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Search Results (285)

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Keywords = Accelerated Failure Time model

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56 pages, 732 KB  
Review
The Erosion of Cybersecurity Zero-Trust Principles Through Generative AI: A Survey on the Challenges and Future Directions
by Dan Xu, Iqbal Gondal, Xun Yi, Teo Susnjak, Paul Watters and Timothy R. McIntosh
J. Cybersecur. Priv. 2025, 5(4), 87; https://doi.org/10.3390/jcp5040087 - 15 Oct 2025
Viewed by 324
Abstract
Generative artificial intelligence (AI) and persistent empirical gaps are reshaping the cyber threat landscape faster than Zero-Trust Architecture (ZTA) research can respond. We reviewed 10 recent ZTA surveys and 136 primary studies (2022–2024) and found that 98% provided only partial or no real-world [...] Read more.
Generative artificial intelligence (AI) and persistent empirical gaps are reshaping the cyber threat landscape faster than Zero-Trust Architecture (ZTA) research can respond. We reviewed 10 recent ZTA surveys and 136 primary studies (2022–2024) and found that 98% provided only partial or no real-world validation, leaving several core controls largely untested. Our critique, therefore, proceeds on two axes: first, mainstream ZTA research is empirically under-powered and operationally unproven; second, generative-AI attacks exploit these very weaknesses, accelerating policy bypass and detection failure. To expose this compounding risk, we contribute the Cyber Fraud Kill Chain (CFKC), a seven-stage attacker model (target identification, preparation, engagement, deception, execution, monetization, and cover-up) that maps specific generative techniques to NIST SP 800-207 components they erode. The CFKC highlights how synthetic identities, context manipulation and adversarial telemetry drive up false-negative rates, extend dwell time, and sidestep audit trails, thereby undermining the Zero-Trust principles of verify explicitly and assume breach. Existing guidance offers no systematic countermeasures for AI-scaled attacks, and that compliance regimes struggle to audit content that AI can mutate on demand. Finally, we outline research directions for adaptive, evidence-driven ZTA, and we argue that incremental extensions of current ZTA that are insufficient; only a generative-AI-aware redesign will sustain defensive parity in the coming threat cycle. Full article
(This article belongs to the Section Security Engineering & Applications)
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16 pages, 5347 KB  
Article
Numerical Assessment of a High-Level Rock Failure Potential Based on a Three-Dimensional Discrete Element Model
by Xin Zhou, Yiding Bao, Weifeng Zhang and Renzhe Zeng
ISPRS Int. J. Geo-Inf. 2025, 14(10), 402; https://doi.org/10.3390/ijgi14100402 - 15 Oct 2025
Viewed by 267
Abstract
The estimation of the area susceptible to rock failure and the prediction of its movement process are pivotal for hazard mitigation, yet they are also challenging. In this study, we proposed a novel integrated method combining field investigation, remote sensing, and three-dimensional discrete [...] Read more.
The estimation of the area susceptible to rock failure and the prediction of its movement process are pivotal for hazard mitigation, yet they are also challenging. In this study, we proposed a novel integrated method combining field investigation, remote sensing, and three-dimensional discrete element method (DEM) simulation to achieve our goal. The field investigation and remote sensing analysis are used for the purpose of ascertaining the deformation phenomenon and the structure of the rock slope, identifying the potential failure position and area of the slope. Subsequently, a three-dimensional DEM simulation is employed to quantitatively assess the potential rock failure-affected area and movement process, based on the above potential failure information. The simulation results demonstrate that potential rock failure persists for approximately 30 s, and its movement process can be categorized into two distinct stages: acceleration and deceleration. The initial acceleration stage is characterized by a duration of 10 s, culminating in a peak average velocity of 13 m/s. The subsequent deceleration stage extends for a duration of 20 s. Notably, the maximum attainable velocity for the segment of rock mass under consideration is estimated to be 50 m/s. Furthermore, the model demonstrates the variation in fracture energy, friction energy, and kinetic energy over time. The potential affected area is 140,000 m2, and approximately 8000 m2 of residential construction will be destroyed if a rock failure occurs. It is imperative to implement measures aimed at the prevention of rock failure in order to mitigate the risk of such an occurrence. Full article
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16 pages, 11319 KB  
Article
Dynamic Response Mechanism and Risk Assessment of Threaded Connections During Jarring Operations in Ultra-Deep Wells
by Zhe Wang, Chunsheng Wang, Zhaoyang Zhao, Shaobo Feng, Ning Li, Xiaohai Zhao and Zhanghua Lian
Modelling 2025, 6(4), 123; https://doi.org/10.3390/modelling6040123 - 10 Oct 2025
Viewed by 208
Abstract
With the frequent occurrence of stuck pipe incidents during the ultra-deep well drilling operation, the hydraulic-while-drilling (HWD) jar has become a critical component of the bottom hole assembly (BHA). However, during jarring operations for stuck pipe release, the drill string experiences severe vibrations [...] Read more.
