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27 pages, 5743 KiB  
Article
In-Field Load Acquisitions on a Variable Chamber Round Baler Using Instrumented Hub Carriers and a Dynamometric Towing Pin
by Filippo Coppola, Andrea Ruffin and Giovanni Meneghetti
Appl. Sci. 2025, 15(15), 8579; https://doi.org/10.3390/app15158579 (registering DOI) - 1 Aug 2025
Abstract
In this work, the load spectra acting in the vertical direction on the hub carriers and in the horizontal longitudinal direction on the drawbar of a trailed variable chamber round baler were evaluated. To this end, each hub carrier was instrumented with appropriately [...] Read more.
In this work, the load spectra acting in the vertical direction on the hub carriers and in the horizontal longitudinal direction on the drawbar of a trailed variable chamber round baler were evaluated. To this end, each hub carrier was instrumented with appropriately calibrated strain gauge bridges. Similarly, the baler was equipped with a dynamometric towing pin, instrumented with strain gauge sensors and calibrated in the laboratory, which replaced the original pin connecting the baler and the tractor during the in-field load acquisitions. In both cases, the calibration tests returned the relationship between applied forces and output signals of the strain gauge bridges. Multiple in-field load acquisitions were carried out under typical maneuvers and operating conditions. The synchronous acquisition of a video via an onboard camera and Global Positioning System (GPS) signal allowed to observe the behaviour of the baler in correspondence of particular trends of the vertical and horizontal loads and to point out the most demanding maneuver in view of the fatigue resistance of the baler. Finally, through the application of a rainflow cycle counting algorithm according to ASTM E1049-85, the load spectrum for each maneuver was derived. Full article
(This article belongs to the Section Mechanical Engineering)
16 pages, 3215 KiB  
Article
The Effect of Collagen Membrane Fixation with Pins on Buccal Bone Regeneration in Immediate Dental Implant Sites: A Preclinical Study in Dogs
by Yuma Hazama, Takahisa Iida, Niklaus P. Lang, Fernando M. Muñoz Guzon, Giovanna Iezzi, Daniele Botticelli and Shunsuke Baba
J. Funct. Biomater. 2025, 16(8), 281; https://doi.org/10.3390/jfb16080281 (registering DOI) - 31 Jul 2025
Abstract
Background: The role of collagen membrane fixation during guided bone regeneration (GBR) remains debatable, particularly in post-extraction sockets with buccal defects and concomitant immediate implant placement. This study evaluated whether or not fixation with titanium pins improved regenerative outcomes. Methods: Six adult Beagle [...] Read more.
Background: The role of collagen membrane fixation during guided bone regeneration (GBR) remains debatable, particularly in post-extraction sockets with buccal defects and concomitant immediate implant placement. This study evaluated whether or not fixation with titanium pins improved regenerative outcomes. Methods: Six adult Beagle dogs received bilateral extractions of the fourth mandibular premolars. An implant was immediately placed in both the distal alveoli, and standardized buccal bone defects (5 mm height, 3–2 mm width) were prepared. All defects were filled with a slowly resorbing equine xenograft and covered by a resorbable pericardium membrane. At the test sites, the membrane was apically fixed with pins, while no fixation was applied to the control sites. After 3 months of healing, histomorphometric analyses were performed. Results: The vertical bone gain of the buccal crest was 3.2 mm in the test sites (pin group) and 2.9 mm in the control sites (no-pin) (p > 0.754). No significant difference was found in terms of bone-to-implant contact (BIC). However, residual graft particles were located significantly more coronally in the pin group compared to the no-pin group (p = 0.021). Morphometric analyses revealed similar new bone formation within the groups, but with higher amounts of residual xenograft and soft tissue in the pin group. Conclusions: Membrane fixation did not significantly enhance vertical bone gain, and although the slightly higher regeneration in the pin group (3.2 mm vs. 2.9 mm) may hold clinical relevance in esthetically sensitive areas and osseointegration, it appeared to limit coronal migration of the grafting material. Full article
(This article belongs to the Special Issue Biomaterials in Dentistry: Current Status and Advances)
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14 pages, 5833 KiB  
Article
Wettability-Enhanced SiC–Graphite Synergy in Al2O3-SiC-C Castables: Carbon Resource Comparation, Sintering Response, and Latent Rheology Effects
by Benjun Cheng, Mingyang Huang, Guoqi Liu, Feng Wu and Xiaocheng Liang
Materials 2025, 18(15), 3618; https://doi.org/10.3390/ma18153618 (registering DOI) - 31 Jul 2025
Abstract
Research on raw materials for Al2O3-SiC-C refractory castables used in blast furnace troughs is relatively well established. However, gaps remain in both laboratory and industrial trials concerning the performance of castables incorporating SiC-modified flake graphite and alternative carbon sources. [...] Read more.
