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Keywords = Quantum Optical Networks

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14 pages, 3979 KB  
Article
Spatial-Multiplexed Four-Channel Optical Amplification via Multiple Four-Wave Mixing in a Double-Λ Atomic System
by Xin Li, Dan Song, Yu-Xia Fan, Rong Miao, Dan Wang, Bao-Dong Yang, Hai-Tao Zhou and Jun-Xiang Zhang
Nanomaterials 2026, 16(3), 184; https://doi.org/10.3390/nano16030184 - 29 Jan 2026
Viewed by 134
Abstract
Optical amplification and spatial multiplexing technologies have important applications in quantum communication, quantum networks, and optical information processing. In this paper, based on the non-reciprocal amplification of a pair of co-propagating conjugate four-wave mixing (FWM) signals induced by a one-way pump field in [...] Read more.
Optical amplification and spatial multiplexing technologies have important applications in quantum communication, quantum networks, and optical information processing. In this paper, based on the non-reciprocal amplification of a pair of co-propagating conjugate four-wave mixing (FWM) signals induced by a one-way pump field in a double-Λ-type hot atomic system, we demonstrate spatially multiplexed multiple FWM processes by introducing a counter-propagating collinear pump field. This configuration enables simultaneous amplification of bidirectional four-channel FWM signals. Furthermore, when the injected signal and pump beams are modulated to Laguerre–Gaussian beams carrying different optical orbital angular momentum (OAM), the OAM of the pump beam is transferred to each amplified field. Through the tilted lens method, we experimentally demonstrate that the OAM of the amplified signal light remains identical to that of the original injected signal light. In contrast, the OAM of the other three newly generated FWM fields is governed by the angular momentum conservation law of their respective FWM processes, which enables the precise manipulation of the OAM for the other generated amplified fields. Theoretical analysis of the dynamical transport equation for the density operator in light–matter interaction processes fully corroborates the experimental results. These findings establish a robust framework for developing OAM-compatible optical non-reciprocal devices based on complex structured light. Full article
(This article belongs to the Special Issue Optical Properties of Nanomaterials: Linear and Nonlinear Behavior)
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35 pages, 7523 KB  
Review
Fiber-Optical-Sensor-Based Technologies for Future Smart-Road-Based Transportation Infrastructure Applications
by Ugis Senkans, Nauris Silkans, Remo Merijs-Meri, Viktors Haritonovs, Peteris Skels, Jurgis Porins, Mayara Sarisariyama Siverio Lima, Sandis Spolitis, Janis Braunfelds and Vjaceslavs Bobrovs
Photonics 2026, 13(2), 106; https://doi.org/10.3390/photonics13020106 - 23 Jan 2026
Viewed by 340
Abstract
The rapid evolution of smart transportation systems necessitates the integration of advanced sensing technologies capable of supporting the real-time, reliable, and cost-effective monitoring of road infrastructure. Fiber-optic sensor (FOS) technologies, given their high sensitivity, immunity to electromagnetic interference, and suitability for harsh environments, [...] Read more.
The rapid evolution of smart transportation systems necessitates the integration of advanced sensing technologies capable of supporting the real-time, reliable, and cost-effective monitoring of road infrastructure. Fiber-optic sensor (FOS) technologies, given their high sensitivity, immunity to electromagnetic interference, and suitability for harsh environments, have emerged as promising tools for enabling intelligent transportation infrastructure. This review critically examines the current landscape of classical mechanical and electrical sensor realization in monitoring solutions. Focus is also given to fiber-optic-sensor-based solutions for smart road applications, encompassing both well-established techniques such as Fiber Bragg Grating (FBG) sensors and distributed sensing systems, as well as emerging hybrid sensor networks. The article examines the most topical physical parameters that can be measured by FOSs in road infrastructure monitoring to support traffic monitoring, structural health assessment, weigh-in-motion (WIM) system development, pavement condition evaluation, and vehicle classification. In addition, strategies for FOS integration with digital twins, machine learning, artificial intelligence, quantum sensing, and Internet of Things (IoT) platforms are analyzed to highlight their potential for data-driven infrastructure management. Limitations related to deployment, scalability, long-term reliability, and standardization are also discussed. The review concludes by identifying key technological gaps and proposing future research directions to accelerate the adoption of FOS technologies in next-generation road transportation systems. Full article
(This article belongs to the Special Issue Advances in Optical Fiber Sensing Technology)
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37 pages, 2575 KB  
Review
A Review of High-Throughput Optical Sensors for Food Detection Based on Machine Learning
by Yuzhen Wang, Yuchen Yang and Huilin Liu
Foods 2026, 15(1), 133; https://doi.org/10.3390/foods15010133 - 2 Jan 2026
Viewed by 535
Abstract
As the global food industry expands and consumers demand higher food safety and quality standards, high-throughput detection technology utilizing digital intelligent optical sensors has emerged as a research hotspot in food testing due to its advantages of speed, precision, and non-destructive operation. Integrating [...] Read more.
