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Journal = Energies
Section = J2: Thermodynamics

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41 pages, 2513 KiB  
Article
Looking at Economics through the Eyes of Thermodynamics
by Vítor A. F. Costa
Energies 2024, 17(11), 2478; https://doi.org/10.3390/en17112478 - 22 May 2024
Cited by 2 | Viewed by 1673
Abstract
Based on Thermodynamics and its well-established First and Second Laws, this work presents and explores their economics counterparts, introducing new concepts, variables, and equations. This includes, among others, the economic counterparts of temperature, reversibility and irreversibility, and entropy and entropy generation resulting from [...] Read more.
Based on Thermodynamics and its well-established First and Second Laws, this work presents and explores their economics counterparts, introducing new concepts, variables, and equations. This includes, among others, the economic counterparts of temperature, reversibility and irreversibility, and entropy and entropy generation resulting from economic irreversibility. The meaning of the new concepts, variables, equations, and their messages are introduced and discussed considering simple yet relevant economic processes. The economic counterparts of the First and Second Law balance equations are set in addition to the base concepts and Laws. These are effective and valuable tools for the analysis of economic processes. Observations from selected economic activities are analyzed using the new concepts, variables, and equations. Full article
(This article belongs to the Section J2: Thermodynamics)
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18 pages, 7330 KiB  
Article
Analysis of the Flow Capacity of Variable Cycle Split Fans at the Middle Speed
by Guangfeng An, Rui Zhou, Xianjun Yu, Baojie Liu and Guanghan Wu
Energies 2024, 17(5), 1194; https://doi.org/10.3390/en17051194 - 2 Mar 2024
Viewed by 1243
Abstract
The next-generation variable cycle engine imposes stricter requirements on a fan’s flow capacity at the middle speed. To tackle this challenge, the implementation of split fans presents as a potential solution. In the present study, we conducted numerical simulations using the commercial software [...] Read more.
The next-generation variable cycle engine imposes stricter requirements on a fan’s flow capacity at the middle speed. To tackle this challenge, the implementation of split fans presents as a potential solution. In the present study, we conducted numerical simulations using the commercial software NUMECA to investigate the aerodynamic performance variation with bypass ratios for variable cycle split fans in “1 + 2” and “2 + 1” configurations at 80% rpm. The results indicate that the flow capacity of the split fans exhibits an increasing trend with a rise in the bypass ratio at 80% rpm and subsequently stabilizes upon reaching a certain bypass ratio. Specifically, the flow capacity of the “2 + 1” split fans is particularly stronger at the small bypass ratios, whereas the “1 + 2” split fans exhibit superior maximum flow capacity at the high bypass ratios. Additionally, there is a significantly faster increase in the flow capacity of the “1 + 2” split fans compared to that of the “2 + 1” split fans. Furthermore, when the flow capacity of the split fans reaches its maximum, both the efficiency and stall margin achieve their optimal values, indicating that the corresponding bypass ratio is optimal. Full article
(This article belongs to the Special Issue Computational Fluid Dynamics in Gas Turbines)
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17 pages, 3284 KiB  
Article
Analysis of Varying Temperature Regimes in a Conductive Strip during Induction Heating under a Quasi-Steady Electromagnetic Field
by Roman Musii, Marek Lis, Petro Pukach, Andriy Chaban, Andrzej Szafraniec, Myroslava Vovk and Nataliia Melnyk
Energies 2024, 17(2), 366; https://doi.org/10.3390/en17020366 - 11 Jan 2024
Cited by 8 | Viewed by 1297
Abstract
Transition processes in a steel conductive strip are analyzed during its induction heating under a quasi-steady electromagnetic field. In particular, the temperature field in the strip is studied. A method of solving corresponding initial boundary problems in a two-dimensional mathematical model for differential [...] Read more.
