Search Results (213)

The Shabaosi gold field is located in the western Mohe Basin, part of the northern Great Xing’an Range, NE China, and contains multiple gold deposits. However, the sources of the ore-forming materials, the fluid evolution, and the genesis of these gold deposits have been disputed, especially regarding the classification of these deposits as either epithermal or orogenic gold systems. Based on detailed field geological investigations and previous research, we conducted systematic research on the Shabaosi, Sanshierzhan, Laogou, and Balifang gold deposits using fluid inclusion and H-O-S-Pb isotope data, with the aim of constraining the fluid properties, sources, and mineralization processes. Fluid inclusion analyses reveal diverse types, including vapor-rich, vapor–liquid, CO₂-bearing, CO₂-rich, and pure CO₂. Additionally, only a very limited number of daughter mineral-bearing fluid inclusions have been observed exclusively in the Laogou gold deposit. During the early stages, the peak temperature primarily ranged from 240 °C to 280 °C, with salinity concentrations between 6 and 8 wt% NaCl equiv., representing a medium–low temperature, low salinity, and a heterogeneous CO₂-CH₄-H₂O-NaCl system. With the influx of meteoric water, the fluids evolved gradually into a simple NaCl-H₂O system with low temperatures (160–200 °C) and salinities (4–6 wt%). The main mineralization stage exhibited peak temperatures of 220–260 °C and salinities of 5–8 wt% NaCl equiv., corresponding to an estimated formation depth of 1.4–3.3 km. The δD_V-SMOW values (−138.3‰ to −97.0‰) and δ¹⁸O_V-SMOW values (−7.1‰ to 16.2‰) indicate that the magmatic–hydrothermal fluids were progressively diluted by meteoric water during mineralization. The sulfur isotopic compositions (δ³⁴S = −0.9‰ to 1.8‰) and lead isotopic ratios (²⁰⁸Pb/²⁰⁴Pb = 38.398–38.579, ²⁰⁷Pb/²⁰⁴Pb = 15.571–15.636, and ²⁰⁶Pb/²⁰⁴Pb = 18.386–18.477) demonstrate that the gold predominantly originated from deep magmatic systems, with potential crustal contamination. Comparative analyses indicate that the Shabaosi gold field should be classified as a epizonal orogenic gold system, which shows distinct differences from epithermal gold deposits and corresponds to the extensional tectonic setting during the late-stage evolution of the Mongol–Okhotsk orogenic belt. Full article

The eutectic PbLi (15.7 at.% Li) alloy appears promising for producing tritium from fertile materials. Currently, in nuclear fusion design, the technologies being explored for tritium extraction in molten phases primarily focus on (i) established processes based on Gas–Liquid Contactor (GLC), such as bubble, packed, or spray columns, or on (ii) exploiting hydrogen permeation phenomena using dense metallic membranes, i.e., Permeation Against Vacuum (PAV). This work introduces a new concept, a Membrane Gas–Liquid Contactor, to address several open issues related to mass transport phenomena within the previously mentioned technologies. The MGLC concept merges the advantages of Permeation Against Vacuum (PAV) and Gas–Liquid Contactor (GLC), which have been extensively applied to extract hydrogen and its isotopes from liquid metals. A comprehensive description of the MGLC’s operation is then provided, suggesting a mass transfer model suitable for the practical application of this new concept. Finally, the results of the experimental campaign conducted on a lab-scale test facility are presented and critically analyzed. Full article