As the global food industry expands and consumers demand higher food safety and quality standards, high-throughput detection technology utilizing digital intelligent optical sensors has emerged as a research hotspot in food testing due to its advantages of speed, precision, and non-destructive operation. Integrating cutting-edge achievements in optics, electronics, and computer science with machine learning algorithms, this technology efficiently processes massive datasets. This paper systematically summarizes the construction principles of intelligent optical sensors and their applications in food inspection. Sensors convert light signals into electrical signals using nanomaterials such as quantum dots, metal nanoparticles, and upconversion nanoparticles, and then employ machine learning algorithms including support vector machines, random forests, and convolutional neural networks for data analysis and model optimization. This enables efficient detection of target substances like pesticide residues, heavy metals, microorganisms, and food freshness. Furthermore, the integration of multiple detection mechanisms—including spectral analysis, fluorescence imaging, and hyperspectral imaging—has significantly broadened the sensors’ application scenarios. Looking ahead, optical sensors will evolve toward multifunctional integration, miniaturization, and intelligent operation. By leveraging cloud computing and IoT technologies, they will deliver innovative solutions for comprehensive monitoring of food quality and safety across the entire supply chain. Full article
(This article belongs to the Special Issue Advances in AI for the Quality Assessment of Agri-Food Products)
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20 pages, 1214 KB  
Article
Three-Basis Loop-Back QKD: A Passive Architecture for Secure and Scalable Quantum Mobile Networks
by Luis Adrián Lizama-Pérez and Patricia Morales-Calvo
Entropy 2025, 27(12), 1249; https://doi.org/10.3390/e27121249 - 11 Dec 2025
Viewed by 345
Abstract
The Loop-Back Quantum Key Distribution (LB-QKD) protocol establishes a bidirectional architecture in which a single photon travels forth and back through the same optical channel. Unlike conventional one-way schemes such as BB84, Alice performs both state preparation and measurement, while Bob acts as [...] Read more.
The Loop-Back Quantum Key Distribution (LB-QKD) protocol establishes a bidirectional architecture in which a single photon travels forth and back through the same optical channel. Unlike conventional one-way schemes such as BB84, Alice performs both state preparation and measurement, while Bob acts as a passive polarization modulator and reflector. This design eliminates detectors at Bob’s side, minimizes synchronization requirements, and enables compact, low-power implementations suitable for quantum-mobile and IoT platforms. An extended three-basis configuration {X,Y,Z} is introduced, preserving the simplicity of the two-basis scheme while improving noise tolerance through enhanced orthogonality-based filtering. Analytical modeling shows that the effective protocol error decreases from Eprotocol(2)=e/2 to Eprotocol(3)=e/3, achieving a 33% improvement in noise resilience. Despite its slightly lower sifting efficiency (η=1/6), the total information gain reaches G=0.26 bits per pulse, maintaining post-sifting throughput comparable to BB84. The protocol doubles the tolerable QBER of conventional QKD, sustaining secure operation up to 22% for two bases and approximately 47.58% for three bases. Its passive, self-verifying architecture enhances resistance to man-in-the-middle, photon-number-splitting, and side-channel attacks, providing a scalable and energy-efficient framework for secure key distribution and authentication in next-generation mobile and distributed quantum networks. Full article
(This article belongs to the Special Issue New Advances in Quantum Communications and Quantum Computing)
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41 pages, 2717 KB  
Review
Quantum Shannon Information Theory—Design of Communication, Ciphers, and Sensors
by Osamu Hirota
Entropy 2025, 27(11), 1158; https://doi.org/10.3390/e27111158 - 14 Nov 2025
Viewed by 997
Abstract
One of the key aspects of Shannon theory is that it provides guidance for designing the most efficient systems, such as minimizing errors and clarifying the limits of coding. This theory has seen great developments in the 50 years since 1948. It has [...] Read more.
