Search Results (22)

Graphene oxide (GO) and reduced graphene oxides (RGOs) show intrinsic electrocatalytic activity towards the electrocatalytic reduction of H₂O₂. Combining these materials with gold nanoparticles results in highly sensitive electrodes, with sensitivity in the nanomolar range because the electrocatalytic properties of GO and nanoparticles are synergistically enhanced. Understanding the factors influencing such synergy is crucial to designing novel catalytically active materials. In this contribution, we study gold nanostructures having shapes of nanospheres (AuNSs), nanourchins (AuNUs), and nanobowls (AuNBs) combined with GO or electrochemically reduced graphene oxide (ERGO). We investigate the amperometric responses of the hybrid layers to H₂O₂. The AuNUs show the highest sensitivity compared to AuNBs and AuNSs. All materials are characterized by electron microscopy and Raman spectroscopy. Raman spectra are deconvoluted by fitting them with five components in the 1000–1800 cm⁻¹ range (D*, D, D”, G, and D′). The interaction between nanoparticles and GO is visualized by the relative intensities of Raman bands (ID/IG) and other parameters in the Raman spectra, like various D”, D* band positions and intensities. The ID/IG parameter is linearly correlated with the sensitivity (R² = 0.97), suggesting that defects in the graphene structure are significant factors influencing the electrocatalytic H₂O₂ reduction. Full article

Improving the accuracy of parking space recognition is crucial in the fields for Automated Valet Parking (AVP) of autonomous driving. In AVP, accurate free space recognition significantly impacts the safety and comfort of both the vehicles and drivers. To enhance parking space recognition and annotation in unknown environments, this paper proposes an automatic parking space annotation approach with tight coupling of Lidar and Inertial Measurement Unit (IMU). First, the pose of the Lidar frame was tightly coupled with high-frequency IMU data to compensate for vehicle motion, reducing its impact on the pose transformation of the Lidar point cloud. Next, simultaneous localization and mapping (SLAM) were performed using the compensated Lidar frame. By extracting two-dimensional polarized edge features and planar features from the three-dimensional Lidar point cloud, a polarized Lidar odometry was constructed. The polarized Lidar odometry factor and loop closure factor were jointly optimized in the iSAM2. Finally, the pitch angle of the constructed local map was evaluated to filter out ground points, and the regions of interest (ROI) were projected onto a grid map. The free space between adjacent vehicle point clouds was assessed on the grid map using convex hull detection and straight-line fitting. The experiments were conducted on both local and open datasets. The proposed method achieved an average precision and recall of 98.89% and 98.79% on the local dataset, respectively; it also achieved 97.08% and 99.40% on the nuScenes dataset. And it reduced storage usage by 48.38% while ensuring running time. Comparative experiments on open datasets show that the proposed method can adapt to various scenarios and exhibits strong robustness. Full article

This paper aims to explore the implications of $U{\left(1\right)}_{L_e-L_{\alpha }}$ gauge symmetries, where $\alpha =\tau ,\mu$, in the neutrino sector through type-(I+II) seesaw mechanisms. To achieve such a hybrid framework, we include a scalar triplet and three right-handed neutrinos. The model can successfully account for the active neutrino masses, mixing angles, mass squared differences, and the CP-violating phase within the $3\sigma$ bounds of NuFit v5.2 neutrino oscillation data. The presence of a new gauge boson at the MeV scale provides an explanation for the muon and electron $(g-2)$ within the confines of their experimental limits. Furthermore, we scrutinize the proposed models in the context of upcoming long-baseline neutrino experiments such as DUNE, P2SO, T2HK, and T2HKK. The findings reveal that P2SO and T2HK have the ability to probe both models in their $5\sigma$-allowed oscillation parameter region, whereas DUNE and T2HKK can conclusively test only the model with $U{\left(1\right)}_{L_e-L_{\mu }}$-symmetry within the $5\sigma$ parameter space if the true values of the oscillation parameters remain consistent with NuFit v5.2. Full article

The genus Xanthoparmelia includes several subcrustose, squamulose, small foliose, and small subfruticose species, primarily in the Southern Hemisphere. Here, we report on the first small foliose species lacking usnic acid in the genus occurring in the Holarctic. The species has been previously known as Lecanora olivascens Nyl., but subsequent studies of the morphology, secondary chemistry, and molecular data of the nuITS rDNA indicate that this species instead belongs to Xanthoparmelia. Consequently, the new combination Xanthoparmelia olivascens (Nyl.) V.J. Rico and G. Amo is proposed, and an epitype is designated here. We discuss the unique presence of a subcrustose Xanthoparmelia species lacking cortical usnic acid in the Northern Hemisphere. This species fits phylogenetically into a clade that was previously only known from the Southern Hemisphere, and hence represents another example of N-S disjunction in lichenized fungi. Full article