Research on raw materials for Al2O3-SiC-C refractory castables used in blast furnace troughs is relatively well established. However, gaps remain in both laboratory and industrial trials concerning the performance of castables incorporating SiC-modified flake graphite and alternative carbon sources. This study investigated the sintering behavior, mechanical properties, and service performance of Al2O3-SiC-C castables utilizing varying contents of modified flake graphite, pitch, and carbon black as carbon sources. Samples were characterized using SEM, XRD, and EDS for phase composition and microstructural morphology analysis. Key findings revealed that the thermal expansion mismatch between the SiC coating and flake graphite in SiC-modified graphite generated a microcrack-toughening effect. This effect, combined with the synergistic reinforcement from both components, enhanced the mechanical properties. The SiC modification layer improved the wettability and oxidation resistance of the flake graphite. This modified graphite further contributed to enhanced erosion resistance through mechanisms of matrix pinning and crack deflection within the microstructure. However, the microcracks induced by thermal mismatch concurrently reduced erosion resistance, resulting in an overall limited net improvement in erosion resistance attributable to the modified graphite. Specimens containing 1 wt.% modified flake graphite exhibited the optimal overall performance. During industrial trials, this formulation unexpectedly demonstrated a water reduction mechanism requiring further investigation. Full article
(This article belongs to the Section Carbon Materials)
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22 pages, 4399 KiB  
Article
Deep Learning-Based Fingerprint–Vein Biometric Fusion: A Systematic Review with Empirical Evaluation
by Sarah Almuwayziri, Abeer Al-Nafjan, Hessah Aljumah and Mashael Aldayel
Appl. Sci. 2025, 15(15), 8502; https://doi.org/10.3390/app15158502 (registering DOI) - 31 Jul 2025
Abstract
User authentication is crucial for safeguarding access to digital systems and services. Biometric authentication serves as a strong and user-friendly alternative to conventional security methods such as passwords and PINs, which are often susceptible to breaches. This study proposes a deep learning-based multimodal [...] Read more.
User authentication is crucial for safeguarding access to digital systems and services. Biometric authentication serves as a strong and user-friendly alternative to conventional security methods such as passwords and PINs, which are often susceptible to breaches. This study proposes a deep learning-based multimodal biometric system that combines fingerprint (FP) and finger vein (FV) modalities to improve accuracy and security. The system explores three fusion strategies: feature-level fusion (combining feature vectors from each modality), score-level fusion (integrating prediction scores from each modality), and a hybrid approach that leverages both feature and score information. The implementation involved five pretrained convolutional neural network (CNN) models: two unimodal (FP-only and FV-only) and three multimodal models corresponding to each fusion strategy. The models were assessed using the NUPT-FPV dataset, which consists of 33,600 images collected from 140 subjects with a dual-mode acquisition device in varied environmental conditions. The results indicate that the hybrid-level fusion with a dominant score weight (0.7 score, 0.3 feature) achieved the highest accuracy (99.79%) and the lowest equal error rate (EER = 0.0018), demonstrating superior robustness. Overall, the results demonstrate that integrating deep learning with multimodal fusion is highly effective for advancing scalable and accurate biometric authentication solutions suitable for real-world deployments. Full article
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14 pages, 3023 KiB  
Article
Tensile and Flexural Behavior of Metal–Polymer Friction Stir Buttstrap Composite Panels
by Arménio N. Correia, Daniel F. O. Braga, Ricardo Baptista and Virgínia Infante
Polymers 2025, 17(15), 2084; https://doi.org/10.3390/polym17152084 - 30 Jul 2025
Viewed by 55
Abstract
This study investigates the friction stir joining of AA6082-T6 aluminum alloy and Noryl GFN2 polymer in a buttstrap configuration, targeting the development of lightweight cylindrical-shaped structures where the polymer provides thermal, chemical, and electrical insulation, while the aluminum ensures mechanical integrity. A parametric [...] Read more.