Türkiye hosts a wide variety of barite deposits that can be broadly classified into two major groups based on their tectonic settings: magmatism-associated and passive margin-hosted deposits. The magmatism-associated deposits include Kızılcaören (F + Ba + REE + Th, Beylikova–Eskişehir), Kirazören (Bulancak–Giresun), and Karacaören (Mesudiye–Ordu). The Kızılcaören deposit formed in relation to the emplacement of a late Oligocene carbonatitic sill, while the Kirazören and Karacaören deposits are associated with the Cretaceous Pontide magmatic arc. Passive margin-hosted deposits occur within various Paleozoic sedimentary lithologies—such as metasandstone, shale, schist, and limestone—and are found in the Taurides and the Arabian Platform. These deposits occur as either concordant or discordant veins. This barite belt extends from Şarkikaraağaç (Isparta), through Hüyük (Konya) and Alanya (Antalya), to Silifke (Mersin), Tordere (Adana), Önsen, Şekeroba (Kahramanmaraş), and Hasköy (Muş). The Paleozoic deposits represent the major barite resources of Türkiye, with an annual production of approximately 300,000 metric tons. Smaller deposits around Gazipaşa (Antalya) contain minor Pb-Zn sulfides. Mesozoic barite deposits are hosted in Triassic dolomites and are associated with Pb-Zn mineralization in the Hakkari region of the Arabian Platform. Pb and Sr isotope data indicate that the barium in these deposits was derived from ancient continental crust. The isotopic compositions of both concordant (stratabound) and discordant (vein-type) barites are generally homogeneous. In northwestern Türkiye, the Sr isotope compositions of the barite deposits align well with those of the Oligocene carbonatite host complex. The ⁸⁷Sr/⁸⁶Sr isotope ratio of the Kızılcaören deposit (0.706‰) is the least radiogenic among Turkish barite deposits, suggesting a mantle contribution. The Kirazören deposit in the Pontide magmatic arc follows with a slightly higher ratio (0.707‰). Triassic barites from the Hakkari region yield ⁸⁷Sr/⁸⁶Sr values around 0.709‰, slightly more radiogenic than coeval seawater. Paleozoic barite deposits show the most radiogenic ⁸⁷Sr/⁸⁶Sr values, including Aydıncık (0.718‰), Şarkikaraağaç (0.714‰), Hasköy (0.713‰), Kahramanmaraş (0.712‰), Tordere, and Hüyük (both 0.711‰), consistent with their respective host rocks. The elevated radiogenic Pb and Sr isotope values in the passive margin-hosted deposits suggest that the barium originated from deeper, barium-enriched rocks, whereas stable sulfur isotope data point to a marine sulfur source. Moreover, Sr and S isotopic signatures indicate that the Paleozoic sediment-hosted deposits formed in association with cold seeps on the seafloor, resembling modern analogs. In contrast, the Mesozoic Karakaya deposit (Hakkari) represents a typical vent-proximal, sediment-hosted deposit with no magmatic signature. Full article

This study critically examines the early Cretaceous carbonate-hosted Zn-Pb (±Ba±Cu) deposits of the Malayer-Esfahan (MEMB) and Yazd-Anarak (YAMB) metallogenic belts in Iran, which have been inaccurately classified as Mississippi Valley type (MVT) deposits by Nejadhadad et al. (2025). Our findings reveal significant differences in mineralogy, fluid inclusion characteristics, and geochemical signatures compared to typical MVT deposits. These deposits are more akin to Irish-type Zn-Pb mineralization and formed in extensional and passive margin environments around the Nain–Baft back-arc basin. The normal faults in this back-arc rift can transform significantly during inversion and compressional tectonics, reactivating to behave as reverse faults and leading to new geological structures and landscapes. Our study highlights barite replacement as a crucial factor in forming sediment-hosted Zn-Pb (±Ba±Cu) and barite-sulfide deposits. Based on textural evidence, fluid inclusion data, and sulfur isotope analyses, we propose that barite plays a fundamental role in controlling subsequent Zn-Pb (±Ba±Cu) mineralization by serving as both a favorable host and a significant sulfur source. Furthermore, diagenetic barite may act as a precursor to diverse types of sediment-hosted Zn-Pb (±Ba±Cu) mineralization, refining genetic models for these deposits. Sulfur isotope analyses of Irish-type deposits show a broad δ³⁴S range (−28‰ to +5‰), indicative of bacterial sulfate reduction (BSR). Nevertheless, more positive δ³⁴S values (+1‰ to +36‰) and textural evidence in shale-hosted massive sulfide (SHMS) deposits suggest a greater role for thermochemical sulfate reduction (TSR) in sulfide mineralization. Full article