One of the key aspects of Shannon theory is that it provides guidance for designing the most efficient systems, such as minimizing errors and clarifying the limits of coding. This theory has seen great developments in the 50 years since 1948. It has played a vital role in enabling the development of modern ultra-fast, stable, and highly dependable information and communication systems. Shannon theory is supported by statistical communication theories such as detection and estimation theory. The theory of communication systems that transmit Shannon information using quantum media is called quantum Shannon information theory, and research began in the 1960s. The theoretical formulation comparable to conventional Shannon theory has been completed. Its important role is to suggest that application of quantum effects will surpass existing communication performance. It would be meaningless if performance, efficiency, and utility were to deteriorate due to quantum effects, even if a certain new function is given. This paper suggests that there are various limitations to utilizing quantum Shannon information theory to benefit real-world communication systems and presents a theoretical framework for achieving the ultimate goal. Finally, we present the perfect secure cipher that overcomes the Shannon impossibility theorem without degrading communication performance and sensors as an example. Full article
(This article belongs to the Section Quantum Information)
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20 pages, 3160 KB  
Article
Machine Learning Framework for Multi-Endpoint Quantum Dot Toxicity Prediction with Organoid Validation and Drug Target Discovery
by Jiafu Yang, Dayu Hu, Pengcheng Xing, Yikai Zhang, Zongjian Ye, Kehan Liu, Jieyi Xia, Jing He, Yijing Qian and Tianshu Wu
Toxics 2025, 13(11), 967; https://doi.org/10.3390/toxics13110967 - 10 Nov 2025
Viewed by 1021
Abstract
Quantum dots (QDs) possess unique optical and electronic properties, enabling wide applications in biomedicine and optoelectronics, but their nanoscale size and surface chemistry could pose potential toxicity risks. This study established a systematic, multi-endpoint framework for QD toxicity assessment. Physicochemical properties of various [...] Read more.
Quantum dots (QDs) possess unique optical and electronic properties, enabling wide applications in biomedicine and optoelectronics, but their nanoscale size and surface chemistry could pose potential toxicity risks. This study established a systematic, multi-endpoint framework for QD toxicity assessment. Physicochemical properties of various QDs and their multiple toxicity endpoints, including cell death, inflammation, and oxidative stress, were collected to build machine learning models (RF, XGBoost, KNN, SVM). The predictive toxic effects were then validated based on the brain organoid. Shapley Additive exPlanations (SHAP) analysis revealed that exposure dose and particle size were key cross-model drivers, while zeta potential and optical properties differentially affected specific toxicity endpoints. Integration of GEO-derived differentially expressed genes with protein–protein interaction networks and molecular docking showed that the proteasome inhibitor Carfilzomib is an efficient interventive drug because of its strongest binding to core targets. In this study, the framework of prediction, validation and intervention effectively evaluated multi-endpoint QD toxicity and provided a systematic approach for safety assessments and strategy developments of nanomaterials. Full article
(This article belongs to the Section Human Toxicology and Epidemiology)
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12 pages, 2037 KB  
Article
Hydrogen-Bond Engineering for Highly Efficient Room-Temperature Phosphorescence with Tunable Multi-Color Emission
by Lin Ding, Zhaorun Tang, Jiyang Long, Xianwen Ke, Ruqian Peng, Ruyi Wei and Xinghai Liu
Spectrosc. J. 2025, 3(4), 28; https://doi.org/10.3390/spectroscj3040028 - 3 Nov 2025
Viewed by 484
Abstract
Achieving long-lived room-temperature phosphorescence (RTP) with high quantum efficiency is of significant interest for applications in anti-counterfeiting, flexible optoelectronic displays, and multi-level information encryption. Here, we presented a hydrogen-bond engineering strategy to enhance RTP performance by progressively increasing the number of hydrogen-bonding sites [...] Read more.
