Search Results (15)

Quorum quenching (QQ) is a promising biological approach that has the potential to control membrane biofouling. However, the implementation of the QQ membrane bioreactor still requires a more systematic and comprehensive understanding, including the selection of membrane materials, the determination of the optimal QQ bacterial dosage, and the use of appropriate media for the immobilization of QQ bacteria, all of which are important to ensure long-term operation. The present study investigated the impact of QQ bacteria on biofilm formation across different polymeric membranes. These include flat sheet membranes, Polytetrafluoroethylene (PTFE), Polysulfones (PSs), and hollow-fibre polyvinylidene difluoride (PVDF) membranes. It also evaluated biofilm development, membrane filtration performance, extracellular polymeric substance (EPS) production, and sludge floc properties, which were characterized using fluorescence microscopy. The results revealed that QQ intervention markedly suppressed quorum sensing (QS), leading to a pronounced, dose-dependent reduction in biofilm thickness, membrane fouling, EPS production and sludge floc size. Biofilm thickness was reduced by 63.5% on PTFE and 55.4% on PS membranes, accompanied by a notable reduction in EPS protein and polysaccharides, thereby weakening the biofilm formation and enhancing membrane filterability. Therefore, the permeability performance of the PVDF membrane improved by 338.2%. Furthermore, sludge settleability was enhanced, and floc size was reduced, resulting in the mitigation of biofilm formation without impacting pollutant degradation. These findings elucidate the material-dependent and dose-responsive mechanism by which QQ regulates EPS synthesis and biofilm formation in MBR. Full article

This research aims to fabricate hydrophobic electrospun air filters with ultra-high performance against virions. In order to achieve this goal, constant basis weight electrospun poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) with low-bead, high-bead, and ultra-high-bead fibre structures were used to fabricate single and multilayer filters by controlling the Dimethylformamide (DMF)-to-acetone ratio of the solvent. The water contact angle of the fabricated layers ranged from 131° for low-bead structures to 135° for ultra-high-bead structures, indicating their overall high hydrophobicity. The size-resolved filtering efficiency and pressure drop tests on the fabricated filters showed that low-bead structure for both single and multilayer filters and high-bead structure for single-layer filters enhance the quality factor remarkably. The results showed that the single-layer ultra-high-bead structure air filters had a filtering efficiency of 99.33%, superior to N95 air filters (96.54%) and comparable to double N95 filters (99.86%). However, the electrospun air filter showed a pressure drop of 169.3 Pa and a quality factor of $27.6\times {10}^{-3} {\mathrm{P}\mathrm{a}}^{-1}$compared to a pressure drop of 388 Pa and quality factor of $16.9\times {10}^{-3} {\mathrm{P}\mathrm{a}}^{-1}$ for double N95 air filters. Therefore, it has a high potential to be used as the filtration media in hospitals, long-term care centers, and masks to provide superior protection against virions for healthcare providers and patients. Full article

Acoustic emission (AE) has received increased interest as a structural health monitoring (SHM) technique for various materials, including laminated polymer composites. Piezoelectric sensors, including PZT (piezoelectric ceramic) and PVDF (piezoelectric polymer), can monitor AE in materials. The thickness of the piezoelectric sensors (as low as 28 µm—PVDF) allows embedding the sensors within the laminated composite, creating a smart material. Incorporating piezoelectric sensors within composites has several benefits but presents numerous difficulties and challenges. This paper provides an overview of acoustic emission testing, concluding with a discussion on embedding piezoelectric AE sensors within fibre-polymer composites. Various aspects are covered, including the underlying AE principles in fibre-based composites, factors that influence the reliability and accuracy of AE measurements, methods to artificially induce acoustic emission, and the correlation between AE events and damage in polymer composites. Full article

