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22 pages, 13298 KB  
Article
Contribution from Subducted Continental Materials to Ultrapotassic Lamprophyre Dykes Associated with Gold Mineralization in the Baiyun Area, Liaodong Peninsula, NE China
by Chenggui Lin, Jingwen Mao, Zhicheng Lv, Xin Chen, Tingjie Yan, Zhizhong Cheng, Zhenshan Pang and Jianling Xue
Minerals 2026, 16(1), 96; https://doi.org/10.3390/min16010096 - 19 Jan 2026
Viewed by 99
Abstract
Ultrapotassic lamprophyre dykes are spatially closely related to gold deposits in collision tectonic belts. However, the potential implication of these lamprophyre dykes to gold deposits remains poorly constrained. Abundant ultrapotassic lamprophyre dykes in the Baiyun gold deposit of Liaodong Peninsula, NE China, are [...] Read more.
Ultrapotassic lamprophyre dykes are spatially closely related to gold deposits in collision tectonic belts. However, the potential implication of these lamprophyre dykes to gold deposits remains poorly constrained. Abundant ultrapotassic lamprophyre dykes in the Baiyun gold deposit of Liaodong Peninsula, NE China, are closely associated with Au orebodies. This presents an excellent opportunity to investigate the genesis and tectonic significance of these dykes, as well as their potential connection to gold mineralization. Here, based on LA-ICPMS zircon U-Pb age, petrogeochemistry, and Sr-Nd-Hf isotopic composition characteristics, we studied the ultrapotassic lamprophyre dykes in the Baiyun gold deposit. Zircon U-Pb dating of lamprophyre dykes is 225.7 ± 1.3 Ma, which is consistent with the previous auriferous pyrite Re-Os data results within error, indicating that the lamprophyre dykes and gold deposits formed simultaneously in the Late Triassic, which coincided with the exhumation of the deeply subducted South Chin Block (SCB). The lamprophyre dykes belong to the shoshonitic series (K2O + Na2O = 6.39–7.57 wt.%, K2O/Na2O = 3.99–8.74) and are enriched with magnesium (MgO = 5.33–6.40 wt.%, Mg# = 58–65), barium (Ba = 2225–3046 ppm), and strontium (Sr = 792–927 ppm), and their (87Sr/86Sr)i isotopic composition ranges from 0.712514 to 0.714831, εNd(t) ranges from −15.4 to −14.1, and zircon εHf(t) values range from −14.3 to −12.5. These correspond to Paleoproterozoic model ages between 2.1 and 2.3 Ga, which are comparable to the ultra-high-pressure metamorphic rocks with the SCB nature found in the Dabie–Sulu orogenic belt. The results demonstrate that the overlying lithospheric mantle was possibly metasomatized by subducted SCB-derived melts before magma generation under the North China Block (NCB) in the Late Triassic. The lamprophyre dykes with high Nb/U and Th/Yb values, enriched Ba, Sr, REE, Na2O + K2O, K2O/Na2O, and the LOI demonstrate that the metasomatic agents were hydrous, high-pressure melts. These melts likely resulted from the partial melting of subducted continental crust, which is attributed to phengite breakdown in the subduction continental channel. The silica-rich melts migrate from the plate into the sub-continental lithospheric mantle (SCLM) and form potassic- and volatile-enriched metasomatized SCLM. Subsequently, the partial melting of metasomatized SCLM due to the decompression and thinning may be the main mechanism to generate the syn-exhumation ultrapotassic magma in a post-collision setting. This study suggests that the SCLM, metasomatized by melts derived from continental crust, plays a key role in generating volatile-rich hydrous SCLM during the continental subduction and collision stage. In contrast, during the post-collision stage, as tectonic forces transition from compressional to extensional, the abundant volatiles and ultrapotassic magma produced from the partially melted and metasomatized lithospheric mantle may significantly contribute to the transportation, enrichment, and precipitation of gold through magmatic-hydrothermal processes, facilitating the formation of gold deposits. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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24 pages, 8121 KB  
Article
Geochemical Characteristics and Geological Significance of Late Cretaceous to Paleocene Intermediate–Acidic Intrusive Rocks in the Qiuwo Area, Southern Margin of the Lhasa Terrane, China
by Min Jia, Fuwei Xie, Yibin Lin, Shuyuan Chen, Yang Yang and Jiancuo Luosang
Minerals 2026, 16(1), 63; https://doi.org/10.3390/min16010063 - 7 Jan 2026
Viewed by 217
Abstract
The Late Cretaceous to Paleocene magmatic evolution along the southern margin of the Lhasa Terrane records a critical transition from oceanic subduction to continental collision, yet its western segment remains underexplored. This study presents integrated petrographic, zircon U–Pb geochronological, zircon Hf isotopic, whole-rock [...] Read more.
