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Search Results (2,669)

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Keywords = Li-Ion batteries

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41 pages, 7308 KiB  
Review
Challenges and Opportunities for Extending Battery Pack Life Using New Algorithms and Techniques for Battery Electric Vehicles
by Pedro S. Gonzalez-Rodriguez, Jorge de J. Lozoya-Santos, Hugo G. Gonzalez-Hernandez, Luis C. Felix-Herran and Juan C. Tudon-Martinez
World Electr. Veh. J. 2025, 16(8), 442; https://doi.org/10.3390/wevj16080442 - 5 Aug 2025
Abstract
The shift from Internal Combustion Engine Vehicles (ICEVs) to Battery Electric Vehicles (BEVs) has accelerated global efforts to decarbonize transportation. However, battery degradation, high costs, and limited lifespan remain critical barriers. This review synthesizes recent innovations to extend Li-ion battery life in BEVs [...] Read more.
The shift from Internal Combustion Engine Vehicles (ICEVs) to Battery Electric Vehicles (BEVs) has accelerated global efforts to decarbonize transportation. However, battery degradation, high costs, and limited lifespan remain critical barriers. This review synthesizes recent innovations to extend Li-ion battery life in BEVs by exploring advances in degradation modeling, adaptive Battery Management Systems (BMSs), electronic component simulations, and real-world usage profiling. The authors have systematically analyzed over 80 recent studies using a PRISMA-guided review protocol. A novel comparative framework highlights gaps in current literature, particularly regarding real-world driving impacts, ripple current effects, and second-life battery applications. This review article critically compares model-driven, data-driven, and hybrid model approaches, emphasizing trade-offs in interpretability, accuracy, and deployment feasibility. Finally, the review links battery life extension to broader sustainability metrics, including circular economy models and predictive maintenance algorithms. This review offers actionable insights for researchers, engineers, and policymakers aiming to design longer-lasting and more sustainable electric mobility systems. Full article
(This article belongs to the Special Issue Electric Vehicle Battery Pack and Electric Motor Sizing Methods)
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18 pages, 1214 KiB  
Article
Predictive Maintenance System to RUL Prediction of Li-Ion Batteries and Identify the Fault Type of Brushless DC Electric Motor from UAVs
by Dragos Alexandru Andrioaia
Sensors 2025, 25(15), 4782; https://doi.org/10.3390/s25154782 - 3 Aug 2025
Viewed by 194
Abstract
Unmanned Aerial Vehicles have started to be used more and more due to the benefits they bring. Failure of Unmanned Aerial Vehicle components may result in loss of control, which may cause property damage or personal injury. In order to increase the operational [...] Read more.
Unmanned Aerial Vehicles have started to be used more and more due to the benefits they bring. Failure of Unmanned Aerial Vehicle components may result in loss of control, which may cause property damage or personal injury. In order to increase the operational safety of the Unmanned Aerial Vehicle, the implementation of a Predictive Maintenance system using the Internet of Things is required. In this paper, the authors propose a new architecture of Predictive Maintenance system for Unmanned Aerial Vehicles that is able to identify the fault type of Brushless DC electric motor and determine the Remaining Useful Life of the Li-ion batteries. In order to create the Predictive Maintenance system within the Unmanned Aerial Vehicle, an architecture based on Fog Computing was proposed and Machine Learning was used to extract knowledge from the data. The proposed architecture was practically validated. Full article
(This article belongs to the Section Fault Diagnosis & Sensors)
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21 pages, 1573 KiB  
Review
A Novel Real-Time Battery State Estimation Using Data-Driven Prognostics and Health Management
by Juliano Pimentel, Alistair A. McEwan and Hong Qing Yu
Appl. Sci. 2025, 15(15), 8538; https://doi.org/10.3390/app15158538 (registering DOI) - 31 Jul 2025
Viewed by 141
Abstract
This paper presents a novel data-driven framework for real-time State of Charge (SOC) estimation in lithium-ion battery systems using a data-driven Prognostics and Health Management (PHM) approach. The method leverages an optimized bidirectional Long Short-Term Memory (Bi-LSTM) network, trained with enhanced datasets filtered [...] Read more.