The Southern Beishan Orogenic Belt (SBOB), an integral part of the Southern Central Asian Orogenic Belt (CAOB), is characterized by extensive Late Paleozoic magmatism. These igneous rocks are the key to studying the tectonic evolution process and the ocean–continent tectonic transformation in the southern margin of the CAOB and Paleo-Asian Ocean. We present zircon U-Pb chronology, in situ Lu-Hf isotopes, and whole-rock geochemistry data for Early–Middle Devonian volcanic rocks in the Sangejing Formation and granites from the Shuangyingshan-Huaniushan (SH) unit in the SBOB. The Wudaomingshiu volcanic rocks (Ca. 411.5 Ma) are calc-alkaline basalt-basaltic andesites with low SiO₂ (47.35~55.59 wt.%) and high TiO₂ (1.46~4.16 wt.%) contents, and are enriched in LREEs and LILEs (e.g., Rb, Ba, and Th), depleted in HREEs and HFSEs (Nb, Ta, and Ti), and weakly enriched in Zr-Hf. These mafic rocks are derived from the partial melting of the depleted lithosphere metasomatized by subduction fluid and contaminated by the lower crust. Wudaomingshui’s high-K calc-alkaline I-type granite has a crystallization age of 383.6 ± 2.2 Ma (MSWD = 0.11, n = 13), high Na₂O (3.46~3.96 wt.%) and MgO (1.25~1.68 wt.%) contents, and a high DI differentiation index (70.69~80.45); it is enriched in LREEs and LILEs (e.g., Rb, Ba, and Th) and depleted in HREEs and HFSEs (e.g., Nb, Ta, and Ti). Granites have variable zircon ε_Hf(t) values (−2.5~3.3) with Mesoproterozoic T_DM2 ages (1310~1013 Ma) and originated from lower crustal melting with mantle inputs and minor upper crustal assimilation. An integrated analysis of magmatic suites in the SBOB, including rock assemblages, geochemical signatures, and zircon ε_Hf(t) values (−2.5 to +3.3), revealed a tectonic transition from advancing to retreating subduction during the Early–Middle Devonian. Full article

A diverse range of granitoids in the North Qilian Orogenic Belt (NQOB) offers valuable insights into the region’s tectonomagmatic evolution. In this study, we undertook a geochronological, mineralogical, geochemical, and zircon Hf isotopic analysis of granodiorites from the Yaogou area of the NQOB. Zircon U-Pb dating reveals that the Yaogou granodiorites formed during the Early–Middle Ordovician (473–460 Ma). The Yaogou granodiorites have high SiO₂ (63.3–71.1 wt.%), high Al₂O₃ (13.9–15.8 wt.%) contents, and low Zr (96–244 ppm), Nb (2.9–18 ppm), as well as low Ga/Al ratios (10,000 × Ga/Al ratios of 1.7–2.9) and FeO^T/MgO ratios (1.9–3.2), and are characterized by elevated concentrations of light rare earth elements and large-ion lithophile elements such as Rb, Th, and U, coupled with significant depletion in heavy rare earth elements and high-field-strength elements including Nb, Ta, and Ti. Additionally, the presence of negative europium anomalies further reflects geochemical signatures typical of I-type granitic rocks. The zircon grains from these rocks display negative ε_Hf(t) values (−14.6 to −10.7), with two-stage Hf model ages (T_DM2) from 2129 to 1907 Ma. These characteristics suggest that the magmatic source of the Yaogou granodiorites likely originated from the partial melting of Paleoproterozoic basement-derived crustal materials within a tectonic environment associated with subduction in the North Qilian Ocean. Integrating regional geological data, we suggest that during the Early Paleozoic, the North Qilian Oceanic slab underwent double subduction: initially southward, followed by a northward shift. Due to the deep northward subduction of the Qaidam continental crust and oceanic crust along the southern margin of the Qilian Orogenic Belt, the southward subduction of the North Qilian ocean was obstructed, triggering a reversal in subduction polarity. This reversal likely decelerated the southward subduction and initiated northward subduction, ultimately leading to the formation of the Yaogou granodiorites. These findings enhance our understanding of the complex tectonic processes that shaped the North Qilian Orogenic Belt during the Early Paleozoic, emphasizing the role of subduction dynamics and continental interactions in the region’s geological evolution. Full article

