Search Results (593)

The solid structure of industrial sinter comprises seven mineral associations (A, B, C, D, Ds, E, N) which have different relative abundances of key minerals, textures and spatial relationships to micro-macropores and hematite nuclei. Among the key characteristics of the mineral associations: (MA), MA-A comprises abundant SFCA-I microplates with hematite; MA-B consists of disseminated fine-grained magnetite in a network of SFCA-III microplates; MA-C is similar to MA-B but contains patches of dendritic SFCA-III with larnite and minor glass; MA-D comprises magnetite surrounded by coarse prisms of SFCA within glass; MA-Ds, a subtype of MA-D, includes SFCA with secondary skeletal hematite; MA-E consists of anhedral to skeletal magnetite or hematite in a matrix of glass; and MA-N comprises unmelted hematite nuclei from iron ore feedstock. SFCA-III and SFCA-I are dominant in MA-B and MA-A, respectively, whilst magnetite is the most common mineral in MA-C, MA-D/Ds and MA-E. Low-temperature sintering samples are largely of MA-A to MA-D (62 area %), which contain higher combined levels of SFCA-SFCA-III and lower levels of magnetite-dominant MA-E (12.6 area %), whereas high-temperature/magnetite sintering examples had high levels of magnetite-dominant MA-E (31.6 area %) and MA-D/Ds (52.1 area %) and low levels of MA-A to MA-C (8.9 area %). It is proposed that the formation of each MA is controlled by the peak sintering temperature attained, the dwell time at higher temperature which adversely allows fractional crystallisation to tie up more Fe in magnetite rather than forming SFCA phases during cooling, and especially a slower rate of cooling which promotes the formation of more SFCA family phases at lower temperatures. However, local variations in chemistry inherited from raw material granulation and assimilation during sintering of Si-rich gangue or ore nuclei are also important. Full article

In this work, a method for leaching black mass from spent Li batteries using oxalic acid was developed and experimentally verified with the objective of selectively separating lithium and cobalt. Oxalic acid proved to be an efficient and selective leaching agent. Under 1 M C₂H₂O₄, 120 min, L:S = 20, 80 °C and 300 rpm, a lithium yield of 90% was achieved, while cobalt dissolution remained low at 1.57%. Subsequently, cobalt spontaneously precipitated from the leachate within several hours, and the solid phase was fully separated after 24 h. The leachate contained minor amounts of accompanying metals, with dissolution yields of 0.5% Mn, 8% Fe and 1.4% Cu. These impurities were removed from the leachate by controlled pH adjustment using NaOH at ambient temperature and 450 rpm, with complete precipitation at pH 12. This procedure generated a purified lithium-rich leachate, which was converted into lithium oxalate by crystallisation at 105 °C. Subsequent calcination of the resulting solid at 450 °C for 30 min produced Li₂CO₃ with a purity of 91%. Based on the experimental findings, a conceptual technological process for selective lithium leaching using oxalic acid was proposed, demonstrating the potential of this method for sustainable lithium recovery. Full article

This study investigated the effects of calcium (Ca²⁺) and iron (II) Fe²⁺ concentrations (0–500 mg/L) on the heterogeneous nucleation and crystallization behavior of struvite (MgNH₄PO₄·6H₂O) through controlled batch precipitation experiments. Struvite formed under different Ca²⁺ and Fe²⁺ concentrations were systematically characterized using XRD, SEM, FTIR, and XPS, while real-time pH and redox potential (Eh) monitoring was employed to elucidate reaction dynamics and thermodynamic speciation and saturation indices were calculated, and classical nucleation theory (CNT) was applied to interpret nucleation behavior. The results show that Ca²⁺ primarily suppresses struvite formation through bulk-phase competition with Mg²⁺ for phosphate, diverting phosphate into Ca–P phases and progressively reducing struvite supersaturation, which leads to decreased crystallinity and distorted Crystal habit. In contrast, Fe²⁺ does not form detectable crystalline Fe-P phases but inhibits struvite crystallization mainly through surface-mediated processes. Surface analyses indicate that Fe-bearing species adsorb onto struvite surfaces and promote amorphous Fe-P deposition, increasing interfacial resistance to nucleation and growth. CNT analysis further reveals that Ca²⁺ inhibition is governed by reduced thermodynamic driving force, whereas Fe²⁺ inhibition is dominated by surface-related kinetic barriers. This study provides mechanistic insight into ion-specific interference during struvite crystallization and offers guidance for optimizing phosphorus recovery in ion-rich wastewater systems. Full article