The Late Cretaceous to Paleocene magmatic evolution along the southern margin of the Lhasa Terrane records a critical transition from oceanic subduction to continental collision, yet its western segment remains underexplored. This study presents integrated petrographic, zircon U–Pb geochronological, zircon Hf isotopic, whole-rock geochemical, and Sr–Nd isotopic data for three distinct phases of intermediate to felsic intrusions from the Qiuwo area in the western segment of the southern Lhasa terrane. The results reveal three distinct magmatic pulses: an early granodiorite emplaced at 89.9 ± 0.75 Ma, followed by a diorite crystallizing at 68.6 ± 0.56 Ma, and a late-stage granodiorite forming at 56.75 ± 0.43 Ma. All three rock units are metaluminous to weakly peraluminous (A/CNK < 1.1), sodic (Na2O > 3.2 wt.%), and dominated by amphibole, with zircon saturation temperatures of 737–786 °C, consistent with I-type granitoid affinity. All units are metaluminous (A/CNK = 0.92–1.00), calc-alkaline to high-K calc-alkaline, and enriched in LILE (K, Th, Rb) while depleted in HFSE (Nb, Ta, P, Ti), with moderate ΣREE (81–130 ppm), elevated (La/Yb)N (9.3–15.8), and negative Eu anomalies (δEu = 0.70–0.89). The early granodiorite is Na-rich (Na2O/K2O = 1.6), whereas the Paleocene granodiorite shows elevated K2O (3.2 wt.%) and reduced Na2O/K2O (~1.0), reflecting progressive crustal thickening and increasing magmatic differentiation. Zr and Hf are relatively enriched, and Sr/Y ratios decrease from 39 to 21, consistent with evolving magmatic conditions from deeper crustal melting in the Late Cretaceous to shallower, more evolved sources in the Paleocene. Zircon Hf isotopes reveal consistently positive εHf(t) values (+10.4 to +4.9), indicating derivation from juvenile basaltic lower crust. Sr–Nd isotopic data further demonstrate a systematic evolution: εNd(t) decreases from +2.7 to −0.1, while (87Sr/86Sr)i increases from 0.7044 to 0.7055, reflecting progressive incorporation of ancient crustal components into the magma source from the early Late Cretaceous to the Paleocene. These findings indicate that the Qiuwo intrusions formed by partial melting of a juvenile basaltic lower crust, with increasing crustal contamination during ascent and emplacement. The temporal progression of magmatism—spanning the waning stages of Neo-Tethyan subduction to the initial India–Eurasia collision (~55 Ma)—supports a model in which slab breakoff and lithospheric delamination triggered decompression melting of the lower crust, while assimilation of older crustal materials intensified as the continental collision progressed. This work provides key geochemical evidence for the transition from arc to post-collisional magmatism in the western Gangdese belt and refines the timing and mechanism of crustal growth in southern Tibet. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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16 pages, 16372 KB  
Article
An Efficient Zircon Separation Method Based on Acid Leaching and Automated Mineral Recognition: A Case Study of Xiugugabu Diabase
by Qiuyun Yuan, Haili Li, Yue Wu, Pengjie Cai, Jiadi Zhao, Weihao Yan, Ferdon Hamit, Ruotong Wang, Zhiqi Chen, Aihua Wang and Ahmed E. Masoud
Minerals 2026, 16(1), 20; https://doi.org/10.3390/min16010020 - 24 Dec 2025
Viewed by 333
Abstract
Cr and Platinum-Group Elements (PGEs), critical metallic elements, are mainly hosted in mafic and ultramafic rocks, but determining these rocks’ mineralization age has long been challenging. Zircon, the primary geochronological mineral, is scarce and fine-grained in such rocks, hindering conventional separation techniques (heavy [...] Read more.
Cr and Platinum-Group Elements (PGEs), critical metallic elements, are mainly hosted in mafic and ultramafic rocks, but determining these rocks’ mineralization age has long been challenging. Zircon, the primary geochronological mineral, is scarce and fine-grained in such rocks, hindering conventional separation techniques (heavy liquid separation, magnetic separation, manual hand-picking) with low efficiency, poor recovery, and significant sample bias. This study develops an integrated workflow: mixed acid leaching enrichment (120 °C), powder stirring for mount preparation, automated mineral identification, and in situ Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA–ICP–MS) dating. Validated on the Xiugugabu diabase in the western Yarlung–Tsangpo Suture Zone (southern Tibet), the workflow yielded weighted mean 206Pb/238U ages of 120.5 ± 3.3 Ma (MSWD = 0.13) and 120.5 ± 2.0 Ma (MSWD = 3.2) for two samples. Consistent with the published Yarlung–Tsangpo Suture Zone (YTSZ) diabase formation ages (130–110 Ma), these confirm the Xiugugabu diabase as an Early Cretaceous Neo–Te–thys oceanic lithosphere residual recording mid-stage spreading. The workflow overcomes traditional limitations: single-sample analytical cycles shorten from 30–50 to 10 days, fine–grained zircon recovery is 15x higher than manual picking, and U–Pb ages are stable. Suitable for large-scale mafic–ultramafic geochronological surveys, it can extend to in situ zircon Hf isotope and trace element analysis, offering multi-dimensional constraints on petrogenesis and tectonic evolution. Full article
(This article belongs to the Special Issue Critical Metal Minerals, 2nd Edition)
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15 pages, 3279 KB  
Article
Geochemical Characteristics, U-Pb Age, and Hf Isotope of Zircons from Muscovite Granite in Aotou Sn Deposit, Eastern Nanling Range, South China
by Wei Li, Na Guo, Jie Lu, Xinghai Lang, Dunmei Lian, Qiwen Yuan and Shuwen Chen
Minerals 2025, 15(12), 1331; https://doi.org/10.3390/min15121331 - 18 Dec 2025
Viewed by 411
Abstract
The Jiulongnao W–Sn ore field in the eastern Nanling Range is characterized by large-scale early Yanshanian magmatic activity and W–Sn mineralization. In recent years, increasing attention has been given to the close relationship between Indosinian magmatic activity and Sn mineralization. The Aotou quartz [...] Read more.
