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Valorization of Waste and Plant Biomasses for Functional Polymer-Based Material Development

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Polymer Applications".

Deadline for manuscript submissions: 31 October 2025 | Viewed by 667

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Special Issue Information

Dear Colleagues,

This Special Issue aims to highlight contributions exploring how waste and/or plant biomasses can be transformed into valuable resources for producing functional materials. The process of valorization refers to recovering valuable components with both functional and structural properties from organic wastes or byproducts, such as agricultural residues, wood wastes, or other plant materials, and converting them into useful products with high added value, like biofuels, biodegradable plastics, or advanced functional materials.

The valorization of waste and plant biomasses addresses both sustainability and waste management concerns by reducing environmental pollution and efficiently utilizing renewable resources. The development of functional materials from these biomasses can contribute to the creation of eco-friendly, cost-effective alternatives in various industries, including electronics, construction, biomedical, and packaging.

There are no restrictions on the processes employed for waste valorization, including extraction and thermochemical conversion. Similarly, all types of advanced materials, such as crystalline, amorphous, nanocomposites, composites, thermosets, and thermoplastics, as well as a broad range of polymers, can be considered. The scope of this Special Issue encompasses different applications ranging from energy storage and water purification to packaging and health-related products. Both original research articles and review papers are welcome.

Dr. Donatella Duraccio
Dr. Giovanna Gomez D’Ayala
Guest Editors

Manuscript Submission Information

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Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • plant biomass
  • waste valorization
  • advanced materials
  • sustainability
  • polymer characterization

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Published Papers (2 papers)

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Research

17 pages, 3721 KiB  
Article
Adsorption of Methylene Blue onto Environmentally Friendly Lignocellulosic Material Obtained from Mature Coltsfoot (Tussilago farfara) Leaves
by Giannin Mosoarca, Cosmin Vancea, Simona Popa, Maria Elena Radulescu-Grad, Mircea Dan, Cristian Tanasie and Sorina Boran
Polymers 2025, 17(11), 1549; https://doi.org/10.3390/polym17111549 - 2 Jun 2025
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Abstract
The present study investigates the potential of a new lignocellulosic adsorbent material obtained from mature coltsfoot (Tussilago farfara) leaves for the removal of methylene blue from aqueous solutions. The material was obtained after minimal processing of the leaves, without chemical or [...] Read more.
The present study investigates the potential of a new lignocellulosic adsorbent material obtained from mature coltsfoot (Tussilago farfara) leaves for the removal of methylene blue from aqueous solutions. The material was obtained after minimal processing of the leaves, without chemical or thermal treatment. The material was first characterized using several specific techniques (FTIR, color analysis). Then, the mechanism of the adsorption process was investigated through studies related to adsorption equilibrium, kinetics, and thermodynamics. The adsorption process is described by the Sips isotherm and the general kinetic model, while the thermodynamic parameters suggest that physical adsorption is the primary mechanism responsible for dye retention. The Taguchi method was used to optimize the adsorption conditions and to identify the most influential controllable factor. ANOVA was used to calculate the percentage contribution of each controllable factor to the dye removal efficiency. pH had the greatest influence on the process (87.78%), while temperature had the least effect (0.16%). The maximum adsorption capacity determined was 278.1 mg/g, being higher than other similar adsorbents. All the results show that coltsfoot (Tussilago farfara) leaves are a very cheap, environmentally friendly, and effective adsorbent for the removal of methylene blue dye from aqueous solutions. Full article
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17 pages, 1971 KiB  
Article
Sustainable Microwave-Assisted Extraction of Hemp Seed Oil as Functional Additive into Polybutylene Succinate (PBS) Films for Food Packaging
by Giovanni Dal Poggetto, Mattia Di Maro, Luca Gargiulo, Donatella Duraccio, Gabriella Santagata and Giovanna Gomez d’Ayala
Polymers 2025, 17(10), 1376; https://doi.org/10.3390/polym17101376 - 16 May 2025
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Abstract
In this study, microwave-assisted extraction (MAE) was performed to recover antioxidant hemp seed oil (HSO) with the purpose of developing polybutylene succinate (PBS)/HSO-based films for active packaging to improve food shelf-life. It was found that MAE achieved comparable yields, structural characteristics, and antioxidant [...] Read more.
In this study, microwave-assisted extraction (MAE) was performed to recover antioxidant hemp seed oil (HSO) with the purpose of developing polybutylene succinate (PBS)/HSO-based films for active packaging to improve food shelf-life. It was found that MAE achieved comparable yields, structural characteristics, and antioxidant activity to Soxhlet extraction, but in significantly less time (2.5 min vs. 6 h). PBS-based films with 0.5 and 1 wt% HSO were prepared by compression molding. Morphological investigation of the PBS-HSO films highlighted uniform oil droplet dispersion and good compatibility. HSO reduced PBS crystallinity but did not affect the α-form of PBS. Thermal analysis showed reductions in Tm and Tc, whereas Tg remained unchanged at −17 °C. PBS containing 1 wt% HSO exhibited a 42% decrease in Young’s modulus, 47% reduction in elongation at break, and 47% decrease in tensile strength due to the plasticizing effect of the oil and, which reduced the intermolecular forces and facilitated polymer chain disentanglement, in agreement with the FTIR analysis, which showed a distinct broadening of the carbonyl stretching region associated with the amorphous phase (1720–1730 cm−1) in the PBS-HSO films compared to neat PBS. Migration tests showed that the films are unsuitable for fatty foods but safe for aqueous, acidic, and alcoholic foods. Full article
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