molecules-logo

Journal Browser

Journal Browser

Advances in Electrochemical Energy Storage Devices 2.0

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Electrochemistry".

Deadline for manuscript submissions: closed (30 September 2022) | Viewed by 12635

Special Issue Editor


E-Mail Website1 Website2
Guest Editor
Faculty of Science and Technology, Bournemouth University, Talbot Campus, Fern Barrow, Poole BH12 5BB, UK
Interests: synthesis and applications of nanomaterials; electrochemical energy storage devices; polymer nanocomposites
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

We are pleased to inform you that Molecules has launched the second edition of the Special Issue “Advances in Electrochemical Energy Storage Devices”.

There is a growing interest in electrochemical energy storage devices to empower portable electronics, electric vehicles and to fulfil the need for the large-scale storage of stationary applications. Despite the significant research efforts of recent years, there remain key challenges to be overcome in the near future. These include improvements to storage energy density and power density, conversion efficiency, cost, cycle life, battery weight and volume, and battery safety.

Chemical and conceptual developments are progressing, with electrolytes, packaging materials, and electrode materials and structures also advancing. There has been a simultaneous focus on the development of flexible energy storage devices, motivated by the rise of wearable electronics. Furthermore, theoretical and experimental studies are seeking to understand the fundamentals of physicochemical processes, including electronic and ionic transport in electrodes, electrolyte phases and stability, electrochemical reactions, material phase changes, and mechanical and thermal stresses.

This Special Issue focuses on recent advancements in electrochemical energy storage technology, encompassing supercapacitors, primary batteries and rechargeable batteries. Contributions of both original articles and comprehensive reviews will cover the latest developments in device architecture, electrode design and materials, thermal and mechanical stress management, large-scale devices, and energy device manufacturing processes.

Prof. Dr. Amor M. Abdelkader
Guest Editor

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Molecules is an international peer-reviewed open access semimonthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2700 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • primary batteries
  • rechargeable batteries
  • supercapacitors
  • hybrid electrochemical energy storage

Benefits of Publishing in a Special Issue

  • Ease of navigation: Grouping papers by topic helps scholars navigate broad scope journals more efficiently.
  • Greater discoverability: Special Issues support the reach and impact of scientific research. Articles in Special Issues are more discoverable and cited more frequently.
  • Expansion of research network: Special Issues facilitate connections among authors, fostering scientific collaborations.
  • External promotion: Articles in Special Issues are often promoted through the journal's social media, increasing their visibility.
  • e-Book format: Special Issues with more than 10 articles can be published as dedicated e-books, ensuring wide and rapid dissemination.

Further information on MDPI's Special Issue polices can be found here.

Published Papers (4 papers)

Order results
Result details
Select all
Export citation of selected articles as:

Research

Jump to: Review

24 pages, 14144 KiB  
Article
Zinc Electrode Cycling in Deep Eutectic Solvent Electrolytes: An Electrochemical Study
by Elisa Emanuele, Andrea Li Bassi, Andrea Macrelli, Claudio Mele, Jacopo Strada and Benedetto Bozzini
Molecules 2023, 28(3), 957; https://doi.org/10.3390/molecules28030957 - 18 Jan 2023
Cited by 10 | Viewed by 2651
Abstract
Among post-lithium ion battery technologies, rechargeable chemistries with Zn anodes bear notable technological promise owing to their high theoretical energy density, lower manufacturing cost, availability of raw materials and inherent safety. However, Zn anodes, when employed in aqueous electrolytes, suffer from hydrogen evolution, [...] Read more.
Among post-lithium ion battery technologies, rechargeable chemistries with Zn anodes bear notable technological promise owing to their high theoretical energy density, lower manufacturing cost, availability of raw materials and inherent safety. However, Zn anodes, when employed in aqueous electrolytes, suffer from hydrogen evolution, passivation, and shape changes. Alternative electrolytes can help tackle these issues, preserving the green and safe characteristics of aqueous-based ones. Deep eutectic solvents (DESs) are promising green and low-cost non-aqueous solvents for battery electrolytes. Specifically, the cycling of Zn anodes in DESs is expected to be reversible, chiefly owing to their dendrite-suppression capability. Nevertheless, apart from a few studies on Zn plating, insight into the cathodic–anodic electrochemistry of Zn in DESs is still very limited. In view of developing DES-based battery electrolytes, it is crucial to consider that a potential drawback might be their low ionic conductivity. Water molecules can be added to the eutectic mixtures by up to 40% to increase the diffusion coefficient of the electroactive species and lower the electrolyte viscosity without destroying the eutectic nature. In this study, we address the electrochemistry of Zn in two different hydrated DESs (ChU and ChEG with ~30% H2O). Fundamental electrokinetic and electrocrystallization studies based on cyclic voltammetry and chronoamperometry at different cathodic substrates are completed with a galvanostatic cycling test of Zn|Zn symmetric CR2032 coin cells, SEM imaging of electrodes and in situ SERS spectroscopy. This investigation concludes with the proposal of a specific DES/H2O/ZnSO4-based electrolyte that exhibits optimal functional performance, rationalized on the basis of fundamental electrochemical data, morphology evaluation and modeling of the cycling response. Full article
(This article belongs to the Special Issue Advances in Electrochemical Energy Storage Devices 2.0)
Show Figures