This paper presents a novel data-driven framework for real-time State of Charge (SOC) estimation in lithium-ion battery systems using a data-driven Prognostics and Health Management (PHM) approach. The method leverages an optimized bidirectional Long Short-Term Memory (Bi-LSTM) network, trained with enhanced datasets filtered via exponentially weighted moving averages (EWMAs) and refined through SHAP-based feature attribution. Compared against a Extended Kalman Filter (EKF) and Unscented Kalman Filter (UKF) across ten diverse drive cycles, the proposed model consistently achieved superior performance, with mean absolute errors (MAEs) as low as 0.40%, outperforming EKF (0.66%) and UKF (1.36%). The Bi-LSTM model also demonstrated higher R2 values (up to 0.9999) and narrower 95% confidence intervals, confirming its precision and robustness. Real-time implementation on embedded platforms yielded inference times of 1.3–2.2 s, validating its deployability for edge applications. The framework’s model-free nature makes it adaptable to other nonlinear, time-dependent systems beyond battery SOC estimation. Full article
(This article belongs to the Special Issue Design and Applications of Real-Time Embedded Systems)
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18 pages, 3493 KiB  
Article
Red-Billed Blue Magpie Optimizer for Modeling and Estimating the State of Charge of Lithium-Ion Battery
by Ahmed Fathy and Ahmed M. Agwa
Electrochem 2025, 6(3), 27; https://doi.org/10.3390/electrochem6030027 - 31 Jul 2025
Viewed by 215
Abstract
The energy generated from renewable sources has an intermittent nature since solar irradiation and wind speed vary continuously. Hence, their energy should be stored to be utilized throughout their shortage. There are various forms of energy storage systems while the most widespread technique [...] Read more.
The energy generated from renewable sources has an intermittent nature since solar irradiation and wind speed vary continuously. Hence, their energy should be stored to be utilized throughout their shortage. There are various forms of energy storage systems while the most widespread technique is the battery storage system since its cost is low compared to other techniques. Therefore, batteries are employed in several applications like power systems, electric vehicles, and smart grids. Due to the merits of the lithium-ion (Li-ion) battery, it is preferred over other kinds of batteries. However, the accuracy of the Li-ion battery model is essential for estimating the state of charge (SOC). Additionally, it is essential for consistent simulation and operation throughout various loading and charging conditions. Consequently, the determination of real battery model parameters is vital. An innovative application of the red-billed blue magpie optimizer (RBMO) for determining the model parameters and the SOC of the Li-ion battery is presented in this article. The Shepherd model parameters are determined using the suggested optimization algorithm. The RBMO-based modeling approach offers excellent execution in determining the parameters of the battery model. The suggested approach is compared to other programmed algorithms, namely dandelion optimizer, spider wasp optimizer, barnacles mating optimizer, and interior search algorithm. Moreover, the suggested RBMO is statistically evaluated using Kruskal–Wallis, ANOVA tables, Friedman rank, and Wilcoxon rank tests. Additionally, the Li-ion battery model estimated via the RBMO is validated under variable loading conditions. The fetched results revealed that the suggested approach achieved the least errors between the measured and estimated voltages compared to other approaches in two studied cases with values of 1.4951 × 10−4 and 2.66176 × 10−4. Full article
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11 pages, 1401 KiB  
Communication
Graphene-Enhanced FePO4 Composites with Superior Electrochemical Performance for Lithium-Ion Batteries
by Jinde Yu, Shuchun Hu, Yaohan Zhang, Yin Liu, Wenjuan Ren, Aipeng Zhu, Yanqi Feng, Zhe Wang, Dunan Rao, Yuqin Yang, Heng Zhang, Runhan Liu and Shunying Chang
Materials 2025, 18(15), 3604; https://doi.org/10.3390/ma18153604 - 31 Jul 2025
Viewed by 226
Abstract
In this study, we successfully synthesized olivine-type FePO4 via an in situ oxidation method and further developed two composite cathode materials (o-FePO4-1/GR-1 and o-FePO4-1/GR-2) by incorporating graphene. The composites were characterized using scanning electron microscopy (SEM), X-ray diffraction [...] Read more.
