Search Results (61)

This study integrates LA-ICP-MS zircon U–Pb ages and the first zircon trace element data from metasedimentary and metaigneous rocks of the Nyong Complex (NyC) in the NW Congo Craton, southern Cameroon, to constrain its petrogenesis, tectonic setting, and crustal evolution. Chondrite-normalized REE patterns show strong HREE enrichment, depleted LREE–MREE, and pronounced positive Ce and negative Eu anomalies, indicating a magmatic origin for the zircons. Trace element signatures suggest that the zircons derived from continental crustal magmas generated under variable oxidation conditions in a long-lived arc-related tectonic environment. Detrital zircon ages range from Archean to Paleoproterozoic, with five major age peaks at 2885 ± 8 Ma, 2775 ± 6 Ma, 2654 ± 7 Ma, 2469 ± 11 Ma, and 2316 ± 11 Ma. These ages correspond to major magmatic and metamorphic events recognized in both the Congo and São Francisco cratons. The preservation of felsic continental crust between 2.9 and 2.2 Ga in the NyC and the Borborema Province (NE Brazil) likely records a critical transition in Earth’s geodynamic regime, marked by enhanced consumption and recycling of mafic crust during Proterozoic accretion compared to the late Archean. This transition reflects the onset of modern-style plate tectonics, enabling craton stabilization and contributing to the assembly of the Nuna/Columbia supercontinent. The NyC is thus interpreted as part of the Trans-Amazonian belt, analogous to that in NE Brazil, and formed during the collision between the Congo and São Francisco cratons. Full article

To reveal the evolution of the North China Craton (NCC) and the breakup process of the Columbia supercontinent, this study conducted zircon geochronology and garnet mineralogical analyses on kimberlites from the Bayan Obo area, on the northern margin of the NCC. Zircon U-Pb dating yielded four groups of concordant ages: 2505 ± 46 Ma, 2210 ± 57 Ma, 1928 ± 58 Ma, and 1455 ± 88 Ma. Among these, 1455 ± 88 Ma represents the formation age of the kimberlite, corresponding to a regional extensional tectonic setting. The other three groups are xenocrystic zircon ages, recording the formation of the Archean basement of the NCC, extensional magmatic activity in the middle Paleoproterozoic, and collisional metamorphic events in the late Paleoproterozoic, respectively. The major element characteristics of the garnets indicate they are granulite-facies crust-derived garnets (G4 type), formed under temperature and pressure conditions of 791 ± 50–876 ± 50 °C and 14 ± 3.0 kbar. This corresponds to a mantle heat flow value of approximately 60 ± 5 mW/m², suggesting an unstable state of the lithosphere in the study area. Combined with the regional geological background, the depositional age of the Bilute Formation in Bayan Obo is determined to be between 1455 and 1524 Ma. The emplacement of kimberlite is related to extensional rifting driven by the breakup of the Columbia supercontinent, and garnets hosted in kimberlite record the crustal extension and mantle magma underplating during the rift-spreading stage of this period. This study provides key petrological and chronological evidence for the tectonic evolution of the northern margin of the NCC and the breakup of the Columbia supercontinent. Full article

