Search Results (2,519)

UNS S41003 is a low-cost, low-carbon ferritic stainless steel that exhibits moderate corrosion resistance but limited mechanical performance. This study evaluates the electrochemical behavior of untreated and thermomechanically treated UNS S41003 samples. Corrosion tests were conducted in acidic electrolytes with varying pH to simulate aggressive environments relevant to industrial and structural applications where exposure to acidic media and corrosive pollutants occurs. Potentiodynamic polarization curves for all samples displayed passive regions typically associated with protective oxide film formation; however, localized pitting corrosion was detected post-test. Electrochemical impedance spectroscopy indicated a marked decrease in corrosion resistance as pH decreased. The corrosion resistance of the treated alloy remained comparable to that of the untreated condition, indicating that thermomechanical processing did not detrimentally affect passivity or corrosion performance under the tested conditions. The literature suggests that the applied treatment enhances mechanical properties, supporting the potential use of this alloy in structural components subjected to acidic environments requiring a balance of mechanical strength and corrosion resistance. Full article

Extreme precipitation events severely impact agriculture, reducing yields and land use efficiency. The spatiotemporal distribution of Total Column Water Vapor (TCWV), the primary gaseous form of water, directly influences sustainable agricultural management. This study, through multi-source data fusion, employs methods including the Mann–Kendall test, sliding change-point detection, wavelet transform, pixel-scale trend estimation, and linear regression to analyze the spatiotemporal dynamics of global TCWV from 1959 to 2023 and its impacts on agricultural systems, surpassing the limitations of single-method approaches. Results reveal a global TCWV increase of 0.0168 kg/m²/year from 1959–2023, with a pivotal shift in 2002 amplifying changes, notably in tropical regions (e.g., Amazon, Congo Basins, Southeast Asia) where cumulative increases exceeded 2 kg/m² since 2000, while mid-to-high latitudes remained stable and polar regions showed minimal content. These dynamics escalate weather risks, impacting sustainable agricultural management with irrigation and crop adaptation. To enhance prediction accuracy, we propose a novel hybrid model combining wavelet transform with LSTM, TCN, and GRU deep learning models, substantially improving multidimensional feature extraction and nonstationary trend capture. Comparative analysis shows that WT-TCN performs the best (MAE = 0.170, R² = 0.953), demonstrating its potential for addressing climate change uncertainties. These findings provide valuable applications for precision agriculture, sustainable water resource management, and disaster early warning. Full article

A just and sustainable energy transition in historically coal-dependent regions like Kentucky requires more than the adoption of new technologies and market-based solutions. This study uses a stated preferences approach to evaluate public support for various attributes of energy transition programs, revealing broad backing for moving away from coal, as indicated by a negative willingness to pay (WTP) for the status quo (–USD 4.63). Key findings show strong bipartisan support for solar energy, with Democrats showing the highest WTP at USD 8.29, followed closely by Independents/Others at USD 8.22, and Republicans at USD 8.08. Wind energy also garnered support, particularly among Republicans (USD 4.04), who may view it as more industry-compatible and less ideologically polarizing. Job creation was a dominant priority across political affiliations, especially for Independents (USD 9.07), indicating a preference for tangible, near-term economic benefits. Similarly, preserving cultural values tied to coal received support among Independents/Others (USD 4.98), emphasizing the importance of place-based identity in shaping preferences. In contrast, social support programs (e.g., job retraining) and certain post-mining land uses (e.g., recreation and conservation) were less favored, possibly due to their abstract nature, delayed benefits, and political framing. Findings from Kentucky offer insights for other coal-reliant states like Wyoming, West Virginia, Pennsylvania, Indiana, and Illinois. Ultimately, equitable transitions must integrate local voices, address cultural and economic realities, and ensure community-driven planning and investment. Full article