This study investigates the friction stir joining of AA6082-T6 aluminum alloy and Noryl GFN2 polymer in a buttstrap configuration, targeting the development of lightweight cylindrical-shaped structures where the polymer provides thermal, chemical, and electrical insulation, while the aluminum ensures mechanical integrity. A parametric analysis was carried out to assess the ability to produce friction stir buttstrap composite panels in a single processing step and assess the resulting tensile and flexural behavior. To that end, travel and rotating speeds ranging from 2150 to 2250 rpm, and 100 to 140 mm/min, respectively, were employed while keeping plunge depth and the tilt angle constant. A total of nine composite joints were successfully produced and subsequently subjected to both tensile and four-point bending tests. The tensile and flexural strength results ranged from 80 to 139 MPa, and 39 to 47 MPa, respectively. Moreover, the microstructural examination revealed that all joints exhibited a defect within the joining region and its size and shape had a significant effect on tensile strength, whereas the flexural strength was less affected with more uniform results. The joining region was also characterized by a decrease in hardness, particularly in the pin-affected region on the aluminum end of the joint, exhibiting a W-shaped pattern. Contrarily, on the polymeric end of the joining region, no significant change in hardness was observed. Full article
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10 pages, 2156 KiB  
Article
Highly Linear Loaded-Line Phase Shifter Utilizing Impedance Transformer and PIN Diode
by Farhad Ghorbani, Amir Dayan, Jiafeng Zhou and Yi Huang
Microwave 2025, 1(2), 7; https://doi.org/10.3390/microwave1020007 - 30 Jul 2025
Viewed by 75
Abstract
This paper presents a highly linear one-bit loaded-line phase shifter that leverages PIN diodes in combination with a coupler-based impedance transformer. The proposed phase shifter adopts a loaded-line topology, where PIN diodes are configured in a parallel-to-ground arrangement to improve linearity performance. To [...] Read more.
This paper presents a highly linear one-bit loaded-line phase shifter that leverages PIN diodes in combination with a coupler-based impedance transformer. The proposed phase shifter adopts a loaded-line topology, where PIN diodes are configured in a parallel-to-ground arrangement to improve linearity performance. To further enhance linearity, a coupler-based impedance transformer is employed to reduce the impedance seen by each PIN diode, thereby minimizing nonlinear behavior. To demonstrate the effectiveness of this design, a one-bit digital phase shifter is developed, simulated, and fabricated to achieve a 45-degree phase shift at 2 GHz. Experimental measurements confirm an input third-order intercept point (IIP3) exceeding 100 dBm under a range of test conditions, validating the proposed architecture’s linearity advantages. Full article
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10 pages, 1855 KiB  
Article
TCAD Design and Optimization of In0.20Ga0.80N/In0.35Ga0.65N Quantum-Dot Intermediate-Band Solar Cells
by Salaheddine Amezzoug, Haddou El Ghazi and Walid Belaid
Crystals 2025, 15(8), 693; https://doi.org/10.3390/cryst15080693 - 30 Jul 2025
Viewed by 130
Abstract
Intermediate-band photovoltaics promise single-junction efficiencies that exceed the Shockley and Queisser limit, yet viable material platforms and device geometries remain under debate. Here, we perform comprehensive two-dimensional device-scale simulations using Silvaco Atlas TCAD to analyze p-i-n In0.20Ga0.80N solar cells [...] Read more.
Intermediate-band photovoltaics promise single-junction efficiencies that exceed the Shockley and Queisser limit, yet viable material platforms and device geometries remain under debate. Here, we perform comprehensive two-dimensional device-scale simulations using Silvaco Atlas TCAD to analyze p-i-n In0.20Ga0.80N solar cells in which the intermediate band is supplied by In0.35Ga0.65N quantum dots located inside the intrinsic layer. Quantum-dot diameters from 1 nm to 10 nm and areal densities up to 116 dots per period are evaluated under AM 1.5G, one-sun illumination at 300 K. The baseline pn junction achieves a simulated power-conversion efficiency of 33.9%. The incorporation of a single 1 nm quantum-dot layer dramatically increases efficiency to 48.1%, driven by a 35% enhancement in short-circuit current density while maintaining open-circuit voltage stability. Further increases in dot density continue to boost current but with diminishing benefit; the highest efficiency recorded, 49.4% at 116 dots, is only 1.4 percentage points above the 40-dot configuration. The improvements originate from two-step sub-band-gap absorption mediated by the quantum dots and from enhanced carrier collection in a widened depletion region. These results define a practical design window centred on approximately 1 nm dots and about 40 dots per period, balancing substantial efficiency gains with manageable structural complexity and providing concrete targets for epitaxial implementation. Full article
(This article belongs to the Section Materials for Energy Applications)
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20 pages, 7725 KiB  
Article
Harmonic Distortion Peculiarities of High-Frequency SiGe HBT Power Cells for Radar Front End and Wireless Communication
by Paulius Sakalas and Anindya Mukherjee
Electronics 2025, 14(15), 2984; https://doi.org/10.3390/electronics14152984 - 26 Jul 2025
Viewed by 211
Abstract
High-frequency (h. f.) harmonic distortion (HD) of advanced SiGe heterojunction bipolar transistor (HBT)-based power cells (PwCs), featuring optimized metallization interconnections between individual HBTs, was investigated. Single tone input power (Pin) excitations at 1, 2, 5, and 10 GHz frequencies were [...] Read more.