The South Sakhalin mud volcano (Sakhalin Island, Russia) emits HCO₃-Cl/Na-Mg water, emanates CO₂ prevailing over CH₄ in the gas phase, and extrudes mud bearing five carbonate mineral species. The study focuses on the distribution, diversity, and origin of the carbonate minerals from the mud volcano (MV) ejecta, in terms of carbon cycle processes. The data presented include a synthesis of field observations, compositions of MV gases and waters, chemistry of carbonate minerals, as well as stable isotope geochemistry of MV waters (δ¹³С, δD, and δ¹⁸O) and carbonates (δ¹³С and δ¹⁸O). The sampled MV waters are isotopically heavy, with δ¹⁸O = +5.7 to +7.5 ‰ VSMOW, δD = −18.0 to −11.0 ‰ VSMOW, and ¹³С (δ¹³С_DIC = +6.9 to +8.1 ‰ VPDB). This composition may be due to the dilution of basinal water with dehydration water released during the diagenetic illitization of smectite. Carbonates in the sampled mud masses belong to three genetically different groups. Mg-rich siderite, (Fe_0.54–0.81Mg_0.04–0.30Ca_0.05–0.23Mn_0.00–0.08)CO₃, disseminated in abundance throughout the mud masses, coexists with common calcite and sporadic ankerite. The trace-element chemistry of Mg-siderite, as well as the oxygen (δ¹⁸O = +34.4 to +36.8 ‰ VSMOW) and carbon (δ¹³C = −1.3 to +0.6 ‰ VPDB) isotopic signatures, confirms its authigenic origin. Siderite formed during early diagenesis of the Upper Cretaceous sandy and clayey marine sediments mobilized by mud volcanism in the area. Another assemblage, composed of dawsonite, siderite, and vein calcite (±kaolinite), represents altered arkose sandstones found as few fragments in the mud. This assemblage may be a marker of later CO₂ flooding into the sandstone aquifer in the geological past. The trace-element chemistry, particular morphology, and heavy C (δ¹³С = +5.5 to +7.0 ‰ VPDB) and O (δ¹⁸О = +39.1 to +39.5 ‰ VSMOW) isotope compositions indicate that aragonite is the only carbonate species that is related to the current MV activity. It crystallized in a shallow reservoir and was maintained by СО₂ released from rapidly ascending liquefied mud and HCO₃-Cl/Na-Mg-type of MV waters. Full article

The six platinum group elements (PGE) are among the rarest elements in the upper continental crust of the earth. Higher values of PGE have been detected in the upper mantle and in chondrite meteorites. The PGE are siderophile and chalcophile elements and are divided into the following: (1) the Ir subgroup (IPGE) = Os, Ir, and Ru and (2) the Pd subgroup (PPGE) = Rh, Pt, and Pd. The IPGE are more refractory and less chalcophile than the PPGE. High concentrations of PGE led, in rare cases, to the formation of mineral deposits. The PGE are carried in discrete phases, the platinum group minerals (PGM), and are included as trace elements into the structure of base metal sulphides (BM), such as pentlandite, chalcopyrite, pyrite, and pyrrhotite. Similarly to PGE, the PGM are also divided into two main groups, i.e., IPGM composed of Os, Ir, and Ru and PPGM containing Rh, Pt, and Pd. The PGM occur both in mafic and ultramafic rocks and are mainly hosted in stratiform reefs, sulphide-rich lenses, and placer deposits. Presently, there are only 169 valid PGM that represent about 2.7% of all 6176 minerals discovered so far. However, 496 PGM are listed among the valid species that have not yet been officially accepted, while a further 641 are considered as invalid or discredited species. The main reason for the incomplete characterization of PGM resides in their mode of occurrence, i.e., as grains in composite aggregates of a few microns in size, which makes it difficult to determine their crystallography. Among the PGM officially accepted by the IMA, only 13 (8%) were discovered before 1958, the year when the IMA was established. The highest number of PGM was discovered between 1970 and 1979, and 99 PGM have been accepted from 1980 until now. Of the 169 PGM accepted by the IMA, 44% are named in honour of a person, typically a scientist or geologist, and 31% are named after their discovery localities. The nomenclature of 25% of the PGM is based on their chemical composition and/or their physical properties. PGM have been discovered in 25 countries throughout the world, with 64 from Russia, 17 from Canada and South Africa (each), 15 from China, 12 from the USA, 8 from Brazil, 6 from Japan, 5 from Congo, 3 from Finland and Germany (each), 2 from the Dominican Republic, Greenland, Malaysia, and Papua New Guinea each, and only 1 from Argentine, Australia, Bulgaria, Colombia, Czech Republic, England, Ethiopia, Guyana, Mexico, Serbia, and Tanzania each. Most PGM phases contain Pd (82 phases, 48% of all accepted PGM), followed, in decreasing order of abundances, by those of Pt 35 phases (21%), Rh 23 phases (14%), Ir 18 phases (11%), Ru 7 phases (4%), and Os 4 phases (2%). The six PGE forming the PGM are bonded to other elements such as Fe, Ni, Cu, S, As, Te, Bi, Sb, Se, Sn, Hg, Ag, Zn, Si, Pb, Ge, In, Mo, and O. Thirty-two percent of the 169 valid PGM crystallize in the cubic system, 17% are orthorhombic, 16% hexagonal, 14% tetragonal, 11% trigonal, 3% monoclinic, and only 1% triclinic. Some PGM are members of a solid-solution series, which may be complete or contain a miscibility gap, providing information concerning the chemical and physical environment in which the mineral was formed. The refractory IPGM precipitate principally in primitive, high-temperature, mantle-hosted rocks such as podiform and layered chromitites. Being more chalcophile, PPGE are preferentially collected and concentrated in an immiscible sulphide liquid, and, under appropriate conditions, the PPGM can precipitate in a thermal range of about 900–300 °C in the presence of fluids and a progressive increase of oxygen fugacity (fO₂). Thus, a great number of Pt and Pd minerals have been described in Ni-Cu sulphide deposits. Two main genetic models have been proposed for the formation of PGM nuggets: (1) Detrital PGM represent magmatic grains that were mechanically liberated from their primary source by weathering and erosion with or without minor alteration processes, and (2) PGM reprecipitated in the supergene environment through a complex process that comprises solubility, the leaching of PGE from the primary PGM, and variation in Eh-pH and microbial activity. These two models do not exclude each other, and alluvial deposits may contain contributions from both processes. Full article