With the frequent occurrence of stuck pipe incidents during the ultra-deep well drilling operation, the hydraulic-while-drilling (HWD) jar has become a critical component of the bottom hole assembly (BHA). However, during jarring operations for stuck pipe release, the drill string experiences severe vibrations induced by the impact loads from the jar, which significantly alter the stress state and dynamic response of the threaded connections—the structurally weakest elements—under cyclic dynamic loading, often leading to fracture failures. here, a thread failure incident of a hydraulic jar in an ultra-deep well in the Tarim Basin, Xinjiang, is investigated. A drill string dynamic impact model incorporating the actual three-dimensional wellbore trajectory is established to capture the time-history characteristics of multi-axial loads at the threaded connection during up and down jarring. Meanwhile, a three-dimensional finite element model of a double-shouldered threaded connection with helix angle is developed, and the stress distribution of the joint thread is analyzed on the boundary condition acquired from the time-history characteristics of multi-axial loads. Numerical results indicate that the axial compression induces local bending of the drill string during down jarring, resulting in significantly greater bending moment fluctuations than in up jarring and a correspondingly higher amplitude of circumferential acceleration at the thread location. Among all thread positions, the first thread root at the pin end consistently experiences the highest average stress and stress variation, rendering it most susceptible to fatigue failure. This study provides theoretical and practical insights for optimizing drill string design and enhancing the reliability of threaded connections in deep and ultra-deep well drilling. Full article
(This article belongs to the Topic Oil and Gas Pipeline Network for Industrial Applications)
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26 pages, 6000 KB  
Article
Leakage Fault Diagnosis of Wind Tunnel Valves Using Wavelet Packet Analysis and Vision Transformer-Based Deep Learning
by Fan Yi, Ruoxi Zhong, Wenjie Zhu, Run Zhou, Ying Wang and Li Guo
Mathematics 2025, 13(19), 3195; https://doi.org/10.3390/math13193195 - 6 Oct 2025
Viewed by 342
Abstract
High-frequency vibrations in annular gap type pressure-regulating valves of wind tunnels can induce fatigue, fracture, and operational failures, posing challenges to safe and reliable operation. This study proposes a hybrid leakage fault diagnosis framework that integrates wavelet packet-based signal analysis with advanced deep [...] Read more.
High-frequency vibrations in annular gap type pressure-regulating valves of wind tunnels can induce fatigue, fracture, and operational failures, posing challenges to safe and reliable operation. This study proposes a hybrid leakage fault diagnosis framework that integrates wavelet packet-based signal analysis with advanced deep learning techniques. Time-domain acceleration signals collected from multiple sensors are processed to extract maximum component energy and its variation rate, identified as sensitive and robust indicators for leakage detection. A fluid–solid coupled finite element model of the valve system further validates the reliability of these indicators under different operational scenarios. Based on this foundation, a Vision Transformer (ViT)-based model is trained on a dedicated database encompassing multiple leakage conditions and sensor arrangements. Comparative evaluation demonstrates that the ViT model outperforms conventional deep learning architectures in terms of accuracy, stability, and predictive reliability. The integrated framework enables fast, automated, and robust leakage diagnosis, providing a comprehensive solution to enhance the monitoring, maintenance, and operational safety of wind tunnel valve systems. Full article
(This article belongs to the Special Issue Numerical Analysis and Finite Element Method with Applications)
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19 pages, 5443 KB  
Article
Effects of Near-Fault Vertical Ground Motion on Seismic Response and Damage in High-Speed Railway Isolated Track–Bridge Systems
by Haiyan Li, Jinyu Ma, Zhiwu Yu and Jianfeng Mao
Buildings 2025, 15(18), 3320; https://doi.org/10.3390/buildings15183320 - 14 Sep 2025
Viewed by 575
Abstract
China’s high-speed railway (HSR) network relies heavily on bridge structures to ensure track regularity, with many lines crossing seismically active near-fault zones. Near-fault ground motions are characterized by significant vertical components (VGMs), which challenge conventional seismic design practices. Although seismic isolation techniques are [...] Read more.
