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20 pages, 3631 KiB

Open AccessEditor’s ChoiceArticle

Effects of Bitumen Thickness on the Aging Behavior of High-Content Polymer-Modified Asphalt Mixture

by Peng Lin, Xueyan Liu, Shisong Ren, Jian Xu, Yi Li and Mingliang Li

Polymers 2023, 15(10), 2325; https://doi.org/10.3390/polym15102325 - 16 May 2023

Cited by 12 | Viewed by 3108

Abstract

The film thickness of asphalt mixtures is critical for determining their performance and aging durability. However, understanding of the appropriate film thickness and its influence on performance and aging behavior for high-content polymer-modified asphalt (HCPMA) mixtures is still limited. This research aims to [...] Read more.

The film thickness of asphalt mixtures is critical for determining their performance and aging durability. However, understanding of the appropriate film thickness and its influence on performance and aging behavior for high-content polymer-modified asphalt (HCPMA) mixtures is still limited. This research aims to examine the relationship between film thickness, performance, and aging behavior of HCPMA mixtures in order to establish an optimal film thickness that ensures satisfactory performance and aging durability. HCPMA specimens with film thicknesses ranging from 6.9 μm to 17 μm were prepared using a 7.5% SBS-content-modified bitumen. Various tests, including Cantabro, SCB, SCB fatigue, and Hamburg wheel-tracking tests, were conducted to evaluate raveling, cracking, fatigue, and rutting resistance before and after aging. The key findings indicate that insufficient film thickness negatively affects aggregate bonding and performance, while excessive thickness reduces mixture stiffness and resistance to cracking and fatigue. A parabolic relationship between the aging index and film thickness was observed, suggesting that increasing film thickness improves aging durability up to a point, beyond which excessive thickness adversely impacts aging durability. The optimal film thickness for HCPMA mixtures, considering performance before and after aging and aging durability, falls within the 12.9 to 14.9 µm range. This range ensures the best balance between performance and aging durability, offering valuable insights for the pavement industry in designing and utilizing HCPMA mixtures. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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15 pages, 4642 KiB

Open AccessArticle

Multi-Objective Optimization of Epoxy Resin Adhesive for Pavement Toughened by Self-Made Toughening Agent

by Huaiqiang Ba, Luxin Guo, Haiyang Huan, Shibo Zhang and Zhiwei Lin

Polymers 2023, 15(8), 1946; https://doi.org/10.3390/polym15081946 - 19 Apr 2023

Cited by 12 | Viewed by 2184

Abstract

Epoxy resin adhesive for pavement is often insufficient in flexibility and toughness. Therefore, a new type of toughening agent was prepared to overcome this shortcoming. To achieve the best toughening effect of a self-made toughening agent on an epoxy resin adhesive, its ratio [...] Read more.

Epoxy resin adhesive for pavement is often insufficient in flexibility and toughness. Therefore, a new type of toughening agent was prepared to overcome this shortcoming. To achieve the best toughening effect of a self-made toughening agent on an epoxy resin adhesive, its ratio to the epoxy resin needs to be optimally selected. A curing agent, a toughening agent, and an accelerator dosage were chosen as independent variables. The epoxy resin’s adhesive tensile strength, elongation at break, flexural strength, and flexural deflection were used as response values to establish a single-objective prediction model of epoxy resin mechanical property indexes. Response surface methodology (RSM) was used to determine the single-objective optimal ratio and analyze the effect of factor interaction on epoxy resin adhesive’s performance indexes. Based on principal component analysis (PCA), multi-objective optimization was performed using gray relational analysis (GRA) to construct a second-order regression prediction model between the ratio and gray relational grade (GRG) to determine the optimal ratio and to validate it. The results showed that the multi-objective optimization using response surface methodology and gray relational analysis (RSM-GRA) was more effective than the single-objective optimization model. The optimal ratio of epoxy resin adhesive was 100 parts of epoxy resin, 160.7 parts curing agent, 16.1 parts toughening agent, and 3.0 parts accelerator. The measured tensile strength was 10.75 MPa, elongation at break was 23.54%, the bending strength was 6.16 MPa, and the bending deflection was 7.15 mm. RSM-GRA has excellent accuracy for epoxy resin adhesive ratio optimization and can provide a reference for the epoxy resin system ratio optimization design of complex components. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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26 pages, 8931 KiB

Open AccessArticle

Developing Performance-Based Mix Design Framework Using Asphalt Mixture Performance Tester and Mechanistic Models

by Jong-Sub Lee, Sang-Yum Lee and Tri Ho Minh Le

Polymers 2023, 15(7), 1692; https://doi.org/10.3390/polym15071692 - 29 Mar 2023

Cited by 5 | Viewed by 3929

Abstract

This paper proposes a performance-based mix design (PBMD) framework to support performance-related specifications (PRS) needed to establish relationships between acceptable quality characteristics (AQCs) and predicted performance, as well as to develop fatigue-preferred, rutting-preferred, and performance-balanced mix designs. The framework includes defining performance tests [...] Read more.

