Search Results (13)

In aquaculture production, manual or fixed-schedule feeding often fails to match the real-time feeding level of fish schools, and overfeeding can lead to feed wastage and water-quality deterioration, which has become a major bottleneck for both large-scale farming efficiency and environmental sustainability. During feeding, intense competition and jumping behaviors generate splashes of varying magnitudes, which can serve as an indirect visual proxy for hunger intensity. In this study, we constructed a frame-level splash-annotated dataset and performed data preprocessing. Building upon YOLO11 pretrained weights, we introduced a P2–P5 four-scale detection head to enhance small-splash recognition, injected EGMA into the backbone C3k2 blocks, and replaced stride-2 downsampling convolutions with a three-branch ADown operator. On the validation set, the proposed YOLO11-PEGA achieved a precision of 0.86 and a recall of 0.80, with mAP@0.5 exceeding 0.80 and mAP@0.5–0.95 exceeding 0.30. Compared with the baseline model, the parameter count was reduced by 72.3%. The results demonstrate that the proposed model maintains stable detection and evaluation performance under complex environmental conditions, providing actionable decision support for feeding-threshold setting, feeding-time determination, and feed-amount adjustment. Full article

(1) Background: The ongoing panzootic of highly pathogenic avian influenza virus (HPAIV) of subtype H5N1, clade 2.3.4.4b, has decimated wild/domestic birds and mammals’ populations worldwide with reports of sporadic cases in humans. (2) Methods: This study aimed to compare the mutational profile of H5N1 avian Influenza virus isolated from a Peruvian natural reserve, with recent data from other related international studies made in human and different species of domestic and wild birds and mammals. Briefly, the near complete protein sequences of the Influenza virus coming from a Calidris alba were analyzed at a multisegmented level, together with 55 samples collected between 2022 and 2024 in different countries. Moreover, the glycosylation patterns were also predicted in silico. (3) Results: A total of 603 amino acid changes were found among H5N1 viruses analyzed, underscoring the detection of critical mutations HA:11I, HA:211I, HA:336T, HA:492D, HA:527I, NA:10T, NA:269L, NA:405T, NP:377N, PA:57R, PA:68S, PA:322V/L, PA:432I, PB2:539V, PB1:207R, PB1:375N, PB1:264D, PB1:429R, PA-X:250Q, PB1-F2:65R, and PB1-F2:42Y, as well as PA:13V, PA-X:13V, PA20T, PA-X:20T, PA:36T PA-X:36T, PA:45S, PA-X:45S, PA:57Q, PA-X:57Q, PA:61I, PA-X:61I, PA:68S, PA-X:68S, PA:70V, PA-X:70V, PA:75Q, PA-X:75Q, PA:85T, PA-X:85T, PA:86I, PA-X:86I, PA:100I, PA-X:100I, PA:142E, PA-X:142E, PA:160E, PA-X:160E, PA:211I, PA-X:211Y, among others, considered of importance under the One Health perspective. Similarly, changes in the N-linked glycosylation sites (NLGs) predicted in both HA and NA proteins were found, highlighting the loss/acquisition or changes in some NLGs, such as 209NNTN, 100 NPTT, 302NSSM (HA) and 70NNTN, 68NISS, and 50NGSV (NA). (4) Conclusions: This study provides our understanding about the evolution of current Influenza A viruses H5N1 HPAIV circulating globally. These findings outline the importance of surveillance updating mutational profiles and glycosylation patterns of these highly evolved viruses. Full article