High-frequency (h. f.) harmonic distortion (HD) of advanced SiGe heterojunction bipolar transistor (HBT)-based power cells (PwCs), featuring optimized metallization interconnections between individual HBTs, was investigated. Single tone input power (Pin) excitations at 1, 2, 5, and 10 GHz frequencies were employed. The output power (Pout) of the fundamental tone and its harmonics were analyzed in both the frequency and time domains. A rapid increase in the third harmonic of Pout was observed at input powers exceeding −8 dBm for a fundamental frequency of 10 GHz in two different PwC technologies. This increase in the third harmonic was analyzed in terms of nonlinear current waveforms, the nonlinearity of the HBT p-n junction diffusion capacitances, substrate current behavior versus Pin, and avalanche multiplication current. To assess the RF power performance of the PwCs, scalar and vectorial load-pull (LP) measurements were conducted and analyzed. Under matched conditions, the SiGe PwCs demonstrated good linearity, particularly at high frequencies. The key power performance of the PwCs was measured and simulated as follows: input power 1 dB compression point (Pin_1dB) of −3 dBm, transducer power gain (GT) of 15 dB, and power added efficiency (PAE) of 50% at 30 GHz. All measured data were corroborated with simulations using the compact model HiCuM L2. Full article
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23 pages, 25086 KiB  
Article
U-Net Segmentation with Bayesian-Optimized Weight Voting for Worn Surface Analysis of a PEEK-Based Tribological Composite
by Yuxiao Zhao and Leyu Lin
Lubricants 2025, 13(8), 324; https://doi.org/10.3390/lubricants13080324 - 24 Jul 2025
Viewed by 285
Abstract
This study presents a U-Net-based automatic segmentation framework for quantitative analysis of surface morphology in a PEEK-based composite following tribological testing. Controlled Pin-on-Disc tests were conducted to characterize tribological performance, worn surfaces were captured by laser scanning microscopy to acquire optical images and [...] Read more.
This study presents a U-Net-based automatic segmentation framework for quantitative analysis of surface morphology in a PEEK-based composite following tribological testing. Controlled Pin-on-Disc tests were conducted to characterize tribological performance, worn surfaces were captured by laser scanning microscopy to acquire optical images and height maps, and the model produced pixel-level segmentation masks distinguishing different regions, enabling high-throughput, objective analysis of worn surface morphology. Sixty-three manually annotated image sets—with labels for fiber, third-body patch, and matrix regions—formed the training corpus. A 70-layer U-Net architecture with four-channel input was developed and rigorously evaluated using five-fold cross-validation. To enhance performance on the challenging patch and fiber classes, the top five model instances were ensembled through Bayesian-optimized weighted voting, achieving significant improvements in class-specific F1 metrics. Segmentation outputs on unseen data confirmed the method’s robustness and generalizability across complex surface topographies. This approach establishes a scalable, accurate tool for automated morphological analysis, with potential extensions to real-time monitoring and other composite systems. Full article
(This article belongs to the Special Issue New Horizons in Machine Learning Applications for Tribology)
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18 pages, 4701 KiB  
Article
Investigation of the Wear Resistance of Hard Anodic Al2O3/IF-WS2 Coatings Deposited on Aluminium Alloys
by Joanna Korzekwa, Adam Jarząbek, Marek Bara, Mateusz Niedźwiedź, Krzysztof Cwynar and Dariusz Oleszak
Materials 2025, 18(15), 3471; https://doi.org/10.3390/ma18153471 - 24 Jul 2025
Viewed by 243
Abstract
The anodic oxide layer’s porosity is considered a functional feature, acting as a reservoir of lubricants. This feature enables the design of self-lubricating systems that effectively reduce friction and wear. To improve the tribological performance of Al2O3 anodic coatings on [...] Read more.
