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Photocatalysis for Organic Pollutants Degradation

A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Photochemistry".

Deadline for manuscript submissions: 31 March 2026 | Viewed by 726

Special Issue Editors


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Guest Editor
Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100084, China
Interests: photodegradation; photocatalysis; selective oxidation
Special Issues, Collections and Topics in MDPI journals

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Guest Editor Assistant
College of Resources and Environmental Science, South-Central Minzu University, Wuhan, China
Interests: photocatalysis; environmental photochemistry; wastewater treatment

Special Issue Information

Dear Colleagues,

Degradation and control of persistent, highly toxic organic pollutants, especially those accumulated in different waters, are pivotal to global ecological security. Advanced oxidation technologies (AOTs) are playing a more and more important role in both source treatment (high concentration) and extensive watershed treatment (low concentration) of these organic pollutants because they are aimed at converting organic pollutants into CO2, H2O, and mineralized inorganic ions. However, for many years, AOTs have remained difficult to apply on a large scale; the main obstacles are high energy consumption and cost. As a result, photocatalytic degradation and photooxidative degradation by utilizing solar energy are the only feasible ways to thoroughly solve the bottleneck of AOT. To this end, researchers focus on designing more efficient photocatalysts through varying composition, structure, morphology, etc. In addition, there are many chemical reactions of environmental pollutants in the natural world, including soil, water, atmosphere, and even plant media forced by solar irradiation.

The photochemical application for eliminating organic pollutants in water mainly includes the following aspects: (1) the processes of organic pollutant molecules being oxidized, reduced, hydrolyzed, and finally broken into CO2, H2O, and inorganic ion X-; (2) photo-induced catalyst (or sensitizer) activates molecular oxygen O2, O3, H2O2, S2O82-, Cl2, ClO2, etc. and the influence factors of the solution; (3) generation pathway and characterization of various species of reactive oxygen species and photo-generated holes/electron pairs in homogeneous or heterogeneous systems; (4) analysis and characterization of intermediate products in degradation of organic pollutants. Therefore, this Special Issue only encompasses the aforementioned four aspects and mainly focuses on the studies of homogeneous and heterogeneous photodegradation degradation of environmental organic pollutants.

Prof. Dr. Wanhong Ma
Guest Editor

Dr. Zhen Wan
Guest Editor Assistant

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Keywords

  • photocatalytic degradation of organic pollutants in waters
  • design and preparation of photocatalyst
  • homo- and heterogeneous photo-catalyzed process
  • intermediate fragments and intermediate organic pollutants
  • reactive oxygen species (ROS)

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Published Papers (1 paper)

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Research

15 pages, 5406 KB  
Article
Synthesis of Straw-Based Hydrothermal Carbonation Carbon and Its Photocatalytic Removal of Cr(VI) and Microcystin-LR
by Yu Luo, Xunxian Chen, Zhen Wan and Yingming Chen
Molecules 2025, 30(22), 4399; https://doi.org/10.3390/molecules30224399 - 14 Nov 2025
Viewed by 392
Abstract
As a cost-effective and environmentally benign photocatalyst, hydrothermal carbonation carbon (HTCC) has been extensively studied in the fields of resource utilization and environmental remediation. In this study, HTCC photocatalysts with efficient photocatalytic performances were prepared from straw using acid modification under hydrothermal conditions. [...] Read more.
As a cost-effective and environmentally benign photocatalyst, hydrothermal carbonation carbon (HTCC) has been extensively studied in the fields of resource utilization and environmental remediation. In this study, HTCC photocatalysts with efficient photocatalytic performances were prepared from straw using acid modification under hydrothermal conditions. The as-prepared HTCC photocatalysts were applied to the degradation of microcystin-LR and the reduction of aqueous Cr(VI). The critical role of acid modification in the photocatalytic performances of the HTCC photocatalysts was systematically investigated. The results demonstrated that acid-modified photocatalysts exhibited a significantly enhanced removal efficiency for Cr(VI) and microcystin-LR under visible light irradiation. A series of characterization techniques, including Raman spectroscopy and N2 adsorption–desorption analysis, revealed that the superior photocatalytic activities of acid-modified HTCC could be attributed to its higher aromatization level, enhanced light-harvesting ability, and increased concentration of active sites compared with pristine HTCC. Furthermore, electron spin resonance (ESR) and trapping experiments indicated that hydrogen radicals (·H) served as the primary active species in the photocatalytic Cr(VI) reduction of straw-based HTCC. This work provides both practical and theoretical insights into the resource utilization of agricultural waste and the remediation of environmental pollution. Full article
(This article belongs to the Special Issue Photocatalysis for Organic Pollutants Degradation)
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