In this study, we successfully synthesized olivine-type FePO4 via an in situ oxidation method and further developed two composite cathode materials (o-FePO4-1/GR-1 and o-FePO4-1/GR-2) by incorporating graphene. The composites were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray Photoelectron Spectroscopy (XPS), revealing a three-dimensional porous layered structure with an enhanced surface area and strong interaction between FePO4 nanoparticles and graphene layers. Electrochemical tests demonstrated that the composite electrodes exhibited significantly improved performance compared to pristine FePO4, with discharge capacities of 147 mAh g−1 at 1C and 163 mAh g−1 at 0.1C for o-FePO4-1/GR-2, approaching the level of LiFePO4. The incorporation of graphene effectively enhanced the electrochemical reaction kinetics, highlighting the innovation of our method in developing high-performance cathode materials for lithium-ion batteries. Full article
(This article belongs to the Section Electronic Materials)
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14 pages, 2351 KiB  
Article
Facile SEI Improvement in the Artificial Graphite/LFP Li-Ion System: Via NaPF6 and KPF6 Electrolyte Additives
by Sepehr Rahbariasl and Yverick Rangom
Energies 2025, 18(15), 4058; https://doi.org/10.3390/en18154058 - 31 Jul 2025
Viewed by 346
Abstract
In this work, graphite anodes and lithium iron phosphate (LFP) cathodes are used to examine the effects of sodium hexafluorophosphate (NaPF6) and potassium hexafluorophosphate (KPF6) electrolyte additives on the formation of the solid electrolyte interphase and the performance of [...] Read more.
In this work, graphite anodes and lithium iron phosphate (LFP) cathodes are used to examine the effects of sodium hexafluorophosphate (NaPF6) and potassium hexafluorophosphate (KPF6) electrolyte additives on the formation of the solid electrolyte interphase and the performance of lithium-ion batteries in both half-cell and full-cell designs. The objective is to assess whether these additives may increase cycle performance, decrease irreversible capacity loss, and improve interfacial stability. Compared to the control electrolyte (1.22 M Lithium hexafluorophosphate (LiPF6)), cells with NaPF6 and KPF6 additives produced less SEI products, which decreased irreversible capacity loss and enhanced initial coulombic efficiency. Following the formation of the solid electrolyte interphase, the specific capacity of the control cell was 607 mA·h/g, with 177 mA·h/g irreversible capacity loss. In contrast, irreversible capacity loss was reduced by 38.98% and 37.85% in cells containing KPF6 and NaPF6 additives, respectively. In full cell cycling, a considerable improvement in capacity retention was achieved by adding NaPF6 and KPF6. The electrolyte, including NaPF6, maintained 67.39% greater capacity than the LiPF6 baseline after 20 cycles, whereas the electrolyte with KPF6 demonstrated a 30.43% improvement, indicating the positive impacts of these additions. X-ray photoelectron spectroscopy verified that sodium (Na+) and potassium (K+) ions were present in the SEI of samples containing NaPF6 and KPF6. While K+ did not intercalate in LFP, cyclic voltammetry confirmed that Na+ intercalated into LFP with negligible impact on the energy storage of full cells. These findings demonstrate that NaPF6 and KPF6 are suitable additions for enhancing lithium-ion battery performance in the popular artificial graphite/LFP system. Full article
(This article belongs to the Special Issue Research on Electrolytes Used in Energy Storage Systems)
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12 pages, 1828 KiB  
Article
Preparation of Comb-Shaped Polyether with PDMS and PEG Side Chains and Its Application in Polymer Electrolytes
by Tomoya Enoki, Ryuta Kosono, Nurul Amira Shazwani Zainuddin, Takahiro Uno and Masataka Kubo
Molecules 2025, 30(15), 3201; https://doi.org/10.3390/molecules30153201 - 30 Jul 2025
Viewed by 281
Abstract
Polyethylene oxide (PEO) is the most well-studied polymer used in solid polymer electrolytes (SPEs) for lithium ion batteries (Li-ion batteries). However, ionic conductivity is greatly reduced in the low temperature range due to the crystallization of PEO. Therefore, methods to suppress the crystallization [...] Read more.
