polymers-logo

Journal Browser

Journal Browser

Advances in 4D Printing: From Smart Materials to Functional Systems

A special issue of Polymers (ISSN 2073-4360). This special issue belongs to the section "Smart and Functional Polymers".

Deadline for manuscript submissions: closed (20 July 2026) | Viewed by 1130

Editors


E-Mail Website
Guest Editor
School of Astronautics, Harbin Institute of Technology, Harbin 150001, China
Interests: smart materials; 4D printing; biological devices
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

This Special Issue focuses on recent advances in 4D printing that bridge the gap between smart material innovation and the realization of functional, system-level applications. Unlike conventional additive manufacturing, 4D printing enables printed structures to actively respond, adapt, and evolve over time when exposed to external stimuli, offering transformative possibilities for intelligent engineering systems.

The scope of this Special Issue encompasses the development and characterization of smart and stimuli-responsive materials, including polymers, composites, hydrogels, and multi-material systems, as well as their integration with structural and mechanical design strategies. Contributions addressing printing processes, toolpath planning, process–structure–property relationships, and multi-scale modeling and simulation are particularly encouraged. In addition, the Issue aims to highlight advances in functional systems enabled by 4D printing, such as soft robotics, biomedical devices, aerospace and mechanical components, energy harvesting systems, and adaptive or reconfigurable structures.

This Special Issue welcomes original research articles, comprehensive review papers, and short communications presenting theoretical, numerical, and experimental studies. Submissions that demonstrate system-level functionality, reliability, and practical performance, or that provide critical perspectives on current challenges and future directions of 4D printing, are especially encouraged.

Dr. Chengjun Zeng
Dr. Xiaozhou Xin
Dr. Wei Zhao
Dr. Cheng Lin
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 250 words) can be sent to the Editorial Office for assessment.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-anonymized peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Polymers is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • 4D printing
  • additive manufacturing
  • smart materials
  • stimuli-responsive materials
  • hydrogels
  • multi-material systems
  • soft robotics
  • biomedical devices
  • aerospace and mechanical components
  • energy harvesting

Benefits of Publishing in a Special Issue

  • Ease of navigation: Grouping papers by topic helps scholars navigate broad scope journals more efficiently.
  • Greater discoverability: Special Issues support the reach and impact of scientific research. Articles in Special Issues are more discoverable and cited more frequently.
  • Expansion of research network: Special Issues facilitate connections among authors, fostering scientific collaborations.
  • External promotion: Articles in Special Issues are often promoted through the journal's social media, increasing their visibility.
  • Reprint: MDPI Books provides the opportunity to republish successful Special Issues in book format, both online and in print.

Further information on MDPI's Special Issue policies can be found here.

Published Papers (1 paper)

Order results
Result details
Select all
Export citation of selected articles as:

Research

27 pages, 13531 KB  
Article
Research on Shape Memory Properties of PETG Based on 4D-Printed Negative Poisson’s Ratio Structures
by Zepeng Liu, Shaogang Liu and Bai Chen
Polymers 2026, 18(9), 1039; https://doi.org/10.3390/polym18091039 - 24 Apr 2026
Viewed by 807
Abstract
This research systematically investigates the shape memory properties of re-entrant hexagonal negative Poisson’s ratio (NPR) honeycomb structures fabricated via 4D printing, using polyethylene terephthalate glycol (PETG) and polylactic acid (PLA) as comparative materials. Periodic honeycomb models with varied wall thicknesses and structural unit [...] Read more.
This research systematically investigates the shape memory properties of re-entrant hexagonal negative Poisson’s ratio (NPR) honeycomb structures fabricated via 4D printing, using polyethylene terephthalate glycol (PETG) and polylactic acid (PLA) as comparative materials. Periodic honeycomb models with varied wall thicknesses and structural unit angles were designed, and their effects on shape recovery time and recovery rate were examined. Response surface methodology (RSM) based on a Box–Behnken design was employed to optimize key process parameters, including the wall thickness, structural unit angle, and mold pressing angle. The results demonstrate that PETG exhibits significantly superior shape memory performance compared to PLA, characterized by a shorter recovery time and higher recovery rate under thermal stimulation. Through RSM optimization, the optimal parameter combination was identified as a wall thickness of 0.5 mm, a structural unit angle of 65°, and a mold pressing angle of 135°, which was subsequently validated experimentally, demonstrating a high degree of consistency between predicted and actual outcomes. This study not only clarifies the influence of the structural parameters on the shape memory behavior of NPR honeycomb systems but also provides parameter guidance and a practical experimental basis for the application of PETG in 4D-printed intelligent structures, with potential implications for soft robotics, aerospace, and biomedical devices. Full article
(This article belongs to the Special Issue Advances in 4D Printing: From Smart Materials to Functional Systems)
Show Figures

Figure 1

Back to TopTop