The Atlantic City–South Pass (ACSP) orogenic gold district, Wind River Mountains, Wyoming, occurs in the Archean South Pass Greenstone Belt primarily within greywackes and igneous rocks metamorphosed to the upper greenschist–lower amphibolite facies. Approximately 10 Mt of gold has been produced from pyrite and arsenopyrite-bearing quartz veins in deformation zones at the brittle–ductile transition. Multiple generations of primary and/or pseudosecondary fluid inclusions in gold-bearing quartz veins include one- and two-phase gaseous CO₂-CH₄ ± N₂ inclusions and two- and three-phase gaseous CO₂-CH₄-H₂O inclusions with rare NaCl daughter minerals. These primary/pseudosecondary inclusions show a broad range of homogenization temperatures (T_h) of 177.2 to 420.0 °C, with salinities of halite-bearing inclusions of >26 wt. % NaCl, with a high concentration of CaCl₂. Secondary aqueous inclusions formed at lower values of T_h (80.9 to 243.4 °C, with one outlier of 301.1 °C). Carbon from graphitic schists associated with gold-quartz veins yields values of δ¹³C = −28.5 to −19.1 per mil, suggesting that the light C isotope compositions of some carbonates (δ¹³C = −11.0 to −1.5 per mil) involved exchange reactions with graphite in the schists. Isotopic compositions of sulfur in sulfides (δ³⁴S = −1.0 to 3.6 per mil), oxygen in vein quartz (δ¹⁸O = 7.36 to 10.38 per mil), and hydrogen in fluid inclusions in vein quartz (δD = −125 to −55 per mil) are permissive of both magmatic-hydrothermal and metamorphic dehydration models for the origin of gold mineralization. However, a potential source of magmatic–hydrothermal fluids, the post-metamorphic Louis Lake granodiorite was unlikely to transport gold in a vapor state to become focused into shear zones as previously proposed. We favor a metamorphic dehydration model in which gold was derived from the South Pass supracrustal sequence and deposited in second-order shear zones that are spatially related to the first-order Roundtop Mountain Deformation Zone. Full article

Recent discoveries of fluorite–barite deposits in the Donghai–Linshu area in northern Jiangsu Province, China, underscore the region’s mineral potential, yet detailed geological investigations remain limited. In this study, we examined monzonite and quartz monzonite from drill cores in the Jiashan mining area using petrography, U–Pb zircon dating, zircon trace element geochemistry, whole-rock geochemistry, and zircon Lu–Hf isotopes. Laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) zircon U–Pb analyses were conducted to constrain the crystallization ages of the monzonite (127.06 ± 0.54 Ma and 126.83 ± 0.75 Ma) and quartz monzonite (127.2 ± 0.5 Ma and 128.59 ± 0.62 Ma) to the Early Cretaceous, marking a significant magmatic event. Many of the zircons contain inherited Neoproterozoic cores (718–760 Ma and 800–860 Ma), indicating the assimilation of deep crustal materials of this age. The monzonite is metaluminous, with moderate SiO₂ (61.61–62.41 wt.%), high alkalis (Na₂O + K₂O = 7.48–7.92 wt.%), and A/CNK = 0.72–0.91. The quartz monzonite has higher SiO₂ (66.26–68.18 wt.%) and alkalis (8.32–9.33 wt.%). Both rock types exhibit similar trace and rare earth element patterns: enrichment in large-ion lithophile and light rare earth elements, depletions in Nb, Ta, and Ti, no significant Zr-Hf depletion, and weak negative Eu anomalies (δEu ≈ 0.84–1.00). Their low Zr + Nb + Ce + Y contents, Ga/Al ratios, and TFeO/MgO ratios indicate that they have an I-type granite affinity. The Early Cretaceous zircons have highly negative ε_Hf(t) values (−33.7 to −23.5) and ancient two-stage model ages (2622–3247 Ma), which are consistent with derivation from Archean crust. The inherited Neoproterozoic zircons have younger Paleo–Mesoproterozoic T_DM2 ages. The evidence suggests that both intrusions were mainly generated by partial melting of ancient Archean basement, with minor mantle input. The magma generation was likely triggered by crustal anatexis induced by the underplating of mantle-derived magmas in an extensional tectonic regime, coeval with Early Cretaceous magmatism in the Sulu orogen. Full article

The age, provenance, and evolution of some terranes in the Klamath Mountains are poorly constrained because of low detrital zircon yields. We present petrography and 947 new detrital and igneous zircon U-Pb ages from the North Fork (NFT), Eastern Hayfork (EHT), and Western Hayfork (WHT) terranes in the central and southern Klamath Mountains. Chert and argillite are abundant in the NFT and EHT, but matrix sandstones with abundant Proterozoic-to-Archean zircon ages indicate that the EHT received more sediment from North America. Detrital zircon ages from the WHT are ~171 Ma with scattered pre-Mesozoic ages, consistent with previous ages and continental input. A younger population of three grains at 145 Ma is interpreted as Pb loss during metamorphism. In the southernmost EHT, a 143 Ma dike correlates with plutons in the northern Sierra Nevada, which were offset from the Klamath Mountains 140–130 Ma. A 158 Ma metavolcanic/metavolcaniclastic rock in the EHT is a possible extrusive equivalent of the Wooley Creek intrusive suite. The metamorphosed EHT matrix has a young population of six ages at 69 Ma, which we tentatively interpret may represent Pb loss during metamorphism. This study documents an exposure of Late Jurassic arc cover sequence and suggests there may be previously unrecognized local metamorphism/magmatism ≤69 Ma. Full article