Achieving long-lived room-temperature phosphorescence (RTP) with high quantum efficiency is of significant interest for applications in anti-counterfeiting, flexible optoelectronic displays, and multi-level information encryption. Here, we presented a hydrogen-bond engineering strategy to enhance RTP performance by progressively increasing the number of hydrogen-bonding sites within a polyvinyl alcohol (PVA) matrix. A series of carbazole-based chromophores (Cz, ICz and 2ICz) were embedded into the PVA network, and their photophysical properties were systematically characterized using steady-state photoluminescence spectra, time-decay spectra, Fourier-transform infrared (FTIR), and Raman and X-ray photoelectron spectroscopy (XPS). Spectroscopic analysis revealed that the increased number of N-H groups significantly strengthened hydrogen-bonding interactions, effectively suppressing non-radiative decay pathways and stabilizing triplet excitons. As a result, the phosphorescence lifetime was prolonged up to 1.68 s with a quantum yield of 38.63%. Furthermore, leveraging the spectral overlap integral between the phosphorescent emission and dye absorption, efficient Förster resonance energy transfer (FRET) was realized, enabling tunable multi-color afterglow emissions. This study establishes a design strategy validated by spectroscopy for high-performance RTP materials and highlights their promising potential in advanced optical encryption and flexible photonic applications. Full article
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26 pages, 3689 KB  
Review
Optical Sensor Technologies for Enhanced Food Safety Monitoring: Advances in Detection of Chemical and Biological Contaminants
by Furong Fan, Zeyu Liao, Zhixiang He, Yaoyao Sun, Kuiguo Han and Yanqun Tong
Photonics 2025, 12(11), 1081; https://doi.org/10.3390/photonics12111081 - 1 Nov 2025
Viewed by 1203
Abstract
Optical sensing technologies are revolutionizing global food safety surveillance through exceptional sensitivity, rapid response, and high portability. This review systematically evaluates five major platforms, revealing unprecedented detection capabilities from sub-picomolar to single-cell resolution. Surface plasmon resonance achieves 0.021 ng/mL detection [...] Read more.
Optical sensing technologies are revolutionizing global food safety surveillance through exceptional sensitivity, rapid response, and high portability. This review systematically evaluates five major platforms, revealing unprecedented detection capabilities from sub-picomolar to single-cell resolution. Surface plasmon resonance achieves 0.021 ng/mL detection limits for veterinary drugs with superior molecular recognition. Quantum dot fluorescence sensors reach 0.17 nM sensitivity for pesticides, enabling rapid on-site screening. Surface-enhanced Raman scattering attains 0.2 pM sensitivity for heavy metals, ideal for trace contaminants. Laser-induced breakdown spectroscopy delivers multi-elemental analysis within seconds at 0.0011 mg/L detection limits. Colorimetric assays provide cost-effective preliminary screening in resource-limited settings. We propose a stratified detection framework that strategically allocates differentiated sensing technologies across food supply chain nodes, addressing heterogeneous demands while eliminating resource inefficiencies from deploying high-precision instruments for routine screening. Integration of microfluidics, artificial intelligence, and mobile platforms accelerates evolution toward multimodal fusion and decentralized deployment. Despite advances, critical challenges persist: matrix interference, environmental robustness, and standardized protocols. Future breakthroughs require interdisciplinary innovation in materials science, intelligent data processing, and system integration, transforming laboratory prototypes into intelligent early warning networks spanning the entire food supply chain. Full article
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14 pages, 2316 KB  
Article
Enhanced Performance of TiO2 Composites for Solar Cells and Photocatalytic Hydrogen Production
by Xue Bai, Jian Chen, Shengxi Du and Yan Xiong
Nanoenergy Adv. 2025, 5(4), 14; https://doi.org/10.3390/nanoenergyadv5040014 - 28 Oct 2025
Viewed by 681
Abstract
Titanium dioxide (TiO2) is widely used in solar cells and photocatalysts, given its excellent photoactivity, low cost, and high structural, electronic, and optical stability. Here, a novel TiO2 composite was prepared by coating TiO2 inverse opal (IO) with TiO [...] Read more.