The anodic oxide layer’s porosity is considered a functional feature, acting as a reservoir of lubricants. This feature enables the design of self-lubricating systems that effectively reduce friction and wear. To improve the tribological performance of Al2O3 anodic coatings on EN AW 5251 aluminium alloys, this paper presents a modification of the coating with tungsten disulfide (IF-WS2) nanopowder and its effect on coating resistance. The wear properties of Al2O3/IF-WS2 coatings in contact with a cast iron pin were investigated. The results include the analysis of the friction coefficient in the reciprocating motion without oil lubrication at two loads, the analysis of the wear intensity of the cast iron pin, the characterisation of wear scars, and the analysis of SGP parameters. Two-level factorial analysis showed that load and nanomodification significantly affected the load-bearing parameter Rk. Incorporation of the modifier, especially under higher loads, reduced the Rk value, thus improving the tribological durability of the contact pair. Both load and nanomodification had a notable impact on the coefficient of friction. The use of IF-WS2-modified coatings reduced the coefficient, and higher loads further enhanced this effect, by approximately 9% at a load of 0.3 MPa and 15% at a load of 0.6 MPa, indicating improved lubricating conditions under greater contact stress. Full article
(This article belongs to the Special Issue Surface Engineering in Materials (2nd Edition))
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14 pages, 4107 KiB  
Article
Thermal Influence on Chirality-Driven Dynamics and Pinning of Transverse Domain Walls in Z-Junction Magnetic Nanowires
by Mohammed Al Bahri, Salim Al-Kamiyani, Mohammed M. Al Hinaai and Nisar Ali
Symmetry 2025, 17(8), 1184; https://doi.org/10.3390/sym17081184 - 24 Jul 2025
Viewed by 199
Abstract
Magnetic nanowires with domain walls (DWs) play a crucial role in the advancement of next-generation memory and spintronic devices. Understanding the thermal effects on domain wall behavior is essential for optimizing performance and stability. This study investigates the thermal chirality-dependent dynamics and pinning [...] Read more.
Magnetic nanowires with domain walls (DWs) play a crucial role in the advancement of next-generation memory and spintronic devices. Understanding the thermal effects on domain wall behavior is essential for optimizing performance and stability. This study investigates the thermal chirality-dependent dynamics and pinning of transverse domain walls (TDWs) in Z-junction nanowires using micromagnetic simulations. The analysis focuses on head-to-head (HHW) and tail-to-tail (TTW) domain walls with up and down chirality under varying thermal conditions. The results indicate that higher temperatures reduce the pinning strength and depinning current density, leading to enhanced domain wall velocity. At 200 K, the HHWdown domain wall depins at a critical current density of 1.2 × 1011 A/m2, while HHWup requires a higher depinning temperature, indicating stronger pinning effects. Similarly, the depinning temperature (Td) increases with Z-junction depth (d), reaching 300 K at d = 50 nm, while increasing Z-junction (λ) weakens pinning, reducing Td to 150 K at λ = 50 nm. Additionally, the influence of Z-junction geometry and magnetic properties, such as saturation magnetization (Ms) and anisotropy constant (Ku), is examined to determine their effects on thermal pinning and depinning. These findings highlight the critical role of chirality and thermal activation in domain wall motion, offering insights into the design of energy-efficient, high-speed nanowire-based memory devices. Full article
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17 pages, 7494 KiB  
Article
The Effect of Strain Aging on the Microstructure and Mechanical Properties of Steel for Reel-Lay Coiled Steel Pipelines
by Yuxi Cao, Guofeng Zuo, Yang Peng, Lin Zhu, Shuai Tong, Shubiao Yin and Xinjun Sun
Materials 2025, 18(15), 3462; https://doi.org/10.3390/ma18153462 - 24 Jul 2025
Viewed by 330
Abstract
Deep-sea oil and gas pipelines undergo significant plastic strain during reel-lay installation. Additionally, the static strain aging phenomenon that occurs during service can further deteriorate the mechanical properties of the pipelines. This study investigates the plastic deformation mechanism of reel-lay pipeline steel by [...] Read more.