This paper proposes a performance-based mix design (PBMD) framework to support performance-related specifications (PRS) needed to establish relationships between acceptable quality characteristics (AQCs) and predicted performance, as well as to develop fatigue-preferred, rutting-preferred, and performance-balanced mix designs. The framework includes defining performance tests and threshold values, developing asphalt mix designs, identifying available performance levels, conducting sensitivity analysis, establishing the relationships between AQCs and predicted performance, and determining performance targets and AQC values for the three PBMDs using predicted performance criteria. Additionally, the framework recommends selecting the PBMD category for each asphalt layer to minimize pavement distresses. In this study, the proposed PBMD protocol was applied to FHWA accelerated loading facility (ALF) materials using asphalt mixture performance tester (AMPT) equipment coupled with mechanistic models. The study developed nine mix designs with varying design VMAs and air voids using the Bailey method. The cracking and rutting performance of the mix designs were determined by direct tension cyclic (DTC) fatigue testing, triaxial stress sweep (TSS) testing, and viscoelastic continuum damage (S-VECD) and viscoplastic shift models for temperature and stress effects. The study found that adjusting the design VMA was the primary way to achieve required performance targets. For fatigue-preferred mix design, the recommended targets were a cracking area of 0 to 1.9%, a rut depth of 10 mm, and a design VMA of 14.6 to 17.6%. For rutting-preferred mix design, the recommended targets were a cracking area of 18%, a rut depth of 0 to 3.8 mm, and a design VMA of 10.1 to 13.1%. For performance-balanced mix design, the recommended targets were a cracking area of 8.1 to 10.7%, a rut depth of 4.6 to 6.4 mm, and a design VMA of 12.6 to 14.3%. Finally, pavement simulation results verified that the proposed PBMD pavement design with fatigue-preferred mix in the bottom layer, performance-balanced mix in the intermediate layer, and rutting-preferred mix in the surface mix could minimize bottom-up cracking propagation without exceeding the proposed rutting performance criterion for long-life. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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18 pages, 6158 KiB

Open AccessArticle

Emission of Volatile Organic Compounds in Crumb Rubber Modified Bitumen and Its Inhibition by Using Montmorillonite Nanoclay

by Gang Liu, Shuaiyin Fang, Yong Wang, Jinjun Liu, Yangshi Liang, Tingwei Cao and Quantao Liu

Polymers 2023, 15(6), 1513; https://doi.org/10.3390/polym15061513 - 18 Mar 2023

Cited by 13 | Viewed by 2697

Abstract

Bitumen emits a large amount of volatile organic compounds (VOCs) during the production and construction of asphalt mixture, which can cause both environmental hazards and health risks. In this study, a setup was designed to collect the VOCs released by base and crumb [...] Read more.

Bitumen emits a large amount of volatile organic compounds (VOCs) during the production and construction of asphalt mixture, which can cause both environmental hazards and health risks. In this study, a setup was designed to collect the VOCs released by base and crumb rubber-modified bitumen (CRMB) binders and their composition was characterized by thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS). Next, organic montmorillonite (Mt) nanoclay was added into CRMB binder and its inhibiting effect on the VOCs emission of the binder was investigated. Finally, the VOCs emission models for the CRMB and Mt-modified CRMB (Mt-CRMB) binders were established according to reasonable assumptions. The results indicated that the VOCs emission of CRMB binder was 3.2 times larger than that of the base binder. Due to its intercalated structure, the nanoclay can reduce the VOCs emission of CRMB binder by 30.6%. Especially, its inhibition effects on alkanes, olefins, and aromatic hydrocarbons were more significant. After finite element verification, the established model based on the Fick’s second law can describe the emission behavior of CRMB and Mt-CRMB binders well. Overall, the Mt nanoclay can be used as an effective modifier to inhibit the VOCs emission of CRMB binder. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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16 pages, 9972 KiB

Open AccessArticle

Self-Healing Performance of Asphalt Concrete with Ca-Alginate Capsules under Low Service Temperature Conditions

by Huoming Wang, Quantao Liu, Jie Wu, Pei Wan and Feiyang Zhao

Polymers 2023, 15(1), 199; https://doi.org/10.3390/polym15010199 - 30 Dec 2022

Cited by 8 | Viewed by 2262

Abstract

Calcium alginate capsules containing rejuvenators represent a promising method for asphalt concrete premaintenance, but their healing capacities under lower temperature conditions are still unknown. This paper investigated the healing performance of asphalt concrete containing calcium alginate capsules at low service temperatures. The Ca-alginate [...] Read more.