Titanium dioxide (TiO2) is widely used in solar cells and photocatalysts, given its excellent photoactivity, low cost, and high structural, electronic, and optical stability. Here, a novel TiO2 composite was prepared by coating TiO2 inverse opal (IO) with TiO2 nanorods (NRs). With a porous three-dimensional network structure, the composite exhibited higher light absorption; enhanced the separation of the electron–hole pairs; deepened the infiltration of the electrolyte; better transported and collected charge carriers; and greatly improved the power conversion efficiency (PCE) of the quantum-dot sensitized solar cells (QDSSCs) based on it, while also boosting its own photocatalytic hydrogen generation efficiency. A very high PCE of 12.24% was achieved by QDSSCs utilizing CdS/CdSe sensitizer. Furthermore, the TiO2 composite exhibited high photocatalytic activity with a H2 release rate of 1080.2 μ mol h−1 g−1, several times that of bare TiO2 IO or TiO2 NRs. Full article
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16 pages, 1183 KB  
Article
Quantum Computing for Transport Network Optimization
by Jiangwei Ju, Zhihang Liu, Yuelin Bai, Yong Wang, Qi Gao, Yin Ma, Chao Zheng and Kai Wen
Entropy 2025, 27(9), 953; https://doi.org/10.3390/e27090953 - 13 Sep 2025
Viewed by 1789
Abstract
Public transport systems play a crucial role in the development of large cities. Bus network design to optimize passenger flow coverage in a global metropolis is a challenging task. As an essential part of bus travel planning, considering the bus transfer factor in [...] Read more.
Public transport systems play a crucial role in the development of large cities. Bus network design to optimize passenger flow coverage in a global metropolis is a challenging task. As an essential part of bus travel planning, considering the bus transfer factor in the existing extremely complex and extensive public bus network usually leads to a optimization problem characterized by high-dimensionality and non-linearity. While classical computers struggle to deal with this kind of problems, quantum computers shed new light into this field. The coherent Ising machine (CIM), a specialized optical quantum computer using a photonic dissipative architecture, has shown its remarkable computational power in combinatorial optimization problems. We construct the classical model and the quadratic unconstrained binary optimization (QUBO) model of the bus route optimization problem, and solve it using a classical computer and CIM, respectively. Our experimental results demonstrate the significant acceleration capability of CIM over classical computers in finding the optimal or near-optimal solutions, albeit subject to the hardware limitations of the 100-qubit CIM. Full article
(This article belongs to the Special Issue Quantum Information: Working Towards Applications)
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37 pages, 1013 KB  
Article
Quantum–Classical Optimization for Efficient Genomic Data Transmission
by Ismael Soto, Verónica García and Pablo Palacios Játiva
Mathematics 2025, 13(17), 2792; https://doi.org/10.3390/math13172792 - 30 Aug 2025
Viewed by 976
Abstract
This paper presents a hybrid computational architecture for efficient and robust digital transmission inspired by helical genetic structures. The proposed system integrates advanced modulation schemes, such as multi-pulse-position modulation (MPPM), high-order quadrature amplitude modulation (QAM), and chirp spread spectrum (CSS), along with Reed–Solomon [...] Read more.