Transition processes in a steel conductive strip are analyzed during its induction heating under a quasi-steady electromagnetic field. In particular, the temperature field in the strip is studied. A method of solving corresponding initial boundary problems in a two-dimensional mathematical model for differential equations of electrodynamics and heat conduction is developed. The Joule heat and the temperature are determined with a high level of accuracy. The defining functions are the temperature and component of the magnetic field intensity vector tangent to the bases and end planes of the strip. To find them, we use cubic approximation of the defining functions’ distribution along the thickness coordinate. The original two-dimensional initial boundary value problems for the defining functions are reduced to one-dimensional initial boundary value problems on their integral characteristics. General solutions for these problems are obtained using the finite integral transformation by the transverse variable and the Laplace transform of the integral by time. Integral characteristics’ expressions are represented as convolutions for functions that describe homogeneous solutions of one-dimensional initial boundary value problems and limiting values of defining functions on the bases and end planes of the strip. The change of temperature under a varying regime in the dimensionless Fourier time and temperature distribution over the strip cross-section in a steady state depending on the parameters of induction heating and the Biot number are numerically analyzed. Varying and constant temperature regimes of the strip under conditions of the near-surface and continuous induction heating are studied. Full article
(This article belongs to the Section J2: Thermodynamics)
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42 pages, 2963 KiB  
Review
Emissions from Light-Duty Vehicles—From Statistics to Emission Regulations and Vehicle Testing in the European Union
by Wiktor Pacura, Katarzyna Szramowiat-Sala and Janusz Gołaś
Energies 2024, 17(1), 209; https://doi.org/10.3390/en17010209 - 30 Dec 2023
Cited by 7 | Viewed by 3672
Abstract
The article offers a comprehensive examination of vehicle emissions, with a specific focus on the European Union’s automotive industry. Its main goal is to provide an in-depth analysis of the factors influencing the emission of microcontaminants from light-duty vehicles and the challenges associated [...] Read more.
The article offers a comprehensive examination of vehicle emissions, with a specific focus on the European Union’s automotive industry. Its main goal is to provide an in-depth analysis of the factors influencing the emission of microcontaminants from light-duty vehicles and the challenges associated with their removal via exhaust aftertreatment systems. It presents statistical insights into the automotive sector and explores the relationships between vehicle categories, fuel types, and the emission of regulated and nonregulated pollutants, as well as relevant legal regulations such as the European Emission Standard. The article delves into the characteristics of vehicle exhaust, compares exhaust-gas aftertreatment systems, and introduces factors affecting emissions from gasoline engines, including downsizing, fuel composition, and engine operating parameters. It also considers the impact of driving style, start–stop systems, and related factors. Concluding, the article offers an overview of vehicle-testing procedures, including emission tests on dynamometer chassis and real driving emissions. With the growing global vehicle population and international environmental regulations, a focus on solid particles containing microcontaminants is paramount, as they pose significant risks to health and the environment. In summary, this article provides valuable insights into vehicle emissions, significantly contributing to our understanding of this crucial environmental issue. Full article
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12 pages, 3018 KiB  
Article
Effect of an Amphoteric Surfactant Concentration on Absorbance, Contact Angle, Surfactant, and Thermal Conductivity of CNT Nanofluids
by Seungyeop Baek, Seunghyeon Lee, Yonmo Sung, Dongmin Shin, Junhyo Kim and Hyomin Jeong
Energies 2024, 17(1), 113; https://doi.org/10.3390/en17010113 - 24 Dec 2023
Cited by 2 | Viewed by 2001
Abstract
In this work, the effects of carbon nanotubes and an amphoteric surfactant, namely lauryl betaine, on the absorbance, contact angle, surface tension, and thermal conductivity of DW were experimentally investigated. The concentration of the carbon nanotubes was 0.5 wt% and that of lauryl [...] Read more.