The Jiulongnao W–Sn ore field in the eastern Nanling Range is characterized by large-scale early Yanshanian magmatic activity and W–Sn mineralization. In recent years, increasing attention has been given to the close relationship between Indosinian magmatic activity and Sn mineralization. The Aotou quartz vein-type Sn deposit is unique for only Sn mineralization without W during the Indosinian period. Seventeen thin-to-thick cassiterite–quartz veins are densely distributed in Ordovician metasandstone and slate, and these veins extend down to the top of the concealed granite. However, both the diagenetic age and the petrological characteristics of the concealed granite remain unclear. This contribution shows that the Aotou muscovite intrusion is a highly fractionated S-type pluton, characterized by a peraluminous, high-K composition, enrichment in LREEs, and depletion of Ba, Sr, Ti, and Eu. In this study, LA–ICP–MS zircon U–Pb dating of the concealed muscovite granite yields emplacement ages of 238.7 ± 1.0 Ma and 225.4 ± 0.9 Ma, indicating that at least two stages of magmatic intrusion occurred in the Triassic, with the diagenetic environment transitioning from a compressional setting to an extensional setting. The εHf(t) values during the two stages are −0.98 to −0.95 and −0.98 to −0.96, and the TDM2 values are 1.78–2.08 Ga and 1.78–2.06 Ga, indicating that two-stage magma was derived from the late Paleoproterozoic lower crustal materials. Comprehensive analysis reveals that the second stage of Indosinian magma intrusion (232–225 Ma) in the Jiulongnao ore field is closely related to Sn mineralization, and the northern Wenying pluton has good prospecting potential for quartz vein-type Sn(–W) deposits. Full article
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16 pages, 14759 KB  
Article
Basalts from Zhangzhongjing Seamount, South China Sea and Their Linkage to a Plume-Modified Mantle Reservoir
by Rong Lu, Hao Zheng, Lei Yang, Anyuan Xie, Xi He, Cong Peng, Zhengyuan Li and Huizhong He
Minerals 2025, 15(12), 1292; https://doi.org/10.3390/min15121292 - 10 Dec 2025
Viewed by 360
Abstract
Basement rock samples were collected from the Zhangzhongjing intraplate seamount in the Southeast sub-basin of the South China Sea (SCS). These alkaline basalts are enriched in light rare earth elements (LREE). The Sr-Nd-Pb-Hf isotopic compositions of the basalts suggest that their parental melts [...] Read more.
Basement rock samples were collected from the Zhangzhongjing intraplate seamount in the Southeast sub-basin of the South China Sea (SCS). These alkaline basalts are enriched in light rare earth elements (LREE). The Sr-Nd-Pb-Hf isotopic compositions of the basalts suggest that their parental melts originated from an Indian Ocean-type mantle source that was mixed with enriched EMII components. Semi-quantitative geochemical modeling indicates that the parental melts of the studied basalts formed through heterogeneous melting starts at depth in the garnet facies and, during its uprising, continue at shallow levels in the spinel facies. Furthermore, qualitative isotopic modeling indicates that the inferred EMII components were most likely derived from the nearby Hainan plume. This study provides invaluable insights into the extent to which the Hainan diapir influenced the geochemical and isotopic composition of the upper mantle beneath the East Sub-basin of the SCS. Full article
(This article belongs to the Special Issue Geochronology and Geochemistry of Alkaline Rocks)
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22 pages, 9176 KB  
Article
Ore Genesis of the Wunuer Zn-Pb-Ag-Mo Deposit from the Central Great Xing’an Range, NE China: Constraints from Geochemical, Isotopic, and Geochronological Features
by Wei Mei, Hongyu Liu, Yiming Chang and Xiaofeng Cao
Minerals 2025, 15(12), 1291; https://doi.org/10.3390/min15121291 - 10 Dec 2025
Viewed by 328
Abstract
The Wunuer deposit is an important hydrothermal Zn-Pb-Ag-Mo polymetallic deposit in the central Great Xing’an Range, NE China. The zinc–lead polymetal mineralization is closely hosted by the volcanic rocks of the Manketouebo formation (rhyolite and lithic crystal tuff) and related to the Mesozoic [...] Read more.