Polyethylene oxide (PEO) is the most well-studied polymer used in solid polymer electrolytes (SPEs) for lithium ion batteries (Li-ion batteries). However, ionic conductivity is greatly reduced in the low temperature range due to the crystallization of PEO. Therefore, methods to suppress the crystallization of PEO at room temperature by cross-linking or introducing a branched structure are currently being investigated. In this study, we synthesized new comb-type ion-conducting polyethers with two different side chains such as polydimethylsiloxane (PDMS) and polyethylene glycol monomethyl ether (mPEG) segments as flexible and ion-conducting segments, respectively. The introduction of the PDMS segment was found to prevent a decrease in ionic conductivity in the low-temperature region, but led to an ionic conductivity decrease in the high temperature region. On the other hand, the introduction of mPEG segments improved ionic conductivity in the high-temperature region. The introduction of mPEG segments with longer chains resulted in a significant decrease in ionic conductivity in the low-temperature region. Full article
(This article belongs to the Special Issue Materials for Emerging Electrochemical Devices—2nd Edition)
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22 pages, 16421 KiB  
Article
Deep Neural Network with Anomaly Detection for Single-Cycle Battery Lifetime Prediction
by Junghwan Lee, Longda Wang, Hoseok Jung, Bukyu Lim, Dael Kim, Jiaxin Liu and Jong Lim
Batteries 2025, 11(8), 288; https://doi.org/10.3390/batteries11080288 - 30 Jul 2025
Viewed by 525
Abstract
Large-scale battery datasets often contain anomalous data due to sensor noise, communication errors, and operational inconsistencies, which degrade the accuracy of data-driven prognostics. However, many existing studies overlook the impact of such anomalies or apply filtering heuristically without rigorous benchmarking, which can potentially [...] Read more.
Large-scale battery datasets often contain anomalous data due to sensor noise, communication errors, and operational inconsistencies, which degrade the accuracy of data-driven prognostics. However, many existing studies overlook the impact of such anomalies or apply filtering heuristically without rigorous benchmarking, which can potentially introduce biases into training and evaluation pipelines. This study presents a deep learning framework that integrates autoencoder-based anomaly detection with a residual neural network (ResNet) to achieve state-of-the-art prediction of remaining useful life at the cycle level using only a single-cycle input. The framework systematically filters out anomalous samples using multiple variants of convolutional and sequence-to-sequence autoencoders, thereby enhancing data integrity before optimizing and training the ResNet-based models. Benchmarking against existing deep learning approaches demonstrates a significant performance improvement, with the best model achieving a mean absolute percentage error of 2.85% and a root mean square error of 40.87 cycles, surpassing prior studies. These results indicate that autoencoder-based anomaly filtering significantly enhances prediction accuracy, reinforcing the importance of systematic anomaly detection in battery prognostics. The proposed method provides a scalable and interpretable solution for intelligent battery management in electric vehicles and energy storage systems. Full article
(This article belongs to the Special Issue Machine Learning for Advanced Battery Systems)
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42 pages, 10454 KiB  
Article
State-of-Charge Estimation of Medium- and High-Voltage Batteries Using LSTM Neural Networks Optimized with Genetic Algorithms
by Romel Carrera, Leonidas Quiroz, Cesar Guevara and Patricia Acosta-Vargas
Sensors 2025, 25(15), 4632; https://doi.org/10.3390/s25154632 - 26 Jul 2025
Viewed by 484
Abstract
This study presents a hybrid method for state-of-charge (SOC) estimation of lithium-ion batteries using LSTM neural networks optimized with genetic algorithms (GA), combined with Coulomb Counting (CC) as an initial estimator. Experimental tests were conducted using medium-voltage (48–72 V) lithium-ion battery packs under [...] Read more.
