Search Results (689)

Minimizing carbon dioxide emissions is crucial due to the generation of energy from fossil fuels. The significance of carbon capture and storage (CCS) technology, which is highly successful in mitigating carbon emissions, has increased. On the other hand, hydrogen is an important energy carrier for storing and transporting energy, and technologies that rely on hydrogen have become increasingly promising as the world moves toward a more environmentally friendly approach. Nevertheless, the integration of CCS technologies into power production processes is a significant challenge, requiring the enhancement of the combined power generation–CCS process. In recent years, there has been a growing interest in process intensification (PI), which aims to create smaller, cleaner, and more energy efficient processes. The goal of this research is to demonstrate the process intensification potential and to model and simulate a hybrid integrated–intensified adsorptive-membrane reactor process for simultaneous carbon capture and hydrogen production. A comprehensive, multi-scale, multi-phase, dynamic, computational fluid dynamics (CFD)-based process model is constructed, which quantifies the various underlying complex physicochemical phenomena occurring at the pellet and reactor levels. Model simulations are then performed to investigate the impact of dimensionless variables on overall system performance and gain a better understanding of this cyclic reaction/separation process. The results indicate that the hybrid system shows a steady-state cyclic behavior to ensure flexible operating time. A sustainability evaluation was conducted to illustrate the sustainability improvement in the proposed process compared to the traditional design. The results indicate that the integrated–intensified adsorptive-membrane reactor technology enhances sustainability by 35% to 138% for the chosen 21 indicators. The average enhancement in sustainability is almost 57%, signifying that the sustainability evaluation reveals significant benefits of the integrated–intensified adsorptive-membrane reactor process compared to HTSR + LTSR. Full article

In chili cultivation, obstacles to continuous cropping significantly compromise crop yield and soil health, whereas crop rotation can enhance the microbial environment of the soil and reduce disease incidence. However, its effects on the diversity of rhizosphere soil microbial communities are not clear. In this study, we analyzed the composition and characteristics of rhizosphere soil microbial communities under chili continuous cropping (CC) and chili–cotton crop rotation (CR) using high-throughput sequencing technology. CR treatment reduced the alpha diversity indices (including Chao1, Observed_species, and Shannon index) of bacterial communities and had less of an effect on fungal community diversity. Principal component analysis (PCA) revealed distinct compositional differences in bacterial and fungal communities between the treatments. Compared with CC, CR treatment has altered the structure of the soil microbial community. In terms of bacterial communities, the relative abundance of Firmicutes increased from 12.89% to 17.97%, while the Proteobacteria increased by 6.8%. At the genus level, CR treatment significantly enriched beneficial genera such as RB41 (8.19%), Lactobacillus (4.56%), and Bacillus (1.50%) (p < 0.05). In contrast, the relative abundances of Alternaria and Fusarium in the fungal community decreased by 6.62% and 5.34%, respectively (p < 0.05). Venn diagrams and linear discriminant effect size analysis (LEfSe) further indicated that CR facilitated the enrichment of beneficial bacteria, such as Bacillus, whereas CC favored enrichment of pathogens, such as Firmicutes. Fusarium solani MG6 and F. oxysporum LG2 are the primary chili root-rot pathogens. Optimal growth occurs at 25 °C, pH 6: after 5 days, MG6 colonies reach 6.42 ± 0.04 cm, and LG2 5.33 ± 0.02 cm, peaking in sporulation (p < 0.05). In addition, there are significant differences in the utilization spectra of carbon and nitrogen sources between the two strains of fungi, suggesting their different ecological adaptability. Integrated analyses revealed that CR enhanced soil health and reduced the root rot incidence by optimizing the structure of soil microbial communities, increasing the proportion of beneficial bacteria, and suppressing pathogens, providing a scientific basis for microbial-based soil management strategies in chili cultivation. Full article