Detrital zircon U–Pb dating from the Muti Formation sheds light on sediment sources and foreland basin development along the northeastern Arabian margin during the Late Cretaceous. The siliciclastic-rich Muti Formation was deposited in a syn-obduction foreland basin that formed as the Semail Ophiolite advanced. Zircon age spectra from eastern (Nakhal and Sayga) and western (Murri) sections are dominated by Neoproterozoic–Cambrian ages (450–900 Ma), linked to the Pan-African orogeny and the Arabian–Nubian Shield, indicating these as the main sediment sources. The Murri section also contains older Mesoproterozoic to Archean zircons, likely recycled from the Nafun Group (part of the Huqf Supergroup), suggesting reworking of ancient Gondwanan cover sequences rather than direct input from the Indian craton. Additional Permian zircons reflect input from Arabian Plate magmatic rocks, while Jurassic–Cretaceous grains indicate material derived from the Semail Ophiolite and related arc terranes. Overall, the Muti Formation records a mixed sediment supply from the Arabian Shield, reworked Gondwanan sandstones, and ophiolitic detritus, marking the transition from a passive margin to a flexural foreland basin. The dominance of Pan-African zircon ages highlights continued recycling of Gondwanan sequences and refines models of Late Cretaceous basin evolution in northern Oman, underscoring the complex, multi-cycle nature of sedimentation in this tectonically active setting. Full article

The West Qinling Orogenic Belt (WQOB) contains a sedimentary succession that is approximately 15 km thick, spanning from the Carboniferous to the Jurassic period. This succession offers critical insights into the tectonic evolution of the Paleo-Tethys Ocean. While previous models have suggested various depositional environments, the late Paleozoic to Mesozoic tectonic evolution of the WQOB is still not fully understood. In this study, we incorporate new detrital zircon U-Pb age data and whole-rock geochemical analyses from six stratigraphic units, dating back to the Carboniferous to Triassic periods in the Xiahe–Hezuo region, alongside existing datasets. The detrital zircon age spectra from the WQOB reveal three distinct groups: Devonian–Carboniferous strata exhibit dominant Neoproterozoic (~800–900 Ma) zircon populations, whereas Permian–Triassic rock samples show prominent Paleoproterozoic (1840–1880 Ma) and Archean (2450–2500 Ma) peaks. A minor Neoproterozoic component in Permian spectra disappears by the Triassic, while Jurassic–Cretaceous assemblages lack Precambrian grains. These trends reflect evolving source terranes linked to Paleo-Tethyan subduction dynamics. Furthermore, the geochemical signatures of the Devonian–Triassic clastic rocks align with the composition of upper continental crust, indicating a tectonic relationship with continental island arcs and active continental margins. By synthesizing these findings with established detrital zircon ages, magmatic records, and geophysical data, we propose that the WQOB underwent pre-Triassic tectonic evolution that was marked by pre-Triassic subduction and localized extension during the process of continental underthrusting. Full article