This study investigates the subsurface rooting of the Merija anticline in the Missour Basin, Morocco, with a focus on copper mineralization exploration. A sequential geophysical workflow was implemented, combining gravity surveys, electrical resistivity (ER), and induced polarization (IP) methods. The gravity data, acquired along spaced profiles extending from outcropping areas to Quaternary-covered zones, clearly delineated the structural continuity of the anticline beneath the cover. The application of trend filtering in covered areas allowed the removal of regional effects, successfully isolating residual anomalies associated with the buried continuation of the anticline. Interpolated Bouguer anomaly maps highlighted a major regional fault, interpreted as controlling the deep rooting of the anticline. A resistivity profile was then deployed perpendicular to this fault, providing detailed imaging of the anticline’s geometry and lithological contrasts. Complementary IP profiles conducted near the mine site targeted the detection of chargeability anomalies associated with copper mineralization dominated by malachite, confirming the electrical signature of copper mineralization, particularly within the sandstone and conglomerate formations of the Lower Cretaceous. To validate the geophysical interpretations, a drilling campaign was conducted, which confirmed the presence of the identified lithological units and the anticline rooting, as revealed by geophysical data. This approach provides a robust framework for copper exploration in the Merija area and can be adapted to similar geological contexts elsewhere. Full article

Improving the ecological resilience in the Yellow River Basin is a crucial way to achieve ecological conservation and high-quality development in the region. Based on the panel data from 2011 to 2023 of 57 cities in the Yellow River Basin, the ecological resilience of each city was measured by using the Catastrophe Progression Model, and its spatial differences and dynamic evolution characteristics were analyzed by the Dagum Gini coefficient and kernel density estimation. At the same time, the STIRPAT model was integrated with the random forest model to identify the key factors influencing urban ecological resilience. The results demonstrated the following: (1) The urban ecological resilience in the Yellow River Basin exhibited a slight upward trend during 2011–2020 and presented a gradient spatial pattern with “high in the east and low in the west”. (2) Hypervariation density is the main source of spatial difference in urban ecological resilience, with trailing and polarization phenomena across the entire basin and its three major subregions. (3) There was significant regional heterogeneity of influences in the urban ecological resilience, with upstream, midstream, and downstream regions characterized by low interference intensity, high sensitivity, and strong adaptability, respectively. Full article

Background/Objectives: In recent years, lipids have emerged as critical regulators of different disease processes, being involved in cancer pathogenesis, progression, and outcome. Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry Imaging (MALDI-MSI) has significantly expanded the technology’s reach, enabling spatially resolved profiling of lipids directly from tissue, including formalin-fixed paraffin-embedded (FFPE) specimens. In this context, MALDI matrix selection is crucial for lipid extraction and ionization, influencing key aspects such as molecular coverage and sensitivity, especially in such specimens with already depleted lipid content. Thus, in this work, we aim to explore the feasibility of mapping lipid species in FFPE clinical samples with MALDI-MSI using 6-aza-2-thiothymine (ATT) as a matrix of choice. Methods: To do so, ATT performances were first compared to those two other matrices commonly used for lipidomic analyses, 2′,5′-dihydroxybenzoic acid (DHB) and Norharmane (NOR), on lipid standards. Results: As a proof-of-concept, we then assessed ATT’s performance for the MALDI-MSI analysis of lipids in FFPE brain sections, both in positive and negative ion modes, comparing results with those obtained from other commonly used dual-polarity matrices. In this context, ATT enabled the putative annotation of 98 lipids while maintaining a well-balanced detection of glycerophospholipids (60.2%) and sphingolipids (32.7%) in positive ion mode. It outperformed both DHB and NOR in the identification of glycolipids (3%) and fatty acids (4%). Additionally, ATT exceeded DHB in terms of total lipid count (62 vs. 21) and class diversity and demonstrated performance comparable to NOR in negative ion mode. Moreover, ATT was applied to a FFPE glioblastoma tissue microarray (TMA) evaluating the ability of this matrix to reveal biologically relevant lipid features capable of distinguishing normal brain tissue from glioblastoma regions. Conclusions: Altogether, the results presented in this work suggest that ATT is a suitable matrix for pathology imaging applications, even at higher lateral resolutions of 20 μm, not only for proteomic but also for lipidomic analysis. This could enable the use of the same matrix type for the analysis of both lipids and peptides on the same tissue section, offering a unique strategic advantage for multi-omics studies, while also supporting acquisition in both positive and negative ionization modes. Full article