In the context of achieving low-carbon goals, building low-carbon energy systems is a crucial development direction and implementation pathway. Renewable energy is favored because of its clean characteristics, but the access may have an impact on the power grid. Microgrid technology provides an effective solution to this problem. Uncertainty exists in single microgrids, so multiple microgrids are introduced to improve system stability and robustness. Electric carbon trading and profit redistribution among multiple microgrids have been challenges. To promote energy commensurability among microgrids, expand the types of energy interactions, and improve the utilization rate of renewable energy, this paper proposes a cooperative operation optimization model of multi-microgrids based on the green certificate and carbon trading mechanism to promote local energy consumption and a low carbon economy. First, this paper introduces a carbon capture system (CCS) and power-to-gas (P2G) device in the microgrid and constructs a cogeneration operation model coupled with a power-to-gas carbon capture system. On this basis, a low-carbon operation model for multi-energy microgrids is proposed by combining the local carbon trading market, the stepped carbon trading mechanism, and the green certificate trading mechanism. Secondly, this paper establishes a cooperative game model for multiple microgrid electricity carbon trading based on the Nash negotiation theory after constructing the single microgrid model. Finally, the ADMM method and the asymmetric energy mapping contribution function are used for the solution. The case study uses a typical 24 h period as an example for the calculation. Case study analysis shows that, compared with the independent operation mode of microgrids, the total benefits of the entire system increased by 38,296.1 yuan and carbon emissions were reduced by 30,535 kg through the coordinated operation of electricity–carbon coupling. The arithmetic example verifies that the method proposed in this paper can effectively improve the economic benefits of each microgrid and reduce carbon emissions. Full article

Nanofiltration (NF) is considered a competitive purification method for acidic stream treatments. However, conventional thin-film composite NF membranes degrade under acid exposures, limiting their applications in industrial acid treatment. For example, wet-process phosphoric acid contains impurities of multivalent metal ions, but NF membrane technologies for impurity removal under harsh conditions are still immature. In this work, we develop a novel strategy of acid-resistant nanofiltration membranes based on interfacial polymerization (IP) of polyethyleneimine (PEI) and cyanuric chloride (CC) with the s-triazine ring. The IP process was optimized by orthogonal experiments to obtain positively charged PEI-CC membranes with a molecular weight cut-off (MWCO) of 337 Da. We further applied it to the approximate industrial phosphoric acid purification condition. In the tests using a mixed solution containing 20 wt% P₂O₅, 2 g/L Fe³⁺, 2 g/L Al³⁺, and 2 g/L Mg²⁺ at 0.7 MPa and 25 °C, the NF membrane achieved 56% rejection of Fe, Al, and Mg and over 97% permeation of phosphorus. In addition, the PEI-CC membrane exhibited excellent acid resistance in the 48 h dynamic acid permeation experiment. The simple fabrication procedure of PEI-CC membrane has excellent acid resistance and great potential for industrial applications. Full article

Direct air capture (DAC), as a complementary strategy to carbon capture and storage (CCS), offers a scalable and sustainable pathway to remove CO₂ directly from the ambient air. This study presents a detailed evaluation of the amine-functionalised metal-organic framework (MOF) sorbent, mmen-Mg₂(dobpdc), for DAC using a temperature–vacuum swing adsorption (TVSA) process. While this sorbent has demonstrated promising performance in point-source CO₂ capture, this is the first dynamic simulation-based study to rigorously assess its effectiveness for low-concentration atmospheric CO₂ removal. A transient one-dimensional TVSA model was developed in Aspen Adsorption and validated against experimental breakthrough data to ensure accuracy in capturing both the sharp and gradual adsorption kinetics. To enhance process efficiency and sustainability, this work provides a comprehensive parametric analysis of key operational factors, including air flow rate, temperature, adsorption/desorption durations, vacuum pressure, and heat exchanger temperature, on process performance, including CO₂ purity, recovery, productivity, and specific energy consumption. Under optimal conditions for this sorbent (vacuum pressure lower than 0.15 bar and feed temperature below 15 °C), the TVSA process achieved ~98% CO₂ purity, recovery over 70%, and specific energy consumption of about 3.5 MJ/KgCO₂. These findings demonstrate that mmen-Mg₂(dobpdc) can achieve performance comparable to benchmark DAC sorbents in terms of CO₂ purity and recovery, underscoring its potential for scalable DAC applications. This work advances the development of energy-efficient carbon removal technologies and highlights the value of step-shape isotherm adsorbents in supporting global carbon-neutrality goals. Full article

Chronic Coronary Syndrome (CCS) significantly impacts quality of life and increases the risk of adverse cardiovascular events, remaining the leading cause of mortality worldwide. The use of sensor technology in medicine is emerging as a promising approach to enhance the management and monitoring of patients across a wide range of diseases. Recent advancements in engineering and nanotechnology have enabled the development of ultra-small devices capable of collecting data on critical physiological parameters. Several sensors integrated in wearable and implantable devices, instruments for exhaled gas analysis, smart stents and tools capable of real time biochemical analysis have been developed, and some of them have demonstrated to be effective in CCS management. Their application in CCS could provide valuable insights into disease progression, ischemic events, and patient responses to therapy. Moreover, sensor technologies can support the personalization of treatment plans, enable early detection of disease exacerbations, and facilitate prompt interventions, potentially reducing the need for frequent hospital visits and unnecessary invasive diagnostic procedures such as coronary angiography. This review explores sensor integration in CCS care, highlighting technological advances, clinical potential, and implementation challenges. Full article