The Wunuer deposit is an important hydrothermal Zn-Pb-Ag-Mo polymetallic deposit in the central Great Xing’an Range, NE China. The zinc–lead polymetal mineralization is closely hosted by the volcanic rocks of the Manketouebo formation (rhyolite and lithic crystal tuff) and related to the Mesozoic granite porphyry. Field evidence and petrographic observations have identified three mineralization stages within this deposit from deep to shallow: (1) late magmatic stage with vein-type Mo mineralization characteristics and mainly related to the deep granite porphyry; (2) magmatic–hydrothermal transition stage characterized by breccia-type Zn mineralization, which occurred within a steep cryptoexplosive breccia; and (3) hydrothermal stage featured by vein-type Zn-Pb-Ag mineralization hosted by the ore-bearing fractured zone. In this contribution, we present the mineralogy, zircon U-Pb age, sphalerite Rb-Sr dating, whole-rock geochemistry, and Hf-S-Pb isotopes of the Wunuer deposit. LA-ICP-MS zircon U-Pb dating of the ore-related granite porphyry, rhyolite, and lithic crystal tuff suggests that the Mo mineralization from the late magmatic stage occurred between 144.8 Ma and 145.8 Ma. The Rb-Sr isochron dating of sphalerite indicates that the hydrothermal stage Zn mineralization age is 121 ± 2.3 Ma, which is related to the volcanism of Baiyin’gaolao Formation in the Wunuer area. The concentrated and positive δ34SV-CDT values (0.17‰~5.40‰) of sulfides, as well as uniform Pb isotope compositions of granite porphyry intrusion and galena, jointly imply a magmatic source of metallogenic materials for Pb-Zn mineralization. Whole-rock geochemistry and Hf-Pb isotopes reveal that the granite porphyry and rhyolite both originated from a mantle-derived juvenile component and assimilated by minor ancient crustal material in an extensional setting. Our study demonstrates the prospect of further exploration for two mineralization events in the hydrothermal polymetallic deposits of the central Great Xing’an Range. Full article
(This article belongs to the Section Mineral Deposits)
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21 pages, 9961 KB  
Article
Geochronology and Geochemistry of Early–Middle Permian Intrusive Rocks in the Southern Greater Xing’an Range, China: Constraints on the Tectonic Evolution of the Paleo-Asian Ocean
by Haihua Zhang, Xiaoping Yang, Xin Huang, Liang Qiu, Gongjian Li, Yujin Zhang, Wei Chen and Haiwei Jiao
Minerals 2025, 15(12), 1288; https://doi.org/10.3390/min15121288 - 8 Dec 2025
Viewed by 476
Abstract
The tectonic evolution of the Paleo-Asian Ocean during the Early to Middle Permian remains a key issue in understanding the geodynamic history of the Central Asian Orogenic Belt. To address this, we conducted petrological, whole-rock geochemical, zircon U–Pb geochronological, and Hf isotopic analyses [...] Read more.
The tectonic evolution of the Paleo-Asian Ocean during the Early to Middle Permian remains a key issue in understanding the geodynamic history of the Central Asian Orogenic Belt. To address this, we conducted petrological, whole-rock geochemical, zircon U–Pb geochronological, and Hf isotopic analyses of Early Permian biotite granodiorite and Middle Permian porphyritic granite from the south-central Great Xing’an Range. Zircon U–Pb dating yields ages of 273.2 ± 1.4 Ma and 264.4 ± 1.5 Ma, indicating that these intrusions emplaced during Early and Middle Permian. Geochemical analyses show that the rocks are characterized by high SiO2 and Al2O3 contents, and low MgO and CaO contents and belong to the metaluminous to weakly peraluminous series, typical of I-type granites. The rocks are enriched in light rare earth elements and large-ion lithophile elements (e.g., Rb, Ba, K), but depleted in heavy rare earth elements and high field strength elements (e.g., Nb, Ta, P, Ti), with weakly negative Eu anomalies. The Early Permian pluton exhibits low-Sr and high-Yb characteristics and thus fall in the plagioclase stability field. In contrast, Middle Permian pluton was derived from magmas generated by partial melting under high-pressure conditions and that, underwent crystal fractionation during ascent to the mid-upper crust, ultimately forming low-Sr and low-Yb type granites. All zircon εHf(t) values are positive (+4.84 to +14.87), with the corresponding two-stage Hf model ages ranging from 345 Ma to 980 Ma, indicating that the magmas were predominantly derived from juvenile crustal materials accreted during the Neoproterozoic to Phanerozoic. Considering these results, we propose that the Paleo-Asian Oceanic plate continued to subduct beneath the Songliao–Xilinhot block to the north during the Early to Middle Permian, with intense subduction and crustal thickening occurring in the Middle Permian. This suggests that the south-central segment of the Great Xing’an Range was situated in an active continental marginal setting during the Early-Middle Permian. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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34 pages, 14879 KB  
Article
Petrogenesis and Tectonic Significance of Early Cretaceous Granites in the Huolin Gol Area, Southern Great Xing’an Range, NE China: Geochronological, Geochemical, and Hf Isotopic Evidence
by Kuo Zhang, Junhui Bi, Hongying Zhou, Hang Chu, Zhongshuai Tian, Jianzhen Geng, Xuliang Qin and Feng Zhang
Minerals 2025, 15(12), 1278; https://doi.org/10.3390/min15121278 - 3 Dec 2025
Viewed by 478
Abstract
Mesozoic granitic rocks are widely developed in the Great Xing’an Range, and determining their emplacement age and genesis is crucial for reconstructing the tectonic-magmatic evolution of Northeast China. This paper reports the petrographic, geochronological, geochemical and zircon Hf isotopic characteristics of granites in [...] Read more.