This study investigates the provenance of the Permian Shihezi Formation (Fm) siliciclastic sediments in the Luonan area, southern margin of the North China Block, which constrain the sediment sources and tectonic evolution of the basin. Our research investigates the heavy mineral characteristics, geochemical features, detrital zircon U-Pb geochronology, and Lu-Hf isotope tracing the provenance characteristics of the Shihezi Fm in this region. Zircon yielded three distinct U-Pb age groups as follows: 320–300 Ma, 1950–1850 Ma, and 2550–2450 Ma. The ε_Hf(t) values of zircons ranged from −41 to 50, and the two–stage Hf model’s ages (T_DM2) values are concentrated between 3940 Ma and 409 Ma, suggesting that magmatic sources likely derive from Early Archaean–Devonian crustal materials. The heavy mineral assemblages are primarily composed of zircon, leucoxene, and magnetite. Further geochemical analyses of the rocks indicate a diverse provenance area and a complex tectonic evolution. Taken together, these results suggest that the provenance of the Shihezi Fm is from the North China Block, with secondary contributions from the Qinling Orogenic Belt and the North Qilian Orogenic Belt. The provenance of Luonan shares similarities with the southern Ordos Basin. Investigating the provenance of the Luonan area along the southern margin of the North China Craton provides critical supplementary constraints for shedding light on the Late Paleozoic tectonothermal events in the Qinling Orogenic Belt. Full article

The Cuyu gold deposit in central Jilin Province in Northeast China is located in the eastern segment of the northern margin of the North China Craton (NCC), as well as the eastern segment of the Xing’an–Mongolian Orogenic Belt (XMOB). Gold ore-bodies are controlled by NW-trending faults and mainly occur in late Hercynian granodiorite. The mineralization process in the Cuyu deposit can be divided into three stages: quartz + coarse grained arsenopyrite + pyrite (stage I), quartz + sericite + pyrite + arsenopyrite + electrum + chalcopyrite + sphalerite (stage II), and quartz + calcite ± pyrite (stage III). Stage II is the most important for gold mineralization. We conducted analyses including petrography, microthermometry, laser Raman spectroscopy of fluid inclusions, and H–O–S–Pb isotopic analysis to elucidate the mineralization processes in the Cuyu deposit. Five types of primary fluid inclusions (FIs) are present in the hydrothermal quartz and calcite grains of the ore: liquid-rich two-phase aqueous fluid inclusions (L-type), vapor-rich two-phase aqueous fluid inclusions (V-type), CO₂-bearing two- or three-phase inclusions (C1-type), CO₂-rich two- or three-phase inclusions (C2-type), and pure CO₂ mono-phase inclusions (C3-type). From stages I to III, the fluid inclusion assemblages changed from L-, C2-, and C3-types to L-, V-, C1-, C2-, and C3-types and, finally, to L-types only. The corresponding homogenization temperatures for stages I to III were 242–326 °C, 202–298 °C, and 106–188 °C, and the salinities were 4.69–9.73, 1.63–7.30, and 1.39–3.53 wt.% NaCl equiv., respectively. The ore-forming fluid system evolved from a NaCl-H₂O-CO₂ ± CH₄ ± H₂S fluid system in stage I and II with immiscible characteristics to a homogeneous NaC-H₂O fluid system in stage III. Microthermometric data for stages I to III show a decreasing trend in homogenization temperatures and salinities. The mineral assemblages, fluid inclusions, and H–O–S–Pb isotopes indicate that the initial ore-forming fluids of stage I were exsolved from diorite porphyrite and characterized by a high temperature and low salinity. The addition of meteoric water in large quantities led to decreases in temperature and pressure, resulting in a NaCl-H₂O-CO₂ ± CH₄ ± H₂S fluid system with significant immiscibility in stage II, facilitating the deposition of gold and associated polymetallic sulfides. The Cuyu gold deposit has a similar ore genesis to those of gold deposits in the Jiapigou–Haigou gold belt (JHGB) of southeastern Jilin Province indicating potential for gold prospecting in the northwest-trending seam of the JHGB. Full article