This study presents a hybrid method for state-of-charge (SOC) estimation of lithium-ion batteries using LSTM neural networks optimized with genetic algorithms (GA), combined with Coulomb Counting (CC) as an initial estimator. Experimental tests were conducted using medium-voltage (48–72 V) lithium-ion battery packs under standardized driving cycles (NEDC and WLTP). The proposed method enhances prediction accuracy under dynamic conditions by recalibrating the LSTM output with CC estimates through a dynamic fusion parameter α. The novelty of this approach lies in the integration of machine learning and physical modeling, optimized via evolutionary algorithms, to address limitations of standalone methods in real-time applications. The hybrid model achieved a mean absolute error (MAE) of 0.181%, outperforming conventional estimation strategies. These findings contribute to more reliable battery management systems (BMS) for electric vehicles and second-life applications. Full article
(This article belongs to the Section Electronic Sensors)
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22 pages, 4225 KiB  
Article
One-Dimensional Simulation of Real-World Battery Degradation Using Battery State Estimation and Vehicle System Models
by Yuya Hato, Wei-hsiang Yang, Toshio Hirota, Yushi Kamiya and Kiyotaka Sato
World Electr. Veh. J. 2025, 16(8), 420; https://doi.org/10.3390/wevj16080420 - 25 Jul 2025
Viewed by 281
Abstract
This study aims to develop a method for analyzing real-world battery degradation in electric vehicles in order to identify the optimal battery management system (BMS) during the early digital phase of vehicle development. Battery management of lithium-ion batteries (LiBs) in electric vehicles is [...] Read more.
This study aims to develop a method for analyzing real-world battery degradation in electric vehicles in order to identify the optimal battery management system (BMS) during the early digital phase of vehicle development. Battery management of lithium-ion batteries (LiBs) in electric vehicles is important to ensure a stable output and to counteract degradation and thermal runaway. To design the optimal system, it is most effective to use a 1D (one-dimensional) vehicle system simulation model, which connects each unit model inside the vehicle, due to the system’s complexity. In order to create a long-term degradation simulation in a vehicle system model, it is important to reduce computational load. Therefore, in this paper, we studied a suitable battery degradation calculation for the vehicle system model based on an equivalent circuit model (ECM) and degradation approximation formulas. After implementing these models, we analyzed long-term degradation behavior through the real-world operation of an electric vehicle driver. We first implemented a high-accuracy ECM using transient charge–discharge tests and Bayesian Optimization. Next, we formulated approximation formulas for degradation prediction based on calendar and cycle degradation tests. Finally, we simulated real-world degradation behavior using these models. The simulation results revealed that even for users who frequently use electric vehicles, degradation under storage conditions is the dominant factor in overall degradation. Full article
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18 pages, 2688 KiB  
Article
Eco-Friendly Leaching of Spent Lithium-Ion Battery Black Mass Using a Ternary Deep Eutectic Solvent System Based on Choline Chloride, Glycolic Acid, and Ascorbic Acid
by Furkan Nazlı, Işıl Hasdemir, Emircan Uysal, Halide Nur Dursun, Utku Orçun Gezici, Duygu Yesiltepe Özçelik, Fırat Burat and Sebahattin Gürmen
Minerals 2025, 15(8), 782; https://doi.org/10.3390/min15080782 - 25 Jul 2025
Viewed by 416
Abstract
Lithium-ion batteries (LiBs) are utilized in numerous applications due to advancements in technology, and the recovery of end-of-life (EoL) LiBs is imperative for environmental and economic reasons. Pyrometallurgical and hydrometallurgical methods have been used in the recovery of metals such as Li, Co, [...] Read more.