The Jiapigou mining district, a world-famous gold-producing district with a capacity that greatly exceeds 180 t Au, has a mining history longer than 200 years. The large amount of Jurassic Au mineralization in this district significantly differs from that in other districts of the North China Craton (130–115 Ma). However, the deep-seated dynamic processes and mechanisms that triggered the unique Jurassic mineralization in the Jiapigou district are poorly understood. Here, we present new data on the geology, petrography, and zircon U–Pb and Lu–Hf isotopes of the typical Huangnihe pluton in the Jiapigou district to address the above issues. The results revealed the following: (1) The Huangnihe pluton comprises mainly fine-grained granite and porphyritic granite, which were emplaced at 187 ± 2 Ma (n = 13) and 166 ± 2 Ma (n = 15), respectively. (2) The Hf isotope data indicate that the two episodes of granites exhibit distinct origins: the former (εHf(t) = −1.4 to +5.3; T_DM2 = 1784–1181 Ma) originated from juvenile lower crust, whereas the latter (εHf(t) = −14.9 to −9.7; T_DM2 = 2987–2518 Ma) was derived from Archean crust. (3) On the basis of published geochemical data, the estimated crustal thicknesses of the Jiapigou district ca. 187 Ma, ca. 175 Ma, and ca. 166 Ma ranged from 45 to 52 km, 43 km, and 58 to 63 km, respectively. Combined with regional observations, the results of this study further reveal the following: (1) The Jurassic magmatism in the Jiapigou district can be subdivided into three episodes: 187–186 Ma, ca. 175 Ma, and 166–165 Ma. (2) The crust in the Jiapigou district gradually thickened during the Jurassic and underwent partial melting during multiple episodes of Paleo-Pacific Plate subduction, thereby generating arc-like calc-alkaline (ca. 187 Ma), adakite-like (ca. 175 Ma), and adakite magmas (ca. 166 Ma) that were emplaced to form corresponding granitoids. Moreover, syn-ore magma mixing between the ca. 175 Ma adakite-like felsic magma and mantle-derived mafic magmas was considered a crucial process in magma evolution. This process in turn promoted the enrichment of ore-forming elements within the magma system, which significantly contributed to the formation of the large Au mineralization in the Jiapigou district. Full article

The Huoqiu Group is located in the southern margin of the North China Craton and is considered an Archean geologic body. Its supracrustal rocks are divided into the Huayuan, Wuji, and Zhouji formations in ascending order. The Wuji and Zhouji formations contain large BIF-type iron deposits. The BIFs show geological and geochemical features of Paleoproterozoic Lake Superior-type rather than Archean Algoma-type. The study of the formation ages and evolutionary history of the Huoqiu Terrane will provide significant guidance for the mineralization and exploration of the Huoqiu iron deposits. In this paper, we collected all available isotopic ages and Hf isotopic compositions obtained from the Huoqiu Terrane and reassessed their accuracy and geological meanings. We conclude that the Wuji and Zhouji formations were not older than 2343 Ma. Therefore, the BIFs hosted in the Wuji and Zhouji formations must be of Paleoproterozoic age. The magmatic zircons from the TTG gneisses and granite yield U-Pb ages of Neoarchean Era, indicating that the Wuji and Zhouji formations of the Huoqiu Group were deposited on an Archean granitic basement that mainly comprises the trondhjemite-tonalite-granodiorite (TTG) gneisses and granites of the “Huayuan Formation”. The Early Precambrian crystalline basement in the Huoqiu area can be divided into the Huayuan Gneiss Complex and the Huoqiu Group, comprising the Wuji and Zhouji formations. The tectonic scenario of granitic complexes overlain by supracrustal rocks in the Huoqiu Terrane has been recognized in the Songshan, Zhongtiao, Xiaoshan, and Lushan Early Precambrian terranes in the southern margin of the North China Craton. As indicated by the zircon U-Pb ages and εHf(t) data, the crustal growth of the Huoqiu Terrane occurred mainly at ~2.9 Ga and ~2.7 Ga. Based on the sedimentary age, environment, and rhythm, the BIFs in the Huoqiu region are considered to be of Lake Superior type and of great potential for Fe ore exploration. Full article