Pollutants and infectious diseases can spread through air with airborne droplets and aerosols. A respiratory mask can decrease the amount of pollutants we inhale and it can protect us from airborne diseases. With the onset of the COVID-19 pandemic, masks became an everyday item used by a lot of people around the world. As most of them are for a single use, the amount of non-recyclable waste increased dramatically. The plastic from which the masks are made pollutes the environment with various chemicals and microplastic. Here, we investigated the time- and size-dependent filtration efficiency (FE) of aerosols in the range of 25.9 to 685.4 nm of five different natural materials whose FE was enhanced using electrospun poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF) fibres. A scanning electron microscope (SEM) was used to determine the morphology and structure of the natural materials as well as the thickness of the PVDF fibres, while the phase of the electrospun fibres was determined by Raman spectroscopy. A thin layer of the electrospun PVDF fibres with the same grammage was sandwiched between two sheets of natural materials, and their FE increased up to 80%. By varying the grammature of the electrospun polymer, we tuned the FE of cotton from 82.6 to 99.9%. Thus, through the optimization of the grammage of the electrospun polymer, the amount of plastic used in the process can be minimized, while achieving sufficiently high FE. Full article

The real-time monitoring of spectral characteristics of microbubble (MB) acoustic emissions permits the prediction of increases in blood–brain barrier (BBB) permeability and of tissue damage in MB-mediated focused ultrasound (FUS) brain therapy. Single-element passive cavitation detectors provide limited spatial information regarding MB activity, greatly affecting the performance of acoustic control. However, an array of receivers can be used to spatially map cavitation events and thus improve treatment control. The spectral content of the acoustic emissions provides additional information that can be correlated with the bio-effects, and wideband receivers can thus provide the most complete spectral information. Here, we develop a miniature polyvinylidene fluoride (PVDF thickness = 110 μm, active area = 1.2 mm²) broadband receiver for the acoustic monitoring of MBs. The receiver has superior sensitivity (2.36–3.87 V/MPa) to those of a commercial fibre-optic hydrophone in the low megahertz frequency range (0.51–5.4 MHz). The receiver also has a wide −6 dB acceptance angle (54 degrees at 1.1 MHz and 13 degrees at 5.4 MHz) and the ability to detect subharmonic and higher harmonic MB emissions in phantoms. The overall acoustic performance of this low-cost receiver indicates its suitability for the eventual use within an array for MB monitoring and mapping in preclinical studies. Full article

A triboelectric power generator/energy harvester is an attractive option for mechanical energy harvesting for smart, wearable applications. This paper reports on the fabrication and evaluation of the energy harvesting performance of Polytetrafluoroethylene/Polyvinylidene Fluoride (PTFE/PVDF) fibre prepared using a one-step electrospinning technique. Different concentrations (0, 1, 2, 3, and 4%wt.) of the 1 μm PTFE powder in the electrospun PVDF fibre were investigated. The electrospun fibre was assembled into a nonwoven fabric mat and tested in the vertical contact separation triboelectric mode by constructing a sandwich structure with electrodes in a book-shaped assembly. The voltage output from the cyclical compressive test for fibres with 4%wt. PTFE in PVDF was five times greater than it was for the 100% PVDF electrospun fibres. The influence of adding nylon fabric as a triboelectric donor material within the assembly was explored. The output of the 4%wt. PTFE/PVDF sample was then tested with and without nylon fabric at different frequencies (3–12 Hz). The results show a further 80% increase in the output voltage with the additional nylon fabric included, and the harvester was able to illuminate up to 95 LEDs. Full article

Photoacoustic endoscopy (PAE) can provide 3D functional, molecular and structural information of tissue deep inside the human body, and thus could be well suited for guiding minimally invasive procedures such as tumour biopsy and fetal surgery. One of the major challenges in the development of miniature PAE probes, in particular, forward-viewing PAE probes, is the integration of a sensitive and broadband ultrasound sensor with the light delivery and scanning system into a small footprint. In this work, we developed a forward-viewing PAE probe enabling optical-resolution microscopy imaging based on a transparent ultrasound sensor coated on the distal end of a multimode optical fibre. The transparent sensor comprised a transparent polyvinylidene fluoride (PVDF) thin film coated with indium tin oxide (ITO) electrodes with a diameter of 2 mm. Excitation laser light was focused and raster-scanned across the facet of the probe tip through the multimode fibre and the PVDF-ITO thin film via wavefront shaping. The sensor had an optical transmission rate of 55–72% in the wavelength range of 400 to 800 nm, a centre frequency of 17.5 MHz and a −10 dB bandwidth of 25 MHz. Singular value decomposition was used to remove a prominent trigger-induced noise, which enabled imaging close to the probe tip with an optically defined lateral resolution of 2 µm. The performance of the imaging probe was demonstrated by obtaining high-fidelity photoacoustic microscopy images of carbon fibres. With further optimisation of the sensitivity, the probe promises to guide minimally invasive procedures by providing in situ, in vivo characterisation of tissue. Full article