As a potential strategic resource of critical metals, deep-sea cobalt-rich crusts represent one of the most promising metal reservoirs within oceanic seamount systems, and their metallogenic mechanism constitutes a frontier topic in deep-sea geoscience research. This review focuses on the cobalt-rich crusts from the Magellan Seamount region in the northwestern Pacific and synthesizes existing geological, mineralogical, and geochemical studies to systematically elucidate their mineralization processes and metal enrichment mechanisms from a microstructural perspective, with particular emphasis on cobalt enrichment and its controlling factors. Based on published observations and experimental evidence, the formation of cobalt-rich crusts is divided into three stages: (1) Mn/Fe colloid formation—At the chemical interface between oxygen-rich bottom water and the oxygen minimum zone (OMZ), Mn²⁺ and Fe²⁺ are oxidized to form hydrated oxide colloids such as δ-MnO₂ and Fe(OH)₃. (2) Key metal adsorption—Colloidal particles adsorb metal ions such as Co²⁺, Ni²⁺, and Cu²⁺ through surface complexation and oxidation–substitution reactions, among which Co²⁺ is further oxidized to Co³⁺ and stably incorporated into MnO₆ octahedral vacancies. (3) Colloid deposition and mineralization—Mn–Fe colloids aggregate, dehydrate, and cement on the exposed seamount bedrock surface to form layered cobalt-rich crusts. This process is dominated by the Fe/Mn redox cycle, representing a continuous evolution from colloidal reactions to solid-phase mineral formation. Biological processes play a crucial catalytic role in the microstructural evolution of the crusts. Mn-oxidizing bacteria and extracellular polymeric substances (EPS) accelerate Mn oxidation, regulate mineral-oriented growth, and enhance particle cementation, thereby significantly improving the oxidation and adsorption efficiency of metal ions. Tectonic and paleoceanographic evolution, seamount topography, and the circulation of Antarctic Bottom Water jointly control the metallogenic environment and metal sources, while crystal defects, redox gradients, and biological activity collectively drive metal enrichment. This review establishes a conceptual framework of a multi-level metallogenic model linking macroscopic oceanic circulation and geological evolution with microscopic chemical and biological processes, providing a theoretical basis for the exploration, prediction, and sustainable development of potential cobalt-rich crust deposits. Full article

