit blasting. For nitrided steel, the problem remains with the hardness and brittleness of the nitrided layer, which allows for the propagation of brittle cracks near the interface and thus reduces the adhesion strength. Full article

Fe(III) oxides were prepared as free nanoparticles and on DNA templates via the precipitation of Fe(III) salts with NaOH in the presence/absence of DNA. Through control of the pH and temperature, FeOOH and Fe₂O₃ were synthesised. The formation of templated materials FeOOH/DNA and Fe₂O₃/DNA was confirmed using UV-Vis absorption and FTIR spectra. The direct optical gap of Fe₂O₃/DNA was estimated as 3.2 eV; the absorption by FeOOH/DNA and Fe₂O₃/DNA at longer wavelengths is weaker, but consistent with indirect gaps near 2 eV. X-ray photoelectron spectra confirmed the presence of Fe(III) and DNA in the templated samples. Analysis of the X-ray diffraction patterns of both templated and non-templated FeOOH and Fe₂O₃ demonstrated that the materials were the α-FeOOH and α-Fe₂O₃ polymorphs with crystallite diameters of the DNA-templated materials estimated as 7.6 nm and 6.8 nm. Transmission electron microscopy showed needle-like crystals of both FeOOH and Fe₂O₃, but the Fe₂O₃ contains some globular structures. In contrast, the morphology of FeOOH/DNA and Fe₂O₃/DNA consists of needle-like crystallites of the respective oxides organised into complex dendritic structures with a length on the 10 μm scale formed by the DNA molecules. Finally, scanned conductance microscopy provided evidence for the conductivity of the FeOOH/DNA after alignment via molecular combing on an Si/SiO₂ substrate. Fe₂O₃/DNA did not exhibit any detectable conductivity. Full article

New Nd³⁺-doped cadmium molybdato-tungstates with the chemical formula of Cd_1−3x▯_xNd_2x(MoO₄)_1−3x(WO₄)_3x (where x = 0.0283, 0.0455, 0.0839, 0.1430, 0.1875, 0.2000, 0.2500, and ▯ denotes a vacant site in the crystal lattice) were successfully synthesized by the high-temperature solid state reaction method, using CdMoO₄ and Nd₂(WO₄)₃ as the initial reactants. The structure and change in their lattice parameters as a function of Nd³⁺ ion concentration were investigated by the XRD (X-ray diffraction) method. The surface morphology and grain size of the doped materials were characterized by SEM (scanning electron microscopy). Their thermal properties and initial reactants were analyzed by DTA-TG (differential thermal analysis coupled with thermogravimetry) techniques. The optical properties of the Nd³⁺-doped cadmium molybdato-tungstates, such as optical band gap, were determined by UV–vis–NIR (ultraviolet–visible–near infrared) spectroscopy. The EPR (electron paramagnetic resonance) technique provided information on the type of magnetic interactions between Nd³⁺ ions. Full article

The fabrication of stable, tailored domain patterns in ferroelectric crystals has wide applications in optical and electronic industries. All-optical ferroelectric poling by pulse laser irradiation has been developed recently. In this work, we studied the creation of the domain structures in MgO-doped lithium tantalate by focused irradiation with a femtosecond near-infrared laser. Cherenkov-type second harmonic generation microscopy was used for domain imaging of the bulk. We have revealed the creation of enveloped domains around the induced microtracks under the action of the depolarization field. The domain growth is due to a pyroelectric field caused by a nonuniform temperature change. The domains in the bulk were revealed to have a three-ray star-shaped cross-section. It was shown that an increase in the field excess above the threshold leads to consequential changes in domain shape from a three-ray star to a triangular and a circular shape. The appearance of comb-like domains as a result of linear scanning was demonstrated. All effects were considered in terms of a kinetic approach, taking into account the domain wall motion by step generation and kink motion driven by excess of the local field over the threshold. The obtained knowledge is useful for the all-optical methods of domain engineering in ferroelectrics. Full article