Deep-sea oil and gas pipelines undergo significant plastic strain during reel-lay installation. Additionally, the static strain aging phenomenon that occurs during service can further deteriorate the mechanical properties of the pipelines. This study investigates the plastic deformation mechanism of reel-lay pipeline steel by subjecting the test steel to 5% pre-strain followed by aging treatment at 250 °C for 1 h. The present study systematically correlates the evolution of mechanical properties with microstructural changes through microstructural characterization techniques such as EBSD, TEM, and XRD. The results demonstrate that after pre-straining, the yield strength of the experimental steel increases due to dislocation strengthening and residual stress generation, while its uniform elongation decreases. Although no significant changes in grain size are observed macroscopically, microstructural characterization reveals a substantial increase in dislocation density within the matrix, forming dislocation cells and walls. These substructures lead to a deterioration of the material’s work hardening capacity. Following aging treatment, the tested steel exhibits further increased yield strength and reduced uniform elongation. After aging treatment, although the dislocation density in the matrix slightly decreases and dislocation tangles are somewhat reduced, the Cottrell atmosphere pinning effect leads to a further decline in work hardening capability, ultimately resulting in the deterioration of plasticity in reel-lay pipeline steel. The instantaneous hardening exponent curve shows that the work hardening phenomenon becomes more pronounced in the tested steel after strain aging as the tempering temperature increases. Full article
(This article belongs to the Section Metals and Alloys)
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9 pages, 3725 KiB  
Article
A Strain-Compensated InGaAs/InGaSb Type-II Superlattice Grown on InAs Substrates for Long-Wavelength Infrared Photodetectors
by Hao Zhou, Chang Liu and Yiqiao Chen
Nanomaterials 2025, 15(15), 1143; https://doi.org/10.3390/nano15151143 - 23 Jul 2025
Viewed by 259
Abstract
In this paper, the first demonstration of a highly strained In0.8Ga0.2As/In0.2Ga0.8Sb type-II superlattice structure grown on InAs substrates by molecular beam epitaxy (MBE) for long-wavelength infrared detection was reported. Novel methodologies were developed to optimize [...] Read more.
In this paper, the first demonstration of a highly strained In0.8Ga0.2As/In0.2Ga0.8Sb type-II superlattice structure grown on InAs substrates by molecular beam epitaxy (MBE) for long-wavelength infrared detection was reported. Novel methodologies were developed to optimize the As and Sb flux growth conditions. The quality of the epitaxial layer was characterized using multiple analytical techniques, including differential interference contrast microscopy, atomic force microscopy, high-resolution X-ray diffraction, and high-resolution transmission electron microscopy. The high-quality superlattice structure, with a total thickness of 1.5 μm, exhibited exceptional surface morphology with a root-mean-square roughness of 0.141 nm over a 5 × 5 μm2 area. Single-element devices with PIN architecture were fabricated and characterized. At 77 K, these devices demonstrated a 50% cutoff wavelength of approximately 12.1 μm. The long-wavelength infrared PIN devices exhibited promising performance metrics, including a dark current density of 7.96 × 10−2 A/cm2 at −50 mV bias and a high peak responsivity of 4.90 A/W under zero bias conditions, both measured at 77 K. Furthermore, the devices achieved a high peak quantum efficiency of 65% and a specific detectivity (D*) of 2.74 × 1010 cm·Hz1/2/W at the peak responsivity wavelength of 10.7 µm. These results demonstrate the viability of this material system for long-wavelength infrared detection applications. Full article
(This article belongs to the Section Nanoelectronics, Nanosensors and Devices)
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20 pages, 3625 KiB  
Article
Improvement in the Corrosion and Wear Resistance of ZrO2-Ag Coatings on 316LVM Stainless Steel Under Tribocorrosive Conditions
by Willian Aperador and Giovany Orozco-Hernández
Coatings 2025, 15(8), 862; https://doi.org/10.3390/coatings15080862 - 22 Jul 2025
Viewed by 302
Abstract
This study investigates the development of silver (Ag)-doped zirconia (ZrO2) coatings deposited on 316LVM stainless steel via the unbalanced magnetron sputtering technique. The oxygen content in the Ar/O2 gas mixture was systematically varied (12.5%, 25%, 37.5%, and 50%) to assess [...] Read more.