Ion-adsorption rare earth deposits are mainly formed by the weathering and leaching of granite ore-forming parent rocks, and heavy rare earth elements (HREEs) are predominantly hosted in this type of deposit. In this study, we focused on the Late Jurassic REE mineralization parent rock, specifically the Shuitou pluton. We employed chronology, petrogeochemistry, and isotope geochemistry to elucidate the REE enrichment process in the granite. The results show that the zircon U–Pb age of the Shuitou pluton is ~150 Ma, and the monazite U–Pb age is ~145 Ma, suggesting that the pluton was formed in the Yanshan Stage. The rocks have high SiO₂ (72.85–75.55 wt%), Al₂O₃ (12.85–14.63 wt%), and K₂O (4.46–5.27 wt%) content, with A/CNK values of 1.05–1.19, differentiation index (DI) values of 87.48–95.59, zircon saturation temperature values of 689–746 °C, Nb/Ta ratios of 2.72–9.54, and Zr/Hf ratios of 7.12–26.11. In addition, the rocks also contain peraluminous minerals such as muscovite and garnet. These characteristics indicate that these rocks belong to highly fractionated S-type granite. The ε_Hf(t) values of zircon and monazite range from −10.04 to −6.78 and from −9.3 to −8.2, respectively, indicating that the magma was primarily derived from Proterozoic metamorphosed sedimentary rocks of crustal origin. In the extensional tectonic setting of South China, a high temperature promotes the melting of REE-enriched accessory minerals, and a higher content of F increases the solubility of REEs in the molten mass. The presence of heavy rare earth minerals, such as garnet, in these rocks contributes to a high content of heavy rare earth elements (HREEs). Additionally, REE-enriched minerals like titanite, bastnaesite, and allanite create the necessary material conditions for the formation of ion-adsorption REE deposits. Full article

Late Mesozoic magmatism in Southeast China extensively reworked the Cathaysia Block’s crust, linked to the Paleo-Pacific Plate subduction beneath East Asia. The northeastern Cathaysia Block, largely covered by Cretaceous volcanic-sedimentary basins, has limited Jurassic exposure to Early Cretaceous intrusions, which provides critical insights into deep crust-mantle processes. In this study, we present zircon U-Pb geochronology and Hf isotope, whole-rock geochemistry, and Sr-Nd isotopes of the Middle Jurassic syenite-granite suites and Early Cretaceous granites with enclaves in the Qingyuan area (SW Zhejiang Province) to constrain their petrogenesis and tectonic significance. Middle Jurassic syenites and alkali-feldspar granites (169–167 Ma) exhibit calc-alkaline to shoshonitic affinities and weakly peraluminous compositions. Early Cretaceous granites (134 Ma) and their enclaves (136 Ma) are high-K calc-alkaline and weakly peraluminous to metaluminous. All samples show LILE and LREE enrichment, HFSE depletion, and negative Eu and Sr anomalies, with only syenites displaying negative Ce anomalies. We suggest that the Middle Jurassic syenites originated from the partial melting of an enriched lithospheric mantle influenced by subduction-related metasomatism. Alkali-feldspar granites derived from partial melting of the basement of the Cathaysia Block. Early Cretaceous granites formed by partial melting of lower crustal mafic rocks, with enclaves representing earlier crystallization products, which were then mechanically mixed with granites. We propose the NE Cathaysia Block underwent significant reworking from the Middle Jurassic to the Early Cretaceous. Middle Jurassic syenites formed in a compressional setting linked to Paleo-Pacific Plate subduction, while Early Cretaceous magmatism reflects lithospheric extension and crust-mantle interaction triggered by slab rollback. Full article