University students are a vulnerable population to the development of disordered eating, such as food addiction (FA) and grazing. FA is an emerging concept characterized by an intense desire to eat hyper-palatable foods. Grazing is characterized by the repetitive and unplanned ingestion of food throughout a period of time. Both FA and grazing have been associated with increased scores of negative urgency (NU) and difficulties in emotion regulation (ER). This study aims to evaluate the frequency of FA and grazing in a university population and to test the direct, total, and indirect effects—via FA—of ER and NU on repetitive eating and compulsive grazing. A total of 338 participants responded to a set of psychological measures assessing these variables. Thirty-six (10.7%) participants met the criteria for FA diagnosis and 184 (54.4%) presented grazing. Confirmatory factor analysis showed acceptable fit indexes for the model tested (χ²₍₁₆₉₅₎ = 3167.575; p < 0.001; CFI = 0.955; NFI = 0.908; TLI = 0.953; SRMR = 0.085; RMSEA = 0.051; CI 90% (0.048; 0.053); P[RMSEA ≤ 0.05] = 0.318) and suggested that FA partially mediated the effect of difficulties in ER and NU on grazing, specifically on compulsive grazing. The results indicate that individuals with difficulties in ER and impulse control under negative emotions are more likely to engage in grazing if food addiction scores are higher. These results highlight the importance of assessing these variables, particularly in at-risk populations such as university students. Full article

In this study, the effects of fin tip thickness and fin root thickness of integral rolled spiral finned tube bundles on flow resistance, heat transfer performance and heat transfer and flow exergy destruction were investigated via mathematical simulation. The correlations between heat transfer and flow resistance performance were fitted with dimensionless numbers. The optimized parameters with performance evaluation criteria (PEC) as the objective were obtained using methods involving computational fluid dynamics and machine learning. The results show the effects of fin tip thickness and fin root thickness on the Nusselt number (Nu), Euler number (Eu), PEC, heat transfer exergy destruction (ExT) and flow exergy destruction (ExP) as obtained via mathematical simulation. A new mathematical correlation is proposed for predicting the Nu and Eu of integral rolled spiral finned tube bundles. Among the four optimization models tested, the random forest regression algorithm was the most accurate algorithm for PEC prediction models. In the studied range, the optimal parameters were a fin tip thickness of 2 mm and a fin root thickness of 3.5 mm. Compared with the initial parameters, when the Reynolds number was 20,380, the PEC increased by 2.53%, the ExP increased by 2.37% and the ExT decreased by 7.96%. Full article

We provide a diversity assessment of the agamid genus Phrynocephalus Kaup, 1825. We analyze COI mtDNA barcodes from 385 individuals sampled all over Phrynocephalus range. We apply the ABGD, ASAP, bGMYC, mlPTP and hsPTP species delimitation algorithms to analyze the COI gene fragment variation and assess the species diversity in Phrynocephalus. Nine species groups are revealed in Phrynocephalus in agreement with earlier studies on the phylogenetic relationships of the genus. We demonstrate that the present taxonomy likely underestimates the actual diversity of the genus. Alternative species delimitation algorithms provide a confusingly wide range of possible number of Phrynocephalus species—from 54 to 103 MOTUs (molecular operational taxonomic units). The ASAP species delimitation scheme recognizing 63 MOTUs likely most closely fits the currently recognized taxonomic framework of Phrynocephalus. We also report on 13 previously unknown Phrynocephalus lineages as unverified candidate species. We demonstrate that the ASAP and the ABGD algorithms likely most closely reflect the actual diversity of Phrynocephalus, while the mlPTP and hsPTP largely overestimate it. We argue that species delimitation in these lizards based exclusively on mtDNA markers is insufficient, and call for further integrative taxonomic studies joining the data from morphology, mtDNA and nuDNA markers to fully stabilize the taxonomy of Phrynocephalus lizards. Full article