Calcium alginate capsules containing rejuvenators represent a promising method for asphalt concrete premaintenance, but their healing capacities under lower temperature conditions are still unknown. This paper investigated the healing performance of asphalt concrete containing calcium alginate capsules at low service temperatures. The Ca-alginate capsules were synthesized, and their morphology, compressive strength, thermal resistance, and relative oil content were evaluated. Besides, evaluations for the healing of asphalt concrete and the rejuvenator-release ratio of the capsules were determined via fracture-healing-refracture testing and Fourier-transform infrared spectrum experiments. Meanwhile, the glass transition temperature and rheological property of asphalt binder after compressive loading under different temperatures were explored via a differential scanning calorimeter and dynamic shear rheometer. The results showed that the capsules had good thermal resistance and mechanical strength. The capsules released less oil under −15, −10, and −5 °C than at 20 °C, and the healing ratios of the asphalt concrete with the capsules at −15, −10, and −5 °C were obviously lower than that at 20 °C. The released rejuvenator from the capsules could decrease the complex modulus and glass transition temperature of the asphalt binder. When compared with low service temperatures, the asphalt binder containing the capsules and serving at a high temperature has a better softening effect and low-temperature performance due to more oil being released. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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18 pages, 5841 KiB

Open AccessArticle

Investigations on Adhesion Characteristics between High-Content Rubberized Asphalt and Aggregates

by Xiaofeng Wang, Jianan Liu, Zhenjun Wang, Haosen Jing and Bo Yang

Polymers 2022, 14(24), 5474; https://doi.org/10.3390/polym14245474 - 14 Dec 2022

Cited by 22 | Viewed by 2461

Abstract

The use of waste tires to prepare rubberized asphalt has been a hot trend in recent years, and the characteristics of adhesion between rubberized asphalt and aggregates are important factors affecting the performance of asphalt pavement. However, there is a lack of uniform [...] Read more.

The use of waste tires to prepare rubberized asphalt has been a hot trend in recent years, and the characteristics of adhesion between rubberized asphalt and aggregates are important factors affecting the performance of asphalt pavement. However, there is a lack of uniform results on the adhesion characteristics of rubberized asphalt. Therefore, crumb-rubber-modified asphalt (CRMA) with 15%, 20%, and 25% rubber contents was prepared in this work, and the basic rheological parameters and cohesive energy of the rubberized asphalt were characterized by DSR. The adhesion properties between rubberized asphalt and aggregates were characterized based on macroscopic binder bond strength (BBS), surface free energy (SFE) theory, and nanoscale atomic force microscopy (AFM) tests. The results show that crumb rubber (CR) can improve the high-temperature elastic properties of asphalt; secondly, CR can have a negative impact on the maximum tensile strength of asphalt and aggregates. CR can improve the SFE parameter of asphalt. The work of adhesion of rubberized asphalt and limestone is the highest, followed by basalt and, finally, granite. Finally, CR can cause the catanaphase in asphalt to gradually break down and become smaller, and the adhesion of rubberized asphalt can be reduced. Overall, CR can reduce the adhesion performance of asphalt, and this work provides a reference for the application of rubberized asphalt. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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20 pages, 5713 KiB

Open AccessArticle

Biopolymeric Capsules Containing Different Oils as Rejuvenating Agents for Asphalt Self-Healing: A Novel Multivariate Approach

by Jose L. Concha, Luis E. Arteaga-Pérez, Irene Gonzalez-Torre, Quantao Liu and Jose Norambuena-Contreras

Polymers 2022, 14(24), 5418; https://doi.org/10.3390/polym14245418 - 11 Dec 2022

Cited by 12 | Viewed by 2490

Abstract

This study evaluated the effect of two encapsulation methods (i.e., dropping funnel and syringe pump), two concentrations of the alginate-based encapsulating material (2%, and 3%), and three oils as bitumen rejuvenators (virgin sunflower oil, waste cooking oil, and virgin engine oil) on the [...] Read more.

This study evaluated the effect of two encapsulation methods (i.e., dropping funnel and syringe pump), two concentrations of the alginate-based encapsulating material (2%, and 3%), and three oils as bitumen rejuvenators (virgin sunflower oil, waste cooking oil, and virgin engine oil) on the morphological, physical, chemical, thermal, and mechanical properties of encapsulated rejuvenators for asphalt self-healing purposes. A general factorial design 2 × 2 × 3 was proposed to design 12 different Ca-alginate capsules. Significant differences on the morphological, physical, and mechanical properties of the capsules were analysed by three-way ANOVA and Tukey HSD Post Hoc analyses. The effect of the type of oil on the self-healing capacity of cracked bitumen samples was also evaluated. The main results showed that the design parameters and their interactions significantly affected the morphological, physical, and mechanical properties of the capsules. Capsules synthesised via syringe pump method, with virgin cooking oil and 2% alginate was the most appropriate for asphalt self-healing purposes since its uniform morphology, encapsulation efficiency up to 80%, thermal degradation below 5% wt., and compressive strength above the reference asphalt compaction load of 10 N. Finally, the healing tests showed that virgin cooking oil can be potentially used as a rejuvenator to promote asphalt crack-healing. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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14 pages, 2543 KiB

Open AccessArticle

Preparation and Macro-Micro Properties of SBS/REOB Modified-Rejuvenated Asphalt

by Jin Li, Li Zhu, Xiaozhou Yan, Chongsheng Xin, Miaozhang Yu and Degang Cheng

Polymers 2022, 14(23), 5071; https://doi.org/10.3390/polym14235071 - 22 Nov 2022

Cited by 2 | Viewed by 1677

Abstract

To solve the problem that waste oil residues cannot be utilized and to reuse the aged asphalt, suitable modifiers were selected to compound the aged asphalt with waste oil residues to study its performance. SBS/REOB modified-rejuvenated asphalt was prepared by a high-speed shearing [...] Read more.