In this paper, a series of Co-free FeCr_0.6Ni_0.6(AlSi)_x (x = 0, 0.1, 0.12, 0.14, 0.16) high-entropy alloys (HEAs) were designed and fabricated by suction casting, and the effects of equi-molar (Al, Si) co-addition in these Fe-rich Fe-Cr-Ni-based HEAs on microstructure, mechanical properties, and corrosion resistance were systematically investigated. It is found that equi-molar (Al, Si) co-addition could cause the phase formation from FCC to FCC + BCC, while the morphologies of the phases change from dendrite-type to sideplate-type. Moreover, trade-off between strength and plasticity occurs with the increase in (Al, Si) co-addition, and the production of ultimate tensile strength and plasticity reaches the highest value when x = 0.12, while there exists a narrow region for x values to realize excellent comprehensive mechanical properties. In addition, similar corrosion resistance in 3.5 wt.% NaCl solution higher than 316L stainless steel could be realized in the HEAs with x = 0.12 and 0.14, while the latter one is slightly lower in pitting corrosion and the width of passive region, which is possibly caused by the increase in the density of phase boundaries. This work provides a novel insight on designing high-performance cost-effective Fe-rich and (Al, Si)-containing (Fe-Cr-Ni)-based HEAs combining high mechanical properties and corrosion resistance. Full article

Carbon–metal composite NiCrFeC coatings, prepared with and without controlled oxygen addition, were investigated to evaluate the influence of oxygen on the structure, mechanical response, and tribological performance. X-ray diffraction revealed that oxygen-containing films (NiCrFeC + O₂) exhibit a mixed metallic–oxide microstructure with CrNi, CrO, and NiO phases, whereas oxygen-free coatings show only CrNi crystalline peaks. The incorporation of oxygen led to a substantial increase in nano-hardness, from 0.84 GPa for NiCrFeC to 1.59 GPa for NiCrFeC + O₂. Scratch testing up to 100 N indicated improved adhesion and higher critical loads for the oxygen-rich coatings. Tribological measurements performed under dry sliding conditions using a sapphire ball showed a significant reduction in friction: NiCrFeC + O₂ stabilized at ~0.20, while NiCrFeC exhibited values between 0.25 and 0.35 at 0.5 N and 0.4–0.5 at 1 N, accompanied by non-uniform sliding due to coating failure. Wear-track analysis confirmed shallower penetration depths and narrower wear scars for NiCrFeC + O₂, despite similar initial roughness (~35 nm). These findings demonstrate that oxygen incorporation enhances hardness, adhesion, and wear resistance while substantially lowering friction, making NiCrFeC + O₂ coatings promising for low-friction dry-sliding applications. Full article

Al-rich NH₄-ZSM-5 with highly oriented crystals was directly synthesized through a one-pot hydrothermal technique, using ammonium nitrate as a metal-free mineralizer. The samples were characterized by XRD, N₂ adsorption–desorption, SEM, FTIR, Py-FTIR, ²⁷Al MAS NMR, ²⁹Si MAS NMR, ¹H MAS NMR, and TGA techniques. The impact of aluminum source, ammonium source, and H₂O/SiO₂ molar ratio was studied. XRD results showed that the ZSM-5 catalyst with a low Si/Al ratio (13) was successfully synthesized without any amorphous phase, including a microporous/mesoporous structure. A low H₂O/SiO₂ molar ratio (75) resulted in coffin-shape surface morphology, large b-axis-oriented particles (ca. 19 µm), and high specific surface area (>300 m² g⁻¹), providing a large portion of straight channels (90.5%). The catalytic activity of the catalysts was evaluated in the CO₂ hydrogenation reaction in tandem configuration with a Na/Fe₂O₃ catalyst. The results confirmed that highly b-oriented crystals improved the product shape selectivity to p-xylene by affecting the diffusion resistance. Therefore, the developed catalyst provided high CO₂ conversion (45%) and high aromatic selectivity (77%), with p-xylene accounting for 82% of the produced xylene compounds, over a long-term time on stream (17 h). These results demonstrate the effectiveness of the direct synthesis strategy in producing Al-rich ZSM-5 catalysts with tailored textural and acidic properties for tandem and shape-selective catalysis. Full article