This study investigates the effects of a vibration force field on the mixing and structural properties of polylactic acid (PLA), polybutylene succinate (PBS), and ethylene–glycidyl methacrylate terpolymer (EGMA) blends. A balanced triple-screw dynamic extrusion process was utilized to prepare PLA/PBS/EGMA composites under various vibration parameters, specifically amplitude and frequency. The results indicate that the introduction of a vibration force field significantly enhances the dispersion of the PLA/PBS/EGMA blend, leading to improved mechanical properties, thermal stability, and crystallization behavior. When the vibration frequency was 6 Hz and the amplitude was 1.0 mm, the impact strength increased from the steady-state value of 70.86 KJ/m² to 88.21 KJ/m². When the amplitude was 0.4 mm and the frequency was 10 Hz, the impact strength reached 81.86 KJ/m². The orthogonal experimental design and entropy method analysis revealed that vibration frequency and amplitude play a dominant role in optimizing mechanical performance, whereas processing temperature and rotor speed exhibit minimal impact. Scanning electron microscopy (SEM) analysis confirmed that the vibration force field reduces phase separation, promoting a finer and more homogeneous dispersion of PBS and EGMA within the PLA matrix. Additionally, TGA and DTG curves suggest that when the vibration amplitude and frequency are lower than specific thresholds, the thermal stability of the blend deteriorates. In contrast, when they exceed those thresholds, thermal stability improves. For instance, with an amplitude of 1.0 mm, the initial degradation temperature (T5) climbs from 328.6 °C to 333.7 °C. At a frequency of 10 Hz, T5 reaches 333.1 °C. These findings provide theoretical support for the application of vibration-assisted extrusion in the development of high-performance biodegradable polymer blends. Full article

This study presents the formulation and comprehensive characterization of compatibilized polyamide 6 (PA6)/cyclic olefin copolymer (COC) blends with the aim of developing a self-healing matrix for thermoplastic structural composites. Rheological analysis highlighted the compatibilizing effect of ethylene glycidyl methacrylate (E-GMA), as evidenced by an increase in viscosity, melt strength (MS), and breaking stretching ratio (BSR), thus improving the processability during film extrusion. E-GMA also decreased COC domain size and improved the interfacial interaction with PA6, which was at the basis of a higher tensile strength and strain at break compared to neat PA6/COC blends. E-GMA also significantly boosted the healing efficiency (HE), measured via fracture toughness tests in quasi-static and impact conditions. The optimal healing temperature was identified as 160 °C, associated with an HE of 38% in quasi-static mode and 82% in impact mode for the PA6/COC blends with an E-GMA content of 5 wt% (PA6COC_5E-GMA). The higher healing efficiency under impact conditions was attributed to the planar fracture surface, which facilitated the flow of the healing agent in the crack zone, as proven by fractography analysis. This work demonstrates the potential of E-GMA in fine-tuning the thermomechanical properties of PA6/COC blends. PA6COC_5E-GMA emerged as the formulation with the best balance between processability and self-healing efficiency, paving the way for advanced multifunctional self-healing thermoplastic composites for structural applications. Full article

Spam messages have emerged as a significant issue in digital communication, adversely affecting users’ mental health, personal safety, and network resources. Traditional spam detection methods often suffer from low detection rates and high false positives, underscoring the need for more effective solutions. This paper proposes the EGMA model, an ensemble learning-based hybrid approach for spam detection in SMS messages, which integrates gated recurrent unit (GRU), multilayer perceptron (MLP), and hybrid autoencoder models utilizing a majority voting algorithm. The EGMA model enhances performance by incorporating additional statistical features extracted from message content and employing text vectorization techniques, such as Term Frequency–Inverse Document Frequency (TF-IDF) and CountVectorizer. The proposed model achieved impressive classification accuracies of 99.28% on the SMS Spam Collection dataset, 99.24% on the Email Spam dataset, 99.00% on the Enron-Spam dataset, 98.71% on the Super SMS dataset, and 95.09% on UtkMl’s Twitter Spam dataset. These results demonstrate that the EGMA model outperforms individual models and existing methods in the literature, providing a robust solution for enhancing spam detection performance and effectively mitigating the threats that spam messages pose in digital communication. Full article