China’s high-speed railway (HSR) network relies heavily on bridge structures to ensure track regularity, with many lines crossing seismically active near-fault zones. Near-fault ground motions are characterized by significant vertical components (VGMs), which challenge conventional seismic design practices. Although seismic isolation techniques are widely adopted, the effects of VGMs on the dynamic response and damage mechanisms of HSR track–bridge systems remain insufficiently studied. To address this gap, this study develops a refined finite element model (FEM) in OpenSEES that integrates CRTS II slab ballastless tracks, bridge structures, and friction pendulum bearing (FPB). Using nonlinear time-history analyses, the research systematically investigates structural responses and damage degrees under different ratios of vertical-to-horizontal peak ground acceleration (αVH) and multiple seismic intensity levels (frequent, design, and rare earthquakes). Key findings reveal that αVH values in near-fault regions frequently range between 0.5 and 1.5, often exceeding current design code specifications. The impact of VGMs intensifies with seismic intensity: negligible under frequent earthquakes but significantly amplifying damage to piers, bearings, and track interlayer components (e.g., sliding layers and CA mortar layers) during design and rare earthquakes. While seismic isolation effectively mitigates structural responses through energy dissipation by bearings, it may increase sliding layer displacements and lead to bearing failure under rare earthquakes. Based on these insights, tiered αVH values are recommended for seismic design: 0.65 for frequent, 0.9 for design, and 1.2 for rare earthquakes. These findings provide critical references for the seismic design of HSR infrastructure in near-fault regions. Full article
(This article belongs to the Special Issue Dynamic Response Analysis of Structures Under Wind and Seismic Loads)
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20 pages, 3473 KB  
Article
The Deterioration of Low-Cycle Fatigue Properties and the Fatigue Life Model of Reinforcing Steel Bars Subjected to Corrosion
by Fangjian Chen, Longzhen Hua and Jing Zhang
Buildings 2025, 15(18), 3313; https://doi.org/10.3390/buildings15183313 - 12 Sep 2025
Viewed by 489
Abstract
Thousands of coastal reinforced concrete structures using HRB400 bars have served for over three decades in China. Their reinforcement simultaneously endures chloride corrosion and seismic action, yet studies on performance degradation remain limited. This paper investigates the low-cycle fatigue (LCF) behavior of HRB400 [...] Read more.
Thousands of coastal reinforced concrete structures using HRB400 bars have served for over three decades in China. Their reinforcement simultaneously endures chloride corrosion and seismic action, yet studies on performance degradation remain limited. This paper investigates the low-cycle fatigue (LCF) behavior of HRB400 bars under various strain amplitudes, systematically analyzing corrosion morphology, cyclic stress–strain response, fatigue life, and underlying mechanisms. Corrosion is induced by an adjusted accelerated method that replicates field conditions. Observations reveal that corrosion pits act as primary crack initiation sites. Crack paths and fracture surfaces progressively follow the local pit geometry as strain and corrosion grow. The detrimental effect of corrosion on LCF life is more pronounced for smaller bars. At a γ of around 8%, 20 mm bars lose 60.7% of the half cycles to failure at ε = ±1.5%, but only 37.5% at ε = ±5.0%. Predictive corrosion-inclusive strain amplitude (εa)–fatigue life models are proposed, yielding R2 = 0.952 (16 mm) and 0.928 (20 mm). A unified LCF predictive model, calibrated on a database of 310 corroded/uncorroded bar tests, is established. The final model comprehensively considers the characteristics of rebars, seismic action, and corrosion damage, improving the conventional relationship between LCF life and seismic loading. This work contributes to the understanding of the fatigue behavior of HRB400 bars and provides support for time-dependent seismic reliability analysis of aging reinforced concrete structures in corrosive environments. Full article
(This article belongs to the Section Building Structures)
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22 pages, 10816 KB  
Article
Research on the Security Scenario Simulation and Evolution Path of China’s Power System Based on the SWITCH-China Model
by Qin Wang, Lang Tang, Yuanzhe Zhu, Jincan Zeng, Xi Liu, Rongfeng Deng, Binghao He, Guori Huang, Minwei Liu and Peng Wang
Energies 2025, 18(18), 4806; https://doi.org/10.3390/en18184806 - 9 Sep 2025
Viewed by 521
Abstract
Accelerated climate warming has led to the frequent occurrence of extreme weather events, resulting in high-frequency, large-scale, and highly destructive power outages and electricity shortages, which serve as a wake-up call for the safe and stable operation of the power system. To predict [...] Read more.