Giant magnetostrictive Tb-Dy-Fe alloys are extensively applied in transducers, actuators, and smart sensors owing to their exceptional magnetostrictive response. Nevertheless, in addition to the fracture failure caused by the inherent brittleness of the Laves intermetallic compound, Tb-Dy-Fe alloys also suffer from severe eddy current losses due to low electrical resistivity, both of which limit the practical application of Tb-Dy-Fe alloys. To further enhance the overall performance of Tb-Dy-Fe alloys and expand their application scope, it has become essential to develop materials that exhibit high magnetostrictive properties, high electrical resistivity and excellent mechanical properties simultaneously. In this work, the effects of Al and Si co-addition on the microstructure and multifunctional properties of directionally solidified Tb_0.27Dy_0.73(Fe_0.9Al_0.075Si_0.025)_1.95 (hereafter TDF-AlSi) alloy were systematically investigated. Microstructural characterization revealed that Al partially substitutes Fe atoms in the matrix phase while promoting Al(Tb,Dy)Fe₂ nanocluster, whereas Si preferentially segregated to grain boundary regions forming Tb₂Si₃ and TbSi_1.75 phases. The bending strength of TDF-AlSi alloy was improved from 43 MPa to 65 MPa, an increase of 51.2%, which was attributed to solid solution strengthening by Al and grain boundary reinforcement by Si-rich precipitates. Meanwhile TDF-AlSi alloy exhibits a 2.4 times increase in electrical resistivity (1.619 μΩ·m), resulting in a 49% reduction of total loss at 1000 Hz. The enhancement of electrical resistivity mainly originated from the lattice distortion induced electron scattering by Al substitution and electron impedance at grain boundaries via silicide precipitation. Accompanied by enhancement of mechanical property and electrical resistivity, TDF-AlSi alloy maintained a high magnetostriction strain of 1212 ppm (200 kA/m, 10 MPa pre-compressive stress). The findings of the present study offer valuable theoretical and experimental insights with regard to the optimization of the performance of magnetostrictive Tb-Dy-Fe alloys. Full article

Sulfides are essential tracers for understanding the redox conditions, diffusion processes, and thermal mechanisms involved in the formation of ordinary chondrites. Their mineralogical and textural evolution provides valuable constraints on the metamorphic history of parent bodies. In this context, the Ksar El Goraane meteorite, which fell in Morocco in 2018 and is classified as an H5 ordinary chondrite, represents a particularly instructive case for investigating sulfur behavior during thermal metamorphism. Petrographic observations combined with geochemical data obtained by electron probe microanalysis (EPMA) and energy-dispersive X-ray spectroscopy (EDS) were used to characterize the main silicate and sulfide phases and to evaluate their degree of chemical equilibration. The compositions of olivine (Fa_18–20), Mg-Rich orthopyroxene, and sodic plagioclase (An_10–15) display limited analytical dispersion and well-recrystallized textures, confirming that Ksar El Goraane experienced an equilibrated metamorphic grade consistent with an H5 ordinary chondrite. The sulfide assemblage is dominated by troilite (FeS), iron-rich pyrrhotite (Fe_1−xS), and pentlandite ((Fe,Ni)₉S₈), with minor occurrences of pyrite (FeS₂). Textural relationships and chemical homogeneity observed in backscattered electron images and elemental maps indicate progressive re-equilibration during thermal metamorphism. Formation and transformation temperatures of the sulfide phases are inferred through comparison with experimental and empirical constraints reported in the literature. These results suggest early high-temperature crystallization of troilite, followed by sulfur depletion leading to pyrrhotite formation, subsequent low-temperature exsolution of pentlandite, and localized late-stage pyrite crystallization. Full article

In this work, the effect of Fe and Si content on microstructure, mechanical properties, and corrosion resistance of 7050 alloy was systematically investigated by room temperature tensile, fracture toughness, and exfoliation corrosion tests, complemented by microstructural characterization through SEM and TEM. The results demonstrate that the impurity elements Fe and Si induce the formation of insoluble Fe-rich phases and Mg₂Si phases in the alloy, respectively. The coexistence of Fe and Si leads to a severe synergistic deterioration effect on mechanical properties. Furthermore, the study reveals that Si has a more profound negative impact on mechanical properties than Fe. While Fe primarily reduces ductility and fracture toughness by initiating microcracks through Fe-rich phases with minimal effect on strength, Si not only forms brittle Mg₂Si phases that impair toughness but also significantly depletes the Mg content in the matrix, thereby reducing the quantity of strengthening phases. This results in a comprehensive and severe decline in strength, plasticity, and toughness. In addition, Fe and Si impurities markedly degrade the exfoliation corrosion resistance of the alloy. Full article