This study investigated the self-healing properties of PA6/COC blends, in particular, the impact of three compatibilizers on the rheological, microstructural, and thermomechanical properties. Dynamic rheological analysis revealed that ethylene glycidyl methacrylate (E-GMA) played a crucial role in reducing interfacial tension and promoting PA6 chain entanglement with COC domains. Mechanical tests showed that poly(ethylene)-graft-maleic anhydride (PE-g-MAH) and polyolefin elastomer-graft-maleic anhydride (POE-g-MAH) compatibilizers enhanced elongation at break, while E-GMA had a milder effect. A thermal healing process at 140 °C for 1 h was carried out on specimens broken in fracture toughness tests, performed under quasi-static and impact conditions, and healing efficiency (HE) was evaluated as the ratio of critical stress intensity factors of healed and virgin samples. All the compatibilizers increased HE, especially E-GMA, achieving 28.5% and 68% in quasi-static and impact conditions, respectively. SEM images of specimens tested in quasi-static conditions showed that all the compatibilizers induced PA6 plasticization and crack corrugation, thus hindering COC flow in the crack zone. Conversely, under impact conditions, E-GMA led to the formation of brittle fractures with planar surfaces, promoting COC flow and thus higher HE values. This study demonstrated that compatibilizers, loading mode, and fracture surface morphologies strongly influenced self-healing performance. Full article

In this work, the copolymers ethylene-glycidyl methacrylate (E-GMA), ethylene methyl methacrylate-glycidyl methacrylate (EMA-GMA), and styrene-(ethylene-butylene)-styrene grafted with maleic anhydride (SEBS-g-MA) were used to compatibilize polystyrene (PS)/poly(caprolactone) (PCL) blends. The blends were processed in a co-rotating twin-screw extruder and injection molded. Samples were investigated by torque rheometry, capillary rheometry, impact strength, tensile strength, heat deflection temperature (HDT), dynamic-mechanical thermal analysis (DMTA), thermogravimetry (TG), and scanning electron microscopy (SEM). Torque rheometry indicated that glycidyl methacrylate functional groups and maleic anhydride groups interact with PCL. Capillary rheometry evidenced that at shear rates lower than 10,000 s⁻¹, the PS/PCL/SEBS-g-MA blends presented the highest apparent viscosity among the blends. Such behavior was possibly due to the good interaction between SEBS-g-MA and the PS and PCL phases. Consequently, the properties of impact strength, elongation at break, tensile strength, and elastic modulus were improved by 30%, 109%, 33.8%, and 13.7%, respectively, compared with the non-compatibilized PS/PCL system. There was a reduction in the HDT of all blends compared with neat PS, given the elastomeric characteristics of PCL and compatibilizers. The DMTA results revealed two independent peaks in the blends (one around −53 °C concerning the PCL phase and another at 107 °C related to PS), confirming their immiscibility. The PS/PCL/SEBS-g-MA blends showed higher morphological stability, confirming their good mechanical properties. Full article

The circular economy promotes plastic recycling, waste minimization, and sustainable materials. Hence, the use of agricultural waste and recycled plastics is an eco-friendly and economic outlook for developing eco-designed products. Moreover, new alternatives to reinforce recycled polyolefins and add value to agroindustrial byproducts are emerging to develop processable materials with reliable performance for industrial applications. In this study, post-consumer recycled high-density polyethylene (rHDPE) and ground rice husk (RH) of 20% w/w were blended in a torque rheometer with or without the following coupling agents: (i) maleic anhydride grafted polymer (MAEO) 5% w/w, (ii) neoalkoxy titanate (NAT) 1.5% w/w, and (iii) ethylene–glycidyl methacrylate copolymer (EGMA) 5% w/w. In terms of processability, the addition of RH decreased the specific energy consumption in the torque experiments with or without additives compared to neat rHDPE. Furthermore, the time to reach thermal stability in the extrusion process was improved with EGMA and MAEO compatibilizers. Tensile and impact test results showed that using coupling agents enhanced the properties of the RH composites. On the other hand, thermal properties analyzed through differential scanning calorimetry and thermogravimetric analysis showed no significant variation for all composites. The morphology of the tensile fracture surfaces was observed via scanning electron microscopy. The results show that these recycled composites are feasible for manufacturing products when an appropriate compatibilizer is used. Full article