Lithium-ion batteries (LiBs) are utilized in numerous applications due to advancements in technology, and the recovery of end-of-life (EoL) LiBs is imperative for environmental and economic reasons. Pyrometallurgical and hydrometallurgical methods have been used in the recovery of metals such as Li, Co, and Ni in the EoL LiBs. Hydrometallurgical methods, which have been demonstrated to exhibit higher recovery efficiency and reduced energy consumption, have garnered increased attention in recent research. Inorganic acids, including HCl, HNO3, and H2SO4, as well as organic acids such as acetic acid and citric acid, are employed in the hydrometallurgical recovery of these metals. It is imperative to acknowledge the environmental hazards posed by these acids. Consequently, solvometallurgical processes, which involve the use of organic solvents with minimal or no water, are gaining increasing attention as alternative or complementary techniques to conventional hydrometallurgical processes. In the context of solvent systems that have been examined for a range of solvometallurgical methods, deep eutectic solvents (DESs) have garnered particular interest due to their low toxicity, biodegradable nature, tunable properties, and efficient metal recovery potential. In this study, the leaching process of black mass containing graphite, LCO, NMC, and LMO was carried out in a short time using the ternary DES system. The ternary DES system consists of choline chloride (ChCl), glycolic acid (GLY), and ascorbic acid (AA). As a result of the leaching process of cathode powders in the black mass without any pre-enrichment process, Li, Co, Ni, and Mn elements passed into solution with an efficiency of over 95% at 60 °C and within 1 h. Moreover, the kinetics of the leaching process was investigated, and Density Functional Theory (DFT) calculations were used to explain the leaching mechanism. Full article
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15 pages, 2830 KiB  
Article
Predictive Framework for Lithium Plating Risk in Fast-Charging Lithium-Ion Batteries: Linking Kinetics, Thermal Activation, and Energy Loss
by Junais Habeeb Mokkath
Batteries 2025, 11(8), 281; https://doi.org/10.3390/batteries11080281 - 22 Jul 2025
Viewed by 333
Abstract
Fast charging accelerates lithium-ion battery operation but increases the risk of lithium (Li) plating—a process that undermines efficiency, longevity, and safety. Here, we introduce a predictive modeling framework that captures the onset and severity of Li plating under practical fast-charging conditions. By integrating [...] Read more.
Fast charging accelerates lithium-ion battery operation but increases the risk of lithium (Li) plating—a process that undermines efficiency, longevity, and safety. Here, we introduce a predictive modeling framework that captures the onset and severity of Li plating under practical fast-charging conditions. By integrating an empirically parameterized SOC threshold model with time-dependent kinetic simulations and Arrhenius based thermal analysis, we delineate operating regimes prone to irreversible Li accumulation. The framework distinguishes reversible and irreversible plating fractions, quantifies energy losses, and identifies a critical activation energy (0.25 eV) associated with surface-limited deposition. Visualizations in the form of severity maps and voltage-zone risk classifications enable direct application to battery management systems. This approach bridges electrochemical degradation modeling with real-time charge protocol design, offering a practical tool for safe, high-performance battery operation. Full article
(This article belongs to the Section Battery Modelling, Simulation, Management and Application)
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35 pages, 5898 KiB  
Article
A Unified Machine Learning Framework for Li-Ion Battery State Estimation and Prediction
by Afroditi Fouka, Alexandros Bousdekis, Katerina Lepenioti and Gregoris Mentzas
Appl. Sci. 2025, 15(15), 8164; https://doi.org/10.3390/app15158164 - 22 Jul 2025
Viewed by 252
Abstract
The accurate estimation and prediction of internal states in lithium-ion (Li-Ion) batteries, such as State of Charge (SoC) and Remaining Useful Life (RUL), are vital for optimizing battery performance, safety, and longevity in electric vehicles and other applications. This paper presents a unified, [...] Read more.