To address the significant degradation of image visibility and contrast in turbid media, this paper proposes an enhanced image dehazing algorithm. Unlike traditional polarimetric dehazing methods that exclusively attribute polarization information to airlight, our approach integrates object radiance polarization and airlight polarization for haze removal. First, sky regions are localized through multi-scale fusion of polarization and intensity segmentation maps. Second, region-specific transmittance estimation is performed by differentiating haze-occluded regions from haze-free regions. Finally, target radiance is solved using boundary constraints derived from non-haze regions. Compared with other dehazing algorithms, the method proposed in this paper demonstrates greater adaptability across diverse scenarios. It achieves higher-quality restoration of targets with results that more closely resemble natural appearances, avoiding noticeable distortion. Not only does it deliver excellent dehazing performance for land fog scenes, but it also effectively handles maritime fog environments. Full article

Sea ice parameters are crucial for polar ship design. During China’s 39th Antarctic Scientific Expedition, ice condition from the entire navigation process of the research vessel Xuelong 2 was recorded using shipborne cameras. To obtain sea ice parameters, two deep learning models, Ice-Deeplab and U-Net, were employed to automatically obtain sea ice concentration (SIC) and sea ice thickness (SIT), providing high-frequency data at 5-min intervals. During the observation period, ice navigation accounted for 32 days, constituting less than 20% of the total 163 voyage days. Notably, 63% of the navigation was in ice fields with less than 10% concentration, while only 18.9% occurred in packed ice (concentration > 90%) or level ice regions. SIT ranges from 100 cm to 234 cm and follows a normal distribution. The results demonstrate that, to achieve enhanced navigation efficiency and fulfill expedition objectives, the research vessel substantially reduced duration in high-concentration ice areas. Additionally, the results of SIC extracted from shipborne camera images were compared with the data from the Copernicus Marine Environment Monitoring Service (CMEMS) satellite remote sensing. In summary, the sea ice parameter data obtained from shipborne camera images offer high spatial and temporal resolution, making them more suitable for engineering applications in establishing sea ice environmental parameters. Full article

In this study, we propose a bidirectional chemical sensor platform based on a reconfigurable ion-sensitive field-effect transistor (R-ISFET) architecture. The device incorporates Ni-silicide Schottky barrier source/drain (S/D) contacts, enabling ambipolar conduction and bidirectional turn-on behavior for both p-type and n-type configurations. Channel polarity is dynamically controlled via the program gate (PG), while the control gate (CG) suppresses leakage current, enhancing operational stability and energy efficiency. A dual-control-gate (DCG) structure enhances capacitive coupling, enabling sensitivity beyond the Nernst limit without external amplification. The extended-gate (EG) architecture physically separates the transistor and sensing regions, improving durability and long-term reliability. Electrical characteristics were evaluated through transfer and output curves, and carrier transport mechanisms were analyzed using band diagrams. Sensor performance—including sensitivity, hysteresis, and drift—was assessed under various pH conditions and external noise up to 5 V_pp (i.e., peak-to-peak voltage). The n-type configuration exhibited high mobility and fast response, while the p-type configuration demonstrated excellent noise immunity and low drift. Both modes showed consistent sensitivity trends, confirming the feasibility of complementary sensing. These results indicate that the proposed R-ISFET sensor enables selective mode switching for high sensitivity and robust operation, offering strong potential for next-generation biosensing and chemical detection. Full article