This paper presents a hybrid computational architecture for efficient and robust digital transmission inspired by helical genetic structures. The proposed system integrates advanced modulation schemes, such as multi-pulse-position modulation (MPPM), high-order quadrature amplitude modulation (QAM), and chirp spread spectrum (CSS), along with Reed–Solomon error correction and quantum-assisted search, to optimize performance in noisy and non-line-of-sight (NLOS) optical environments, including VLC channels modeled with log-normal fading. Through mathematical modeling and simulation, we demonstrate that the number of helical transmissions required for genome-scale data can be drastically reduced—up to 95% when using parallel strands and high-order modulation. The trade-off between redundancy, spectral efficiency, and error resilience is quantified across several configurations. Furthermore, we compare classical genetic algorithms and Grover’s quantum search algorithm, highlighting the potential of quantum computing in accelerating decision-making and data encoding. These results contribute to the field of operations research and supply chain communication by offering a scalable, energy-efficient framework for data transmission in distributed systems, such as logistics networks, smart sensing platforms, and industrial monitoring systems. The proposed architecture aligns with the goals of advanced computational modeling and optimization in engineering and operations management. Full article
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12 pages, 4710 KB  
Article
Generation of Higher-Order Hermite–Gaussian Modes Based on Physical Model and Deep Learning
by Tai Chen, Chengcai Jiang, Jia Tao, Long Ma and Longzhou Cao
Photonics 2025, 12(8), 801; https://doi.org/10.3390/photonics12080801 - 10 Aug 2025
Viewed by 1874
Abstract
The higher-order Hermite–Gaussian (HG) modes exhibit complex spatial distributions and find a wide range of applications in fields such as quantum information processing, optical communications, and precision measurements. In recent years, the advancement of deep learning has emerged as an effective approach for [...] Read more.
The higher-order Hermite–Gaussian (HG) modes exhibit complex spatial distributions and find a wide range of applications in fields such as quantum information processing, optical communications, and precision measurements. In recent years, the advancement of deep learning has emerged as an effective approach for generating higher-order HG modes. However, the traditional data-driven deep learning method necessitates a substantial amount of labeled data for training, entails a lengthy data acquisition process, and imposes stringent requirements on system stability. In practical applications, these methods are confronted with challenges such as the high cost of data labeling. This paper proposes a method that integrates a physical model with deep learning. By utilizing only a single intensity distribution of the target optical field and incorporating the physical model, the training of the neural network can be accomplished, thereby eliminating the dependency of traditional data-driven deep learning methods on large datasets. Experimental results demonstrate that, compared with the traditional data-driven deep learning method, the method proposed in this paper yields a smaller root mean squared error between the generated higher-order HG modes. The quality of the generated modes is higher, while the training time of the neural network is shorter, indicating greater efficiency. By incorporating the physical model into deep learning, this approach overcomes the limitations of traditional deep learning methods, offering a novel solution for applying deep learning in light field manipulation, quantum physics, and other related fields. Full article
(This article belongs to the Section Data-Science Based Techniques in Photonics)
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8 pages, 4923 KB  
Proceeding Paper
A Hardware Measurement Platform for Quantum Current Sensors
by Frederik Hoffmann, Ann-Sophie Bülter, Ludwig Horsthemke, Dennis Stiegekötter, Jens Pogorzelski, Markus Gregor and Peter Glösekötter
Eng. Proc. 2025, 101(1), 11; https://doi.org/10.3390/engproc2025101011 - 4 Aug 2025
Viewed by 1033
Abstract
A concept towards current measurement in low and medium voltage power distribution networks is presented. The concentric magnetic field around the current-carrying conductor should be measured using a nitrogen-vacancy quantum magnetic field sensor. A bottleneck in current measurement systems is the readout electronics, [...] Read more.