Accelerated climate warming has led to the frequent occurrence of extreme weather events, resulting in high-frequency, large-scale, and highly destructive power outages and electricity shortages, which serve as a wake-up call for the safe and stable operation of the power system. To predict safety risks, this study constructs a baseline scenario and five power security scenarios based on the SWITCH-China model, systematically assessing the impact of external shocks on the power system’s evolution path and carbon reduction economics. The results indicate that external shocks are the key factors influencing the power system’s installed capacity structure and generation mix. The increase in demand forces the substitution of non-fossil energy. In the demand growth scenario, by 2060, wind and solar installed capacity will be 1.034 billion kilowatts higher than in the baseline scenario. Rising fuel costs will accelerate the exit of fossil fuel units. In the fuel cost increase scenario, 765 million kilowatts of coal power were reduced cumulatively across three time points. Wind and solar outages, along with transmission failures, lead to significant local economic investments while also causing inter-provincial carbon transfer. In the wind and solar outage scenario, provinces with a high proportion of wind and solar, such as Guangdong and Guizhou, see an increase in carbon emissions of 31 million tons and 8 million tons, respectively. Conversely, provinces with a lower proportion of wind and solar, such as Inner Mongolia and Xinjiang, reduce carbon emissions by 46 million tons and 39 million tons, respectively. Energy storage development supports the expansion of non-fossil energy in the power system. The study recommends accelerating wind and solar deployment, building a storage system at the scale of hundreds of billions of kilowatt-hours, and optimizing the inter-provincial transmission network to address the dual challenges of power security and carbon neutrality. Full article
(This article belongs to the Special Issue Planning, Operation, and Control of New Power Systems: 2nd Edition)
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12 pages, 1983 KB  
Article
Non-Destructive Evaluation of HTV’s Thermal-Oxidative Aging Using Terahertz Dielectric Spectroscopy
by Tengyi Zhang, Li Cheng, Shuo Zhang, Bo Tao and Yipu Tang
Materials 2025, 18(17), 4176; https://doi.org/10.3390/ma18174176 - 5 Sep 2025
Viewed by 768
Abstract
Thermal oxidative aging failure of high-temperature vulcanized silicone rubber (HTV) in high-voltage insulators is the core hidden danger of power grid security. In this study, terahertz time domain spectroscopy (THz-TDS) and attenuated total reflection infrared spectroscopy (ATR-FTIR) were combined to reveal the quantitative [...] Read more.
