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Recent Advances in Polymer Degradation and Recycling

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Circular and Green Sustainable Polymer Science".

Deadline for manuscript submissions: 31 July 2026 | Viewed by 1346

Special Issue Editor


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Guest Editor
Department of Chemical Engineering and Materials Science, Yuan Ze University, 135 Yuan-Tung Road, Chung-Li, Taoyuan 32003, Taiwan
Interests: catalytic reaction; polymer recycling; biochemical engineering; process design using ASPEN
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Special Issue Information

Dear Colleagues,

The accelerating transition toward a circular polymer economy has created an urgent need for advanced scientific and technological solutions that enable efficient, selective, and sustainable recycling of diverse plastic materials. Modern polymer waste streams, including engineered plastics, composite systems, elastomers, and bio-based polymers, pose challenges that extend beyond the capabilities of conventional mechanical recycling. This Special Issue, titled “Recent Advances in Polymer Degradation and Recycling,” aims to present cutting-edge research that deepens mechanistic understanding while advancing practical recycling strategies.

We invite contributions focused on thermal, catalytic, hydrolytic, enzymatic, oxidative, and photochemical degradation pathways, as well as innovative chemical recycling technologies such as depolymerization, solvent-assisted processes, and reactive extrusion. Research on catalyst development, reaction engineering, product selectivity, and monomer recovery efficiency is particularly welcome. Studies integrating computational tools such as machine learning, multiscale simulation, and kinetic modeling to accelerate process optimization and materials design are strongly encouraged.

By bringing together interdisciplinary work from polymer chemistry, materials science, reaction engineering, and environmental science, this Special Issue seeks to provide a comprehensive overview of state-of-the-art advances and future directions in polymer degradation and recycling. Advanced analytical and characterization techniques for upcycling polymers are preferred. Our goal is to promote fundamental insights and applied innovations that support scalable recycling solutions and sustainable polymer value chains.

This Special Issue welcomes manuscripts that address:

  • Fundamental mechanisms of polymer degradation (thermal, catalytic, hydrolytic, oxidative, enzymatic, photochemical).
  • Chemical recycling and depolymerization of polyesters, polyamides, polyurethanes, polyolefins, elastomers, and bio-based polymers.
  • Novel depolymerization technologies, including solvent-assisted recycling, microwave/plasma-assisted degradation, and reactive extrusion.
  • Catalyst development, reaction engineering, selective chain scission, and energy-efficient process design.
  • Kinetic modeling, multiscale simulation, machine-learning-assisted reaction prediction, and data-driven process optimization.
  • Advanced analytical and characterization techniques for degradation intermediates and products.
  • Upcycling pathways converting waste polymers into high-value chemicals, fuels, monomers, or functional materials.
  • Sustainability assessments, circular economy models, and industrial case studies for scalable polymer recycling.

Prof. Dr. Ho-Shing Wu
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 250 words) can be sent to the Editorial Office for assessment.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • polymer degradation
  • polymer recycling
  • chemical recycling
  • depolymerization
  • catalytic degradation
  • hydrolysis
  • glycolysis
  • enzymatic depolymerization
  • thermal degradation
  • photodegradation
  • reaction kinetics
  • mechanistic modeling
  • waste polymer valorization
  • upcycling
  • circular polymer economy
  • advanced characterization
  • bio-based polymers
  • mixed-plastic waste
  • process intensification
  • sustainable materials engineering

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Published Papers (1 paper)

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Review

29 pages, 1688 KB  
Review
Extracting Caprolactam from PA6 Waste: Progress in Chemical Recycling and Sustainable Practices
by Damayanti Damayanti, Mega Pristiani and Ho-Shing Wu
Polymers 2026, 18(8), 940; https://doi.org/10.3390/polym18080940 - 11 Apr 2026
Viewed by 1103
Abstract
This review critically evaluates current PA6 recycling technologies, with a specific focus on caprolactam-oriented chemical recycling pathways, including hydrolysis, pyrolysis, glycolysis, ammonolysis, hydrothermal treatment, ionic-liquid-assisted depolymerization, and microwave-assisted processes. Reported caprolactam yields vary significantly depending on reaction conditions and catalyst systems, ranging from [...] Read more.
This review critically evaluates current PA6 recycling technologies, with a specific focus on caprolactam-oriented chemical recycling pathways, including hydrolysis, pyrolysis, glycolysis, ammonolysis, hydrothermal treatment, ionic-liquid-assisted depolymerization, and microwave-assisted processes. Reported caprolactam yields vary significantly depending on reaction conditions and catalyst systems, ranging from below 60 wt% in conventional hydrolysis to above 90 wt% under optimized catalytic, hydrothermal, or microwave-assisted conditions. Among these approaches, microwave-assisted hydrolysis and catalytic depolymerization have emerged as particularly promising, offering substantially reduced reaction times (minutes rather than hours), improved energy efficiency, and high monomer selectivity at moderate temperatures (typically 200–350 °C). This review integrates kinetic modeling approaches, analytical methods for monitoring depolymerization, and downstream separation considerations that govern monomer purity and recyclability. Key challenges, including energy demand, feedstock contamination, scalability, and economic competitiveness, are critically discussed in relation to industrial implementation. Overall, hydrolysis-based and microwave-assisted chemical recycling routes are the most viable pathways for closed-loop recycling of PA6. Future progress will rely on integrated reaction–separation–repolymerization designs, catalyst optimization, and process intensification to enable sustainable and industrially relevant PA6 circularity. Full article
(This article belongs to the Special Issue Recent Advances in Polymer Degradation and Recycling)
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