To solve the problem that waste oil residues cannot be utilized and to reuse the aged asphalt, suitable modifiers were selected to compound the aged asphalt with waste oil residues to study its performance. SBS/REOB modified-rejuvenated asphalt was prepared by a high-speed shearing mechanism with aged asphalt, Recycled Engine Oil Bottom (REOB), Styrenic Block Copolymers (SBS) modifier, and stabilizer. The effects of SBS content, REOB content, shear time, and shear rate on the conventional physical properties of asphalt were studied by orthogonal grey correlation analysis, and the optimum preparation scheme of SBS/REOB modified-rejuvenated asphalt was determined. The high and low temperature rheological properties of SBS/REOB modified-rejuvenated asphalt were studied using the Multiple Stress Creep Recover (MSCR) test and bending beam rheological (BBR) test. The mechanism of SBS/REOB on the modification and regeneration of aged asphalt was explored through four component tests and Fourier transforms infrared spectroscopy. The results show that the optimum preparation scheme is 4.5% SBS dosage, 9% REOB dosage, 50~60 min shear time, and 4500 r/min shear rate. The addition of SBS improves the elastic recovery performance and high temperature deformation resistance of REOB rejuvenated asphalt. At the same time, the S-value decreases and the m-value increases, which significantly improves the low temperature cracking resistance of REOB rejuvenated asphalt. The addition of REOB achieves component blending and regeneration of aged asphalt by supplementing the light components. After the addition of SBS absorbs the light component and swelling reaction occurs, the whole modification-regeneration process is mainly physical co-mixing and co-compatibility. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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15 pages, 5001 KiB

Open AccessArticle

Rheological Behaviors and Damage Mechanism of Asphalt Binder under the Erosion of Dynamic Pore Water Pressure Environment

by Wentao Wang, Kang Zhao, Tingting Xie, Huifang Liu, Guanyi Zhao and Linbing Wang

Polymers 2022, 14(21), 4731; https://doi.org/10.3390/polym14214731 - 4 Nov 2022

Cited by 2 | Viewed by 1694

Abstract

Asphalt binder plays an important role in the overall resistance of asphalt mixture to the moisture damage induced by a dynamic pore water pressure environment. This study evaluates the moisture sensitivity of asphalt binder from the perspective of rheological behaviors using the dynamic [...] Read more.

Asphalt binder plays an important role in the overall resistance of asphalt mixture to the moisture damage induced by a dynamic pore water pressure environment. This study evaluates the moisture sensitivity of asphalt binder from the perspective of rheological behaviors using the dynamic shear rheometer (DSR) and the bending beam rheometer (BBR) methods at high, medium, and low temperatures. The damage mechanism is further discussed quantitatively based on the Fourier transform infrared spectroscopy (FTIR) method. The results indicate that a longer conditioning duration is beneficial for asphalt binder to recover its adhesion at 60 °C in multiple stress creep recover (MSCR) tests, but the increasing pore water pressure magnitude of 60 psi held an opposite effect in this study. The asphalt binder’s fatigue life at 20 °C in linear amplitude sweep (LAS) tests decreased obviously with conditioning duration and environmental severity, but the reducing rate gradually slowed down, while the groups of 50 psi—4000 cycles and 60 psi—4000 cycles held a comparable erosion effect. Both the stiffness and relaxation moduli at −12 °C in the BBR tests exhibited an obvious decreasing trend with conditioning duration and environmental severity. The erosion effect on the asphalt binder was gradually enhanced, but it also exhibited a slightly more viscous performance. Water conditioning induced several obvious characteristic peaks in the FTIR absorbance spectra of the asphalt binder. The functional group indexes presented a trend of non-monotonic change with conditioning duration and environmental severity, which made the asphalt binder show complicated rheological behaviors, such as non-monotonic variations in performance and the abnormal improving effect induced by dynamic pore water pressure conditioning. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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14 pages, 1375 KiB

Open AccessArticle

Study on Low-Temperature and Fatigue Performance of High RAP Content Hot Recycled Asphalt Mixture Based on the Degree of Blending (DOB)

by Jianming Wu, Hao Sun, Lixia Wan, Jiangang Yang and Shuyi Wang

Polymers 2022, 14(21), 4520; https://doi.org/10.3390/polym14214520 - 25 Oct 2022

Cited by 7 | Viewed by 2023

Abstract

This paper selected three kinds of AC-20 hot-mix recycled asphalt mixtures with high RAP content (30%, 40%, and 50%). It obtains a mixture of different degrees of miscibility by changing RAP preheating temperatures and mixing temperatures. The calculation formula of the degree of [...] Read more.