In the present study, numerical simulations are performed to identify the role of Reynolds number (Re), Richardson number (Ri) and free-stream orientations (α) on flow structures, aerodynamic parameters and heat transfer characteristics for the conditions (20 ≤ Re ≤ 120, 0° ≤ α ≤ 90° and 0 ≤ Ri ≤ 1.6). Prandtl number (Pr) and cylinder orientation (ϕ) are kept fixed at 0.71 and 0°. The Oberbeck–Boussinesq approximation is used to account for buoyancy effects. The governing equations of continuity, momentum and energy are discretized on a colocated body-fitted grid by employing a finite difference method. A viscous implicit pressure correction scheme is employed to advance the discrete solution in time. Contour maps of mean/steady drag coefficient and Nusselt number on (α-Ri) plane are plotted for 20 ≤ Re ≤ 120. From these contour maps, it is possible to identify the ranges of parameters (α, Ri) that can yield a relatively high mean/steady heat transfer rate accompanied by relatively low values of mean/steady drag coefficient. For [70° ≤ α ≤ 90°, 0 ≤ Ri ≤ 1.6], such a scenario is possible for any Re ∈ [20, 120]. The Strouhal number is observed to be maximum for Re = 120 at α = 45° and Ri = 1.2. Mean or steady coefficient of lift for any free-stream orientation (α ≠ 0°) is found to be highest at Re = 20 and Ri = 1.6. Sensitivity of (C_D)_{Ri = 0.0} to α is observed to be minimum for Re = 20 and maximum for Re = 120. Sensitivity of the ratio C_D(Ri,α)/C_D(0,α) to Re is observed to be lower for unsteady flows than for steady flows, and it decreases with an increase in Re at a fixed value of Ri. Mean Nusselt number (Nu) in the forced flow regime increases significantly with an increase in Re at a fixed α. The Nusselt number is observed to be more sensitive to Ri for steady flows than for unsteady flows. The percentage increase in the ratio Nu(Ri,α)/Nu(0,α) for the entire range of Re is found to be 14.07%, 14.13%, 11.74% and 10.62% at α = 30°, 45°, 60° and 90°. At a fixed Ri, the Nusselt number ratio is found to decrease with an increase in Re for the entire range of α except for α = 90°. It is observed that the rate of heat transfer from the faces of the cylinder increases with an increase in Re for the entire ranges of α and Ri. Full article

For the objective of enhancing the heat transfer ability of spray cooling, a single-nozzle open-loop spray cooling experiment platform was established with a data measuring system. Based on the surface heat transfer coefficient obtained from the experiment, combined with the visualization system to observe the distribution of droplets during the spray cooling process, the influence of heating power, medium flow rate, nozzle height and typical additives on heating surface coverage and heat transfer characteristics were investigated. The criterion non-dimensional criteria equations for Nu, Re, Pr and size coefficients were fitted and analyzed in comparison with experimental data. The main conclusions are as follows: considering the temperature distribution characteristics of the heating surface and the shape of the spray cone, the heat transfer performance can be optimized by increasing the coverage rate under high heat flux when the flow rate changes, appropriately reducing the coverage rate under low heat flux, and appropriately reducing the coverage rate when the height changes, which creates complete coverage in the droplet concentration area to improve the surface heat transfer capacity. Furthermore, the heat transfer coefficients were improved by 29.3%, 21.8% and 23.8% with different additives (CTAB, ethanol and CTAB–ethanol mixtures) in the working fluid. Each solution had an optimal concentration and heat transfer deterioration was observed at high concentrations. When using non-dimensional criteria equations for parameter calculations, the data are more accurate after considering the effect of dimensional coefficients. Full article

The newly discovered galactic black hole candidate (BHC) MAXI J1348-630 showed two major outbursts in 2019, just after its discovery. Here, we provide a detailed spectral and temporal analysis of the less-studied second outburst using archive data from multiple satellites, namely Swift, MAXI, NICER, NuSTAR and AstroSat. The outburst continued for around two and a half months. Unlike the first outburst from this source, this second outburst was a ‘failed’ one. The source did not transition to soft or intermediate spectral states. During the entire outburst, the source was in the hard state with high dominance of non-thermal photons. The presence of strong shocks are inferred from spectral fitting using a TCAF model. In NuSTAR spectra, weak reflection is observed from spectral fitting. Low-frequency quasi-periodic oscillations are also detected in AstroSat data. Full article

Flavonoids are polyphenolic compounds largely present in fruits and vegetables possessing antioxidant properties, anti-inflammatory and antibacterial activities. Their use in clinical practice is very poor due to their low bioavailability, susceptibility to oxidation and degradation. Moreover, their slight solubility in biological fluids and a consequent low dissolution rate leads to an irregular absorption from solid dosage forms, even though, anti-inflammatory formulations could be used as support for several disease treatment, i.e. the COVID-19 syndrome. To improve flavonoid bioavailability particle size of the powder can be reduced to make it breathable and to promote the absorption in the lung tissues. Supercritical fluid based antisolvent technique has been used to produce naringin particles, with size, shape and density as well as free flowing properties able to fit inhalation needs. The dried particles are produced with the removal of the solvent at lower temperatures compared to the most used traditional micronization processes, such as spray drying. The best breathable fraction for naringin particles is obtained for particles with a d₅₀~7 µm manufactured at 35 °C-150 bar and at 60 °C-130 bar, corresponding to 32.6% and 36.7% respectively. The powder is produced using a high CO₂ molar fraction (0.99) that assure a better removal of the solvent. NuLi-1 cell line of immortalised bronchial epithelial cells adopted to evaluate powder cytotoxicity indicated after 24 h absence of toxicity at concentration of 25 µM. Full article