The accurate estimation and prediction of internal states in lithium-ion (Li-Ion) batteries, such as State of Charge (SoC) and Remaining Useful Life (RUL), are vital for optimizing battery performance, safety, and longevity in electric vehicles and other applications. This paper presents a unified, modular, and extensible machine learning (ML) framework designed to address the heterogeneity and complexity of battery state prediction tasks. The proposed framework supports flexible configurations across multiple dimensions, including feature engineering, model selection, and training/testing strategies. It integrates standardized data processing pipelines with a diverse set of ML models, such as a long short-term memory neural network (LSTM), a convolutional neural network (CNN), a feedforward neural network (FFNN), automated machine learning (AutoML), and classical regressors, while accommodating heterogeneous datasets. The framework’s applicability is demonstrated through five distinct use cases involving SoC estimation and RUL prediction using real-world and benchmark datasets. Experimental results highlight the framework’s adaptability, methodological transparency, and robust predictive performance across various battery chemistries, usage profiles, and degradation conditions. This work contributes to a standardized approach that facilitates the reproducibility, comparability, and practical deployment of ML-based battery analytics. Full article
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23 pages, 2233 KiB  
Article
A Novel Back Propagation Neural Network Based on the Harris Hawks Optimization Algorithm for the Remaining Useful Life Prediction of Lithium-Ion Batteries
by Yuyang Zhou, Zijian Shao, Huanhuan Li, Jing Chen, Haohan Sun, Yaping Wang, Nan Wang, Lei Pei, Zhen Wang, Houzhong Zhang and Chaochun Yuan
Energies 2025, 18(14), 3842; https://doi.org/10.3390/en18143842 - 19 Jul 2025
Viewed by 282
Abstract
Remaining useful life (RUL) serves as a pivotal metric for quantifying lithium-ion batteries’ state of health (SOH) in electric vehicles and plays a crucial role in ensuring their safety and reliability. In order to achieve accurate and reliable RUL prediction, a novel RUL [...] Read more.
Remaining useful life (RUL) serves as a pivotal metric for quantifying lithium-ion batteries’ state of health (SOH) in electric vehicles and plays a crucial role in ensuring their safety and reliability. In order to achieve accurate and reliable RUL prediction, a novel RUL prediction method which employs a back propagation (BP) neural network based on the Harris Hawks optimization (HHO) algorithm is proposed. This method optimizes the BP parameters using the improved HHO algorithm. At first, the circle chaotic mapping method is utilized to solve the problem of the initial value. Considering the problem of local convergence, Gaussian mutation is introduced to improve the search ability of the algorithm. Subsequently, two key health factors are selected as input features for the model, including the constant-current charging isovoltage rise time and constant-current discharging isovoltage drop time. The model is validated using aging data from commercial lithium iron phosphate (LiFePO4) batteries. Finally, the model is thoroughly verified under an aging test. Experimental validation using training sets comprising 50%, 60%, and 70% of the cycle data demonstrates superior predictive performance, with mean absolute error (MAE) values below 0.012, root mean square error (RMSE) values below 0.017 and mean absolute percentage error (MAPE) within 0.95%. The results indicate that the model significantly improves prediction accuracy, robustness and searchability. Full article
(This article belongs to the Section D: Energy Storage and Application)
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17 pages, 4099 KiB  
Article
Tetramethylene Sulfone (TMS) as an Electrolyte Additive for High-Power Lithium-Ion Batteries
by Wenting Liu, Gangxin Chen, Ningfeng Wang, Xianzhong Sun, Chen Li, Yanan Xu, Xiaohu Zhang, Xiong Zhang and Kai Wang
Batteries 2025, 11(7), 270; https://doi.org/10.3390/batteries11070270 - 17 Jul 2025
Viewed by 383
Abstract
High-power lithium-ion batteries impose stringent requirements on output power. Tetramethylene sulfone (TMS), serving as a novel electrolyte additive, effectively enhances the stability of electrolytes under high-voltage conditions due to its high flash point and high dielectric constant, thereby boosting the output performance of [...] Read more.
High-power lithium-ion batteries impose stringent requirements on output power. Tetramethylene sulfone (TMS), serving as a novel electrolyte additive, effectively enhances the stability of electrolytes under high-voltage conditions due to its high flash point and high dielectric constant, thereby boosting the output performance of lithium-ion batteries. In this work, we selected lithium hexafluorophosphate (LiPF6) as the lithium salt, using a solvent carrier consisting of a mixture of ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate (EMC). TMS was added as an additive to create a novel high-power electrolyte system. We prepared five electrolytes with different TMS concentrations and conducted in-depth investigations into their impacts on the performance of lithium-ion batteries. The findings indicate that the electrolytes with TMS ratios of 2 wt% and 5 wt% demonstrated good synergistic cathode–anode stability in the NCM//soft carbon system, and the electrolyte with a 5 wt% TMS ratio demonstrated the most significant improvement in the overall performance of the full battery. Full article
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