This study investigates the development of silver (Ag)-doped zirconia (ZrO2) coatings deposited on 316LVM stainless steel via the unbalanced magnetron sputtering technique. The oxygen content in the Ar/O2 gas mixture was systematically varied (12.5%, 25%, 37.5%, and 50%) to assess its influence on the resulting coating properties. In response to the growing demand for biomedical implants with improved durability and biocompatibility, the objective was to develop coatings that enhance both wear and corrosion resistance in physiological environments. The effects of silver incorporation and oxygen concentration on the structural, tribological, and electrochemical behavior of the coatings were systematically analyzed. X-ray diffraction (XRD) was employed to identify crystalline phases, while atomic force microscopy (AFM) was used to characterize surface topography prior to wear testing. Wear resistance was evaluated using a ball-on-plane tribometer under simulated prosthetic motion, applying a 5 N load with a bone pin as the counter body. Corrosion resistance was assessed through electrochemical impedance spectroscopy (EIS) in a physiological solution. Additionally, tribocorrosive performance was investigated by coupling tribological and electrochemical tests in Ringer’s lactate solution, simulating dynamic in vivo contact conditions. The results demonstrate that Ag doping, combined with increased oxygen content in the sputtering atmosphere, significantly improves both wear and corrosion resistance. Notably, the ZrO2-Ag coating deposited with 50% O2 exhibited the lowest wear volume (0.086 mm3) and a minimum coefficient of friction (0.0043) under a 5 N load. This same coating also displayed superior electrochemical performance, with the highest charge transfer resistance (38.83 kΩ·cm2) and the lowest corrosion current density (3.32 × 10−8 A/cm2). These findings confirm the high structural integrity and outstanding tribocorrosive behavior of the coating, highlighting its potential for application in biomedical implant technology. Full article
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12 pages, 395 KiB  
Article
Effects of Translucency-Enhancing Coloring Liquids on the Mechanical Properties of 3Y- and 4Y-TZP Zirconia Ceramics
by Andreas Pfeffer, Sebastian Hahnel, Angelika Rauch and Martin Rosentritt
Ceramics 2025, 8(3), 92; https://doi.org/10.3390/ceramics8030092 - 22 Jul 2025
Viewed by 229
Abstract
The aim of translucency-enhancing liquids (TEL) is to locally influence the phase composition of zirconia in order to increase its translucency. This study aimed to determine the influence of TEL on 3Y- and 4Y-TZP zirconia concerning roughness, hardness, wear, flexural strength, dynamic stability [...] Read more.
The aim of translucency-enhancing liquids (TEL) is to locally influence the phase composition of zirconia in order to increase its translucency. This study aimed to determine the influence of TEL on 3Y- and 4Y-TZP zirconia concerning roughness, hardness, wear, flexural strength, dynamic stability and fracture force of fixed dental prostheses after thermal cycling and mechanical loading. Two zirconia materials (4Y-TZP; 3Y-TZP-LA, n = 8 per material and test) were investigated with and without prior application of TEL. Two-body wear tests were performed in a pneumatic pin-on-block design (50 N, 120,000 cycles, 1.6 Hz) with steatite balls (r = 1.5 mm) as antagonists. Mean and maximum vertical loss as well as roughness (Ra, Rz) were measured with a 3D laser-scanning microscope (KJ 3D, Keyence, J). Antagonist wear was determined as percent area of the projected antagonist area. Martens hardness (HM; ISO 14577-1) and biaxial flexural strength (BFS; ISO 6872) were investigated. The flexural fatigue limit BFSdyn was determined under cyclic loading in a staircase approach with a piston-on-three-ball-test. Thermal cycling and mechanical loading (TCML: 2 × 3000 × 5 °C/55 °C, 2 min/cycle, H2O dist., 1.2 × 106 force á 50 N) was performed on four-unit fixed dental prostheses (FDPs) (n = 8 per group) and the fracture force after TCML was determined. Statistics: ANOVA, Bonferroni test, Kaplan–Meier survival, Pearson correlation; α = 0.05. TEL application significantly influences roughness, hardness, biaxial flexural strength, dynamic performance, as well as fracture force after TCML in 3Y-TZP. For 4Y-TZP, a distinct influence of TEL was only identified for BFS. The application of TEL on 3Y- or 4Y-TZP did not affect wear. TEL application has a strong effect on the mechanical properties of 3Y-TZP and minor effects on 4Y-TZP. All effects of the TEL application are of a magnitude that is unlikely to restrict clinical application. Full article
(This article belongs to the Special Issue Advances in Ceramics, 3rd Edition)
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