This paper selected three kinds of AC-20 hot-mix recycled asphalt mixtures with high RAP content (30%, 40%, and 50%). It obtains a mixture of different degrees of miscibility by changing RAP preheating temperatures and mixing temperatures. The calculation formula of the degree of blending (DOB) of RAP asphalt interface recycling is proposed. The DSR test quantitatively characterized the DOB mixture’s low temperature, and fatigue properties were tested by beam bending test and four-point bending fatigue test. The prediction models of the recycled mixture’s low temperature and fatigue properties were proposed. The RAP preheating temperature is the most critical factor that dominates both transfers of RAP asphalt to the surface of new aggregate and the effective blending of old and new asphalt. DOB has a significant great influence on low-temperature performance and fatigue performance. The DOB of recycled asphalt can be improved by adjusting and optimizing the process parameters of plant hot recycled mixture to effectively improve the recycled mixture’s low-temperature crack resistance and fatigue lifetime. The optimal RAP dosage and mixing process of required performance can be obtained based on the prediction models to save experimental time and cost. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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18 pages, 7272 KiB

Open AccessArticle

Study on the Influence of Nano-OvPOSS on the Compatibility, Molecular Structure, and Properties of SBS Modified Asphalt by Molecular Dynamics Simulation

by Lei Feng, Peng Zhao, Tongdan Chen and Minghai Jing

Polymers 2022, 14(19), 4121; https://doi.org/10.3390/polym14194121 - 1 Oct 2022

Cited by 11 | Viewed by 2457

Abstract

The present research is carried out to inspect the influence of nano-OvPOSS (octavinyl oligomeric silsesquioxane) with different particle sizes on styrene-butadiene-styrene (SBS) modified asphalt through the method of molecular dynamics simulation. This nanomaterial is investigated for the first time to be used in [...] Read more.

The present research is carried out to inspect the influence of nano-OvPOSS (octavinyl oligomeric silsesquioxane) with different particle sizes on styrene-butadiene-styrene (SBS) modified asphalt through the method of molecular dynamics simulation. This nanomaterial is investigated for the first time to be used in asphalt modification. With the construction of modified asphalt simulation models and the analysis of their mixing energy, radius of gyration (R_g), radial distribution function (RDF), ratio of free volume (RFV), heat capacity, bulk modulus, and shear modulus, this study elucidates the influence of nano-OvPOSS on the compatibility between SBS and asphalt, on the structure of SBS as well as that of asphalt molecules and on the temperature stability and mechanical properties of SBS modified asphalt. The results show that nano-OvPOSS not only is compatible with SBS as well as with asphalt, but also is able to improve the compatibility between SBS and asphalt. Nano-OvPOSS is able to reinforce the tractility of branched chains of SBS and make SBS easier to wrap the surrounding asphalt molecules. The free movement space of molecules in the SBS modified asphalt system also shrinks. Moreover, the addition of nano-OvPOSS into SBS modified asphalt results in higher heat capacity, bulk modulus, and shear modulus of modified asphalt. All of these effects contribute to a more stable colloidal structure as well as more desirable temperature stability and deformation resistance of the modified asphalt system. The overall results of the study show that nano-OvPOSS can be used as a viable modifier to better the performance of conventional SBS modified asphalt. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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17 pages, 4969 KiB

Open AccessArticle

Study of the Microscopic Mechanism of Natural Rubber (Cis-1, 4-Polyisoprene, NR)/Polyethylene (PE) Modified Asphalt from the Perspective of Simulation

by Yujing Chen, Kui Hu, Caihua Yu, Dongdong Yuan and Xiaoyi Ban

Polymers 2022, 14(19), 4087; https://doi.org/10.3390/polym14194087 - 29 Sep 2022

Cited by 10 | Viewed by 2542

Abstract

This paper aims to study the interaction mechanism of waste tire/plastic modified asphalt from the microscopic perspective of molecules. Based on BIOVIA Materials Studio, a classic four-component asphalt model consisting of asphaltene (C₁₄₉H₁₇₇N₃O₂S₂), [...] Read more.