The Xulaojiugou Pb–Zn deposit, situated in the eastern Xing’an-Mongolia Orogenic Belt (XMOB), represents a medium-scale Pb–Zn deposit in central Heilongjiang Province, NE China. The mineralization occurs mainly near the contact zone of porphyritic biotite granite, medium-grained monzogranite, and marble in the Early Cambrian Qianshan Formation. Orebodies exhibit typical skarn characteristics and are structurally controlled by NE trending faults. To constrain the metallogenic age, ore-forming processes, and sources of ore-forming materials, we conducted integrated geochemical analyses, Re–Os isotope dating, in situ sulfur isotope analysis, and trace element analysis. Five molybdenite samples provided a Re–Os isochron age of 184.6 ± 3.0 Ma, indicating Early Jurassic mineralization. In situ δ³⁴S values from 20 sphalerite and 9 galena samples ranged from 5.31‰ to 5.83‰, suggesting derivation of sulfur from a deep magmatic source. Trace element analysis of 42 spots from three sphalerite samples revealed formation temperatures of 248–262 °C, which are consistent with mesothermal conditions. Integrated with regional tectonic evolution, the Xulaojiugou deposit is genetically linked to medium-grained monzogranite emplacement and represents a typical skarn polymetallic deposit, which is genetically associated with the regional porphyry–skarn metallogenic system that developed during the Early Yanshanian (Jurassic) tectonic–magmatic event and was driven by the subduction of the Paleo-Pacific plate. Full article

The Beishan Orogenic Belt, situated along the southern margin of the Central Asian Orogenic Belt, represents a critical tectonic domain that archives the prolonged subduction–accretion processes and Paleo-Asian Ocean closure from the Early Paleozoic to the Mesozoic. Early Permian magmatism, exhibiting the most extensive spatial-temporal distribution in this belt, remains controversial in its geodynamic context: whether it formed in a persistent subduction regime or was associated with mantle plume activity or post-collisional extension within a rift setting. This study presents an integrated analysis of petrology, zircon U-Pb geochronology, in situ Hf isotopes, and whole-rock geochemistry of Early Permian granites from the Tiancang area in the southern Beishan Orogenic Belt, complemented by regional comparative studies. Tiancang granites comprise biotite monzogranite, monzogranite, and syenogranite. Zircon U-Pb dating of four samples yields crystallization ages of 279.3–274.1 Ma. These granites are classified as high-K calc-alkaline to calc-alkaline, metaluminous to weakly peraluminous I-type granites. Geochemical signatures reveal the following: (1) low total rare earth element (REE) concentrations with light REE enrichment ((La/Yb)_N = 3.26–11.39); (2) pronounced negative Eu anomalies (Eu/Eu* = 0.47–0.71) and subordinate Ce anomalies; (3) enrichment in large-ion lithophile elements (LILEs: Rb, Th, U, K) coupled with depletion in high-field-strength elements (HFSEs: Nb, Ta, P, Zr, Ti); (4) zircon ε_Hf(t) values ranging from −10.5 to −0.1, corresponding to Hf crustal model ages (T_DMC) of 1.96–1.30 Ga. These features collectively indicate that the Tiancang granites originated predominantly from partial melting of Paleoproterozoic–Mesoproterozoic crustal sources with variable mantle contributions, followed by extensive fractional crystallization. Regional correlations demonstrate near-synchronous magmatic activity across the southern/northern Beishan and eastern Tianshan Orogenic belts. The widespread Permian granitoids, combined with post-collisional magmatic suites and rift-related stratigraphic sequences, provide compelling evidence for a continental rift setting in the southern Beishan during the Early Permian. This tectonic regime transition likely began with lithospheric delamination after the Late Carboniferous–Early Permian collisional orogeny, which triggered asthenospheric upwelling and crustal thinning. These processes ultimately led to the terminal closure of the Paleo-Asian Ocean’s southern branch, followed by intracontinental evolution. Full article