Thermal oxidative aging failure of high-temperature vulcanized silicone rubber (HTV) in high-voltage insulators is the core hidden danger of power grid security. In this study, terahertz time domain spectroscopy (THz-TDS) and attenuated total reflection infrared spectroscopy (ATR-FTIR) were combined to reveal the quantitative structure–activity relationship between dielectric response and chemical group evolution of HTV during accelerated aging at 200 °C for 80 days. In this study, HTV flat samples were made in the laboratory, and the dielectric spectrum of HTV in the range of 0.1 THz to 0.4 THz was extracted by a terahertz time–domain spectrum platform. ATR-FTIR was used to analyze the functional group change trend of HTV during aging, and the three-stage evolution of the dielectric real part (0.16 THz), the dynamics of the carbonyl group, the monotonic rise of the dielectric imaginary part (0.17 THz), and the linear response of silicon-oxygen bond breaking were obtained by combining the double Debye relaxation theory. Finally, three aging stages of HTV were characterized by dielectric loss angle data. The model can warn about the critical point of early oxidation and main chain fracture and identify the risk of insulation failure in advance compared with traditional methods. This study provides a multi-scale physical basis for nondestructive life assessment in a silicon rubber insulator. Full article
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21 pages, 4474 KB  
Article
A Validated CFD Model for Gas Exchange in Hollow Fiber Membrane Oxygenators: Incorporating the Bohr and Haldane Effects
by Seyyed Hossein Monsefi Estakhrposhti, Jingjing Xu, Margit Gföhler and Michael Harasek
Membranes 2025, 15(9), 268; https://doi.org/10.3390/membranes15090268 - 4 Sep 2025
Viewed by 933
Abstract
Chronic respiratory diseases claim nearly four million lives annually, making them the third leading cause of death worldwide. Extracorporeal membrane oxygenation (ECMO) is often the last line of support for patients with severe lung failure. Still, its performance is limited by an incomplete [...] Read more.
Chronic respiratory diseases claim nearly four million lives annually, making them the third leading cause of death worldwide. Extracorporeal membrane oxygenation (ECMO) is often the last line of support for patients with severe lung failure. Still, its performance is limited by an incomplete understanding of gas exchange in hollow fiber membrane (HFM) oxygenators. Computational fluid dynamics (CFD) has become a robust oxygenator design and optimization tool. However, most models oversimplify O2 and CO2 transport by ignoring their physiological coupling, instead relying on fixed saturation curves or constant-content assumptions. For the first time, this study introduces a novel physiologically informed CFD model that integrates the Bohr and Haldane effects to capture the coupled transport of oxygen and carbon dioxide as functions of local pH, temperature, and gas partial pressures. The model is validated against in vitro experimental data from the literature and assessed against established CFD models. The proposed CFD model achieved excellent agreement with experiments across blood flow rates (100–500 mL/min ), with relative errors below 5% for oxygen and 10–15% for carbon dioxide transfer. These results surpassed the accuracy of all existing CFD approaches, demonstrating that a carefully formulated single-phase model combined with physiologically informed diffusivities can outperform more complex multiphase simulations. This work provides a computationally efficient and physiologically realistic framework for oxygenator optimization, potentially accelerating device development, reducing reliance on costly in vitro testing, and enabling patient-specific simulations. Full article
(This article belongs to the Section Membrane Applications for Gas Separation)
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16 pages, 4764 KB  
Article
Simulation and Finite Element Analysis of the Electrical Contact Characteristics of Closing Resistors Under Dynamic Closing Impacts
by Yanyan Bao, Kang Liu, Xiao Wu, Zicheng Qiu, Hailong Wang, Simeng Li, Xiaofei Wang and Guangdong Zhang
Energies 2025, 18(17), 4714; https://doi.org/10.3390/en18174714 - 4 Sep 2025
Viewed by 940
Abstract
Closing resistors in ultra-high-voltage (UHV) gas-insulated circuit breakers (GCBs) are critical components designed to suppress inrush currents and transient overvoltages during switching operations. However, in practical service, these resistors are subjected to repeated mechanical impacts and transient electrical stresses, leading to degradation of [...] Read more.