Mesozoic granitic rocks are widely developed in the Great Xing’an Range, and determining their emplacement age and genesis is crucial for reconstructing the tectonic-magmatic evolution of Northeast China. This paper reports the petrographic, geochronological, geochemical and zircon Hf isotopic characteristics of granites in the Huolin Gol area of the southern Great Xing’an Range to determine the formation age, source nature and geodynamic background of the rocks in this area. Zircon U–Pb dating results show that the granites in the study area were formed in the Early Cretaceous (134–130 Ma), rather than the Late Jurassic as previously thought. The granites have SiO2 contents ranging from 75.02 to 78.53 wt.%, Na2O = 3.55–3.89 wt.%, K2O = 3.98–5.11 wt.%, Na2O/K2O = 0.72–0.97, A/CNK = 1.04–1.14. Their rare earth element (REE) distribution patterns are all right-inclined, with LREE/HREE = 3.89–12.41, (La/Yb)N = 2.39–18.86, Eu/Eu* = 0.02–0.17. Trace element spider diagrams show significant enrichment in Rb, Th, U, K, Pb and LREEs, and depletion in Ba, Nb, Ta, Sr, P, Ti and HREEs. The zircon εHf(t) values range from +6.4 to +15.0, and the two-stage Hf model ages (TDM2) range from 773 to 226 Ma. These characteristics indicate that the granitic rocks belong to the weakly peraluminous high-K calc-alkaline I-type granite, derived from partial melting of newly generated juvenile continental crust materials. Combined with the coeval magmatic associations, spatial distribution patterns, and regional tectonic evolution, we propose that the Early Cretaceous granitic rocks in the study area formed in an active continental margin setting, with their geodynamic mechanism linked to the subduction of the Paleo-Pacific Plate beneath the East Asian continent. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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21 pages, 3340 KB  
Article
Zircon U-Pb-Hf Isotopes, Whole-Rock Geochemistry and Sr-Nd Isotopes of Early Neoproterozoic Intrusion in the Erguna Block, NE China: Petrogenesis and Tectonic Implications
by Zhanlong Li, Ji Feng, Tianyu Zhao, Yang Liu, Rui Wang, Yanan Zhang and Fuling Fan
Minerals 2025, 15(12), 1245; https://doi.org/10.3390/min15121245 - 25 Nov 2025
Viewed by 441
Abstract
The early crustal evolution of microcontinental fragments in the Central Asian Orogenic Belt remains poorly constrained. Among these fragments, the Erguna Block records extensive Neoproterozoic magmatism that provides key constraints on its tectono-magmatic development in relation to the Rodinia supercontinent cycle. To furthering [...] Read more.
The early crustal evolution of microcontinental fragments in the Central Asian Orogenic Belt remains poorly constrained. Among these fragments, the Erguna Block records extensive Neoproterozoic magmatism that provides key constraints on its tectono-magmatic development in relation to the Rodinia supercontinent cycle. To furthering constrain the Neoproterozoic magmatic evolution of the Erguna Block, an integrated investigation combining petrography, zircon U-Pb and Lu-Hf isotopic analyses, whole-rock geochemistry, and Sr-Nd isotope data was carried out on the newly recognized Fengshuishan intrusion in northern Alongshan. Zircon U-Pb ages of 810 ± 5 Ma and 807 ± 4 Ma were obtained from granitic samples, while the dioritic sample gave an age of 773 ± 2 Ma, representing a major Neoproterozoic magmatic episode. The 810–807 Ma granites show positive zircon εHf(t) (+0.09 to +12.1) and whole-rock εNd(t) (+0.50 to +1.77), suggesting derivation mainly from partial melting of Mesoproterozoic juvenile crust with minor contribution from mantle-derived materials. In contrast, ca. 773 Ma gabbroic diorite exhibits εHf(t) values of −1.23 to +4.3 and an εNd(t) value of +1.33, implying a contribution from an enriched mantle source. These Fengshuishan igneous rocks show A-type geochemical signatures, enriched in Rb, Th, and Pb but depleted in Ba, Sr, and Eu. Integrating these data with regional geological evidence, we infer that the Fengshuishan intrusion formed in an intraplate extensional regime, recording an important phase of crust–mantle interaction during the Neoproterozoic. These results expand the record of Neoproterozoic igneous rocks in the Erguna Block and offer new constraints on its role within the Rodinia supercontinent. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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18 pages, 7190 KB  
Article
Chronology, Geochemistry, and Tectonic Implications of Early Cretaceous Granitoids in the Ranwu Area, Eastern Gangdese Belt
by Xinjie Yang, Meiling Dong, Yanyun Wang, Chao Teng, Dian Xiao, Jun Cao, Xiqing Chen and Jie Shao
Minerals 2025, 15(11), 1188; https://doi.org/10.3390/min15111188 - 12 Nov 2025
Viewed by 445
Abstract
The Gangdese Belt is sandwiched between the Yarlung–Zangbo Suture Zone (YZSZ) and the Bangong–Nujiang Suture Zone (BNSZ), and witnessed large-scale magmatic activity during the Early Cretaceous period. Currently, controversies remain regarding the petrogenetic mechanism and tectonic setting of the Early Cretaceous magmatism in [...] Read more.