In this work, the effects of carbon nanotubes and an amphoteric surfactant, namely lauryl betaine, on the absorbance, contact angle, surface tension, and thermal conductivity of DW were experimentally investigated. The concentration of the carbon nanotubes was 0.5 wt% and that of lauryl betaine was 100, 500, and 1000 ppm in distilled water. From the absorbance measurement results, the addition of lauryl betaine could increase the absorbance in the wavelength range of UV and visible rays (200~1000 nm). In addition, the higher the surfactant concentration, the higher the dispersibility. The contact angle of the distilled water showed a monotonic decreasing trend with an increase in the surfactant blending ratio, while there were no significant changes in that of the carbon nanotube nanofluid. Analogous behaviors were observed in the surface tension measurements. The surface tension of the distilled water dramatically decreased with an increase in the surfactant blending ratio. The highest decrement was 46.05% at the surfactant concentration of 1000 ppm. In contrast, there were no significant changes in the case of the carbon nanotube nanofluid. Adding 0.5 wt% of the carbon nanotubes to distilled water could substantially enhance the thermal conductivity up to approximately 3%. The degradation effect of the amphoteric surfactant on the thermal conductivity of the fluids was observed in both distilled water and nanofluids. Full article
(This article belongs to the Section J2: Thermodynamics)
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16 pages, 4075 KiB  
Article
Impact of K-H Instability on NOx Emissions in N2O Thermal Decomposition Using Premixed CH4 Co-Flow Flames and Electric Furnace
by Juwon Park, Suhyeon Kim, Siyeong Yu, Dae Geun Park, Dong Hyun Kim, Jae-Hyuk Choi and Sung Hwan Yoon
Energies 2024, 17(1), 96; https://doi.org/10.3390/en17010096 - 23 Dec 2023
Viewed by 1505
Abstract
This study systematically investigates the formation of NOx in the thermal decomposition of N2O, focusing on the impact of Kelvin–Helmholtz (K-H) instability in combustion environments. Using premixed CH4 co-flow flames and an electric furnace as distinct heat sources, we [...] Read more.
This study systematically investigates the formation of NOx in the thermal decomposition of N2O, focusing on the impact of Kelvin–Helmholtz (K-H) instability in combustion environments. Using premixed CH4 co-flow flames and an electric furnace as distinct heat sources, we explored NOx emission dynamics under varying conditions, including reaction temperature, residence time, and N2O dilution rates (XN2O). Our findings demonstrate that diluting N2O around a premixed flame increases flame length and decreases flame propagation velocity, inducing K-H instability. This instability was quantitatively characterized using Richardson and Strouhal numbers, highlighting N2O’s role in augmenting oxygen supply within the flame and significantly altering flame dynamics. The study reveals that higher XN2O consistently led to increased NO formation independently of nozzle exit velocity (ujet) or co-flow rate, emphasizing the influence of N2O concentration on NO production. In scenarios without K-H instability, particularly at lower ujet, an exponential rise in NO2 formation rates was observed, due to the reduced residence time of N2O near the flame surface, limiting pyrolysis effectiveness. Conversely, at higher ujet where K-H instability occurs, the formation rate of NO2 drastically decreased. This suggests that K-H instability is crucial in optimizing N2O decomposition for minimal NOx production. Full article
(This article belongs to the Section J2: Thermodynamics)
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26 pages, 2487 KiB  
Article
Thermodynamic Evaluation of the Energy Self-Sufficiency of the Tyre Pyrolysis Process
by Alexander A. R. Gamboa, Leila R. dos Santos, Cristiane A. Martins, Ana M. A. Rocha, Carlos A. Alvarado-Silva and João A. de Carvalho
Energies 2023, 16(24), 7932; https://doi.org/10.3390/en16247932 - 6 Dec 2023
Cited by 1 | Viewed by 2130
Abstract
The aim of this paper is to evaluate the energy self-sufficiency of the tyre pyrolysis process using the pyrolysis gas produced as a heat source. Experimental data on the properties of the tyre and the main pyrolysis products (char, pyrolysis gas, and condensable [...] Read more.