This paper aims to study the interaction mechanism of waste tire/plastic modified asphalt from the microscopic perspective of molecules. Based on BIOVIA Materials Studio, a classic four-component asphalt model consisting of asphaltene (C₁₄₉H₁₇₇N₃O₂S₂), resin (C₅₉H₈₅NOS), aromatic (C46H50S), and saturate (C₂₂H₄₆) was constructed. Waste tires are represented by natural rubber (NR), which uses cis-1, 4-polyisoprene as a repeating unit. In contrast, waste plastics are characterized by polyethylene (PE), whose optimum degree of polymerization is determined by the difference in solubility parameters. Then, the above molecular models are changed to a stable equilibrium state through the molecular dynamics process. Finally, the interaction process is analyzed and inferred using the indexes of radial distribution function, diffusion coefficient, and concentration distribution; further, the interaction mechanism is revealed. The results show that the optimal degree of polymerization of PE is 12, so the solubility parameter between PE and NR-modified asphalt is the lowest at 0.14 (J/cm³) ^1/2. These models are in agreement with the characteristics of amorphous materials with the structures ordered in the short-range and long-range disordered. For NR-modified asphalt, the saturate moves fastest, and its diffusion coefficient reaches 0.0201, followed by that of the aromatic (0.0039). However, the molecule of NR ranks the slowest in the NR-modified asphalt. After the addition of PE, the diffusion coefficient of resin increased most significantly from 0.0020 to 0.0127. NR, PE, and asphaltene have a particular attraction with the lightweight components, thus changing to a more stable spatial structure. Therefore, using NR and PE-modified asphalt can change the interaction between asphalt molecules to form a more stable system. This method not only reduces the large waste disposal task but also provides a reference for the application of polymer materials in modified asphalt. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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15 pages, 6344 KiB

Open AccessArticle

Comprehensive Study on the Performance of Waste HDPE and LDPE Modified Asphalt Binders for Construction of Asphalt Pavements Application

by Usman Ghani, Bakht Zamin, Muhammad Tariq Bashir, Mahmood Ahmad, Mohanad Muayad Sabri Sabri and Suraparb Keawsawasvong

Polymers 2022, 14(17), 3673; https://doi.org/10.3390/polym14173673 - 4 Sep 2022

Cited by 26 | Viewed by 5379

Abstract

This research is aimed at investigating the mechanical behavior of the bitumen by the addition of high-density polyethylene (HDPE) and low-density polyethylene (LDPE) obtained from waste plastic bottles and bags. Polymers (HDPE and LDPE) with percentages of 0%, 2%, 4%, and 6% in [...] Read more.

This research is aimed at investigating the mechanical behavior of the bitumen by the addition of high-density polyethylene (HDPE) and low-density polyethylene (LDPE) obtained from waste plastic bottles and bags. Polymers (HDPE and LDPE) with percentages of 0%, 2%, 4%, and 6% in shredded form by weight of bitumen were used to evaluate the spectroscopic, structural, morphological, and rheological properties of polymer-modified binders. The rheological properties for different factors; viscosity (ἠ) from Rotational Viscometer (RV), rutting factor G*/Sin (δ), fatigue characteristics G*. Sin (δ), for the modified binder from dynamic shear rheometer (DSR), Short and long-term aging from rolling thin film oven (RTFO), and pressure aging vessel (PAV) was determined. The thermal characteristics, grain size, and texture of polymers for both LDPE and HDPE were found using bending beam rheometer (BBR) and X-ray diffraction (XRD), respectively. Fourier transform infrared (FTIR) analysis revealed the presence of polymer contents in the modified binder. Scanning electron microscopy (SEM) images revealed the presence of HDPE and LDPE particles on the surface of the binder. Creep Rate (m) and Stiffness (S) analysis in relationship with temperature showed a deduction in stress rate relaxation. Results have revealed the best rutting resistance for 6% HDPE. It also showed an improvement of 95.27% in G*/Sin (δ) which increased the performance of the bituminous mix. Similarly, the addition of 4% LDPE resulted in maximum dynamic viscosity irrespective of the temperatures. Moreover, fatigue resistance has shown a significant change with the HDPE and LDPE. The festinating features of waste plastic modified binder make it important to be used in the new construction of roads to address the high viscosity and mixing problems produced by plastic waste and to improve the performance of flexible pavements all over the world. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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21 pages, 7428 KiB

Open AccessArticle

Rheological Properties of Styrene-Butadiene-Styrene Asphalt Mastic Containing High Elastic Polymer and Snow Melting Salt

by Yangsen Cao, Jiarong Li, Zhuangzhuang Liu, Xinzhou Li, Fan Zhang and Baozeng Shan

Polymers 2022, 14(17), 3651; https://doi.org/10.3390/polym14173651 - 2 Sep 2022

Cited by 11 | Viewed by 2103

Abstract

Sprinkled snow melting salt (SMS) exerts a snow melting effect and also has a negative impact on the asphalt pavement and the environment. Salt storage pavement technology can alleviate these two problems. However, non-alkaline SMSs may have the risk of affecting asphalt mastic [...] Read more.

