Geochemistry and Mineralogy of Polymetallic Deep-Sea Deposits

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Mineral Deposits".

Deadline for manuscript submissions: 31 July 2026 | Viewed by 994

Special Issue Editors


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Guest Editor
Laoshan Laboratory, Qingdao 266237, China
Interests: deep-sea critical mineral deposits

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Guest Editor
Instituto Oceanográfico, Universidade de São Paulo, Praça do Oceanográfico 191, São Paulo 05508-120, Brazil
Interests: stable isotope geochemistry; marine geochemistry
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Special Issue Information

 Dear Colleagues,

Limited land-based mineral resources will not support sustainable human development in the future. Required resources are largely present, as extrapolated by available data, in the world’s oceans. It is widely believed that deep-sea polymetallic mineral deposits contain enormous volumes of mineral resources, which could make substantial contributions to future raw material supplies. Main types of deep-sea polymetallic deposits include ferromanganese (polymetallic) nodules, ferromanganese (cobalt-rich) crusts, massive seafloor sulfides, and rare-earth elements and yttrium (REY)-rich sediments. Collectively, they are strongly enriched in broadly recognized critical minerals, including Co, Ni, REY, Li, Cu, Mo, and Mn. The formation of these deep-sea deposits has been linked to different geodynamic settings and geological processes. Geochemical and mineralogical studies are urgently required to address the unknown areas of these deposits, which will provide valuable insights into understanding the Earth’s metal cycles and deep-sea mining. In this Special Issue, we welcome the submissions of review and regular research papers that focus on the geochemistry and mineralogy of polymetallic deep-sea deposits to address problems encompassing the distribution and characteristics of polymetallic deep-sea deposits, metal enrichment mechanisms, metal accumulation processes, resource potential assessment, applications of big data and artificial intelligence in studying deep-sea deposits, numerical simulation, deep-ocean exploration, mining, and the ecosystemic factors and environmental impacts of deep-sea mining.

Dr. Yachun Cai
Prof. Dr. Christian Millo
Guest Editors

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Keywords

  • polymetallic deep-sea deposits
  • ferromanganese nodule
  • ferromanganese (cobalt-rich) crusts
  • seafloor massive sulfides
  • rare-earth elements and yttrium (REY)-rich sediments
  • metal resources
  • deep-sea mining

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Published Papers (1 paper)

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Review

23 pages, 4062 KB  
Review
Nanoscale Microstructure and Microbially Mediated Mineralization Mechanisms of Deep-Sea Cobalt-Rich Crusts
by Kehui Zhang, Xuelian You, Chao Li, Haojia Wang, Jingwei Wu, Yuan Dang, Qing Guan and Xiaowei Huang
Minerals 2026, 16(1), 91; https://doi.org/10.3390/min16010091 - 17 Jan 2026
Viewed by 522
Abstract
As a potential strategic resource of critical metals, deep-sea cobalt-rich crusts represent one of the most promising metal reservoirs within oceanic seamount systems, and their metallogenic mechanism constitutes a frontier topic in deep-sea geoscience research. This review focuses on the cobalt-rich crusts from [...] Read more.
As a potential strategic resource of critical metals, deep-sea cobalt-rich crusts represent one of the most promising metal reservoirs within oceanic seamount systems, and their metallogenic mechanism constitutes a frontier topic in deep-sea geoscience research. This review focuses on the cobalt-rich crusts from the Magellan Seamount region in the northwestern Pacific and synthesizes existing geological, mineralogical, and geochemical studies to systematically elucidate their mineralization processes and metal enrichment mechanisms from a microstructural perspective, with particular emphasis on cobalt enrichment and its controlling factors. Based on published observations and experimental evidence, the formation of cobalt-rich crusts is divided into three stages: (1) Mn/Fe colloid formation—At the chemical interface between oxygen-rich bottom water and the oxygen minimum zone (OMZ), Mn2+ and Fe2+ are oxidized to form hydrated oxide colloids such as δ-MnO2 and Fe(OH)3. (2) Key metal adsorption—Colloidal particles adsorb metal ions such as Co2+, Ni2+, and Cu2+ through surface complexation and oxidation–substitution reactions, among which Co2+ is further oxidized to Co3+ and stably incorporated into MnO6 octahedral vacancies. (3) Colloid deposition and mineralization—Mn–Fe colloids aggregate, dehydrate, and cement on the exposed seamount bedrock surface to form layered cobalt-rich crusts. This process is dominated by the Fe/Mn redox cycle, representing a continuous evolution from colloidal reactions to solid-phase mineral formation. Biological processes play a crucial catalytic role in the microstructural evolution of the crusts. Mn-oxidizing bacteria and extracellular polymeric substances (EPS) accelerate Mn oxidation, regulate mineral-oriented growth, and enhance particle cementation, thereby significantly improving the oxidation and adsorption efficiency of metal ions. Tectonic and paleoceanographic evolution, seamount topography, and the circulation of Antarctic Bottom Water jointly control the metallogenic environment and metal sources, while crystal defects, redox gradients, and biological activity collectively drive metal enrichment. This review establishes a conceptual framework of a multi-level metallogenic model linking macroscopic oceanic circulation and geological evolution with microscopic chemical and biological processes, providing a theoretical basis for the exploration, prediction, and sustainable development of potential cobalt-rich crust deposits. Full article
(This article belongs to the Special Issue Geochemistry and Mineralogy of Polymetallic Deep-Sea Deposits)
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