Closing resistors in ultra-high-voltage (UHV) gas-insulated circuit breakers (GCBs) are critical components designed to suppress inrush currents and transient overvoltages during switching operations. However, in practical service, these resistors are subjected to repeated mechanical impacts and transient electrical stresses, leading to degradation of their electrical contact interfaces, fluctuating resistance values, and potential failure of the entire breaker assembly. Existing studies mostly simplify the closing resistor as a constant resistance element, neglecting the coupled electro-thermal–mechanical effects that occur during transient events. In this work, a comprehensive modeling framework is developed to investigate the dynamic electrical contact characteristics of a 750 kV GCB closing resistor under transient closing impacts. First, an electromagnetic transient model is built to calculate the combined inrush and power-frequency currents flowing through the resistor during its pre-insertion period. A full-scale mechanical test platform is then used to capture acceleration signals representing the mechanical shock imparted to the resistor stack. These measured signals are fed into a finite element model incorporating the Cooper–Mikic–Yovanovich (CMY) electrical contact correlation to simulate stress evolution, current density distribution, and temperature rise at the resistor interface. The simulation reveals pronounced skin effect and current crowding at resistor edges, leading to localized heating, while transient mechanical impacts cause contact pressure to fluctuate dynamically—resulting in a temporary decrease and subsequent recovery of contact resistance. These findings provide insight into the real-time behavior of closing resistors under operational conditions and offer a theoretical basis for design optimization and lifetime assessment of UHV GCBs. Full article
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36 pages, 46887 KB  
Article
Dynamic Impact and Vibration Response Analysis of Steel–UHPC Composite Containment Under Aircraft Impact
by Guopeng Ren, Rong Pan, Feng Sun and Guoliang Zhou
Buildings 2025, 15(17), 3130; https://doi.org/10.3390/buildings15173130 - 1 Sep 2025
Viewed by 581
Abstract
The growing concerns over nuclear power plant safety in the wake of extreme impact events have highlighted the need for containment structures with superior resistance to large commercial aircraft strikes. Conventional reinforced concrete containment has shown limitations in withstanding high-mass and high-velocity impacts, [...] Read more.
The growing concerns over nuclear power plant safety in the wake of extreme impact events have highlighted the need for containment structures with superior resistance to large commercial aircraft strikes. Conventional reinforced concrete containment has shown limitations in withstanding high-mass and high-velocity impacts, posing potential risks to structural integrity and operational safety. Addressing this challenge, this study focuses on the dynamic impact resistance and vibration behavior of steel–ultra-high-performance concrete (S-UHPC) composite containment, aiming to enhance nuclear facility resilience under beyond-design-basis aircraft impact scenarios. Validated finite element models in LS-DYNA were developed to simulate impacts from four representative large commercial aircraft types, considering variations in wall and steel plate thicknesses, UHPC grades, and soil–structure interaction conditions. Unlike existing studies that often focus on isolated parameters, this work conducts a systematic parametric analysis integrating multiple aircraft types, structural configurations, and foundation conditions, providing comprehensive insights into both global deformation and high-frequency vibration behavior. Comparative analyses with conventional reinforced concrete containment were performed, and floor response spectra were evaluated to quantify high-frequency vibration characteristics under different site conditions. The results show that S-UHPC containment reduces peak displacement by up to ~24% compared to reinforced concrete of the same thickness while effectively localizing core damage without through-thickness failure. In addition, aircraft impacts predominantly excite 90–125 Hz vibrations, with soft soil conditions amplifying acceleration responses by more than four times, underscoring the necessity of site-specific dynamic analysis in nuclear containment and equipment design. Full article
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20 pages, 12575 KB  
Article
Seismic Fragility of Large-Span Elevated U-Shaped Aqueduct Based on Incremental Dynamic Analysis
by Jing Wei and Xinjun Yan
Appl. Sci. 2025, 15(17), 9623; https://doi.org/10.3390/app15179623 - 1 Sep 2025
Viewed by 450
Abstract
This study uses a U-shaped aqueduct structure in a specific irrigation area as the research object to examine the damage patterns of large-span elevated U-shaped aqueduct structures under seismic action. A single-span aqueduct model that integrates fluid–structure interaction is created with the finite [...] Read more.