The stir-frying process in Chinese cooking has produced serious emissions of oily particles, which are an important source of urban air pollution. In particular, the complex composition of fine particulate may pose a threat to human respiratory and immune systems. However, current filtration methods for oily particulate fumes have low filtration efficiency, high resistance, and high equipment costs. In polypropylene (PP) electret filters, efficiency rapidly decreases and pressure drop (wind resistance) sharply increases after the adsorption of oily particles, due to the oleophilic properties of the PP fibre. We addressed this issue of filter performance degradation by fabricating a sodium perfluorooctanoate (SPFO) oleophobic coating on polyvinylidene fluoride (PVDF) fibre membranes for oily particle filtration. The SPFO coating showed a promising oleophobic effect even at low concentrations, which suggests it has oleophobic properties for different oil types and can be modified for different substrates. This fabricated oleophobic coating is thermostable and the oleophobic effect is unaffected by temperatures from 0 to 100 °C. By modifying the SPFO coating on the PVDF membrane, a high filtration efficiency (89.43%) and low wind resistance (69 Pa) was achieved without oil adhesion, so the proposed coating can be applied in the filtration and purification of oily fine particles and offers a potential strategy for preventing atmospheric oil pollution. Full article

Solution blow spinning (SBS) is gaining popularity for producing fibres for smart textiles and energy harvesting due to its operational simplicity and high throughput. The whole SBS process is significantly dependent on the characteristics of the attenuation force, i.e., compressed air. Although variation in the fibre morphology with varying air input pressure has been widely investigated, there is no available literature on the experimentally determined flow characteristics. Here, we have experimentally measured and calculated airflow parameters, namely, output air pressure and velocity in the nozzle wake at 12 different pressure values between 1 and 6 bar and 11 different positions (retracted 5 mm to 30 mm) along the centreline. The results obtained in this work will answer many critical questions about optimum protrusion length for the polymer solution syringe and approximate mean fibre diameter for polyvinylidene fluoride (PVDF) at given output air pressure and velocity. The highest output air pressure and velocity were achieved at a distance of 3–5 mm away from the nozzle wake and should be an ideal location for the apex of the polymer solution syringe. We achieved 250 nm PVDF fibres when output air pressure and velocity were 123 kPa and 387 m/s, respectively. Full article

New bio-based polymers capable of either outperforming fossil-based alternatives or possessing new properties and functionalities are of relevant interest in the framework of the circular economy. In this work, a novel bio-based polycarvone acrylate di-epoxide (PCADE) was used as an additive in a one-step straightforward electrospinning process to endow the fibres with functionalisable epoxy groups at their surface. To demonstrate the feasibility of the approach, poly(vinylidene fluoride) (PVDF) fibres loaded with different amounts of PCADE were prepared. A thorough characterisation by TGA, DSC, DMTA and XPS showed that the two polymers are immiscible and that PCADE preferentially segregates at the fibre surface, thus developing a very simple one-step approach to the preparation of ready-to-use surface functionalisable fibres. We demonstrated this by exploiting the epoxy groups at the PVDF fibre surface in two very different applications, namely in epoxy-based carbon fibre reinforced composites and membranes for ω-transaminase enzyme immobilisation for heterogeneous catalysis. Full article

This work investigates a new generation structural health monitoring (SHM) system for fibre metal laminates (FML) based on an embedded thermoplastic film with compounded piezoceramics, termed piezo-active fibre metal laminate (PFML). The PFML is manufactured using near-series processes and its potential as a passive SHM system is being investigated. A commercial Polyvinylidene fluoride (PVDF) sensor film is used for comparative evaluation of the sensor signals. Furthermore, thermoset and thermoplastic-based FML are equipped with the sensor films and evaluated. For this purpose, static and dynamic three-point bending tests are carried out and the data are recorded. The data obtained from the sensors and the testing machine are compared with the type and time of damage by means of intelligent signal processing. By using a smart sensor system, further investigations are planned which the differentiation between various failure modes, e.g., delamination or fibre breakage. Full article