The aim of this paper is to evaluate the energy self-sufficiency of the tyre pyrolysis process using the pyrolysis gas produced as a heat source. Experimental data on the properties of the tyre and the main pyrolysis products (char, pyrolysis gas, and condensable vapours) have been compiled for a pyrolysis temperature range from 698 to 848 K. The laws of thermodynamics were used to calculate the energy demand of the tyre pyrolysis process, which was divided into heat for the pyrolysis reaction and heat transferred to the carrier gas. The pyrolysis gas was composed of 15 components, and its composition was calculated using a nonstoichiometric equilibrium model. For the temperature range studied, the heat required for the pyrolysis reaction was between 1.41 and 2.16 kJ/g of tyre. In addition, hydrocarbons (71 to 73 wt.%) were the major components in the calculated pyrolysis gas composition. An average lower heating value of 37.3 MJ/kg was calculated for the pyrolysis gas. The heat required for the tyre pyrolysis reaction was provided for burning 30–50% of the pyrolysis gas produced, thus making it self-sustaining. Energy self-sufficiency may not be achieved if the heat losses due to poor reactor insulation are high. However, this problem can be overcome by heating the combustion air using the heat released by the pyrolysis products during cooling. Full article
(This article belongs to the Section J2: Thermodynamics)
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20 pages, 12715 KiB  
Article
Numerical Investigation of Unsteady Rotor–Stator Interaction Mechanism and Wake Transportation Characteristics in a Compressor with Non-Uniform Tip Clearance Rotor
by Guochen Zhang, Zhipeng Li, Qijiao Wang, Zhihui Xu and Zhiyuan Cao
Energies 2023, 16(23), 7907; https://doi.org/10.3390/en16237907 - 4 Dec 2023
Cited by 1 | Viewed by 1586
Abstract
This study aims to numerically investigate a transonic compressor by solving the unsteady Reynolds-averaged Navier–Stokes equations. The flow mechanisms related to unsteady flow were carefully examined and compared between rotors with non-uniform tip clearance (D1) and small-value tip clearance (P1). The unsteady flow [...] Read more.
This study aims to numerically investigate a transonic compressor by solving the unsteady Reynolds-averaged Navier–Stokes equations. The flow mechanisms related to unsteady flow were carefully examined and compared between rotors with non-uniform tip clearance (D1) and small-value tip clearance (P1). The unsteady flow field near the 50% and 95% blade span characterized by unsteady rotor–stator interaction was analyzed in detail for near-stall (NS) conditions. According to the findings, the perturbation of unsteady aerodynamic force for the stator is much bigger than that of the rotor. At the mid-gap between the rotor and stator, the perturbation of tangential velocity of the D1 scheme in the rotor and stator frame is reduced. At the rotor’s outlet region, the perturbation intensity is divided into three main perturbation regions, which are respectively concentrated in the TLV near the upper endwall, the corner separation at the blade root, and the wake of the whole blade span. Through the analysis of the wake transportation characteristics, it was found that when the wake passes through the stator blade surface, the wake exerts a substantial influence on the flow within the stator passage. It further leads to notable pressure perturbations on the stator’s surface, as well as affecting the development and flow loss of the boundary layer. The negative jet effect induces opposite secondary flow velocity on both sides of the wake near the stator’s surfaces. Therefore, the velocity at a specific point on the stator’s suction surface will decrease and then increase. Conversely, the velocity at a particular point on the pressure surface will increase and then decrease. Full article
(This article belongs to the Special Issue Computational Fluid Dynamics in Gas Turbines)
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26 pages, 34823 KiB  
Article
Hydrogen Cooling of Turbo Aggregates and the Problem of Rotor Shafts Materials Degradation Evaluation
by Alexander I. Balitskii, Andriy M. Syrotyuk, Maria R. Havrilyuk, Valentina O. Balitska, Valerii O. Kolesnikov and Ljubomyr M. Ivaskevych
Energies 2023, 16(23), 7851; https://doi.org/10.3390/en16237851 - 30 Nov 2023
Cited by 2 | Viewed by 1789
Abstract
Changes in the properties of 38KhN3MFA steel, from which the rotor shaft is made, were investigated by comparing the hardness of the shaft surface and hydrogen concentration in the chips and analyzing changes in the morphology of the chips under the influence of [...] Read more.