Cenozoic plutonic rocks in northeast Saveh, part of the central Urumieh–Dokhtar Magmatic Arc (UDMA) in Iran, comprise monzonite, monzodiorite, gabbro, and gabbrodiorite. Geochemical, zircon U-Pb geochronology, and Hf isotopic data reveal that these plutonic rocks belong to a medium-K calc-alkaline, metaluminous series with arc-related signatures. Zircon U-Pb ages (ca. 60 to 3 Ma) indicate prolonged magmatic evolution from the Middle Paleocene to the Middle Pliocene. Contrary to earlier reports of a 15 Ma period of reduced magmatic activity (ca. 72–57 Ma), our data indicate a shorter interval (ca. 10–12 Ma) during which magmatic activity decreased significantly. Key magmatic pulses occurred during the Late Eocene (ca. 40–47 Ma), Early Miocene (ca. 23–18 Ma), and Late Miocene–Pliocene (ca. 11–5.2 Ma), with geochemical data indicating a subduction-related origin. The most recent magmatic pulses in the central UDMA, potentially extending across the entire UDMA, are dated between 5 and 2.5 Ma, identified in a cluster of zircons from gabbroic rocks, which could correspond to the concluding stages of slab steepening related to continental subduction. Zircon εHf(t) values (−11.43 to 12.5) and geochemical data suggest fractional crystallization, crustal assimilation, and mantle-derived melts. The clinopyroxene crystallization temperatures (1150–1200 °C) and supporting geochemical data imply that magma was produced in a metasomatized spinel–lherzolite mantle at depths <80 km. This generation is associated with asthenospheric upwelling and slab rollback, which, in turn, triggered the partial melting of the lithosphere and fueled the region’s magmatic activity. Full article

The dispersed elements Ga, Ge, and In are crucial strategic mineral resources often enriched in Pb-Zn deposits. The Chipu Pb-Zn deposit, located on the western edge of the Yangtze Block, lies to the north of the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn metallogenic province with large amounts of Emeishan basalt. Based on trace element and in situ sulfur isotope analyses by (LA)-ICP-MS, sphalerite is the main carrier mineral for Ga (17~420 ppm), Ge (3.87~444 ppm), and In (31~720 ppm). Ga or Ge correlate significantly with Cu, while In substitutes for Zn in sphalerite alongside Fe. Key substitution reactions include Ga³⁺ + Cu⁺ ↔ 2Zn²⁺, Ge⁴⁺ + 2Cu⁺ ↔ 3Zn²⁺, and 2In³⁺ + Fe²⁺ ↔ 4Zn²⁺. Sphalerite crystallized at medium to low temperatures (114–195 °C). Sulfide δ³⁴S values (+3.48 to +24.74‰) suggest sulfur mainly originated from Dengying Formation marine sulfates via thermochemical sulfate reduction (TSR). Metal-bearing fluid release at 30 Ma post-Emeishan mantle plume activity (261–257 Ma) coincides with the Chipu deposit’s mineralization period (230–200 Ma), suggesting the Chipu deposit is associated with Emeishan plume activity. The magmatic activity drove basinal brine circulation, extracting In from intermediate-felsic igneous rocks and metamorphic basement. Elevated temperatures promoted the coupling of Fe and In into sphalerite, causing anomalous In enrichment. Full article