Features of the tubular type of heat exchanger were examined experimentally in the current study. A rig is fitted with a novel insert as a negative heat transfer increase technique. The core fluid used is air under steady heat flux and a turbulent discharge state (6000 ≤ Re ≤ 19,500) conditions. Two heat transfer augmentation inserts are employed; one is the basket turbulators utilized as a turbulator and placed inside the heat exchanger with a constant pitch ratio (PR = 150 mm), and the other is the basket turbulators together with twisted tape that are installed at the core of the basket turbulators. The measurements illustrated that the Nusselt number (Nu) was found to be higher by about 131.8%, 169.5%, 187.7%, and 206.5% in comparison with the plain heat exchanger for basket turbulators and the combined basket–twisted tape inserts with y/w = 6, 3, and 2, respectively. The highest thermal efficiency factor of the increased tubular heat exchanger is 1.63 times more elevated than that of the simple heat exchanger on average, due to a binary basket-quirky strip for a twisting percentage y/w equal to 2 under steady pumping energy. Further, practical correlations for the Nusselt number, as well as friction characteristics, were established and presented. Full article

In this study, Response Surface Methodology (RSM) and multi-objective genetic algorithm were used to obtain optimum parameters of the channels with frustum of a cone with better flow and heat transfer performance. Central composite face-centered design (CCF) was applied to the experimental design of the channel parameters, and on this basis, the response surface models were constructed. The sensitivity of the channel parameters was analyzed by Sobol’s method. The multi-objective optimization of the channel parameters was carried out with the goal of achieving maximum Nusselt number ratio (Nu/Nu₀) and minimum friction coefficient ratio (f/f₀). The results show that the root mean square errors (RSME) of the fitted response surface models are less than 0.25 and the determination coefficients (R²) are greater than 0.93; the models have high accuracy. Sobol’s method can quantitatively analyze the influence of the channel parameters on flow and heat transfer performance of the channels. When the response is Nu/Nu₀, from high to low, the total sensitivity indexes of the channel parameters are frustum of a cone angle (α), Reynolds number (Re), spanwise spacing ratio (Z₂/D), and streamwise spacing ratio (Z₁/D). When the response is f/f₀, the total sensitivity indexes of the channel parameters from high to low are Re, Z₁/D, α and Z₂/D. Four optimization channels are selected from the Pareto solution set obtained by multi-objective optimization. Compared with the reference channel, the Nu/Nu₀ of the optimized channels is increased by 21.36% on average, and the f/f₀ is reduced by 9.16% on average. Full article

The adaptive significance of sympatric mitochondrial (mtDNA) variation and the role of selective mechanisms that maintain it are debated to this day. Isofemale lines of Drosophila obscura collected from four populations were backcrossed within populations to construct experimental lines, with all combinations of mtDNA Cyt b haplotypes and nuclear genetic backgrounds (nuDNA). Individuals of both sexes from these lines were then subjected to four fitness assays (desiccation resistance, developmental time, egg-to-adult viability and sex ratio) on two experimental temperatures to examine the role of temperature fluctuations and sex-specific selection, as well as the part that interactions between the two genomes play in shaping mtDNA variation. The results varied across populations and fitness components. In the majority of comparisons, they show that sympatric mitochondrial variants affect fitness. However, their effect should be examined in light of interactions with nuDNA, as mito-nuclear genotype was even more influential on fitness across all components. We found both sex-specific and temperature-specific differences in mitochondrial and mito-nuclear genotype ranks in all fitness components. The effect of temperature-specific selection was found to be more prominent, especially in desiccation resistance. From the results of different components tested, we can also infer that temperature-specific mito-nuclear interactions rather than sex-specific selection on mito-nuclear genotypes have a more substantial role in preserving mtDNA variation in this model species. Full article

In this contribution, we summarise the determination of neutrino masses and mixing arising from global analysis of data from atmospheric, solar, reactor, and accelerator neutrino experiments performed in the framework of three-neutrino mixing and obtained in the context of the NuFIT collaboration. Apart from presenting the latest status as of autumn 2021, we discuss the evolution of global-fit results over the last 10 years, and mention various pending issues (and their resolution) that occurred during that period in the global analyses. Full article