The aim of this study was to develop a bioimaging probe based on magnetic iron oxide nanoparticles (MIONs) surface functionalized with the copolymer (p(MAA-g-EGMA)), which were radiolabeled with the positron emitter Gallium-68. The synthesis of the hybrid MIONs was realized by hydrolytic condensation of a single ferrous precursor in the presence of the copolymer. The synthesized MagP MIONs displayed an average D_h of 87 nm, suitable for passive targeting of cancerous tissues through the enhanced permeation and retention (EPR) effect after intravenous administration, while their particularly high magnetic content ascribes strong magnetic properties to the colloids. Two different approaches were explored to develop MIONs radiolabeled with ⁶⁸Ga: the chelator-mediated approach, where the chelating agent NODAGA-NHS was conjugated onto the MIONs (MagP-NODAGA) to form a chelate complex with ⁶⁸Ga, and the chelator-free approach, where ⁶⁸Ga was directly incorporated onto the MIONs (MagP). Both groups of NPs showed highly efficient radiolabeling with ⁶⁸Ga, forming constructs which were stable with time, and in the presence of PBS and human serum. Ex vivo biodistribution studies of [⁶⁸Ga]Ga- MIONs showed high accumulation in the mononuclear phagocyte system (MPS) organs and satisfactory blood retention with time. In vivo PET imaging with [⁶⁸Ga]Ga-MagP MIONs was in accordance with the ex vivo biodistribution results. Finally, the MIONs showed low toxicity against 4T1 breast cancer cells. These detailed studies established that [⁶⁸Ga]Ga- MIONs exhibit potential for application as tracers for early cancer detection. Full article

Crystallization kinetics of various blends of poly(lactic acid) (PLA)/polyolefin elastomer (POE) was studied through nonisothermal experimental investigations and theoretical approaches. The PLA/POE blends were prepared in a melt mixing process by using two types of POEs and compatibilizers. The rubber phases used were adopted on the basis of polyethylene (PE) and polypropylene (PP) type olefin elastomers. The effects of two kinds of compatibilizers containing ethylene vinyl acetate copolymer (EVA) and ethylene acrylic ester-glycidyl methacrylate terpolymer (EGMA) on the morphology and various parameters of crystallization of PLA were investigated using scanning electron microscopy (SEM) and differential scanning calorimeter (DSC) measurements, respectively. The morphology investigations on PLA blends containing PP based olefin elastomers showed that the introduction of EGMA compatibilizer into the matrix led to a more than 100% reduction in the size of the rubber droplets. The experimental measurements of crystallization behavior of various PLA/POE blends showed that the POEs and compatibilizers could cause a fall in the initial crystallization temperature more than 13 °C. The theoretical approaches used for studying the kinetics of crystallization of PLA in the presence of various POEs and compatibilizers indicated a decrease in the crystallinity of PLA and a 64% reduction in the activation energy compared to the neat PLA. The results suggest that the largest variation in the crystallization kinetic parameters of PLA was resulted from the PP based olefin elastomer and EGMA compatibilizer. Full article

In this report, poly(lactic acid) (PLA) and Poly(butylene adipate-co-terephthalate) (PBAT) with three kinds of compatibilizers were melt blended under intensive shear flow. A self-made parallel three-screw extruder was developed to generate such flow during the process. Mechanical properties, chemical reactions among PLA, PBAT and compatibilizers, rheological behavior and morphology were investigated. The mechanical tests showed that the notched impact strength of super-tough composite with 10 wt% EGMA is about 20 times than that of pure PLA. The Fourier transform infrared spectroscopy (FT-IR) results showed that the epoxy functional groups or maleic anhydride functional groups of KT-20, KT-915 and EGMA reacted with the hydroxyl groups of PLA or PBAT macromolecules, resulting in a bridge of PLA and PBAT. About rheological properties, the tan δ—angular frequency curves and the η’’- η’ curves confirmed the chemical reactions mentioned above and indicated better compatibility of η’’- η’ between PLA and PBAT, respectively. Meanwhile, the loss modulus and storage modulus—angular frequency curves demonstrated the discrepancy of different compatibilizer components. In particular, from scanning electron microscopy (SEM) images, it can be seen that the phase size and dispersion uniformity of PBAT adjusted by compatibilizer, corresponding to better compatibility that is described in the η’’- η’ curves. The approach for producing super-tough PLA/PBAT/compatibilizer by intensive shear flow provides a viable direction for further improving PLA performance. Full article