Changes in the properties of 38KhN3MFA steel, from which the rotor shaft is made, were investigated by comparing the hardness of the shaft surface and hydrogen concentration in the chips and analyzing changes in the morphology of the chips under the influence of various factors. The microstructures obtained from the surface of the rotor shaft samples are presented, and histograms reflecting the parameters of the structural components are constructed. An abbreviated diagram of the “life cycle” of the turbine rotor shaft is given. It was found that, during long-term operation (up to 250 thousand hours), the hardness of the rotor shaft surface decreases from 290 HB to 250 HB. It was recorded that, in the microstructure of the shaft during 250 thousand hours of operation, the amount of cementite decreased from 87% to 62%, and the proportion of free ferrite increased from 5% to 20%. The average values of ferrite microhardness decreased from 1.9 GPa to 1.5 GPa. An increase in the content of alloying elements in carbides was recorded: Cr and V—by 1.15–1.6 times; and Mo—by 2.2–2.8 times. With the help of the developed program (using computer vision methods), changes in their microrelief were detected to study photos of chips. Full article
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21 pages, 8437 KiB  
Article
RANS Prediction of Losses and Transition Onset in a High-Speed Low-Pressure Turbine Cascade
by Nicola Rosafio, Gustavo Lopes, Simone Salvadori, Sergio Lavagnoli and Daniela Anna Misul
Energies 2023, 16(21), 7348; https://doi.org/10.3390/en16217348 - 30 Oct 2023
Cited by 3 | Viewed by 1790
Abstract
Current trends in aero-engine design are oriented at designing high-lift low-pressure turbine blades to reduce engine weight and dimensions. Therefore, the validation of numerical methods able to correctly capture the boundary layer transition at cruise conditions with a steady inflow for high-speed blades [...] Read more.
Current trends in aero-engine design are oriented at designing high-lift low-pressure turbine blades to reduce engine weight and dimensions. Therefore, the validation of numerical methods able to correctly capture the boundary layer transition at cruise conditions with a steady inflow for high-speed blades is of great relevance for turbine designers. The present paper details numerical simulations of a novel open-access high-speed low-pressure turbine test case that are performed using RANS-based transition models. The test case is the SPLEEN C1 cascade, tested in transonic conditions at the von Karman Institute for Fluid Dynamics. Both physics-based and correlation-based transition models are employed to predict blade loading, boundary layer characteristics, and wake development. 2D simulations are run for a wide range of operating conditions ranging from low to high transonic Mach numbers (0.7–0.95) and from low to moderate Reynolds numbers (70,000–120,000). The γ-Re˜θt transition model shows a good performance over the whole range of simulated operating conditions, thus demonstrating a good capability in both reproducing blade loading and average losses, although the wake’s width is underestimated. This leads to an overestimation of the total pressure deficit in the center of the wake which can exceed experimental measurements by more than 50%. On the other hand, the k-ν2-ω model achieves satisfactory results at Ma6,is = 0.95, where the boundary layer state is affected by the presence of a weak shock impinging on the blade suction side which thickens the boundary layer, leading to a predicted shape factor equal to five, downstream of the shock. However, at low and moderate Mach numbers, the k-ν2-ω model predicts long or open separation bubbles contrary to the experimental findings, thus indicating insufficient turbulence production downstream of the boundary layer separation. The slow boundary layer transition in the aft region of the suction side that is exhibited by the k-ν2-ω model also affects the prediction of the outlet flow, featuring large peaks of a total pressure deficit if compared to both the experimental measurements and the γ-Re˜θt predictions. For the k-ν2-ω model, the maximum overestimation of the total pressure deficit is approximately 60%. Full article
(This article belongs to the Special Issue Computational Fluid Dynamics in Gas Turbines)
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15 pages, 6345 KiB  
Article
Prediction of Thermal Conductivity of Litz Winding by Least Square Method and GA-BP Neural Network Based on Numerical Simulations
by Qi Dong and Xiaoli Fu
Energies 2023, 16(21), 7295; https://doi.org/10.3390/en16217295 - 27 Oct 2023
Cited by 1 | Viewed by 1691
Abstract
This paper proposes a Litz winding numerical-simulation model considering the transposition effect, and uses the transient-plane-source method to verify the numerical-simulation method. In addition, numerical methods were adopted to further investigate the impact of filling rate and epoxy-resin type, and their combined effects, [...] Read more.