The Gangdese Belt is sandwiched between the Yarlung–Zangbo Suture Zone (YZSZ) and the Bangong–Nujiang Suture Zone (BNSZ), and witnessed large-scale magmatic activity during the Early Cretaceous period. Currently, controversies remain regarding the petrogenetic mechanism and tectonic setting of the Early Cretaceous magmatism in the eastern Gangdese Belt. To clarify these controversies, this study conducted systematic petrogeochemical analysis on the Ranwu pluton in the eastern Gangdese Belt. The results show that the main rock types of the Ranwu pluton are monzogranite and granodiorite. The LA-ICP-MS zircon U-Pb ages of the monzogranite (sample CZTW1105) and granodiorite (sample CZTW2051) are 116.3 ± 0.5 Ma and 114.6 ± 0.6 Ma, respectively, collectively indicating that the Ranwu pluton formed during the Early Cretaceous period. The results of in situ zircon Hf isotope analysis show that the εHf(t) values range from −5.0 to 0.5, with corresponding Hf crustal model ages (TDMC) of 1139–1494 Ma. The Ranwu pluton belongs to the high-K calc-alkaline series and is classified as I-type granite. Combined with geochemical characteristics and tectonic setting discrimination diagrams, it is determined that the granites of this period have geochemical signatures of post-collisional granites and formed in a tectonic setting during the transition from a compressional to an extensional regime. The occurrence of Early Cretaceous post-collisional granites marks the end of the main orogenic stage in the Bangong–Nujiang Suture Zone, and the Gangdese Belt has since transitioned into a tectonic environment of the post-orogenic extensional stage. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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28 pages, 18316 KB  
Article
Chemistry of Zircon and Its Implication on the Petrogenesis of Cretaceous Volcanic Rocks from the Southeastern Coast of Zhejiang Province, South China
by Zhijie Zeng, Zengcai Tang, Uzair Siddique, Yifan Wang, Jian Liu, Bingzhen Fu and Zilong Li
Minerals 2025, 15(11), 1147; https://doi.org/10.3390/min15111147 - 31 Oct 2025
Viewed by 671
Abstract
The Cretaceous marks the peak of magmatic activity in southeastern (SE) China, which is attributed to the subduction of the paleo-Pacific plate beneath the South China Block. This region constitutes a significant igneous belt along the active continental margin of the western Pacific. [...] Read more.
The Cretaceous marks the peak of magmatic activity in southeastern (SE) China, which is attributed to the subduction of the paleo-Pacific plate beneath the South China Block. This region constitutes a significant igneous belt along the active continental margin of the western Pacific. Despite extensive research, the origin and evolution of Cretaceous felsic volcanic rocks are still debated. This study investigates the characteristics of zircon U-Pb-Hf isotopes and trace elements, and whole-rock geochemistry of Cretaceous volcanic rocks from the Wenzhou–Taizhou region in SE Zhejiang, and discusses their spatio-temporal patterns and petrogenesis. The results indicate that rhyolitic volcanic rocks formed during the period ca. 114 Ma and 95 Ma, representing two distinct magmatic episodes spanning the transition from the late Early to early Late Cretaceous. The late Early Cretaceous and early Late Cretaceous volcanic rocks are of a hybrid crust–mantle origin, as evidenced by their distinct Nb/Ta ratios, zircon εHf(t) values, and variable trace element enrichments (Ti, Hf, U, Nb, and Yb). These compositional signatures suggest partial melting of late Paleoproterozoic to early Mesoproterozoic basement materials, with increasing mantle contributions over time. Both volcanic phases exhibit elevated Nb/Yb, Th/Nb, and U/Yb ratios, indicating a subduction-modified source akin to arc magmas. Together with calculated initial melt temperatures (<800 °C for Early Cretaceous, >800 °C for Late Cretaceous) and whole-rock rare-earth elements (REEs) distribution patterns (U-shaped with δEu = 0.37–0.65, seagull-shaped with δEu = 0.19–0.62, respectively), it is suggested that both phases of the volcanic magmas were generated through water-assisted (hydrous) melting, whereas the later phase formed at relatively higher temperatures and with a diminished water contribution via dehydration melting under extensional conditions. The generation of voluminous high-silica magmas in the SE China coastal region is probably linked to the rollback and retreat of the paleo-Pacific plate. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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31 pages, 9920 KB  
Article
Genesis of Early Cretaceous Magmatism in the Western Gangdese Belt, Southern Tibet: Implications for Neo-Tethyan Oceanic Slab Subduction
by Jiqing Lin, Ke Gao, Zizheng Wang, Zhongbiao Xu and Yongping Pan
Minerals 2025, 15(11), 1143; https://doi.org/10.3390/min15111143 - 30 Oct 2025
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Abstract
Research on the Mesozoic–Cenozoic magmatism and the tectonic framework within the Lhasa Terrane is voluminous. However, the sparse documentation of Early Cretaceous magmatism in this region fuels ongoing debate over the prevailing tectonic regime during this time period (i.e., normal subduction vs. flat [...] Read more.