A concept towards current measurement in low and medium voltage power distribution networks is presented. The concentric magnetic field around the current-carrying conductor should be measured using a nitrogen-vacancy quantum magnetic field sensor. A bottleneck in current measurement systems is the readout electronics, which are usually based on optically detected magnetic resonance (ODMR). The idea is to have a hardware that tracks up to four resonances simultaneously for the detection of the three-axis magnetic field components and the temperature. Normally, expensive scientific instruments are used for the measurement setup. In this work, we present an electronic device that is based on a Zynq 7010 FPGA (Red Pitaya) with an add-on board, which has been developed to control the excitation laser, the generation of the microwaves, and interfacing the photodiode, and which provides additional fast digital outputs. The T1 measurement was chosen to demonstrate the ability to read out the spin of the system. Full article
(This article belongs to the Proceedings of The 11th International Conference on Time Series and Forecasting)
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14 pages, 1081 KB  
Article
Optical Frequency Comb-Based Continuous-Variable Quantum Secret Sharing Scheme
by Runsheng Peng, Yijun Wang, Hang Zhang, Yun Mao and Ying Guo
Mathematics 2025, 13(15), 2455; https://doi.org/10.3390/math13152455 - 30 Jul 2025
Viewed by 957
Abstract
Quantum secret sharing (QSS) faces inherent limitations in scaling to multi-user networks due to excess noise introduced by highly asymmetric beam splitters (HABSs) in chain-structured topologies. To overcome this challenge, we propose an optical frequency comb-based continuous-variable QSS (OFC CV-QSS) scheme that establishes [...] Read more.
Quantum secret sharing (QSS) faces inherent limitations in scaling to multi-user networks due to excess noise introduced by highly asymmetric beam splitters (HABSs) in chain-structured topologies. To overcome this challenge, we propose an optical frequency comb-based continuous-variable QSS (OFC CV-QSS) scheme that establishes parallel frequency channels between users and the dealer via OFC-generated multi-wavelength carriers. By replacing the chain-structured links with dedicated frequency channels and integrating the Chinese remainder theorem (CRT) with a decentralized architecture, our design eliminates excess noise from all users using HABS while providing mathematical- and physical-layer security. Simulation results demonstrate that the scheme achieves a more than 50% improvement in maximum transmission distance compared to chain-based QSS, with significantly slower performance degradation as users scale to 20. Numerical simulations confirm the feasibility of this theoretical framework for multi-user quantum networks, offering dual-layer confidentiality without compromising key rates. Full article
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20 pages, 4322 KB  
Article
The 1D Hybrid Material Allylimidazolium Iodoantimonate: A Combined Experimental and Theoretical Study
by Hela Ferjani, Rim Bechaieb, Diego M. Gil and Axel Klein
Inorganics 2025, 13(7), 243; https://doi.org/10.3390/inorganics13070243 - 15 Jul 2025
Cited by 1 | Viewed by 1282
Abstract
The one-dimensional (1D) Sb(III)-based organic–inorganic hybrid perovskite (AImd)21[SbI5] (AImd = 1-allylimidazolium) crystallizes in the orthorhombic, centrosymmetric space group Pnma. The structure consists of corner-sharing [SbI6] octahedra forming 1D chains separated by allylimidazolium cations. Void [...] Read more.
The one-dimensional (1D) Sb(III)-based organic–inorganic hybrid perovskite (AImd)21[SbI5] (AImd = 1-allylimidazolium) crystallizes in the orthorhombic, centrosymmetric space group Pnma. The structure consists of corner-sharing [SbI6] octahedra forming 1D chains separated by allylimidazolium cations. Void analysis through Mercury CSD software confirmed a densely packed lattice with a calculated void volume of 1.1%. Integrated quantum theory of atoms in molecules (QTAIM) and non-covalent interactions index (NCI) analyses showed that C–H···I interactions between the cations and the 1[SbI5]2− network predominantly stabilize the supramolecular assembly followed by N–H···I hydrogen bonds. The calculated growth morphology (GM) model fits very well to the experimental morphology. UV–Vis diffuse reflectance spectroscopy allowed us to determine the optical band gap to 3.15 eV. Density functional theory (DFT) calculations employing the B3LYP, CAM-B3LYP, and PBE0 functionals were benchmarked against experimental data. CAM-B3LYP best reproduced Sb–I bond lengths, while PBE0 more accurately captured the HOMO–LUMO gap and the associated electronic descriptors. These results support the assignment of an inorganic-to-organic [Sb–I] → π* charge-transfer excitation, and clarify how structural dimensionality and cation identity shape the material’s optoelectronic properties. Full article
(This article belongs to the Section Inorganic Materials)
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