We report information on the protolith, the Triassic retrograde metamorphism, and anatexis recorded in zircons extracted from granitic gneiss and biotite schist in the Sulu orogenic zone, central China. The schist is enclosed within the granitic gneiss in the form of a lens. Zircon grains from the schist sample indicate anatexis occurred at 214.6 ± 3.6 Ma (MSWD = 5.1), with ε_Hf (t) values ranging from −22.6 to −18.3, corresponding to T_DM^C(Hf) ages between 2675 Ma and 2407 Ma. The granitic gneiss originated from magmatic rock formed at 774 ± 32 Ma (MSWD = 5.7) and subsequently underwent metamorphism at ~211 Ma. Three zircon cores from the granitic gneiss exhibit ε_Hf (t) values ranging from −13.6 to −6.3, with T_DM ^C(Hf) ages spanning 2487–2075 Ma. Six zircon rims from the gneiss yield ε_Hf (t) values of −14.7 to −13.3, and T_DM ^C(Hf) ages ranging from 2176 to 2092 Ma. We believe that the protolith of granitic gneiss is the Neoproterozoic magmatic rock, whose tectonic affinity is the northern margin of the Yangtze craton. The granitic gneiss experienced Triassic collisional orogeny-related metamorphism and subsequent retrograde metamorphism, with the timing of retrograde overprinting consistent with zircon-recorded anatexis in the schist. In addition, the protoliths of both the gneiss and schist exhibit close affinity to Archean-Paleoproterozoic crustal sources. Full article

Archean craton comprises ancient and stable continental lithosphere, lacking significant seismic activity, magmatic activity, and tectonic deformation. Typically, its lithospheric mantle exhibits high electrical resistivity. However, within the Archean Tanzanian cratonic mantle, a high conductivity layer has been discovered, with an electrical conductivity of approximately 0.1 S/m. We conducted the electrical conductivity experiments on olivine aggregates containing sodium carbonate at the pressure of 3 GPa and the temperature ranging from 600 to 1200 °C. It was found that a very small amount of alkali-carbonate melt can significantly increase the electrical conductivity of dunite. The mass fraction of alkali-carbonate melt is less than 2.0 wt% in the highly conductive layer of the Tanzanian cratonic mantle. The permeability barriers made the melts preserve within the depth range of 80 to 120 km. Therefore, the presence of alkali-rich carbonate melts may be the best mechanism to explain the high conductivity anomaly in the lithospheric mantle of the Tanzanian craton. In contrast, the carbonate melts with high mobility migrated directly to shallow depths along fractures in the mobile belt/rift zone, leaving a dry and resistive residual mantle. Full article

The Mesoproterozoic (~1470 Ma) Wolf River batholith (WRB) is exposed over 6500 km², encompassing 11 plutons that crosscut the Archean Marshfield and Proterozoic Penokean terranes. As the WRB is the classically defined anorogenic batholith, to test this hypothesis, seven igneous phases were analyzed using anisotropy of magnetic susceptibility (AMS), as a proxy for magmatic flow during intrusion, and the samples recorded a sub-horizontal emplacement in six different orientations. Paleopoles from six of eight igneous samples preserve a wide variety of sub-vertical orientations with two reversed and four normal polarities. The synorogenic Baldwin Conglomerate is the youngest rock (<1460 Ga) associated with WRB. Magnetic fabrics are horizontal, but multidomain and paleopole signatures, where interpretable, are sub-vertical. The North American APWP places middle Laurentia at low-latitude during Geon 14, and all our paleopoles are sub-vertical, not sub-horizontal, again suggesting post-intrusion deformation. Moreover, the McCauley gneiss (1886 Ma; U-Pb zircon), Rib Mountain Quartzite (1750 Ma MDA; U-Pb zircon, n = 150), Dells of the Eau Claire rhyolite (1483 Ma; U-Pb zircon, 1469 Ma; monazites-in-garnet), and Baldwin conglomerate (1460 Ma MDA; U-Pb zircons, n = 150) are sub-vertical inliers (xenoliths) in the igneous suite; the Proterozoic Wausau turbidite (1850 Ma MDA; U-Pb zircon, n = 150) was intruded by the WRB and dips 25°W. Here, we present a reinterpretation of the WRB as a deformed synorogenic rather than an anorogenic intrusion. Full article