The siphon effect between airports has amplified the polarization in passenger throughput, undermining the balanced development and sustainability of airport clusters. The airport siphon effect occurs when one airport attracts a disproportionate share of passengers, concentrating traffic at the expense of others, which affects the overall resilience of the entire airport cluster. To address this issue, this study proposes a siphon index, expands the range of ground transportation options for passengers, and establishes a zero-siphon model to assess the impact of siphoning on the resiliency of airport clusters. Using this framework, four major airport clusters in China were selected as research subjects, with regional aviation accessibility serving as a measure of resilience. The results showed that among the four airport clusters, the siphon effect is most pronounced in the Guangzhou region. To explore the implications of this effect further, three airport disruption scenarios were simulated to assess the resilience of the Pearl River Delta airport cluster. The results indicated that the intensity and timing of disruptive events significantly affect airport cluster resilience, with hub airports being particularly sensitive. This study analyzes the risks associated with excessive route concentration, providing policymakers with critical insights to enhance the sustainability, equity, and resilience of airport clusters. The proposed strategies facilitate coordinated infrastructure development, optimized air–ground intermodal connectivity, and risk mitigation. These measures contribute to building more sustainable and adaptive aviation networks in rapidly urbanizing regions. Full article

The equivalent source method (ESM) is a core algorithm in integrated radiation-propagation acoustic field modeling. However, in challenging marine environments, including deep-sea and polar regions, where sound speed profiles exhibit strong vertical gradients, the ESM must increase waveguide stratification to maintain accuracy. This causes computational costs to scale exponentially with the number of layers, compromising efficiency and limiting applicability. To address this, this paper proposes a modal equivalent source (MES) model employing normal modes as basis functions instead of free-field Green’s functions. This model constructs a set of normal mode bases using full-depth hydroacoustic parameters, incorporating water column characteristics into the basis functions to eliminate waveguide stratification. This significantly reduces the computational matrix size of the ESM and computes acoustic fields in range-dependent waveguides using a single set of normal modes, resolving the dual limitations of inadequate precision and low efficiency in such environments. Concurrently, for the construction of basis functions, this paper also proposes a fast computation method for eigenvalues and eigenmodes in waveguide contexts based on phase functions and difference equations. Furthermore, coupling the MES method with the Finite Element Method (FEM) enables integrated computation of underwater target radiation and propagation fields. Multiple simulations demonstrate close agreement between the proposed model and reference results (errors < 4 dB). Under equivalent accuracy requirements, the proposed model reduces computation time to less than 1/25 of traditional ESM, achieving significant efficiency gains. Additionally, sea trial verification confirms model effectiveness, with mean correlation coefficients exceeding 0.9 and mean errors below 5 dB against experimental data. Full article

Considering the high plasticity of FoxP3⁺ regulatory T (Treg) cells and Interleukin (IL)-17-producing Th17 cells, we hypothesized that a Th17 inflammatory milieu may impair the functional properties of Treg cells in chronic inflammatory arthritides. Therefore, a cross-sectional explorative analysis was set up in patients with psoriatic arthritis (PsoA), rheumatoid arthritis, or spondyloarthritis to investigate the features of Th17 and Treg cells. T cell subpopulation counts, FOXP3 mRNA expression, CpG methylation of the FOXP3 gene, and the suppressive capacity of isolated Treg cells were determined. Ex vivo analysis of PsoA-derived peripheral blood lymphocytes showed a Th17-mediated inflammation. It was accompanied by demethylation of the FOXP3 promotor and Treg-specific demethylated region (TSDR) in Treg cells which, however, resulted neither in elevated FOXP3 mRNA expression nor in increased suppressive Treg cell capacity. To clarify this conundrum, in vitro stimulation of isolated Treg cells with Th17-inducing cytokines (IL-1β, IL-6, IL-23, TGFβ), recombinant IL-17, or the anti-IL-17A antibody secukinumab was performed, demonstrating that cell culture conditions polarizing towards Th17, but not IL-17 itself, impair the suppressive function of Treg cells, accompanied by diminished FOXP3 mRNA expression due to hypermethylation of the FOXP3 promotor and TSDR. This potential causal relationship between Th17 inflammation and impaired Treg cell function requires attention regarding the development of immunomodulatory therapies. Full article