The microstructural evolution and phase stability in Fe–Mn–Al alloys play a decisive role in determining their mechanical performance and potential applications. This study investigates the precipitation behavior and crystallography of the β-Mn phase in an Fe–28.6 Mn–10.9 Al (wt.%) alloy subjected to annealing at 1100 °C, followed by water quenching and subsequent isothermal holding at temperatures between 500 °C and 900 °C for 20 h. Microstructural analysis using X-ray diffraction, optical and electron microscopy revealed a single body-centered cubic (BCC) ferritic matrix above 850 °C and the formation of β-Mn precipitates with Widmanstätten side-plate morphology at lower temperatures. The β-Mn phase was thermally stable between ~500 °C and 850 °C, with the volume fraction increasing with temperature and reaching a maximum near 650 °C. The β-Mn precipitates coarsened progressively with increasing temperature and were found to be richer in Mn than the surrounding Fe-rich BCC matrix. Crystallographic analysis established an orientation relationship (OR) of ($02\overline{1}$)_β // (100)_α and [$\overline{1}12$]_β // [012]α, where // denotes nearly parallel alignment, signifying a semi-coherent interface between the two structures. These findings clarify β-Mn precipitation, its interfacial relationship with ferrite, and its thermal stability in high-Mn Fe–Mn–Al alloys, offering guidance for microstructural design in next-generation lightweight steels. Full article

In Al–Fe alloys, the mechanical properties are determined by the morphology of iron-rich phases. In this work, AA8176(Al-1Fe)-nY (n = 0, 0.3, 0.5, 0.7, and 0.9 wt.%) alloys were prepared by the cast method. The effects of yttrium (Y) addition on the microstructure and mechanical properties of AA8176 alloy were studied using various techniques including optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), cooling curve analysis and tensile tests. The results revealed that the optimal refinement effect was achieved when the amount of Y content was 0.5 wt.%. When the Y content increased from 0 to 0.5 wt.%, the coarse needle-like Al₁₃Fe₄ phases were gradually transformed into short rod-like morphology and some fine Al₁₀Fe₂Y phases were formed around the Al₁₃Fe₄ phases. The average length of iron-rich phases was decreased from 10.01 μm to 2.65 μm. Additionally, as the Y content increased from 0 to 0.5 wt.%, the secondary dendrite arm spacing (SDAS) of AA8176 alloy was reduced from 31.33 μm to 20.24 μm. Furthermore, the mechanical properties of the AA8176 alloy were improved due to the modified microstructure. With the addition of 0.5 wt.% Y, the ultimate tensile strength, yield strength, elongation, and Vickers hardness were improved to 96.86 MPa, 57.21 MPa, 23.1%, and 30.55 HV, respectively, compared to 84.47 MPa, 50.71 MPa, 18.6%, and 27.28 HV for the unmodified AA8176 alloy. It is proposed that the growth of α-Al dendrite and Al₁₃Fe₄ phases were effectively inhibited by segregation of Y atoms around α-Al dendrite and Al₁₃Fe₄ phases during solidification. And the Al₁₀Fe₂Y phases were formed by these Y atoms with Al and Fe elements. However, the formation of coarse Al₁₀Fe₂Y phases was promoted by excessive Y content, resulting in a substantial degradation in mechanical properties. Full article

The green synthesis of silver nanoparticles (AgNPs) by bacteria is a strategic route for sustainable nanobiotechnology; however, the genomic and biochemical mechanisms that make it possible remain poorly defined. In this study, bacteria native to silver-bearing mine tailings in Taxco (Mexico) were isolated, capable of tolerating up to 5 mM of AgNO₃ and producing extracellular AgNPs. Spectroscopic (430–450 nm) and structural (XRD, fcc cubic phase) characterization confirmed the formation of AgNPs with average sizes of 17–21 nm. FTIR evidence showed the participation of extracellular proteins and polysaccharides as reducing and stabilizing agents. Genomic analyses assigned the isolates as Lysinibacillus fusiformis 31HCl and L. xylanilyticus G1-3. Genome mining revealed extensive repertoires of genes involved in uptake, transport, efflux and detoxification of metals, including P-type ATPases, RND/ABC/CDF transporters, Fe/Ni/Zn uptake systems, and metal response regulators. Notably, homologues of the silP gene, which encode Ag⁺ translocator ATPases, were identified, suggesting convergent adaptation to silver-rich environments. Likewise, multiple nitroreductases (YodC, YdjA, YfKO) were detected, candidates for mediating electron transfer from NAD(P)H to Ag⁺. These findings support the role of Lysinibacillus as microbial nanofactories equipped with specialized molecular determinants for silver tolerance and AgNP assembly, providing a functional framework for microorganism-based nanobiotechnology applications. Full article