Research on the Mesozoic–Cenozoic magmatism and the tectonic framework within the Lhasa Terrane is voluminous. However, the sparse documentation of Early Cretaceous magmatism in this region fuels ongoing debate over the prevailing tectonic regime during this time period (i.e., normal subduction vs. flat subduction). The present study investigates the Luerma pyroxenite and Boyun granitoid in the Western Lhasa Terrane through zircon U-Pb dating, whole-rock geochemistry, mineral chemistry, and Sr-Nd-Hf isotopes. The findings date the formation of Luerma pyroxenite at 115 Ma and Boyun granites at 113 Ma to the Early Cretaceous period (115–113 Ma). SiO2 content of pyroxenite is relatively low (34.27–44.16 wt.%), characterized by an enrichment in large ion lithophile elements (LILEs), light rare earth elements (LREEs), and a depletion in heavy field strength elements (HSFEs), indicative of a metasomatic origin. The εNd (t) and εHf (t) values of the Early Cretaceous ultrabasic rocks range from +2.1 to +2.7 and −0.8 to +10.1, respectively, suggesting their derivation from an enriched mantle source with asthenospheric material incorporation. The Early Cretaceous granodiorites and their mafic enclaves belong to the high-K calc-alkaline series, and show enrichment in LILEs (e.g., Rb, Ba, U, and Th) and depletion in HFSEs (e.g., Nb, Ta, Ti, and Zr). The acidic rocks and their developed mafic enclaves exhibit the geochemical characteristics of trace elements found in island arc magmas. Their εNd (t) values are (−6.0–−5.0), while their εHf (t) values are (−11.7–−1.8); the MMEs εHf (t) values are (−4.1–+0.9). In summary, the Early Cretaceous pyroxenite in the Gangdese Belt originated from a combination of asthenospheric and enriched lithospheric mantle melts, while the granitoids were generated by partial melting of the mantle wedge, a process driven by metasomatism resulting from the slab-derived fluids. At the same time, heat from upwelling mantle-derived melts induced the partial melting of lower crustal materials, leading to the formation of acidic magmas through varying degrees of mixing with basic magmas. This study suggests that Early Cretaceous magmatic activity occurred within a northward subduction setting, characterized by the rotation and fragmentation of the Neo-Tethys oceanic crust. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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24 pages, 9733 KB  
Article
Geochemistry and Diagenetic Mineralization of Early Cretaceous Highly Differentiated Granites, Offshore Eastern Shandong, China
by Ruiyang Liu, Yaoqi Zhou, Tongtong Chen and Huasheng Qi
Minerals 2025, 15(11), 1141; https://doi.org/10.3390/min15111141 - 30 Oct 2025
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Abstract
Large-scale Mesozoic granites are widespread in the offshore area of eastern Shandong Province, China. This study aims to refine the granite classification and explore the degree of granite differentiation and ore-bearing potential in the study area. We conducted field investigations in Dazhushan, Xiaozhushan, [...] Read more.
Large-scale Mesozoic granites are widespread in the offshore area of eastern Shandong Province, China. This study aims to refine the granite classification and explore the degree of granite differentiation and ore-bearing potential in the study area. We conducted field investigations in Dazhushan, Xiaozhushan, and Laoshan plutons. The analytical methods included petrography, whole-rock geochemistry, Sr–Nd–Pb–Li isotopes, zircon U–Pb dating, in situ Hf isotopes, and microanalysis (LA-ICP-MS) of plagioclase. The results reveal high-silica (SiO2 > 70%), highly differentiated (DI > 90) granites emplaced during the Early Cretaceous (113.12–121.78 Ma). Sr–Nd–Pb isotopes indicate magma derived from a crustal source (ISr = 0.7032–0.7242; εNd(t) = −12.45~−20.46). Critically, the spodumene-bearing Dazhushan granites exhibit high Li content with limited isotopic fractionation (δ7Li = 1.00–4.62‰; Li = 8.64–93 ppm), signaling high ore potential. In contrast, the Xiaozhushan granites are barren (δ7Li = 3.31–4.92‰; Li = 0.66–4.01 ppm). This study identified I-type (Laoshan) and I-S type (Dazhushan and Xiaozhushan) highly differentiated granites formed by plagioclase fractionation, with Dazhushan being the most promising for mineralization. Full article
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31 pages, 20520 KB  
Article
Genesis of the Baijianshan Skarn-Type Zn-Cu Polymetallic Deposit, Chinese Eastern Tianshan: Constraints from Geology, Geochronology and Geochemistry
by Fenwei Cheng, Shuai Zhang, Jianxin Wu, Baofeng Huang and Di Zhang
Minerals 2025, 15(11), 1107; https://doi.org/10.3390/min15111107 - 24 Oct 2025
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Abstract
The Baijianshan deposit is the sole skarn Zn-Cu polymetallic deposit in the Xiaoshitouquan ore field, Xinjiang, China. Its ore genesis remains controversial, which hinders understanding of the relationship between skarn-type Zn-Cu and adjacent epithermal Ag-Cu-Pb-Zn mineralization and consequently impedes further regional exploration. LA-ICP-MS [...] Read more.