In the context of the dual-carbon goals, this study proposes a cooperative game-theoretic optimization strategy to enhance the energy utilization efficiency, operational efficiency, and cost-effectiveness of integrated energy systems (IESs) while simultaneously reducing carbon emissions, improving operational flexibility, and mitigating renewable energy variability. To achieve these goals, an IES framework integrating power-to-gas (P2G) technology and carbon capture and storage (CCS) facilities is established to regulate carbon emissions. The system incorporates P2G conversion units and thermal components—specifically, hydrogen fuel cells, electrolyzers, reactors, and electric boilers—aiming to maximize energy conversion efficiency and asset utilization. A cooperative game-theoretic optimization model is developed to facilitate collaboration among multiple stakeholders within the coalition, which employs the Shapley value method to ensure equitable distribution of the cooperative surplus, thereby maximizing collective benefits. The model is solved using an improved gray wolf optimizer (IGWO). The simulation results demonstrate that the proposed strategy effectively coordinates multi-IES scheduling, significantly reduces carbon emissions, facilitates the efficient allocation of cooperation gains, and maximizes overall system utility. Full article

Direct Air Capture (DAC) is emerging as a critical climate change mitigation strategy, offering a pathway to actively remove atmospheric CO₂. This comprehensive review synthesizes advancements in DAC technologies, with a particular emphasis on the pivotal role of nanostructured solid sorbent materials. The work critically evaluates the characteristics, performance, and limitations of key nanomaterial classes, including metal–organic frameworks (MOFs), covalent organic frameworks (COFs), zeolites, amine-functionalized polymers, porous carbons, and layered double hydroxides (LDHs), alongside solid-supported ionic liquids, highlighting their varied CO₂ uptake capacities, regeneration energy requirements, and crucial water sensitivities. Beyond traditional temperature/pressure swing adsorption, the review delves into innovative DAC methodologies such as Moisture Swing Adsorption (MSA), Electro Swing Adsorption (ESA), Passive DAC, and CO₂-Binding Organic Liquids (CO₂ BOLs), detailing their unique mechanisms and potential for reduced energy footprints. Despite significant progress, the widespread deployment of DAC faces formidable challenges, notably high capital and operational costs (currently USD 300–USD 1000/tCO₂), substantial energy demands (1500–2400 kWh/tCO₂), water interference, scalability hurdles, and sorbent degradation. Furthermore, this review comprehensively examines the burgeoning global DAC market, its diverse applications, and the critical socio-economic barriers to adoption, particularly in developing countries. A comparative analysis of DAC within the broader carbon removal landscape (e.g., CCS, BECCS, afforestation) is also provided, alongside an address to the essential, often overlooked, environmental considerations for the sustainable production, regeneration, and disposal of spent nanomaterials, including insights from Life Cycle Assessments. The nuanced techno-economic landscape has been thoroughly summarized, highlighting that commercial viability is a multi-faceted challenge involving material performance, synthesis cost, regeneration energy, scalability, and long-term stability. It has been reiterated that no single ‘best’ material exists, but rather a portfolio of technologies will be necessary, with the ultimate success dependent on system-level integration and the availability of low-carbon energy. The review paper contributes to a holistic understanding of cutting-edge DAC technologies, bridging material science innovations with real-world implementation challenges and opportunities, thereby identifying critical knowledge gaps and pathways toward a net-zero carbon future. Full article