Figure 1

12 pages, 5160 KiB  
Article
Novel Supercapacitor Electrode Derived from One Dimensional Cerium Hydrogen Phosphate (1D-Ce(HPO4)2.xH2O)
by Jong Hee Yoon, Bak Jinsoo, Inho Cho, Rajangam Vinodh, Bruno G. Pollet, Rajendran Suresh Babu, Hee-Je Kim and Sungshin Kim
Molecules 2022, 27(22), 7691; https://doi.org/10.3390/molecules27227691 - 9 Nov 2022
Cited by 11 | Viewed by 2028
Abstract
In this manuscript, we are reporting for the first time one dimensional (1D) cerium hydrogen phosphate (Ce(HPO4)2.xH2O) electrode material for supercapacitor application. In short, a simple hydrothermal technique was employed to prepare Ce(HPO4)2.xH [...] Read more.
In this manuscript, we are reporting for the first time one dimensional (1D) cerium hydrogen phosphate (Ce(HPO4)2.xH2O) electrode material for supercapacitor application. In short, a simple hydrothermal technique was employed to prepare Ce(HPO4)2.xH2O. The maximum surface area of 82 m2 g−1 was obtained from nitrogen sorption isotherm. SEM images revealed Ce(HPO4)2.xH2O exhibited a nanorod-like structure along with particles and clusters. The maximum specific capacitance of 114 F g−1 was achieved at 0.2 A g−1 current density for Ce(HPO4)/NF electrode material in a three-electrode configuration. Furthermore, the fabricated symmetric supercapacitor (SSC) based on Ce(HPO4)2.xH2O//Ce(HPO4)2.xH2O demonstrates reasonable specific energy (2.08 Wh kg−1), moderate specific power (499.88 W kg−1), and outstanding cyclic durability (retains 92.7% of its initial specific capacitance after 5000 GCD cycles). Full article
(This article belongs to the Special Issue Advances in Electrochemical Energy Storage Devices 2.0)
Show Figures

Figure 1

11 pages, 8482 KiB  
Article
Sulfur Nanoparticle-Decorated Nickel Cobalt Sulfide Hetero-Nanostructures with Enhanced Energy Storage for High-Performance Supercapacitors
by Yedluri Anil Kumar, Anuja A. Yadav, Bandar Ali Al-Asbahi, Seok-Won Kang and Md Moniruzzaman
Molecules 2022, 27(21), 7458; https://doi.org/10.3390/molecules27217458 - 2 Nov 2022
Cited by 15 | Viewed by 2274
Abstract
Transition-metal sulfides exaggerate higher theoretical capacities and were considered a type of prospective nanomaterials for energy storage; their inherent weaker conductivities and lower electrochemical active sites limited the commercial applications of the electrodes. The sheet-like nickel cobalt sulfide nanoparticles with richer sulfur vacancies [...] Read more.
Transition-metal sulfides exaggerate higher theoretical capacities and were considered a type of prospective nanomaterials for energy storage; their inherent weaker conductivities and lower electrochemical active sites limited the commercial applications of the electrodes. The sheet-like nickel cobalt sulfide nanoparticles with richer sulfur vacancies were fabricated by a two-step hydrothermal technique. The sheet-like nanoparticles self-combination by ultrathin nanoparticles brought active electrodes entirely contacted with the electrolytes, benefiting ion diffusion and charges/discharges. Nevertheless, defect engineers of sulfur vacancy at the atomic level raise the intrinsic conductivities and improve the active sites for energy storage functions. As a result, the gained sulfur-deficient NiCo2S4 nanosheets consist of good specific capacitances of 971 F g−1 at 2 A g−1 and an excellent cycle span, retaining 88.7% of the initial capacitance over 3500 cyclings. Moreover, the values of capacitance results exhibited that the fulfilling characteristic of the sample was a combination of the hydrothermal procedure and the surface capacitances behavior. This novel investigation proposes a new perspective to importantly improve the electrochemical performances of the electrode by the absolute engineering of defects and morphologies in the supercapacitor field. Full article
(This article belongs to the Special Issue Advances in Electrochemical Energy Storage Devices 2.0)
Show Figures

Graphical abstract

Review

Jump to: Research

17 pages, 4102 KiB  
Review
Recent Configurational Advances for Solid-State Lithium Batteries Featuring Conversion-Type Cathodes
by Kuan-Cheng Chiu, Jeng-Kuei Chang and Yu-Sheng Su
Molecules 2023, 28(12), 4579; https://doi.org/10.3390/molecules28124579 - 6 Jun 2023
Cited by 6 | Viewed by 4391
Abstract
Solid-state lithium metal batteries offer superior energy density, longer lifespan, and enhanced safety compared to traditional liquid-electrolyte batteries. Their development has the potential to revolutionize battery technology, including the creation of electric vehicles with extended ranges and smaller more efficient portable devices. The [...] Read more.
Solid-state lithium metal batteries offer superior energy density, longer lifespan, and enhanced safety compared to traditional liquid-electrolyte batteries. Their development has the potential to revolutionize battery technology, including the creation of electric vehicles with extended ranges and smaller more efficient portable devices. The employment of metallic lithium as the negative electrode allows the use of Li-free positive electrode materials, expanding the range of cathode choices and increasing the diversity of solid-state battery design options. In this review, we present recent developments in the configuration of solid-state lithium batteries with conversion-type cathodes, which cannot be paired with conventional graphite or advanced silicon anodes due to the lack of active lithium. Recent advancements in electrode and cell configuration have resulted in significant improvements in solid-state batteries with chalcogen, chalcogenide, and halide cathodes, including improved energy density, better rate capability, longer cycle life, and other notable benefits. To fully leverage the benefits of lithium metal anodes in solid-state batteries, high-capacity conversion-type cathodes are necessary. While challenges remain in optimizing the interface between solid-state electrolytes and conversion-type cathodes, this area of research presents significant opportunities for the development of improved battery systems and will require continued efforts to overcome these challenges. Full article
(This article belongs to the Special Issue Advances in Electrochemical Energy Storage Devices 2.0)
Show Figures

Figure 1

Back to TopTop