Characterizing alteration and its geochemical signature provides critical information relevant to ore-deposit genesis and its related footprint; for porphyry-type deposits, zoned potassic-phyllic-propylitic alteration and metal enrichment are critical features. Here we integrate earlier lithological and mineralogical studies of the (10+ Moz Au) Archean Côté Gold porphyry-type Au(-Cu) deposit (Ontario, Canada) with identified alteration types to provide exploration vectors. The ca. 2740 tonalite-quartz diorite-diorite intrusive complex and co-temporal Au(-Cu) mineralization as disseminations, breccias and veins are co-spatial with ore-related alteration types (amphibole, biotite, muscovite). An early, locally developed amphibole event coring the deposit is followed by emplacement of a Au(-Cu) mineralized biotite-rich magmatic-hydrothermal breccia body and broad halo of disseminated biotite and quartz veining. These rocks record gains via mass balance calculations of K, Fe, Mg, LILE, and LREE with Au, Cu, Mo, Ag, Se and Bi. Later muscovite alteration is enriched in K, Rb, Cs, Ba, CO₂, and LOI with varied Au, Cu, Mo, Te, As, and Bi values. A strong albite overprint records extreme Na gains with the loss of most other elements, including ore metals (i.e., Au, Cu). Together these data define an Au-Cu-Mo-Ag-Te-Bi-Se core co-spatial with biotite breccia versus a peripheral stockwork and sheeted vein zone with a Te-Se-Zn-Pb-As association. These features further support the posited porphyry-type model for the Côté Gold Au(-Cu) deposit. Full article

The Xiangluwanzi gold deposit, located in the southern Jilin Province of Northeast China, is hosted within the Jurassic Guosong Formation, and surrounded by Archean granitoids. The ore bodies are governed by near-EW and NE-trending faults. Four alteration/mineralization stages have been distinguished: I, pyrite–sericite–quartz; II, gold–pyrite–quartz; III, sphalerite–quartz–carbonate; and IV, quartz–carbonate. Four types of fluid inclusions (FIs) were identified: pure CO₂, CO₂-rich, CO₂-bearing, and NaCl–H₂O fluid inclusions. Stage-I quartz veins contain all FIs, whereas stage II quartz veins host CO₂-rich, CO₂-bearing, and NaCl-H₂O FIs. Only NaCl–H₂O FIs were present in stages-III and -IV quartz veins. The homogenization temperatures of the FIs range, respectively, from 233 to 279, 185–242, 171–217, and 148–170 °C in stages I–IV, having salinities of 2.62–8.54, 2.81–7.58, 4.32–6.58, and 3.37–5.25 wt% NaCl equivalents, respectively. The H (−93.5‰ to −75.9‰) and O (^δ18O_H2O = −5.8‰ to 4.6‰) isotopic compositions suggest magmatic water was gradually diluted by meteoric water. Carbon isotopic values (22.8‰ to −17.8‰) suggest the incorporation of organic carbon from surrounding strata via water–rock interactions. Fluid boiling, fluid mixing, and water–rock interactions are the primary mechanisms driving mineral precipitation. Full article

The Neoarchean diorite- and tonalite-dominated Chibougamau pluton (Canada) is ideal for case studies dedicated to the petrogenesis and timing of emplacement of fertile magmatic systems and associated Cu-Au porphyry systems. Using whole-rock analyses, geochronology, and zircon chemistry, it is determined that an early magmatic phase (pre-2714 Ma) is derived from a dioritic magma with a moderate ƒO₂ (ΔFMQ 0 to +1), which is optimal for transporting Au and Cu, and that diorite is a potentially fertile magma. Field descriptions indicate that the main mineralizing style consists of sulfide-filled hairline fractures and quartz–carbonate veins. This is likely the consequence of fluid circulation facilitated by a well-developed diaclase network formed following the intrusion of magma at about 4–7 km depth in a competent hosting material. The petrographic features of fluid inclusions (FIs), considered with their microthermometric data and evaporate mound chemistry, suggest the exsolution of early CO₂-rich fluids followed by the unmixing of later aqueous saline fluids characterized by a magmatic signature (i.e., Na-, Ca-, Fe-, Mn-, Ba-, and Cl-F). The type of magmatism and its oxidation state, age relationships, the nature of mineralization, and fluid chemistry together support a model whereby metalliferous fluids are derived from an intermediate hydrous magma. This therefore enforces a porphyry-type metallogenic model for this Archean setting. Full article