This study combines convolutional neural network (CNN) recognition technology, Greenwich engineering software, and statistical yearbook methods to evaluate rural solar, wind, and biomass energy resources in pilot cities in China, respectively. The CNN method enables the rapid identification of the available roof area, and Greenwich software provides wind resource simulation with local terrain adaptability. The results show that the capacity of photovoltaic power generation reaches approximately 15.63 GW, the potential of wind power is 458.3 MW, and the equivalent of agricultural waste is 433,900 tons of standard coal. The city is rich in wind, solar, and biomass resources. By optimizing the hybrid power generation system through genetic algorithms, wind energy, solar energy, biomass energy, and coal power are combined to balance the annual electricity demand in rural areas. The energy trends under different demand growth rates were predicted through the LEAP model, revealing that in the clean coal scenario of carbon capture (WSBC-CCS), clean coal power and renewable energy will dominate by 2030. Carbon dioxide emissions will peak in 2024 and return to the 2020 level between 2028 and 2029. Under the scenario of pure renewable energy (H_WSB), SO₂/NO_x will be reduced by 23–25%, and carbon dioxide emissions will approach zero. This study evaluates the renewable energy potential, power system capacity optimization, and carbon emission characteristics of pilot cities at a macro scale. Future work should further analyze the impact mechanisms of data sensitivity on these assessment results. Full article

Carbon Capture and Storage (CCS) is a key technology for reducing anthropogenic greenhouse gas emissions, in which pipelines play a vital role in transporting CO₂ captured from industrial emitters to geological storage sites. To aid the efficient and safe operation of the CO₂ transport infrastructure, robust, accurate, and reliable solutions for monitoring pipelines transporting industrial CO₂ streams are urgently needed. This literature review study summarizes the monitoring objectives and identifies the problems and relevant mathematical algorithms developed for optimization of monitoring systems for pipeline transportation of water, oil, and natural gas, which can be relevant to the future CO₂ pipelines and pipeline networks for CCS. The impacts of the physical properties of CO₂ and complex designs and operation scenarios of CO₂ transport on the pipeline monitoring systems design are discussed. It is shown that the most relevant to liquid- and dense-phase CO₂ transport are the sensor placement optimization methods developed in the context of detecting leaks and flow anomalies for water distribution systems and pipelines transporting oil and petroleum liquids. The monitoring solutions relevant to flow assurance and monitoring impurities in CO₂ pipelines are also identified. Optimizing the CO₂ pipeline monitoring systems against several objectives, including the accuracy of measurements, the number and type of sensors, and the safety and environmental risks, is discussed. Full article

This paper examines the impact of carbon capture and storage (CCS) deployment on national carbon intensity (CI) across 43 countries from 2010 to 2020. Using a dynamic common correlated effects (DCCE) log–log panel, we estimate the elasticity of CI with respect to sectoral CCS facility counts within four income-group panels and the full sample. In the high-income panel, CCS in direct air capture, cement, iron and steel, power and heat, and natural gas processing sectors produces statistically significant CI declines of 0.15%, 0.13%, 0.095%, 0.092%, and 0.087% per 1% increase in facilities, respectively (all p < 0.05). Upper-middle-income countries exhibit strong CI reductions in direct air capture (–0.22%) and cement (–0.21%) but mixed results in other sectors. Lower-middle- and low-income panels show attenuated or positive elasticities—reflecting early-stage CCS adoption and infrastructure barriers. Robustness checks confirm these patterns both before and after the 2015 Paris Agreement and between emerging and developed economy panels. Spatial analysis reveals that the United States and United Kingdom achieved 30–40% CI reductions over the decade, whereas China, India, and Indonesia realized only 10–20% declines (relative to a 2010 baseline), highlighting regional deployment gaps. Drawing on these detailed income-group insights, we propose tailored policy pathways: in high-income settings, expand tax credits and public–private infrastructure partnerships; in upper-middle-income regions, utilize blended finance and technology-transfer programs; and in lower-income contexts, establish pilot CCS hubs with international support and shared storage networks. We further recommend measures to manage CCS’s energy and water penalties, implement rigorous monitoring to mitigate leakage risks, and design risk-sharing contracts to address economic uncertainties. Full article

3D (three-dimensional) property volume is an important data carrier for 3D land administration by using 3D cadastral technology, which can be used to express the legal space (property rights) scope matching with physical entities such as buildings and land. A 3D property volume is represented by a dense set of 3D coordinate points arranged in a predefined order and is displayed alongside the parcel map for reference and utilization by readers. To store a 3D property volume in the database, it is essential to record the connectivity relationships among the original 3D coordinate points, the associations between points and lines for representing boundary lines, and the relationships between lines for defining surfaces. Only by preserving the data structure that represents the relationships among points, lines, and surfaces can the 3D property volume in a parcel map be fully reconstructed. This approach inevitably results in the database storage volume significantly exceeding the original size of the point set, thereby causing storage redundancy. Consequently, this paper introduces a reversible 3D property volume compression coding method (called 3DPV-CC) to address this issue. By analyzing the distribution characteristics of the coordinate points of the 3D property volume, a specific rule for sorting the coordinate points is designed, enabling the database to have the ability of data storage and recovery by merely storing a reordered point set. The experimental results show that the 3DPV-CC method has excellent support capabilities for 3D property volumes of the vertical and slopped types, and can compress and restore the coordinate point set of the 3D property volume for drawing 3D parcel maps. The compression capacity of our method in the test is between 23.66% and 38.42%, higher than the general data compression methods (ZIP/7Z/RAR: 8.37–10.32%). By means of this method, land or real estate administrators from government departments can store 3D property volume data at a lower cost. This is conducive to enhancing the informatization level of land management. Full article