This paper proposes a Litz winding numerical-simulation model considering the transposition effect, and uses the transient-plane-source method to verify the numerical-simulation method. In addition, numerical methods were adopted to further investigate the impact of filling rate and epoxy-resin type, and their combined effects, on thermal conductivity. To facilitate engineering design, the discrete data points were fitted using the least square method to obtain a straightforward and application-friendly polynomial empirical formula. On this basis, the GA-BP neural network was used to analyze the data in order to seek out more accurate prediction results for the entire data set. As a result, compared with the least square method, the error between the prediction result and the target value in the x direction was reduced by 87.04%, and the error in the z direction was reduced by 84.97%. Full article
(This article belongs to the Section J2: Thermodynamics)
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21 pages, 12143 KiB  
Article
Coherent Structures Analysis of Methanol and Hydrogen Flames Using the Scale-Adaptive Simulation Model
by José A. Parra Rodríguez, Marco A. Abad Romero, Oliver M. Huerta Chávez, Luis R. Rangel-López, José C. Jiménez-Escalona and Jorge Diaz Salgado
Energies 2023, 16(20), 7074; https://doi.org/10.3390/en16207074 - 13 Oct 2023
Cited by 1 | Viewed by 1237
Abstract
Computational fluid dynamics techniques were applied to reproduce the characteristics of the liquid methanol burner described in a previous paper by Guevara et al. In this work, the unstable Reynolds-averaged Navier–Stokes (U-RANS) approach known as the Scale-Adaptive Simulation (SAS) model was employed, together [...] Read more.
Computational fluid dynamics techniques were applied to reproduce the characteristics of the liquid methanol burner described in a previous paper by Guevara et al. In this work, the unstable Reynolds-averaged Navier–Stokes (U-RANS) approach known as the Scale-Adaptive Simulation (SAS) model was employed, together with the steady nonadiabatic flamelets combustion model, to characterize and compare methanol and hydrogen flames. These flames were compared to determine whether this model can reproduce the coherent dynamic structures previously obtained using the LES model in other investigations. The LES turbulence model still entails a very high computational cost for many research centers. Conversely, the SAS model allows for local activation and amplification, promoting the transitions of momentum equations from the stationary to the transient mode and leading to a dramatic reduction in computational time. It was found that the global temperature contour of the hydrogen flame was higher than that of methanol. The air velocity profile peaks in the methanol flame were higher than those in hydrogen due to the coherent structures formed in the near field of atomization. Both flames presented coherent structures in the form of PVC; however, in the case of hydrogen, a ring-type vortex surrounding the flame was also developed. The axial, tangential, and radial velocity profiles of the coherent structures along the axial axis of the combustion chamber were analyzed at a criterion of Q = 0.003. The investigation revealed that the radial and tangential components had similar behaviors, while the axial velocity components differed. Finally, it was found that, using the SAS model, the coherent dynamic structures of the methanol flame were different from those obtained in previous works using the LES model. Full article
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14 pages, 1767 KiB  
Article
Reduction in Fuel Consumption in Biomass-Fired Power Plant Using Hybrid Drying System
by Somchart Chantasiriwan
Energies 2023, 16(17), 6225; https://doi.org/10.3390/en16176225 - 27 Aug 2023
Cited by 1 | Viewed by 1923
Abstract
Fuels used in biomass power plants usually have high moisture contents. Two methods of fuel drying that have been proposed are steam drying and flue gas drying. Steam drying requires extracted steam as its energy source, whereas flue gas drying requires flue gas [...] Read more.
Fuels used in biomass power plants usually have high moisture contents. Two methods of fuel drying that have been proposed are steam drying and flue gas drying. Steam drying requires extracted steam as its energy source, whereas flue gas drying requires flue gas leaving the boiler as its energy source. Previous works have mostly been concerned with the integration of either dryer in a power plant. There have been a few investigations on the integration of both dryers. This paper proposes a novel hybrid drying system that uses a steam dryer to dry a portion of the fuel. Exhaust vapor from the steam dryer is then used for the heating of combustion air, which increases the flue gas temperature. The higher flue gas temperature increases the potential of the flue gas dryer, which is used to dry another portion of the fuel. It is shown that the hybrid drying system is capable of reducing fuel consumption to 7.76% in a 50 MW power plant. Furthermore, the integration of hybrid drying is shown to be economically justified because the simple payback period is 4.28 years. Full article
(This article belongs to the Section J2: Thermodynamics)
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36 pages, 20092 KiB  
Review
Recent Design and Synthesis Strategies for High-Performance Supercapacitors Utilizing ZnCo2O4-Based Electrode Materials
by Kanakaraj Aruchamy, Athinarayanan Balasankar, Subramaniyan Ramasundaram and Tae Hwan Oh
Energies 2023, 16(15), 5604; https://doi.org/10.3390/en16155604 - 25 Jul 2023
Cited by 19 | Viewed by 3439
Abstract
ZnCo2O4 has emerged as a promising electrode material for supercapacitor applications due to its unique properties and potential for high-performance energy storage. As a transition metal oxide, ZnCo2O4 offers eco-friendly characteristics and favorable diffusion properties, making it [...] Read more.