Sprinkled snow melting salt (SMS) exerts a snow melting effect and also has a negative impact on the asphalt pavement and the environment. Salt storage pavement technology can alleviate these two problems. However, non-alkaline SMSs may have the risk of affecting asphalt mastic properties and further affecting the mechanical properties of asphalt pavements. Therefore, the general properties and rheological properties of two styrene-butadiene-styrene-modified asphalts with and without high elastic polymer were studied after adding SMS. The asphalt mastic without a high elastic agent is defined as the SBS group, and the other group is the HEA group. Our results show that the HEA group shows a lower penetration and a higher softening point, ductility, and viscosity than the SBS group. The more the SMS, the more the reduction effect of the general performance. The elastic recovery of asphalt mastic decreases with the content of SMS. SMS has no obvious effect on the ratio of the viscous and elastic composition of asphalt mastic. The creep of asphalt mastic increases with the content of SMS. The high elastic polymer can significantly reduce the creep, and even the strain of HEA100 is smaller than that of SBS00. SMS increases the creep stiffness and reduces the creep rate at low temperature. Although SMS increases the potential of asphalt pavement to melt ice and snow, it also reduces the high-temperature rutting resistance and low-temperature crack resistance of asphalt mastic. Salt storage pavement materials can be used in combination with high elastic polymers to reduce the negative effects brought by SMSs. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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11 pages, 4534 KiB

Open AccessArticle

Evaluation of the Rheological Properties of Virgin and Aged Asphalt Blends

by Tao Liu, Weidang Duan, Jialin Zhang, Qiuping Li, Jian Xu, Jie Wang, Yongchun Qin and Rong Chang

Polymers 2022, 14(17), 3623; https://doi.org/10.3390/polym14173623 - 1 Sep 2022

Cited by 3 | Viewed by 1528

Abstract

To evaluate the effects of the source and admixture of aged asphalt on the rheological properties of reclaimed asphalt binders, the relative viscosity (Δη), relative rutting factor (ΔG*/sinδ), and relative fatigue factor (ΔG*sinδ) were selected as evaluation indicators based on the [...] Read more.

To evaluate the effects of the source and admixture of aged asphalt on the rheological properties of reclaimed asphalt binders, the relative viscosity (Δη), relative rutting factor (ΔG*/sinδ), and relative fatigue factor (ΔG*sinδ) were selected as evaluation indicators based on the Strategic Highway Research Program (SHRP) tests to characterize the rheological properties of a reclaimed asphalt binder under medium- and high-temperature conditions. The results of the study showed that the viscosity, rutting factor, and fatigue factor of the reclaimed asphalt binder increased with the addition of aged asphalt; however, the effect of the source and admixture of aged asphalt could not be assessed. The relative viscosity, relative rutting factor, and relative fatigue factor are sensitive to the source, admixture, temperature, and aging conditions, which shows the superiority of these indicators. Moreover, the relative viscosity and relative rutting factor decreased linearly with increasing temperature under high-temperature conditions, while the relative fatigue factor increased linearly with increasing temperature under medium-temperature conditions. In addition, the linear trends of the three indicators were independent of the source and admixture of aged asphalt. These results indicate that the evaluation method used in this study can be used to assess the effects of virgin asphalt and aged asphalt on the rheological properties of reclaimed asphalt binders, and has the potential for application. The viscosity of recycled asphalt increases, and the rutting factor and fatigue factor both increase. The high-temperature stability of reclaimed asphalt is improved, and the fatigue crack resistance is weakened. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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17 pages, 4283 KiB

Open AccessArticle

Evaluating the Effect of Polymer Modification on the Low-Temperature Rheological Properties of Asphalt Binder

by Bagdat Teltayev, Erik Amirbayev and Boris Radovskiy

Polymers 2022, 14(13), 2548; https://doi.org/10.3390/polym14132548 - 22 Jun 2022

Cited by 6 | Viewed by 2282

Abstract

This paper investigates the viscoelastic properties of oxidized neat bitumen and three polymer-modified binders at low temperatures. The earlier proposed interrelated expressions for the relaxation modulus and for the creep compliance of bitumen binders are further developed. The results of creep testing of [...] Read more.

This paper investigates the viscoelastic properties of oxidized neat bitumen and three polymer-modified binders at low temperatures. The earlier proposed interrelated expressions for the relaxation modulus and for the creep compliance of bitumen binders are further developed. The results of creep testing of the binders on a bending beam rheometer at the six temperatures from −18 °C to −36 °C are presented. The results were analyzed using the equations developed for the relaxation modulus and the relaxation time spectrum. Viscosities at the low temperatures of tested binders were estimated. Approximate interrelations between the loss modulus and the relaxation spectrum were presented. The method for the determination of the glass transition temperature of a binder in terms of the relaxation time spectrum is proposed. The glass transition temperatures of tested binders were determined by the proposed method and compared with ones determined by the standard loss modulus-peak method. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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16 pages, 7372 KiB

Open AccessArticle

Viscoelastic Behavior and Phase Structure of High-Content SBS-Modified Asphalt

by Dongdong Yuan, Chengwei Xing, Wei Jiang, Jingjing Xiao, Wangjie Wu, Pengfei Li and Yupeng Li

Polymers 2022, 14(12), 2476; https://doi.org/10.3390/polym14122476 - 17 Jun 2022

Cited by 28 | Viewed by 2926

Abstract

To investigate the effect of styrene-butadiene-styrene (SBS) modifier content on the viscoelastic behavior of SBS-modified asphalt (SBSMA) at different temperatures and phase structures, the star SBS modifier was chosen to fabricate seven types of SBSMA with different contents. Multiple stress creep recovery (MSCR), [...] Read more.