The increasing integration of digital technologies in healthcare has expanded the attack surface for privacy violations in critical systems such as electronic health records (EHRs), telehealth platforms, and medical device software. However, current vulnerability detection datasets lack domain-specific privacy annotations essential for compliance with healthcare regulations like HIPAA and GDPR. This study presents C3-VULMAP, a novel and large-scale dataset explicitly designed for privacy-aware vulnerability detection in healthcare software. The dataset comprises over 30,000 vulnerable and 7.8 million non-vulnerable C/C++ functions, annotated with CWE categories and systematically mapped to LINDDUN privacy threat types. The objective is to support the development of automated, privacy-focused detection systems that can identify fine-grained software vulnerabilities in healthcare environments. To achieve this, we developed a hybrid construction methodology combining manual threat modeling, LLM-assisted synthetic generation, and multi-source aggregation. We then conducted comprehensive evaluations using traditional machine learning algorithms (Support Vector Machines, XGBoost), graph neural networks (Devign, Reveal), and transformer-based models (CodeBERT, RoBERTa, CodeT5). The results demonstrate that transformer models, such as RoBERTa, achieve high detection performance (F1 = 0.987), while Reveal leads GNN-based methods (F1 = 0.993), with different models excelling across specific privacy threat categories. These findings validate C3-VULMAP as a powerful benchmarking resource and show its potential to guide the development of privacy-preserving, secure-by-design software in embedded and electronic healthcare systems. The dataset fills a critical gap in privacy threat modeling and vulnerability detection and is positioned to support future research in cybersecurity and intelligent electronic systems for healthcare. Full article

This study is devoted to a comprehensive technical and economic assessment of the prospects for the development of the oil and gas sector in the Republic of Mozambique in the context of the global energy transition. The analysis of key gas projects, including Coral South FLNG and Mozambique LNG, focused on their technological features, economic parameters and environmental impact. It is shown that the introduction of floating liquefaction technology reduces capital expenditures, increases operational flexibility, and minimizes infrastructure risks, especially in conditions of geopolitical instability. Based on a comparative analysis of the projects, it was found that the use of modular solutions and the integration of carbon capture and storage (CCS) systems contribute to improving sustainability and investment attractiveness. A patent analysis of technological innovations was carried out, which made it possible to substantiate the prospects for using nanotechnologies and advanced CO₂ capture systems for further development of the sector. The results of the study indicate the need to strengthen content localization, develop human capital, and create effective revenue management mechanisms to ensure sustainable growth. The developed strategic development concept is based on the principles of the sixth technological paradigm, which implies an emphasis on environmental standards and technological modernization, including on the basis of nanotechnology. Thus, it is established that the successful implementation of gas projects in Mozambique can become the basis for long-term socio-economic development of the country, provided that technological and institutional innovations are integrated. Full article

Freezing of gait (FOG) is a disabling symptom associated with Parkinson’s disease (PD). Its understanding and effective treatment is compromised due to the difficulty in reliably triggering FOG in clinical and laboratory environments. The Cleveland Clinic-Virtual Home Environment (CC-VHE) platform was developed to address the challenges of eliciting FOG by combining an omnidirectional treadmill with immersive virtual reality (VR) environments to induce FOG under physical, emotional, and cognitive triggers. Recent developments in deep brain stimulation devices that sense neural signals from the subthalamic nucleus in real time offer the potential to understand the underlying neural mechanism(s) of FOG. This manuscript presents the coupling of the CC-VHE technology, VR paradigms, and the experimental and analytical methods for recording and analyzing synchronous cortical, subcortical, and kinematic data as an approach to begin to understand the nuanced neural pathology associated with FOG. To evaluate the utility and feasibility of coupling VR and neural sensing technology, initial data from one participant are included. Full article