The Baijianshan deposit is the sole skarn Zn-Cu polymetallic deposit in the Xiaoshitouquan ore field, Xinjiang, China. Its ore genesis remains controversial, which hinders understanding of the relationship between skarn-type Zn-Cu and adjacent epithermal Ag-Cu-Pb-Zn mineralization and consequently impedes further regional exploration. LA-ICP-MS U-Pb dating on zircons from the granite and granite porphyry from the mining area yielded ages of 311 ± 1.7 Ma and 312 ± 1.6 Ma, respectively. The corresponding zircon εHf(t) values and TDM ages are 8.7–9.9 and 624–555 Ma for the granite, and 7.2–9.9 and 673–552 Ma for the granite porphyry. These granites are metaluminous, high-K calc-alkaline I-type granites, with high LREE/HREE ratios (4.92–9.03) and pronounced negative Eu anomalies. They are enriched in K, Th, U, Zr, and Hf, with significant depletions in Sr, P, and Ti. Combined geological and geochemical evidence indicate that these Late Carboniferous granites were derived from the juvenile crustal and formed in subduction-related back basin. Two-phase aqueous inclusions in the ore-bearing quartz and calcite have homogenization temperatures ranging from 117 to 207 °C and 112 to 160 °C, respectively, with the salinities in the ranges of 0.18~7.17 and 0.53~5.26 wt% NaCl eq. The S and Pb isotopic compositions of sulfides in the ores indicate that the ore-forming metals were sourced from the medium-acidic magmatite. The δ18OH2O and δDH2O values of hydrothermal fluids range from −6.97% to −5.84% and −106.8% to −99.6%, respectively, suggesting that the ore-forming fluids originated from the mixing of magmatic and meteoric water. Fluid mixing and corresponding conductive cooling were identified as the principal mechanism triggering the metallic mineral precipitation. The Baijianshan skarn Zn-Cu polymetallic deposit shares contemporaneous magmatic-mineralization ages and analogous material sources with the epithermal polymetallic deposits in the Xiaoshitouquan ore field, collectively constituting a unified skarn-epithermal metallogenic system. This hypothesis indicates that the deep parts of the epithermal deposits within the Yamansu volcanic rocks possess potential for exploring the porphyry-skarn-type deposits. Full article
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21 pages, 5448 KB  
Article
The First Discovery of A1-Type Granite in the Meibaqieqin Region, Central Lhasa Terrane, Xizang
by Yi Yang, Junkang Zhao, Ke Gao, Zhi Zhang, Shuai Ding, Jiansheng Gong, Jianyang Wu, Peiyan Xu and Yingxu Li
Minerals 2025, 15(10), 1093; https://doi.org/10.3390/min15101093 - 21 Oct 2025
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Abstract
This study documents the first A1-type granite identified on the southern margin of the central Lhasa terrane: a two-mica syenogranite pluton in the Meibaqieqin region. Because A-type granite provides sensitive records of crustal melting and lithospheric extension, this pluton offers important insights into [...] Read more.
This study documents the first A1-type granite identified on the southern margin of the central Lhasa terrane: a two-mica syenogranite pluton in the Meibaqieqin region. Because A-type granite provides sensitive records of crustal melting and lithospheric extension, this pluton offers important insights into magmatic processes and tectonic evolution along the southern margin of the Lhasa terrane. We analyzed two sample suites collected from different sites within the same pluton using zircon U–Pb geochronology and Hf isotopes, whole-rock geochemistry and Nd isotope. Zircon U–Pb weighted mean ages were 130.5 ± 0.7 Ma and 130.0 ± 0.7 Ma, placing emplacement in the Early Cretaceous. Zircon εHf(t) values ranged from −11.29 to −9.00 and −11.04 to −7.27, with two-stage Hf model ages (TDM2) of 1.76–1.90 Ga and 1.65–1.89 Ga. Whole-rock εNd(t) values clustered between −11.77 and −11.36, yielding two-stage Nd model ages (TNdDM2) of 1.85–1.88 Ga. Geochemically, the pluton is high-K calc-alkaline. These isotopic signatures indicate derivation predominantly from ancient crustal sources with a little mantle material. Chondrite-normalized REE patterns are overall right-inclined and display a V-shaped profile. Together with trace-element characteristics, these features support classification as A1-type granite. Regional comprehensive data suggest that pluton emplacement was controlled mainly by lithospheric extension related to northward subduction of the Neo-Tethyan oceanic plate, with a lesser contribution from southward subduction along the Bangongco–Nujiang suture. The source characteristics and geodynamic context differ markedly from A2-type granites on the northern margin of the central Lhasa terrane, which reflect distinct magmatic sources and tectonic regimes. Full article
(This article belongs to the Special Issue Tectonic Evolution of the Tethys Ocean in the Qinghai–Tibet Plateau)
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