This study systematically investigated the corrosion evolution and protective mechanisms of X80 pipeline steel in Xinjiang’s saline soil environments under freeze–thaw cycling conditions. Combining regional soil characterization with laboratory-constructed corrosion systems, we employed electrochemical impedance spectroscopy, potentiodynamic polarization, and surface analytical techniques to quantify temporal–spatial corrosion behavior across 30 freeze–thaw cycles. Experimental results revealed a distinctive corrosion resistance pattern: initial improvement (cycles 1–10) attributed to protective oxide layer formation, followed by accelerated degradation (cycles 10–30) due to microcrack propagation and chloride accumulation. Synchrotron X-ray diffraction analyses identified sulfate–chloride ion synergism as the primary driver of localized corrosion disparities in heterogeneous soil matrices. A comparative evaluation of asphalt-coated specimens demonstrated a 62%–89% corrosion rate reduction, with effectiveness directly correlating with coating integrity and thickness (200–500 μm range). Molecular dynamics simulations using Materials Studio revealed atomic-scale ion transport dynamics at coating–substrate interfaces, showing preferential Cl⁻ permeation through coating defects. These multiscale findings establish quantitative relationships between environmental stressors, coating parameters, and corrosion kinetics, providing a mechanistic framework for optimizing protective coatings in cold-region pipeline applications. Full article

The planktonic pteropod Limacina helicina is increasingly studied as a bioindicator of climate-driven changes in polar marine ecosystems. Although broadly distributed across the Arctic Basin and the North Pacific, its population structure and dispersal pathways remain poorly understood, especially in the Siberian Arctic. We analyzed mitochondrial COI sequences from populations sampled in the Barents, Kara, Laptev, East Siberian, and White Seas, as well as adjacent Pacific regions. Three major haplogroups (H1, H2, H3) were identified with distinct spatial patterns. H1 is widespread, occurring across the Pacific and most Arctic seas except the White Sea. H2 is confined to the western Arctic shelves (Barents–Kara–Laptev), and H3 is unique to the White Sea. We found a pronounced genetic discontinuity corresponding to hydrographic barriers, particularly the strong freshwater inflow from the Lena River, which restricts eastward dispersal of H2 from the Laptev to the East Siberian Sea. These patterns suggest postglacial expansions from geographically separated populations that survived the Last Glacial Maximum in isolated marine regions. The White Sea population is highly isolated and genetically distinct. Our results highlight how both glacial history and modern oceanography shape Arctic plankton diversity and define biogeographic boundaries in a rapidly changing climate. Full article

The charge structure and lightning activities during the development stage of a thunderstorm with a hail-falling process in Datong County of Qinghai Province on 16 August 2014 were studied by using a multi-station observation network composed of a very-high-frequency, three-dimensional, lightning-radiation-source location system and broadband electric field. The research results show that two discharge regions appeared during the development stage of the thunderstorm. The charge structure was all a negative dipolar polarity in two discharge regions; however, the heights of the charge regions were different. The positive-charge region at a height of 2–3.5 km corresponds to −1–−10 °C and the negative-charge region at a height of 3.5–5 km corresponds to −11–−21 °C in one discharge region; the positive-charge region at a height of 4–5 km corresponds to −15–−21 °C and the negative-charge region at a height of 5–6 km corresponds to −21–−29 °C in another region. The charge regions with the same polarity at different heights in the two discharge regions gradually connected with the occurrence of the hail-falling process during the development stage of the thunderstorm, and the overall height of the charge regions decreased. All the intracloud lightning flashes that occurred in the thunderstorm were of inverted polarity discharge, and the horizontal transmission distance of the discharge channel was short, all within 10 km. The negative intracloud lightning flash, negative cloud-to-ground lightning flash, and positive cloud-to-ground lightning flash generated during the thunderstorm process accounted for 83%, 16%, and 1% of the total number of lightning flashes, respectively. Negative cloud-to-ground lightning flashes mainly occurred more frequently in the early phase of the thunderstorm development stage. As the thunderstorm developed, the frequency of intracloud lightning flashes became greater than that of negative cloud-to-ground lightning flashes, and finally far exceeded it. The frequency of lightning flashes decreases sharply and the intensity of thunderstorms decreases during the hail-falling period. Full article