This study uses a U-shaped aqueduct structure in a specific irrigation area as the research object to examine the damage patterns of large-span elevated U-shaped aqueduct structures under seismic action. A single-span aqueduct model that integrates fluid–structure interaction is created with the finite element program ANSYS. The incremental dynamic analysis approach is utilized to perform nonlinear dynamic time–history assessments for three types of bearings—plate rubber bearings, pot rubber bearings and lead-core rubber bearings—under conditions of an empty condition, a half-full condition and a design water level. Seismic fragility curves for the bearings and piers subjected to transverse seismic stress are developed using capacity–demand ratio models and specified damage limit states. The findings demonstrate that the likelihood of aqueduct components being damaged increases substantially as seismic intensity increases, with bearings failing before piers. Under the conditions of empty, half-full and design water levels, the structural mass increases as a result of higher water levels. This alters the dynamic response characteristics and increases the likelihood of failure in a variety of damage states. The probability of plate rubber bearings experiencing minor damage exceedance increases from 11.75% to 61.6% as the water level rises from vacant to design conditions. Lead-core rubber bearings provide better seismic isolation than plate rubber bearings and pot rubber bearings. This greatly lowers the aqueduct structure’s displacement response and damage likelihood. Under design water level circumstances, the chance of mild damage to lead rubber bearings is 8.64%, at a peak ground acceleration of 0.4 g. The damage probabilities for the pot rubber bearings and the plate rubber bearings are 80.68% and 97.45%, respectively. The research findings establish a theoretical foundation for the seismic design and damage evaluation of aqueduct structures in places with high seismic activity, ensuring the stable operation of water transfer projects and sustainable water resource utilization, presenting considerable technical applicability. Full article
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26 pages, 10183 KB  
Article
Macro-Microscopic Characterization and Long-Term Performance Prediction of Polyvinyl Chloride Under Hydrothermal Aging Based on Creep Behavior Analysis
by Hui Li, Xiaoxiao Su, Guan Gong, Aoxin Shao and Yanan Zheng
Polymers 2025, 17(17), 2320; https://doi.org/10.3390/polym17172320 - 27 Aug 2025
Viewed by 704
Abstract
The creep behavior of rigid polyvinyl chloride (PVC) in hydrothermal environments can compromise its long-term stability and load-bearing capacity, potentially leading to deformation or structural failure. Understanding this degradation is critical for ensuring the durability and safety of PVC in engineering applications such [...] Read more.
The creep behavior of rigid polyvinyl chloride (PVC) in hydrothermal environments can compromise its long-term stability and load-bearing capacity, potentially leading to deformation or structural failure. Understanding this degradation is critical for ensuring the durability and safety of PVC in engineering applications such as pipelines and building materials. In this study, accelerated hydrothermal aging tests were carried out on PVC under controlled conditions of 60 °C and 90% relative humidity (RH). Short-term tensile creep tests at four different stress levels were conducted both before and after aging. Microstructural changes associated with the PVC’s creep behavior were analyzed using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and other microscopic characterization techniques. These analyses provided a detailed microscopic interpretation of how hydrothermal exposure and applied loads influenced the macroscopic creep performance of the PVC, thereby elucidating the correlation between its macroscopic mechanical behavior and microstructural evolution. By applying the time–stress equivalence principle and the time–aging equivalence principle, the short-term creep behavior was characterized to predict long-term performance. The accelerated characterization curve can effectively predict the creep behavior of PVC under a stress level of 16 MPa over approximately 6.5 years in an environment of 60 °C and 90% RH. At the same time, the master creep modulus curve of PVC under any aging duration and stress level can be established under the specified environmental conditions of 60 °C and 90% RH. Long-term creep curves were fitted using a locally structured derivative Kelvin model, demonstrating that this model can effectively simulate the long-term creep behavior of PVC under hydrothermal conditions. The results indicate that at a stress level of 16 MPa, PVC is expected to undergo creep damage and failure after approximately 15 years in such an environment. These findings provide a critical reference for assessing the long-term performance of PVC in hydrothermal environments. Full article
(This article belongs to the Special Issue Aging Behavior and Durability of Polymer Materials, 2nd Edition)
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23 pages, 5691 KB  
Article
Mechanistic Investigation of the Corrosion Behavior of Organic Zn14Al1.4 Composite Coating Under Simulated Tropical Marine Atmospheric Conditions
by Hao Zhang, Hao Yu, Chang Liu, Yesheng Huang, Haoyu Wu, Pan Yi, Kui Xiao and Jin Gao
Coatings 2025, 15(9), 981; https://doi.org/10.3390/coatings15090981 - 22 Aug 2025
Viewed by 826
Abstract
The coupled factors of high temperature, high humidity, and high salinity in tropical marine atmospheres severely threaten the long-term service performance of power transmission and transformation infrastructure. This paper establishes an accelerated cyclic testing protocol (salt spray → drying → damp heat → [...] Read more.