To investigate the effect of styrene-butadiene-styrene (SBS) modifier content on the viscoelastic behavior of SBS-modified asphalt (SBSMA) at different temperatures and phase structures, the star SBS modifier was chosen to fabricate seven types of SBSMA with different contents. Multiple stress creep recovery (MSCR), linear amplitude sweep (LAS), and low-temperature frequency sweep tests were adopted to study the influence of SBS modifier content on the viscoelastic performance of SBSMA at high to low temperatures. The SBSMA’s microstructure with different contents was investigated using a fluorescence microscope. The results indicated that the change in non-recoverable creep compliance and creep recovery rate was bounded by 4.5% content at high temperatures, with an apparent turning point. The changing slope of content at less than 4.5% was much higher than that of the content greater than 4.5%. At medium temperatures, the fatigue life of SBSMA increased exponentially with the rising modifier content. The rate of increase in fatigue life was the largest as the content increased from 4.5% to 6.0%. At low temperatures, the low-temperature viscoelastic property index G (60 s) of SBSMA decreased logarithmically as the modifier content increased. In terms of the microscopic phase structure, the SBS modifier gradually changed from the dispersed to the continuous phase state with the increasing SBS modifier content. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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Review

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19 pages, 2855 KiB

Open AccessReview

Review of the Application of Microwave Heating Technology in Asphalt Pavement Self-Healing and De-icing

by Letao Zhang, Zihan Zhang, Weixiao Yu and Yinghao Miao

Polymers 2023, 15(7), 1696; https://doi.org/10.3390/polym15071696 - 29 Mar 2023

Cited by 18 | Viewed by 3258

Abstract

In the past decades, a large amount of research was conducted to investigate the application prospect of microwave heating technology in improving the efficiency of asphalt pavement self-healing and de-icing. This paper reviewed the achievements in this area. Firstly, the properties of asphalt [...] Read more.

In the past decades, a large amount of research was conducted to investigate the application prospect of microwave heating technology in improving the efficiency of asphalt pavement self-healing and de-icing. This paper reviewed the achievements in this area. Firstly, the properties of asphalt concrete after microwave heating were summarized, including microwave sensitivity and heating uniformity. Then, the evaluation indicators and influence factors of the self-healing properties of the asphalt mixtures heated by microwave were reviewed. Finally, the application of microwave heating in asphalt pavement de-icing was explored. In addition, asphalt pavement aging due to microwave heating was also reviewed. It was found that microwave heating technology has good prospects in promoting asphalt pavement self-healing and de-icing. There are also some problems that should be studied in depth, such as the cost-effectiveness of microwave-sensitive additives (MSAs), the performance of the pavement with MSAs, mechanism-based self-healing performance indicators, and the aging of asphalt pavements under cycling microwave heating. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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33 pages, 5619 KiB

Open AccessReview

Applications of Synthetic, Natural, and Waste Fibers in Asphalt Mixtures: A Citation-Based Review

by Adham Mohammed Alnadish, Narinderjit Singh Sawaran Singh and Aawag Mohsen Alawag

Polymers 2023, 15(4), 1004; https://doi.org/10.3390/polym15041004 - 17 Feb 2023

Cited by 22 | Viewed by 8581

Abstract

The utilization of synthetic, natural, and waste fibers in asphalt mixtures is constantly increasing due to the capability of fibers to improve the mechanical performance of asphalt mixes. The combination of fibers in asphalt mixes contributes to ecological sustainability and cost benefits. The [...] Read more.

The utilization of synthetic, natural, and waste fibers in asphalt mixtures is constantly increasing due to the capability of fibers to improve the mechanical performance of asphalt mixes. The combination of fibers in asphalt mixes contributes to ecological sustainability and cost benefits. The objective of this paper is to introduce a citation-based review on the incorporation of synthetic, natural, and waste fibers in bitumen, dense-graded asphalt mix, stone mastic asphalt, and porous asphalt mix. Additionally, this article aims to identify research gaps and provide recommendations for further work. The outputs of this article demonstrated that there has recently been a growing interest in the use of natural and waste fibers in asphalt mixtures. However, more future studies are needed to investigate the performance of fiber-modified stone mastic asphalt and porous asphalt mix in terms of resistance to aging and low-temperature cracking. Furthermore, the period of natural fibers’ biodegradability in asphalt mixtures should be investigated. Full article

(This article belongs to the Special Issue Application of Polymer Materials in Pavement Design)

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