ZnCo2O4 has emerged as a promising electrode material for supercapacitor applications due to its unique properties and potential for high-performance energy storage. As a transition metal oxide, ZnCo2O4 offers eco-friendly characteristics and favorable diffusion properties, making it an attractive candidate for sustainable energy storage systems. However, the poor conductivity and low surface area of ZnCo2O4 have posed challenges for its optimal utilization in supercapacitors. Various innovative approaches have been explored to overcome these limitations, including the development of ZnCo2O4 with different morphologies such as core-shell and porous structures. This review work aims to provide a comprehensive analysis of diverse synthesis methods employed in recent studies, including hydrothermal growth, solvothermal synthesis, wet chemical methods, and miscellaneous synthesis techniques, each offering unique advantages and influencing the properties of the synthesized materials. The synthesis conditions, such as precursor concentrations, temperature, annealing time, and the incorporation of dopants or additional materials, were found to play a crucial role in determining the electrochemical performance of ZnCo2O4-based supercapacitor electrodes. Core-shell heterostructures based on ZnCo2O4 exhibited versatility and tunability, with the choice of shell material significantly impacting the electrochemical performance. The incorporation of different materials in composite electrodes, as well as doping strategies, proved effective in enhancing specific capacitance, stability, surface area, and charge transfer characteristics. Controlled synthesis of ZnCo2O4 with diverse morphologies and porosity was crucial in improving mechanical strength, surface area, and ion diffusion capabilities. The findings provide valuable insights for the design and engineering of high-performance supercapacitor electrodes based on ZnCo2O4, and suggest exciting avenues for further exploration, including advanced characterization techniques, novel doping strategies, scale-up of synthesis methods, and integration into practical supercapacitor devices. Continued research and development in this field will contribute to the advancement of energy storage technologies and the realization of efficient and sustainable energy storage systems. Full article
(This article belongs to the Section J2: Thermodynamics)
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21 pages, 5734 KiB  
Review
Strategies to Reduce Emissions from Diesel Engines under Cold Start Conditions: A Review
by Xuewen Zhang, Xiang Huang, Peiyong Ni and Xiang Li
Energies 2023, 16(13), 5192; https://doi.org/10.3390/en16135192 - 6 Jul 2023
Cited by 7 | Viewed by 5686
Abstract
Reducing diesel engine emissions under cold start conditions has become much more valuable as environmental issues become more important. Regarding diesel engine emissions under cold start conditions, this review summarizes the emission mechanisms and specifically focuses on the research progress of four reduction [...] Read more.
Reducing diesel engine emissions under cold start conditions has become much more valuable as environmental issues become more important. Regarding diesel engine emissions under cold start conditions, this review summarizes the emission mechanisms and specifically focuses on the research progress of four reduction strategies: biodiesel utilization, intake heating, injection optimization, and aftertreatment technologies. In general, adding biodiesel and Di-Ethyl-Ether (DEE) could provide the benefit of reducing emissions and maintaining engine performance. Intake heating and appropriate injection strategies could also effectively reduce emissions under cold start conditions. Unlike normal operating conditions, lean nitrogen oxide traps (LNT) or electrically heated catalysts (EHC) should be utilized in the aftertreatment of diesel engines to minimize emissions under cold start conditions. By offering the valuable information above, this review could be a helpful reference in reduction strategies for diesel engines under cold start conditions in both academia and industry. Full article
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