The coupled factors of high temperature, high humidity, and high salinity in tropical marine atmospheres severely threaten the long-term service performance of power transmission and transformation infrastructure. This paper establishes an accelerated cyclic testing protocol (salt spray → drying → damp heat → drying) to evaluate performance and elucidate the dynamic corrosion failure mechanisms of the organic Zn14Al1.4 composite coating. By integrating multiphysical characterization techniques (SEM, EDS, XPS) with electrochemical analysis, this study for the first time elucidates the dynamic transformation of corrosion products: initially dominated by Zn(OH)2, progressing to complex passive phases such as Zn5(OH)8Cl2·H2O, Zn5(OH)6(CO3)2, and Zn6Al2(OH)16CO3 in the mid-term, and ultimately dominated by Fe-based products (FeO, Fe2O3, Fe3O4, FeOOH) that drive interfacial failure. And a four-stage corrosion evolution model was defined: incubation period, accelerated degradation phase, substrate nucleation stage, and catastrophic failure phase. The investigation reveals a shift in the coating/substrate interface failure mechanism from purely physical barrier effects to electrochemical synergy, providing a theoretical framework for the optimized design and service-life prediction of anticorrosive coatings for transmission and transformation equipment in tropical environments. Full article
(This article belongs to the Section Corrosion, Wear and Erosion)
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13 pages, 885 KB  
Article
The G-allele of rs10830963 in MTNR1B Exerts Stage-Specific Effects Across the Trajectory of Type 2 Diabetes: A Multi-State Analysis
by Yao Huang, Xiuping Dou, Man He, Yang Su, Hualiang Lin and Yin Yang
Int. J. Mol. Sci. 2025, 26(16), 7855; https://doi.org/10.3390/ijms26167855 - 14 Aug 2025
Cited by 1 | Viewed by 885
Abstract
Although the MTNR1B single nucleotide polymorphism rs10830963 has been strongly associated with the onset of type 2 diabetes (T2D), its association with the progression and prognosis of T2D has been understudied. We conducted this prospective analysis based on the UK Biobank cohort study. [...] Read more.
Although the MTNR1B single nucleotide polymorphism rs10830963 has been strongly associated with the onset of type 2 diabetes (T2D), its association with the progression and prognosis of T2D has been understudied. We conducted this prospective analysis based on the UK Biobank cohort study. Microvascular complications (MIC) of T2D in this study included diabetic retinopathy, diabetic neuropathy, and diabetic kidney disease. Macrovascular complications (MAC) of T2D included diabetic coronary artery disease, diabetic cerebrovascular disease, and diabetic peripheral vascular disease. The multi-state model was used to analyze the association between the polymorphism of rs10830963 and the trajectory of T2D. The accelerated failure time (AFT) model was used to assess the association between rs10830963 and the onset of T2D and T2D comorbidities. A total of 283,531 middle- and old-age participants were included. During a median follow-up of 13.7 years, 11,947 participants developed T2D, 1556 participants developed MIC, 1797 participants developed MAC, and 618 participants died. In the additive model, the G risk allele of rs10830963 was significantly associated with an increased risk of the transition from T2D-free to T2D (HR = 1.050, 95% CI: 1.020, 1.079) and a decreased risk of the transition from T2D to MIC (HR = 0.918, 95% CI: 0.850, 0.992), particularly from T2D to diabetic retinopathy (HR = 0.882, 95% CI: 0.782, 0.995). Besides, the G risk allele of rs10830963 accelerated the transition from T2D-free to T2D (Time Ratio [TR] = 0.966, 95% CI: 0.947, 0.986) and slowed down the transition from T2D to MIC (TR = 1.067, 95% CI: 1.030, 1.105). The MTNR1B single nucleotide polymorphism rs10830963 was associated with an increased risk of T2D and a decreased risk of MIC, particularly diabetic retinopathy among T2D individuals. Our results highlight that rs10830963 might play differential roles in the onset and progression of T2D. Full article
(This article belongs to the Section Molecular Genetics and Genomics)
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