Computational fluid dynamics (CFD) was used to investigate characteristics of high-speed air as it is expelled from a solution blow spinning (SBS) nozzle using a k-ε turbulence model. Air velocity, pressure, temperature, turbulent kinetic energy and density contours were generated and analysed in order to achieve an optimal attenuation force for fibre production. A bespoke convergent nozzle was used to produce polyvinylidene fluoride (PVDF) fibres at air pressures between 1 and 5 bar. The nozzle comprised of four parts: a polymer solution syringe holder, an air inlet, an air chamber, and a cap that covers the air chamber. A custom-built SBS setup was used to produce PVDF submicron fibres which were consequently analysed using scanning electron microscope (SEM) for their morphological features. Both theoretical and experimental observations showed that a higher air pressure (4 bar) is more suitable to achieve thin fibres of PVDF. However, fibre diameter increased at 5 bar and intertwined ropes of fibres were also observed. Full article

Poly(vinylidene fluoride) has attracted interest from the biomaterials community owing to its stimuli responsive piezoelectric property and promising results for application in the field of tissue engineering. Here, solution blow spinning and electrospinning were employed to fabricate PVDF fibres and the variation in resultant fibre properties assessed. The proportion of piezoelectric β-phase in the solution blow spun fibres was higher than electrospun fibres. Fibre production rate was circa three times higher for solution blow spinning compared to electrospinning for the conditions explored. However, the solution blow spinning method resulted in higher fibre variability between fabricated batches. Fibrous membranes are capable of generating different cellular response depending on fibre diameter. For this reason, electrospun fibres with micron and sub-micron diameters were fabricated, along with successful inclusion of hydroxyapatite particles to fabricate stimuli responsive bioactive fibres. Full article

Poly(vinylidene fluoride) nanocomposites processed with different morphologies, such as porous and non-porous films and fibres, have been prepared with silica nanoparticles (SiNPs) of varying diameter (17, 100, 160 and 300 nm), which in turn have encapsulated perylenediimide (PDI), a fluorescent molecule. The structural, morphological, optical, thermal, and mechanical properties of the nanocomposites, with SiNP filler concentration up to 16 wt %, were evaluated. Furthermore, cytotoxicity and cell proliferation studies were performed. All SiNPs are negatively charged independently of the pH and more stable from pH 5 upwards. The introduction of SiNPs within the polymer matrix increases the contact angle independently of the nanoparticle diameter. Moreover, the smallest ones (17 nm) also improve the PVDF Young’s modulus. The filler diameter, physico-chemical, thermal and mechanical properties of the polymer matrix were not significantly affected. Finally, the SiNPs’ inclusion does not induce cytotoxicity in murine myoblasts (C2C12) after 72 h of contact and proliferation studies reveal that the prepared composites represent a suitable platform for tissue engineering applications, as they allow us to combine the biocompatibility and piezoelectricity of the polymer with the possible functionalization and drug encapsulation and release of the SiNP. Full article

One of the major challenges for the realization of ultra-light weight and intelligent materials with advanced sensing/actuation capabilities, is related to, among other things, the integration in the material of non-invasive but indeed highly performing sensors and actuators. The reduction in scale, weight, and flexibility of the sensing devices represents a critical aspect to reach this goal. These unique properties are here reached by using flexible piezoelectric polymer (Polyvinylidene fluoride, PVDF) nanofibers as sensing elements. The nanofibers, that in this case study are randomly distributed, form an ultra-thin nanostructured porous mat that was deposited through a far field electrospinning approach. The process was optimized to obtain a dominant β phase in the polymer to enhance the piezoelectric response. The electrospun fibers were characterized at different scales: at the molecular level to understand the β phase content (FTIR spectroscopy), as well as at the macroscopic level to investigate the resulting ferroelectric and electromechanical response The results presented in this paper show the great capability of the nanostructured porous mat to work as ultra-light weight dynamic sensing system. Its scalable size and intrinsic properties make it an ideal solution for the development of advanced intelligent materials that can work at different length-scales. Full article