As is an excellent bio-based polymer material, poly(lactic acid) (PLA)’s brittle nature greatly restricts its extensive applications. Herein, poly(butylene succinate) (PBS) was introduced to toughening PLA by melt blending using a self-made triple screw extruder through in situ reactive with ethylene-methyl acrylate-glycidyl methacrylate (EGMA). The effect of EGMA concentrations on the mechanical properties, morphology, interfacial compatibility of PLA/PBS blends were studied. Fourier transform infrared (FT-IR) results demonstrated that the epoxy group of EGMA reacts with the hydroxyl groups of PLA and PBS, which proved the occurrence of interfacial reactions among the tri-component. The significantly improved compatibility between PLA and PBS after EGMA incorporation was made evident by scanning electron microscope (SEM) characterization results. Meanwhile, the contact angle test predicted that the EGMA was selectively localized at the interface between PLA and PBS, and the result was verified by morphological analysis of cryofracture and etched samples. The EGMA improves the compatibility of PLA/PBS blends, and consequently leads to a significantly increased toughness with the elongation at break occurring 83 times more when 10 wt % EGMA was introduced than neat PLA, while impact strength also enhanced by twentyfold. Ultimately, the toughening mechanism of PLA based polymers was established based on the above analysis, exploring a new way for the extensive application for degradable material. Full article

The influence of ethylene glycol methacrylate (EGMA) to the hydration and transition behaviors of thermo-responsive interpenetrating polymeric network (IPN) hydrogels containing sodium alginate, N-isopropylacrylamide (NIPAAm), and EGMA were investigated. The molar ratios of NIPAAm and EGMA were varied from 20:0 to 19.5:0.5 and 18.5:1.5 in the thermo-responsive alginate-Ca²⁺/P(NIPAAm-co-EGMA) IPN hydrogels. Due to the more hydrophilicity and high flexibility of EGMA, the IPN hydrogels exhibited higher lower critical solution temperature (LCST) and lower glass transition temperature (T_g) when the ratio of EGMA increases. The swelling/deswelling kinetics of the IPN hydrogels could be controlled by adjusting the NIPAAm/EGMA molar ratio. A faster water uptake rate and a slower water loss rate could be realized by increase the amount of EGMA in the IPN hydrogel (the shrinking rate constant was decreased from 0.01207 to 0.01195 and 0.01055 with the changing of NIPAAm/EGMA ratio from 20:0, 19.5:0.5 to 18.5:1.5). By using 2-Isopropylthioxanthone (ITX) as a photo initiator, the obtained alginate-Ca²⁺/P(NIPAAm-co-EGMA₃₆₀) IPN hydrogels were successfully immobilized on cotton fabrics. The surface and cross section of the hydrogel were probed by scanning electron microscopy (SEM). They all exhibited a porous structure, and the pore size was increased with the amount of EGMA. Moreover, the LCST values of the fabric-grafted hydrogels were close to those of the pure IPN hydrogels. Their thermal sensitivity remained unchanged. The cotton fabrics grafted with hydrogel turned out to be much softer with the continuous increase of EGMA amount. Therefore, compared with alginate-Ca²⁺/PNIPAAm hydrogel, alginate-Ca²⁺/P(NIPAAm-co-EGMA₃₆₀) hydrogel is a more promising candidate for wound dressing in the field of biomedical textile. Full article